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RESEARCH PAPER · Light Science & Applications · 2022

An excellent deep-ultraviolet birefringent material based on [BO2]∞ infinite chains

Fangfang Zhang, Xinglong Chen, Min Zhang, Wenqi Jin, Shujuan Han, Zhihua Yang, Shilie Pan

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An excellent deep-ultraviolet birefringent material based on [BO2]∞ infinite chainsOriginalLi 7 SrScB 12 O 24 and Li 7 Ba 0.6 Ca 0.4 ScB 12 O 24 : two new quaternary rare-earth borates with short UV cutoff edges4Na 3 YB 8 O 15 : a new rare-earth borate with an infinite one-dimensional [B 8 O 15 ] ∞ chain and a short ultraviolet cutoff edge8Design of novel deep-UV nonlinear optical materials with one-dimensional functional module [BO2]∞ chain and fluorine-driven short phase-matching43Sn3B10O17Cl2 Achieving Birefringence Enhancement by Stereochemical Activity Lone Pair9Li2PbB2O5: A Pyroborate with Large Birefringence Induced by the Synergistic Effect of Stereochemical Active Lone Pair Cations and π-Conjugated [B2O5] Groups14Li0.5Na0.5AlB2O4F2: Fluoroaluminoborate with Aligned 1∞[BO2] Chain Induced by Unprecedented [AlO3F3]6− Species Features Enhanced Birefringence30LiNaB6O9F2: A Promising UV NLO Crystal Having Fluorine‐Directed Optimal Performances and Double Interpenetrating 3[B6O9F2]∞ Networks33Aluminoborates as Nonlinear Optical Materials79Aluminoborates as Nonlinear Optical Materials14Design of deep-ultraviolet nonlinear optical materials based on fundamental building blocks with excellent microscopic properties1Noncentrosymmetric versus Centrosymmetric: Halogen Induced Variable Coordination Modes of Sn2+ and Structural Transition in Sn3B3O7X (X = Cl and Br)17A Cation-Driven Approach toward Deep-Ultraviolet Nonlinear Optical Materials17Enhancement of birefringence and refractive index dispersion optimization from iodates to fluorooxoiodates1Enhancing birefringence of non-π-conjugated sulfate systems through rare-earth metal-centered polyhedra10Heteroanion-introduction-driven birefringence enhancement in oxychalcogenide Ba 3 M II Ge 3 O 2 S 8 (M II = Mn, Cd)19K 5 [B 3 O 3 F 4 (OH)] 2 (NO 3 ): the first hydroxyfluorooxoborate-nitrate with a short ultraviolet cutoff edge and large birefringence18Li2AB5O8F2 (A = Na and K): two new deep-ultraviolet transparent fluorooxoborates with moderate birefringence designed by targeted dimensional modulation7Linear π-conjugated units of the D ∞h point group as superior ultraviolet birefringent units1Mg 2 Pb 2 Si 2 O 7 F 2 : a new lead-containing alkali earth metal silicate fluoride with a short cutoff edge2Mg assists in modulating the dimensionalities of the anionic frameworks of borates1Open honeycomb frameworks of sulphides AHg 4 Ga 5 S 12 (A = Rb, Cs) exhibiting infrared nonlinear optical properties12Recent progress in borate-based short-wavelength nonlinear optical crystals with boron–oxygen skeleton modification28Stereochemically active lone-pair-driven giant enhancement of birefringence from three-dimensional CsZn 4 Ga 5 Se 12 to two-dimensional CsZnAsSe 319BaB2P2O8F2: A Fluoroborophosphate with [B2P2O8F2]∞ Layers and Deep-Ultraviolet Cutoff Edge4Ba2B9O13F4·BF4: first fluorooxoborate with unprecedented infinite [B18O26F8] tubes and deep-ultraviolet cutoff edge14[K2PbX][Ga7S12] (X = Cl, Br, I): The First Lead‐Containing Cationic Moieties with Ultrahigh Second‐Harmonic Generation and Band Gaps Exceeding the Criterion of 2.33 eV46Structural Motif Cosubstitution Strategy for Designing Fluoroaluminoborate with the Sr2Be2B2O7-Type Double-Layered Structure14Target‐Driven Design of Deep‐UV Nonlinear Optical Materials via Interpretable Machine Learning125CaB2O2F4: A Novel [BOF2]∞-Based Structural Template with a Strong Second Harmonic Generation Response and Large Band Gap2Chain‐like [S x ] ( x =2–6) Units Realizing Giant Birefringence with Transparency in the Near‐Infrared for Optoelectronic Materials53Chain‐like [S x ] ( x =2–6) Units Realizing Giant Birefringence with Transparency in the Near‐Infrared for Optoelectronic Materials5Theoretical Prediction‐Assisted Synthesis and Characterization of Infrared Nonlinear Optical Material NaSrBS324“Cation Activation”: An Effective Strategy for the Enhancement of Birefringence36Birefringence Regulation by Clarifying the Relationship Between Stereochemically Active Lone Pairs and Optical Anisotropy in Tin‐based Ternary Halides56Birefringence Regulation by Clarifying the Relationship Between Stereochemically Active Lone Pairs and Optical Anisotropy in Tin‐based Ternary Halides2HgB2S4: A d10 Metal Thioborate with Giant Birefringence and Wide Band Gap31Prediction of Promising Deep Ultraviolet Nonlinear Optical Materials in the Li 2 O–B 2 O 3 System7Special Issue on the 120th Anniversary of Shandong University0Target-Oriented Synthesis of Borate Derivatives Featuring Isolated [B3O3] Six-Membered Rings as Structural Features20Three Polyborates with High-Symmetry [B12O24] Units Featuring Different Dimensions of Anion Groups8Improved Birefringence Activated by Tetrahedra Decorated with a Single Linear Unit38Improved Birefringence Activated by Tetrahedra Decorated with a Single Linear Unit1Ultraviolet Crystal with Strong Optical Nonlinearity by Creating Halogen-Centered Secondary Building Blocks15Fluorooxoborate Promoting the Exploration of Short-Wavelength Linear and Nonlinear Optical Crystals with Expected Properties and Versatile Structures27The Strategy to Improve the Phase Matching Ability in Tetrahedron‐Based Deep‐Ultraviolet Nonlinear Optical Crystals21Introduction of the [B–O/F] Units Enhances the Band Gap and Birefringence from Na6Mg3B10O18F6 to K3NaB10O16F211Three Borates Belonging to the A(I)7Ae(II)Re(III)2B15O30 Family as Promising Nonlinear Optical Crystals12Ba3.75MgB7O14F2.5: A Mixed Alkaline-Earth Metal Borate Fluoride with Short Ultraviolet Cutoff Edge and Large Birefringence91178 nm self-Q-switched Raman laser generation enabled by BaTeW2O9 crystal2Growth and spectral properties of a novel praseodymium-doped alpha-barium borate laser crystal1Visible to mid-infrared giant in-plane optical anisotropy in ternary van der Waals crystals41PbTeB 4 O 9 : a lead tellurium borate with unprecedented fundamental building block [B 4 O 10 ] and large birefringence12Rb 3 MgB 5 O 10 and LiBaAl(BO 3 ) 2 : covalent tetrahedra MO 4 -containing borates with deep-ultraviolet cutoff edges9A Sharp Improvement of Sulfate's Birefringence Induced by the Synergistic Effect of Heteroleptic and Dimeric Strategies14K 2 RbB 8 PO 16 : A Borophosphate with Moderate Birefringence and Deep-Ultraviolet Transmission10Achieving great optical anisotropy with the well-directed alignment of π-conjugated groups due to hydrogen bonds9Ca 3 Al 2 B 8 O 18 : borate with a graphene-like layer featuring two types of topological six-membered rings induced by [AlO 4 ] units7Crystal clear: unveiling giant birefringence in organic–inorganic cocrystals33CsAlB 3 O 6 Cl: the rational construction of a KBBF-type structure with aligned 2 ∞ [AlB 3 O 6 Cl] layers via introducing unprecedented [AlO 3 Cl] tetrahedra5Exploration of antimony( iii ) oxyhalides via single-site substitution in quest of large birefringence10Exploration of silver borates with diverse low-dimensional anion frameworks by introducing monovalent heteroanions6Exploring short-wavelength birefringent crystals via triggering cooperative arrangement between different π-conjugated groups8K 2 MgMoP 2 O 10 and K 3 Mg 2 MoP 3 O 14 : two new molybdophosphates exhibiting different optical anisotropies induced by variable dimensionality of the anion framework4K, Rb-hydroxyborates series with deep-ultraviolet KRbB 5 O 8 (OH) possessing moderate second harmonic generation response0NaB(OH) 3 CH 3 : a deep-ultraviolet optical crystal with unprecedented methyl-modified [B(OH) 3 CH 3 ] units6New antimony fluorooxoborates with strong birefringence and unprecedented structural characterisation19Partial substitution with a significant effect: coexistence of a wide band gap and large birefringence in the oxychalcogenide AEGe 2 O 4 Se (AE = Sr and Ba)17Prediction of ultraviolet optical materials in the K 2 O–B 2 O 3 system1Recent advances in rational structure design for nonlinear optical crystals: leveraging advantageous templates153Research progress in optical materials with cationic organic planar π-conjugated groups containing CN bonds34Strategically designed metal-free deep-ultraviolet birefringent crystals with superior optical properties18Syntheses, structures and properties of two new members of the pentaborate family: NaKB 5 O 8 (OH)·H 2 O and KB 5 O 8 ·2H 2 O3Screening Large Birefringent Materials via Halogen Regulation in Ternary d0-Transition Metal Oxyhalides8KNa 2 Lu(BO 3 ) 2 : A Rare-Earth Borate Crystal Characterized by an Enhanced Birefringence and Wide Ultraviolet Transparency Range19AYSO4F2 (A = K, Rb): [YO4F4] Polyhedra Enhancement of Birefringence in Non-π-Conjugated Sulfate Systems9Trithionic guanidine: A novel semi-organic short-wave ultraviolet nonlinear optical sulfate with dimeric heteroleptic tetrahedra14Unleashing the potential of π-conjugated [B2O3(OH)2] to enhance birefringence in DUV crystals9A Universal Design Strategy Achieving Large Birefringence and Short Phase‐Matching Capability of Optical Materials via Dissimilating Non‐π‐Conjugated Units6Na3K6(CO3)3(NO3)2X·6H2O (X = NO3, Cl, Br): Exploring High-Performance UV Birefringent Crystals Induced by Coplanar π-Conjugated CO3 and NO3 Groups15Zn(C6H4NO2)2·4H2O: A Solar-Blind Birefringent Crystal52D Materials‐Based Pulsed Solid‐State Laser: Status and Prospect18Review on birefringence in borates based on birefringence-active functional groups and arrangements57Breaking Boundaries: Giant Ultraviolet Birefringence in Dimension‐Reduced Zn‐Based Crystals66Breaking Boundaries: Giant Ultraviolet Birefringence in Dimension‐Reduced Zn‐Based Crystals8NH4Y(SO4)2·H2O and NH4YSO4F2: Two New Ammonium‐Rare Earth Metal Sulfates with Enhanced Optical Anisotropy and Deep Ultraviolet Transmission3(C3N2H5)B3O3F2(OH)2: Realizing Large Birefringence via a Synergistic Effect between Anion F/OH‐Ratio Optimization and Cation Activation25Sulfate Derivatives with Heteroleptic Tetrahedra: New Deep‐Ultraviolet Birefringent Materials in which Weak Interactions Modulate Functional Module Ordering61Sulfate Derivatives with Heteroleptic Tetrahedra: New Deep‐Ultraviolet Birefringent Materials in which Weak Interactions Modulate Functional Module Ordering4Na2B6SO13 with unprecedented [B6SO13]∞ double chains and largest birefringence among borosulfates induced by the uniform arrangement of [B3O7] units19Functional Modules Map of Unexplored Chemical Space: Guiding the Discovery of Giant Birefringent Materials76Achieving the Birefringence Optimization by Methyl Modulation in Organic Nonlinear Optical Crystals15A2Cd(PO3)4 (A = K, Rb, Cs): Series of cadmium polyphosphates with infinite 1[(PO3)4]ꝏ chains and deep ultraviolet transparency windows2Rb 1.87 Cs 1.13 B 8 O 13 (NO 3 ): a new acentric borate-nitrate with two types of three-dimensional interpenetrating lattices1Structural Evolution and Optical Properties of Hydroxyfluorooxoborates MM′2n-1[B3O3F4(OH)]n (M = K, Cs, and Rb; M′ = K, NH4, and Cs; n = 1, 2, and 3)12The New Paradigm of Ligand Substitution-Driven Enhancement of Anisotropy from SO4 Units in Short-Wavelength Region14Electron‐Lattice Synergistic Coordination for Boosting the Electro‐Optic Response of the Crystal4[C(NH2)3]2S2O6: A SBBO-Like Dithionate Crystal with Large Optical Anisotropy14Designing a Heteroleptic Tetrahedral Group with an Ultrahigh Polarizability Anisotropy by Optimizing the Bonding Electrons Activity and Their Distribution14Hg4InS2Cl5: Achieving Giant Optical Anisotropy by Introducing Well‐Aligned Linear [Hg2S2] Units14Structural modification of hydroxyborates by adjusting the number of shared oxygen atoms and hydroxyl groups for further performance enhancement1K6NaCaRe2(B5O10)3 (Re = Y, Lu): Two NLO Compounds Exhibiting a Short Absorption Edge in the A7–xA’xAeRe2(B5O10)3 (x = 0, 1) Family4Deep ultraviolet transparent borophosphates LiAB 2 P 2 O 9 (A = NH 4 , K) and LiNaB 2 P 2 O 8 (OH) 2 ·H 2 O exhibiting a moderate second-harmonic generation response4Emergent Mid‐Infrared Nonlinear Optical Candidates With Targeted Balance Performances17Cation tuning in anionic framework hydroborates: tailored deep-ultraviolet optical crystals with large birefringence1CN 4 H 7 B 3 O 3 F 2 (OH) 2 : short-wave UV hydroxyfluorooxyborate crystals with large birefringence2CsBO(OH) 2 : a new hydroxyborate with the rare [BO(OH) 2 ] group and a deep ultraviolet cutoff edge3Expanding silver fluorooxoborate crystal chemistry: Ag 2 B 5 O 8 F with 3D double interpenetrating frameworks and Ag 3 B 5 O 8 F 2 with 2D layers5Li 2 CeRbB 18 O 30 and Li 2 Cs 2 SrB 18 O 30 : promising low-birefringence materials for UV and deep UV zero-order waveplates4Na 2 PbB 6 O 10 SO 4 and Ca 2.58 Pb 0.42 B 6 O 11 SO 4 : first borate–sulfates featuring 3D porous borate anionic frameworks0Optimizing optical anisotropy in low-dimensional structures via intralayer hydrogen bonding modulation and anionic substitution17RbB 7 O 10 (OH) 2 and NaB 11 O 16 (OH) 2 : alkali metal hydroxyborates with two-dimensional layered structures and large birefringence1Stereochemically active lone pair-induced large optical anisotropy in a novel infrared birefringent crystal Ba 2 La 2 Sb 4 S 10 (S 2 )5The impact of anionic group arrangement on the optical properties of the arsenate series0β-LaTeBO 5 and RETeBO 5 (RE = Y, Gd, Tb): explorations of new optical materials in the RE( iii )–Te( iv )–B–O system7新型非线性光学晶体和双折射晶体的研究进展（特邀）4Pb 4 O 3 I 2 : A Lead Oxyhalide IR Optical Crystal with an Unprecedented 1 ∞ [O 3 Pb 4 ] Chain Featuring a Wide Transmittance Range and Large Birefringence3Highly Polarizable Phosphorus‐Centered Tetrahedra and π‐Conjugated Carbon‐Centered Triangular Moieties Inducing Large Anisotropy and Short‐Wavelength Phase‐Matching23Na3Y2F3P2O8 and K4Y3F5P4O14: [YOF] Polyhedra Inducing Birefringence Enhancement in Non-π-Conjugated Phosphate Systems3K2PbB5P3O17: A Mixed-Coordinated Borophosphate with Enhanced Birefringence Driven by the [B2O5] Unit5Na2MP3O9 (M = K, Rb): Two Potential Zero-Order Waveplate Materials with DUV Cutoff Edges2Regulation of Refractive Index by Halogens in Two-Dimensional Layered Methylsulfonate Halides7Size effect of cations in the A2B3O4F3 family: Based on the new member Cs2B3O4F34Three Cases of Borates with Different Dimensional Frameworks Induced by Metal Cations1Ultra‐High Optical Anisotropy with UV Transmission Achieved by Rational Arrangement of Extended π‐Conjugated Groups5Ultra‐High Optical Anisotropy with UV Transmission Achieved by Rational Arrangement of Extended π‐Conjugated Groups46Designed Metal‐Free Quasi‐1D Crystals with Giant Birefringence8Metal Cation Engineered UV Birefringent Crystals in π‐Conjugated Sulfonates with Record‐High Optical Anisotropy17Synthesis, characterization and theoretical calculations of a new rare-earth fluoride with a DUV cutoff edge1Recent progress in structural design strategies of high-birefringence optical crystals54Ultrabroadband Infrared Polarization Beam Combiner Based on Calomel Crystals with High Efficiency Exceeding 92% and Low Wavefront Distortion8Research progress and future prospect of chalcogenides with large optical anisotropy46[C( NH2 )3] 2SiF6 : Design of Deep Ultraviolet Crystals with Large Birefringence Based on a Fluorination‐Oriented Strategy13A novel metal-free crystal demonstrating superior birefringence attributed to the synergistic interaction of dual π-conjugated units8Reversal Enhancement of Birefringence by Stereochemically Active Lone Pairs in Sn(II)-Based Mixed Halides0Cation-modulated aligned arrangement of [B3O7] units in an unprecedented 2∞[B3O5] layer with remarkable birefringence10Giant Birefringence and Strong Third-Order Nonlinear Optical Response in a Hybrid Crystal Templated by a Push–Pull π-Conjugated System6Low‐Dimensional Organic–Inorganic Hybrid Metal Halide with Large Optical Anisotropy9A3ZnNO3X4 (A = Rb, NH4, X = Cl, I): Regulating Cations and Halides Yields Birefringent Crystals with Significantly Enhanced Optical Anisotropy5Anion-Ordered [B3O5(OH)2] Induced by Crystal Water with Deep Ultraviolet Transparency and Large Birefringence in Boron-Rich Borophosphates4Promising UV/DUV nonlinear optical materials with X-membered (X = multiples of 6) rings in anhydrous inorganic borates20Regulating the coplanarity of π-conjugated units through hydrogen bonding in FAHC2O4 and FAH2C3N3S3 crystals5Five-Membered [C 5 O 5 ] 2 – Rings as Birefringence-Active Genes for Ultrabirefringent Crystals27Enhancement of Birefringence in Alkali Metal Sulfates Induced by Rare Earth Metal-Centered Polyhedra and Structure Regulation via Cations2Highly sensitive self-calibrating birefringence measurement based on anisotropic laser feedback polarization effect11Anomalous Refractive Index Modulation and Giant Birefringence in 2D Ferrielectric CuInP 2 S 62Ultra‐Small Birefringence Continuous‐Tuning and Full‐Band Zero‐Order Waveplate Devices2Ba 3 (MoO 2 F 3 )PO 4 F 2 : Rational Design and Synthesis of an Alkaline-Earth Phosphate Fluoride as a Birefringent Crystal1Tuning birefringence in alkaline-earth metal oxyhalides through diverse mixed-cation coordination architectures1Achieving Ultra‐High Optical Anisotropy via Structural Regulation and Coplanar Engineering of Extended π‐Conjugated [H 2–x C 3 N 3 S 3 ] (x = 1, 2) Groups3Na2(C6H4NO3)2·H2O: A promising ultraviolet nonlinear optical crystal with strong second-harmonic generation effect and large birefringence1

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  1. Li 7 SrScB 12 O 24 and Li 7 Ba 0.6 Ca 0.4 ScB 12 O 24 : two new quaternary rare-earth borates with short UV cutoff edges

    New Journal of Chemistry · 2022-01-01

    Jianbang Chen, Jie Zhang, Aixin Zhu, Xuchu Huang

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  2. Na 3 YB 8 O 15 : a new rare-earth borate with an infinite one-dimensional [B 8 O 15 ] ∞ chain and a short ultraviolet cutoff edge

    Dalton Transactions · 2022-01-01

    Jianlong Huang, Chengfa Wu, Jianbang Chen, Zhiyong Guo, Wenjuan Ma, Feng Yu, Bin Dai

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  3. Design of novel deep-UV nonlinear optical materials with one-dimensional functional module [BO2]∞ chain and fluorine-driven short phase-matching

    Materials Today Physics · 2022-10-03

    Abudukadi Tudi, Congwei Xie, Shilie Pan, Zhihua Yang

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  4. Sn3B10O17Cl2 Achieving Birefringence Enhancement by Stereochemical Activity Lone Pair

    Inorganic Chemistry · 2022-11-01

    Lihan Deng, Mengfan Wu, Zhihua Yang, Shujuan Han, Shilie Pan

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  5. Li2PbB2O5: A Pyroborate with Large Birefringence Induced by the Synergistic Effect of Stereochemical Active Lone Pair Cations and π-Conjugated [B2O5] Groups

    Inorganic Chemistry · 2022-11-04

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  6. Li0.5Na0.5AlB2O4F2: Fluoroaluminoborate with Aligned 1∞[BO2] Chain Induced by Unprecedented [AlO3F3]6− Species Features Enhanced Birefringence

    Advanced Optical Materials · 2022-11-17

    Ziting Yan, Dongdong Chu, Min Zhang, Zhihua Yang, Shilie Pan

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  7. LiNaB6O9F2: A Promising UV NLO Crystal Having Fluorine‐Directed Optimal Performances and Double Interpenetrating 3[B6O9F2]∞ Networks

    Advanced Optical Materials · 2022-12-03

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  8. Aluminoborates as Nonlinear Optical Materials

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  9. Aluminoborates as Nonlinear Optical Materials

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  10. Design of deep-ultraviolet nonlinear optical materials based on fundamental building blocks with excellent microscopic properties

    New Journal of Chemistry · 2022-12-22

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  11. Noncentrosymmetric versus Centrosymmetric: Halogen Induced Variable Coordination Modes of Sn2+ and Structural Transition in Sn3B3O7X (X = Cl and Br)

    Inorganic Chemistry · 2022-12-30

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  12. A Cation-Driven Approach toward Deep-Ultraviolet Nonlinear Optical Materials

    Research · 2023-01-01

    Cong Hu, Meng Cheng, Wenqi Jin, Jian Wei Han, Zhihua Yang, Shilie Pan

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  13. Enhancement of birefringence and refractive index dispersion optimization from iodates to fluorooxoiodates

    New Journal of Chemistry · 2023-01-01

    Shi‐Bin Wang, Jie Zhang, Jianbang Chen, Peng Han, Na Lei, Xuchu Huang

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  14. Enhancing birefringence of non-π-conjugated sulfate systems through rare-earth metal-centered polyhedra

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  15. Heteroanion-introduction-driven birefringence enhancement in oxychalcogenide Ba 3 M II Ge 3 O 2 S 8 (M II = Mn, Cd)

    Inorganic Chemistry Frontiers · 2023-01-01

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  16. K 5 [B 3 O 3 F 4 (OH)] 2 (NO 3 ): the first hydroxyfluorooxoborate-nitrate with a short ultraviolet cutoff edge and large birefringence

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    Luyong Zhang, Shi‐Bin Wang, Fangfang Zhang, Zhihua Yang, Xueling Hou

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  17. Li2AB5O8F2 (A = Na and K): two new deep-ultraviolet transparent fluorooxoborates with moderate birefringence designed by targeted dimensional modulation

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  18. Linear π-conjugated units of the D ∞h point group as superior ultraviolet birefringent units

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  19. Mg 2 Pb 2 Si 2 O 7 F 2 : a new lead-containing alkali earth metal silicate fluoride with a short cutoff edge

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  20. Mg assists in modulating the dimensionalities of the anionic frameworks of borates

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  21. Open honeycomb frameworks of sulphides AHg 4 Ga 5 S 12 (A = Rb, Cs) exhibiting infrared nonlinear optical properties

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  22. Recent progress in borate-based short-wavelength nonlinear optical crystals with boron–oxygen skeleton modification

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  23. Stereochemically active lone-pair-driven giant enhancement of birefringence from three-dimensional CsZn 4 Ga 5 Se 12 to two-dimensional CsZnAsSe 3

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  24. BaB2P2O8F2: A Fluoroborophosphate with [B2P2O8F2]∞ Layers and Deep-Ultraviolet Cutoff Edge

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  25. Ba2B9O13F4·BF4: first fluorooxoborate with unprecedented infinite [B18O26F8] tubes and deep-ultraviolet cutoff edge

    Science China Chemistry · 2023-02-23

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  26. [K2PbX][Ga7S12] (X = Cl, Br, I): The First Lead‐Containing Cationic Moieties with Ultrahigh Second‐Harmonic Generation and Band Gaps Exceeding the Criterion of 2.33 eV

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  27. Structural Motif Cosubstitution Strategy for Designing Fluoroaluminoborate with the Sr2Be2B2O7-Type Double-Layered Structure

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  28. Target‐Driven Design of Deep‐UV Nonlinear Optical Materials via Interpretable Machine Learning

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  29. CaB2O2F4: A Novel [BOF2]∞-Based Structural Template with a Strong Second Harmonic Generation Response and Large Band Gap

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  30. Chain‐like [S x ] ( x =2–6) Units Realizing Giant Birefringence with Transparency in the Near‐Infrared for Optoelectronic Materials

    Angewandte Chemie International Edition · 2023-03-29

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  31. Chain‐like [S x ] ( x =2–6) Units Realizing Giant Birefringence with Transparency in the Near‐Infrared for Optoelectronic Materials

    Angewandte Chemie · 2023-03-29

    Guangmao Li, Zhihua Yang, Xueling Hou, Shilie Pan

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  32. Theoretical Prediction‐Assisted Synthesis and Characterization of Infrared Nonlinear Optical Material NaSrBS3

    Advanced Optical Materials · 2023-05-05

    Yihan Yun, Mengfan Wu, Congwei Xie, Zhihua Yang, Guangmao Li, Shilie Pan

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  33. “Cation Activation”: An Effective Strategy for the Enhancement of Birefringence

    Advanced Optical Materials · 2023-05-12

    Chenhui Hu, Mengfan Wu, Miao Zhang, Jian Wei Han, Xueling Hou, Feng Zhang, Zhihua Yang, Shilie Pan

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  34. Birefringence Regulation by Clarifying the Relationship Between Stereochemically Active Lone Pairs and Optical Anisotropy in Tin‐based Ternary Halides

    Angewandte Chemie International Edition · 2023-05-13

    Jingyu Guo, Junben Huang, Abudukadi Tudi, Xueling Hou, Shujuan Han, Zhihua Yang, Shilie Pan

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  35. Birefringence Regulation by Clarifying the Relationship Between Stereochemically Active Lone Pairs and Optical Anisotropy in Tin‐based Ternary Halides

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  38. Special Issue on the 120th Anniversary of Shandong University

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  40. Three Polyborates with High-Symmetry [B12O24] Units Featuring Different Dimensions of Anion Groups

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  42. Improved Birefringence Activated by Tetrahedra Decorated with a Single Linear Unit

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  43. Ultraviolet Crystal with Strong Optical Nonlinearity by Creating Halogen-Centered Secondary Building Blocks

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  44. Fluorooxoborate Promoting the Exploration of Short-Wavelength Linear and Nonlinear Optical Crystals with Expected Properties and Versatile Structures

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  45. The Strategy to Improve the Phase Matching Ability in Tetrahedron‐Based Deep‐Ultraviolet Nonlinear Optical Crystals

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  46. Introduction of the [B–O/F] Units Enhances the Band Gap and Birefringence from Na6Mg3B10O18F6 to K3NaB10O16F2

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  47. Three Borates Belonging to the A(I)7Ae(II)Re(III)2B15O30 Family as Promising Nonlinear Optical Crystals

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  48. Ba3.75MgB7O14F2.5: A Mixed Alkaline-Earth Metal Borate Fluoride with Short Ultraviolet Cutoff Edge and Large Birefringence

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  49. 1178 nm self-Q-switched Raman laser generation enabled by BaTeW2O9 crystal

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