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RESEARCH PAPER · Inorganic Chemistry · 2021

Cs2ZnSn3S8: A Sulfide Compound Realizes a Large Birefringence by Modulating the Dimensional Structure

Tian Tian, Zefen Li, Naizheng Wang, Sangen Zhao, Jiayue Xu, Zheshuai Lin, Dajiang Mei

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Cs2ZnSn3S8: A Sulfide Compound Realizes a Large Birefringence by Modulating the Dimensional StructureOriginalCsCu 3 SbS 4 : rational design of a two-dimensional layered material with giant birefringence derived from Cu 3 SbS 442Ba 6 In 2 Ge 2 Te 15 : a THz birefringent material with an intriguing quasi-[Te 5 ] 4− chain possessing large optical anisotropy and an ultrawide transmission range7SrZnSnSe4: A quaternary selenide with large second harmonic generation and birefringence40NaBaBS3: A Promising Infrared Functional Material with Large Birefringence Induced by π-Conjugated [BS3] Units32Rb2FeGe3S8 and Cs2FeGe3S8: New layered chalcogenides in A2MIIMIV3Q8 family with antiferromagnetic property6Hg2P2S6: A layered mercury hexathiodiphosphate (IV) with large birefringence11Sharp Enhancement of Birefringence in Antimony Oxalates Achieved by the Cation–Anion Synergetic Interaction Strategy38Tailored Ordered Structures with Functional Units of Distorted [NbO6] and Antiparallel [GeO4] for Enhanced Birefringence in Germanate Crystal15Ba4cd2ge2te9: A Promising Infrared Functional Crystal with Large Birefringent And Photoluminescent Properties0Stereochemically active lone-pair-driven giant enhancement of birefringence from three-dimensional CsZn 4 Ga 5 Se 12 to two-dimensional CsZnAsSe 319Tunable Salt-Inclusion Chalcogenides for Ion Exchange, Photoluminescence, and Scintillation12Partial substitution induced structural transformation and enhanced nonlinear optical properties of Na2GaxIn6-xSe10 (x = 3, 3.76)23Chain‐like [S x ] ( x =2–6) Units Realizing Giant Birefringence with Transparency in the Near‐Infrared for Optoelectronic Materials53Chain‐like [S x ] ( x =2–6) Units Realizing Giant Birefringence with Transparency in the Near‐Infrared for Optoelectronic Materials5Theoretical Prediction‐Assisted Synthesis and Characterization of Infrared Nonlinear Optical Material NaSrBS324Gradual Increase in Birefringence of Antimony Oxalates through Precise Tuning of the Sb3+/[C2O4]2– Ratio7Effects of different groups on phase-matching and SHG in “3+4” Pn materials0From [Ba3S][GeS4] to [Ba3CO3][MS4] (M = Ge, Sn): Enhancing optical anisotropy in IR birefringent crystals via functional group implantation11BaSbBS 4 : a record-high-performance birefringent crystal identified by a target-driven closed-loop strategy28Cationic substitution engineering induces a new quaternary chalcogenide in the A–M IIIA –M IVA –Q system for optical crystal applications1Research progress and future prospect of chalcogenides with large optical anisotropy46Layered Ternary Indium Chalcogenides Ba5In2S8 and β-BaIn2Se4: Structural Diversity and Large Birefringence in β-BaIn2Se42SrZnSiS4: Shattering the 4.0 eV Threshold toward Dual-Optimized Bandgap and Second-Harmonic Generation7Achieving High‐Birefringence Thiophosphates From Low Polarizability Anisotropy Units by an Axial Linear Matching Strategy1A Composition-Matched Intermediate Reveals Site-Specific Symmetry Evolution with Retained Second-Harmonic Generation in Supertetrahedral Sulfides0

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  1. CsCu 3 SbS 4 : rational design of a two-dimensional layered material with giant birefringence derived from Cu 3 SbS 4

    Inorganic Chemistry Frontiers · 2021-12-01

    Chang Liu, Shenghua Zhou, Chao Zhang, Yaying Shen, Xiaoyan Liu, Hua Lin, Yi Liu

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  2. Ba 6 In 2 Ge 2 Te 15 : a THz birefringent material with an intriguing quasi-[Te 5 ] 4− chain possessing large optical anisotropy and an ultrawide transmission range

    Inorganic Chemistry Frontiers · 2022-01-01

    Mengran Sun, Xingyu Zhang, Wenhao Xing, Ece Uykur, Wenlong Yin, Zheshuai Lin, Jiyong Yao

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  3. SrZnSnSe4: A quaternary selenide with large second harmonic generation and birefringence

    Journal of Alloys and Compounds · 2022-01-25

    Fengjuan Hou, Dajiang Mei, Yiling Zhang, Fei Liang, Jian Wang, Jie Lü, Zheshuai Lin, Yuandong Wu

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  4. NaBaBS3: A Promising Infrared Functional Material with Large Birefringence Induced by π-Conjugated [BS3] Units

    Chemistry of Materials · 2022-05-25

    Yihan Yun, Wenlong Xie, Yi Huang, Zhihua Yang, Kui Wu, Guangmao Li, Shilie Pan

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  5. Rb2FeGe3S8 and Cs2FeGe3S8: New layered chalcogenides in A2MIIMIV3Q8 family with antiferromagnetic property

    Journal of Solid State Chemistry · 2022-06-02

    Weikang Wang, Wangzhu Cao, Ling‐Yun Zhang, Guobao Li, Yuandong Wu, Shaoguo Wen, Dajiang Mei

    Read original paper ↗ ·

  6. Hg2P2S6: A layered mercury hexathiodiphosphate (IV) with large birefringence

    Journal of Solid State Chemistry · 2022-07-18

    Li-Jia Yao, Chun‐Li Hu, Zhi Gang Fang, Jiang‐Gao Mao

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  7. Sharp Enhancement of Birefringence in Antimony Oxalates Achieved by the Cation–Anion Synergetic Interaction Strategy

    Inorganic Chemistry · 2022-07-27

    Die Zhang, Qiang Wang, Liying Ren, Liling Cao, Ling Huang, Daojiang Gao, Jian Bi, Guohong Zou

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  8. Tailored Ordered Structures with Functional Units of Distorted [NbO6] and Antiparallel [GeO4] for Enhanced Birefringence in Germanate Crystal

    Advanced Optical Materials · 2022-09-01

    Wenli Zhao, Jinmiao Jiao, Yuheng She, Fei Liang, Ning Ye, Zhanggui Hu, Yicheng Wu, Conggang Li

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  9. Ba4cd2ge2te9: A Promising Infrared Functional Crystal with Large Birefringent And Photoluminescent Properties

    SSRN Electronic Journal · 2023-01-01

    Mengran Sun, Haojian Su, Wenhao Liu, Jiyong Yao

    Read original paper ↗ ·

  10. Stereochemically active lone-pair-driven giant enhancement of birefringence from three-dimensional CsZn 4 Ga 5 Se 12 to two-dimensional CsZnAsSe 3

    Inorganic Chemistry Frontiers · 2023-01-01

    Chao Zhang, Mao‐Yin Ran, Xin Chen, Shenghua Zhou, Hua Lin, Yi Liu

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  11. Tunable Salt-Inclusion Chalcogenides for Ion Exchange, Photoluminescence, and Scintillation

    Chemistry of Materials · 2023-01-23

    Anna A. Berseneva, Lakshani W. Masachchi, Luiz Gustavo Jacobsohn, Hans‐Conrad zur Loye

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  12. Partial substitution induced structural transformation and enhanced nonlinear optical properties of Na2GaxIn6-xSe10 (x = 3, 3.76)

    Materials Today Physics · 2023-02-13

    Jun Li, Wen‐Dong Yao, Jia-Nuo Li, Xiaohui Li, Wenlong Liu, Sheng‐Ping Guo

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  13. Chain‐like [S x ] ( x =2–6) Units Realizing Giant Birefringence with Transparency in the Near‐Infrared for Optoelectronic Materials

    Angewandte Chemie International Edition · 2023-03-29

    Guangmao Li, Zhihua Yang, Xueling Hou, Shilie Pan

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  14. Chain‐like [S x ] ( x =2–6) Units Realizing Giant Birefringence with Transparency in the Near‐Infrared for Optoelectronic Materials

    Angewandte Chemie · 2023-03-29

    Guangmao Li, Zhihua Yang, Xueling Hou, Shilie Pan

    Read original paper ↗ ·

  15. Theoretical Prediction‐Assisted Synthesis and Characterization of Infrared Nonlinear Optical Material NaSrBS3

    Advanced Optical Materials · 2023-05-05

    Yihan Yun, Mengfan Wu, Congwei Xie, Zhihua Yang, Guangmao Li, Shilie Pan

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  16. Gradual Increase in Birefringence of Antimony Oxalates through Precise Tuning of the Sb3+/[C2O4]2– Ratio

    Inorganic Chemistry · 2024-07-11

    Dan Wang, Han Luo, Tingyu Wang, Xuehua Dong, Liling Cao, Ling Huang, Guohong Zou

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  17. Effects of different groups on phase-matching and SHG in “3+4” Pn materials

    Physica B Condensed Matter · 2024-07-15

    Chaoyi Zhu, Guojie Jin

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  18. From [Ba3S][GeS4] to [Ba3CO3][MS4] (M = Ge, Sn): Enhancing optical anisotropy in IR birefringent crystals via functional group implantation

    Chinese Journal of Structural Chemistry · 2024-10-24

    Yong‐Fang Shi, Shenghua Zhou, Zuju Ma, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  19. BaSbBS 4 : a record-high-performance birefringent crystal identified by a target-driven closed-loop strategy

    Chemical Science · 2025-01-01

    Ming‐Zhi Zhang, Yue Zhao, Chun‐Li Hu, Jiang‐Gao Mao

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  20. Cationic substitution engineering induces a new quaternary chalcogenide in the A–M IIIA –M IVA –Q system for optical crystal applications

    CrystEngComm · 2025-01-01

    Yue Wang, Xuezhong Li, Zihao Lou, Yong‐Fang Shi

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  21. Research progress and future prospect of chalcogenides with large optical anisotropy

    Coordination Chemistry Reviews · 2025-06-20

    Zhen-Cheng Wu, Sheng‐Ping Guo

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  22. Layered Ternary Indium Chalcogenides Ba5In2S8 and β-BaIn2Se4: Structural Diversity and Large Birefringence in β-BaIn2Se4

    Crystal Growth & Design · 2025-08-21

    Jinlong Shi, Pifu Gong, Jiyong Yao

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  23. SrZnSiS4: Shattering the 4.0 eV Threshold toward Dual-Optimized Bandgap and Second-Harmonic Generation

    Inorganic Chemistry · 2025-09-04

    Huilin Yin, Xia Wu, Shuchang Wu, Changsheng Sun, Chengxiao Wang, Jiaman Sun, Yang Liu, Xiao‐Ming Jiang, Ximeng Lv, Dajiang Mei

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  24. Achieving High‐Birefringence Thiophosphates From Low Polarizability Anisotropy Units by an Axial Linear Matching Strategy

    Advanced Optical Materials · 2026-05-18

    Ming‐Zhi Zhang, C Hu, Yi‐Wen Shan, Jiang‐Gao Mao

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  25. A Composition-Matched Intermediate Reveals Site-Specific Symmetry Evolution with Retained Second-Harmonic Generation in Supertetrahedral Sulfides

    Inorganic Chemistry · 2026-10-12

    KuiXian Cai, Ximeng Lv, Chuang Liu, Shuchang Wu, Zichang Wang, Yang Liu, Bin Luo, Xiao‐Ming Jiang, Dajiang Mei

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