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RESEARCH PAPER · Inorganic Chemistry · 2004

Asymmetric Cationic Coordination Environments in New Oxide Materials: Synthesis and Characterization of Pb4Te6M10O41 (M = Nb5+ or Ta5+)

Kang Min Ok, P. Shiv Halasyamani

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Asymmetric Cationic Coordination Environments in New Oxide Materials: Synthesis and Characterization of Pb4Te6M10O41 (M = Nb5+ or Ta5+)OriginalAsymmetric Cationic Coordination Environments in New Oxide Materials: Synthesis and Characterization of Pb4Te6M10O41 (M: Nb5+ or Ta5+).0Mixed-Metal Tellurites: Synthesis, Structure, and Characterization of Na1.4Nb3Te4.9O18 and NaNb3Te4O16126Syntheses, Crystal Structures, and Properties of Six New Lanthanide(III) Transition Metal Tellurium(IV) Oxyhalides with Three Types of Structures37Synthesis, crystal structure and magnetic property of a new nickel selenite chloride: Ni5(SeO3)4Cl221Luminescent Lanthanide Selenites and Tellurites Decorated by MoO4 Tetrahedra or MoO6 Octahedra: Nd2MoSe2O10, Gd2MoSe3O12, La2MoTe3O12, and Nd2MoTe3O1253[Cd2(Te6O13)][Cd2Cl6] and Cd7Cl8(Te7O17): Novel Tellurium(IV) Oxide Slabs and Unusual Cadmium Chloride Architectures35Na2Te3Mo3O16: A New Molybdenum Tellurite with Second-Harmonic Generating and Pyroelectric Properties232Synthesis, Structure, and Characterization of Novel Two- and Three-Dimensional Vanadates: Ba2.5(VO2)3(SeO3)4·H2O and La(VO2)3(TeO6)·3H2O60Syntheses, crystal structures and characterizations of BaZn(SeO3)2 and BaZn(TeO3)Cl222Se2(B2O7): A New Type of Second-Order NLO Material355Synthesis and crystal structure of a novel ternary oxoborate, PbBiBO420Syntheses, Structural Studies, and Magnetic Properties of Divalent Cu and Co Selenites with Organic Constituents31New Members in the Nin+1(QO3)nX2 Family: Unusual 3D Network Based on Ni4ClO3 Cubane-like Clusters in Ni7(TeO3)6Cl235Synthesis, Crystal Structure and Characterization of the Barium Zinc Tellurate Disilicate: Ba3Zn6[TeO6][Si2O7]210Synthesis, structure, and characterization of a new two-dimensional lead(II) vanadate, Ba3PbV4O1415Synthesis, crystal and band structures, and optical properties of a new lanthanide–alkaline earth tellurium(IV) oxide: La2Ba(Te3O8)(TeO3)230Ni3(Mo2O8)(XO3) (X = Se, Te): The First Nickel Selenite- and Tellurite-Containing Mo4 Clusters36New Luminescent Solids in the Ln−W(Mo)−Te−O−(Cl) Systems35Two New Noncentrosymmetric Polar Oxides: Synthesis, Characterization, Second-Harmonic Generating, and Pyroelectric Measurements on TlSeVO5 and TlTeVO5115New Organically Templated Copper(I) Sulfites: the Role of Sulfite Anion as Both Soft and Hard Ligand17(NH4)2Te2WO8: A New Polar Oxide with Second-Harmonic Generating, Ferroelectric, and Pyroelectric Properties88Explorations of New Types of Second‐Order Nonlinear Optical Materials in Cd(Zn)‐VV‐TeIV‐O Systems109Syntheses, crystal structures and optical properties of the first strontium selenium(IV) and tellurium(IV) oxychlorides: Sr3(SeO3)(Se2O5)Cl2 and Sr4(Te3O8)Cl432New Organically Templated Ln(III)−Cu(I) Heteronuclear Sulfite Bromides13Organic–inorganic hybrid based on the molybdenum tellurite5Explorations of new phases in the GaIII/InIII–MoVI–SeIV/TeIV–O systems46New Polar Oxides: Synthesis, Characterization, Calculations, and Structure−Property Relationships in RbSe2V3O12 and TlSe2V3O12125Explorations of New Phases in the GaIII/InIII-CuII-SeIV-O System15BaNbO(IO3)5: A New Polar Material with a Very Large SHG Response331Syntheses and characterization of two oxoborates, (Pb3O)2(BO3)2MO4 (M=Cr, Mo)16Synthesis, Structure, and Characterization of a Layered Mixed Metal Oxychloride, PbVO3Cl8Hydrothermal syntheses, crystal structures and magnetic properties of two new mixed metal copper( i ) sulfites10Syntheses, Crystal Structures, and Properties of Five New Transition Metal Molybdenum(VI) Selenites and Tellurites54Explorations of new quaternary phases in the LnIII–VV(d0)–SeIV–O (Ln = Nd, Eu, Gd, Tb) systems23Hydrothermal syntheses, crystal structures and physicochemical properties of 2-D and 3-D inorganic coordination cobalt(ii)-sulfite polymers9The Role of Stereoactive Lone Pairs in Templated Vanadium Tellurite Charge Density Matching21A Series of New Phases Containing Three Different Asymmetric Building Units55Syntheses, crystal structures, and properties of three new metal selenites Na2Co2(SeO3)3, Na2Co1.67Ni0.33(SeO3)3, and Na2Ni2(SeO3)315A Series of New Ternary and Quaternary Compounds in the LiI−GaIII−TeIV−O System37Syntheses and Crystal Structures of a Series of Alkaline Earth Vanadium Selenites and Tellurites41A series of new phases in the alkali metal–NbV/TaV–SeIV/TeIV–O systems19[R-C7H16N2][V2Te2O10] and [S-C7H16N2][V2Te2O10]; new polar templated vanadium tellurite enantiomers34Syntheses, Crystal Structures, Magnetic and Luminescent Properties of two Classes of Molybdenum(VI) Rich Quaternary Lanthanide Selenites34PbMSeO6 (M = Mo and W): New quaternary mixed metal selenites with asymmetric cationic coordination environments37Second-Order Nonlinear Optical Materials Based on Metal Iodates, Selenites, and Tellurites60Syntheses, crystal structures and SHG properties of a series of polar alkali-metal molybdenum(vi) selenites based on strandberg-type [Mo5O15(SeO3)2]4− polyanion28Single-crystal oxoborate (Pb3O)2(BO3)2WO4: Growth and characterization11Unusual Coordination for Plutonium(IV), Cerium(IV), and Zirconium(IV) in the Cationic Layered Materials [M2Te4O11]X2 (M = Pu, Ce, Zr; X = Cl, Br)29Na1.4InTe3.6O9.4: New Variant of a Hexagonal Tungsten Oxide (HTO)-Like Layered Framework Containing Both a Main-Group Cation, In3+, and a Lone-Pair Cation, Te4+14Y2MoSe3O12 and Y2MoTe3O12: Solid-state synthesis, structure determination, and characterization of two new quaternary mixed metal oxides containing asymmetric coordination environment22Dimensional and Coordination Number Reductions in a Large Family of Lanthanide Tellurite Sulfates21A series of novel mercury( i ) selenites and tellurites containing SOJT Mo 6+ cations18Structural and magnetic studies on three new mixed metal copper( ii ) selenites and tellurites16Structure–Property Correlations in the Heterobimetallic 4f/3d Materials Ln2M(TeO3)2(SO4) (Ln = Y, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, or Lu; M = Co or Zn)25Explorations of New SHG Materials in the Alkali-Metal–Nb5+–Selenite System33A series of new silver selenites with d 0 -TM cations19Controlled synthesis and upconversion luminescence properties of LiYF4:Yb0.2Er0.02nanoparticles12Structural motifs in heteroleptic copper and cadmium selenites7Role of Bis(triphenylphosphine)iminium Cation [PNP]+ on the Crystal Packing of [PNP]+[HSeO3]− Solvate Salt2[Ag 2 M(Te 2 O 5 ) 2 ]SO 4 (M = Ce IV or Th IV ): A New Purely Inorganic d/f-Heterometallic Cationic Material12Mild Synthesis and Structural Characterization of a Novel Vanadyl Selenite-Hydrogen Selenite Phase, Na[VO(SeO3)(HSeO3)]·1,5H2O2Designing Silicates as Deep‐UV Nonlinear Optical (NLO) Materials using Edge‐Sharing Tetrahedra147Designing Silicates as Deep‐UV Nonlinear Optical (NLO) Materials using Edge‐Sharing Tetrahedra43KIn0.33IIITe0.67VITe2IVO7: Zirconolite-like Mixed-Valent Metal Oxide with a 3D Framework2A new rare-earth oxyborate Ba 3 BiPbEuO(BO 3 ) 4 and the luminescence properties of the Ba 3 BiPbY 1− x Eu x O(BO 3 ) 4 phosphors6Lead Tellurite Crystals BaPbTe2O6 and PbVTeO5F with Large Nonlinear-/Linear-Optical Responses due to Active Lone Pairs and Distorted Octahedra20Two Purely Inorganic Cationic Tellurite Materials Based on Group IB Metal Tetrafluoroborates with Similar Lamellar Cationic Layers: [Cu2F(Te2O5)](BF4) and [Ag18O2(Te4O9)4(Te3O8)(BF4)2]·2HBF42Syntheses, Crystal Structure, and Second Harmonic Generation Response of Four Novel Noncentrosymmetric Tellurites of Quaternary A/M/Te/O (A = Ba, Sr, Ca; M = V, Nb, Ta) System: BaTa4Te3O17, BaNb4Te3O17, SrTa4Te3O17, and CaV2TeO84Combining rigid and deformable groups to construct a robust birefringent crystal for compact polarization components25Air‐Stable 2D van der Waals MgTeMoO6 Exhibits Strong In‐plane Optical Anisotropy7High-selectivity fluoride capture by purely inorganic copper tellurite of Cu7F2(TeO3)6: Adsorption performance and mechanistic insights0

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  1. Asymmetric Cationic Coordination Environments in New Oxide Materials: Synthesis and Characterization of Pb4Te6M10O41 (M: Nb5+ or Ta5+).

    ChemInform · 2004-08-19

    Kang Min Ok, P. Shiv Halasyamani

    Read original paper ↗ ·

  2. Mixed-Metal Tellurites: Synthesis, Structure, and Characterization of Na1.4Nb3Te4.9O18 and NaNb3Te4O16

    Inorganic Chemistry · 2005-05-01

    Kang Min Ok, P. Shiv Halasyamani

    Read original paper ↗ ·

  3. Syntheses, Crystal Structures, and Properties of Six New Lanthanide(III) Transition Metal Tellurium(IV) Oxyhalides with Three Types of Structures

    Inorganic Chemistry · 2005-06-29

    Yueling Shen, Jiang‐Gao Mao

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  4. Synthesis, crystal structure and magnetic property of a new nickel selenite chloride: Ni5(SeO3)4Cl2

    Journal of Solid State Chemistry · 2005-08-11

    Yueling Shen, Jiang‐Gao Mao, Hai‐Long Jiang

    Read original paper ↗ ·

  5. Luminescent Lanthanide Selenites and Tellurites Decorated by MoO4 Tetrahedra or MoO6 Octahedra: Nd2MoSe2O10, Gd2MoSe3O12, La2MoTe3O12, and Nd2MoTe3O12

    Inorganic Chemistry · 2005-11-02

    Yue-Ling Shen, Hai‐Long Jiang, Jian Xu, Jiang‐Gao Mao, Kok Wai Cheah

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  6. [Cd2(Te6O13)][Cd2Cl6] and Cd7Cl8(Te7O17): Novel Tellurium(IV) Oxide Slabs and Unusual Cadmium Chloride Architectures

    Inorganic Chemistry · 2005-12-16

    Hai‐Long Jiang, Jiang‐Gao Mao

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  7. Na2Te3Mo3O16: A New Molybdenum Tellurite with Second-Harmonic Generating and Pyroelectric Properties

    Chemistry of Materials · 2006-03-28

    Eun Ok Chi, Kang Min Ok, Yetta Porter, P. Shiv Halasyamani

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  8. Synthesis, Structure, and Characterization of Novel Two- and Three-Dimensional Vanadates: Ba2.5(VO2)3(SeO3)4·H2O and La(VO2)3(TeO6)·3H2O

    Inorganic Chemistry · 2006-04-01

    T. Sivakumar, Kang Min Ok, P. Shiv Halasyamani

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  9. Syntheses, crystal structures and characterizations of BaZn(SeO3)2 and BaZn(TeO3)Cl2

    Journal of Solid State Chemistry · 2006-04-27

    Hai‐Long Jiang, Mei‐Ling Feng, Jiang‐Gao Mao

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  10. Se2(B2O7): A New Type of Second-Order NLO Material

    Journal of the American Chemical Society · 2006-05-26

    Fang Kong, Shuping Huang, Zhong-Ming Sun, Jiang‐Gao Mao, Wen‐Dan Cheng

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  11. Synthesis and crystal structure of a novel ternary oxoborate, PbBiBO4

    Journal of Solid State Chemistry · 2006-06-15

    Xuean Chen, Jianlong Zuo, Xinan Chang, Yinghua Zhao, Hegui Zang, Weiqiang Xiao

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  12. Syntheses, Structural Studies, and Magnetic Properties of Divalent Cu and Co Selenites with Organic Constituents

    Chemistry - A European Journal · 2006-07-24

    Mei‐Ling Feng, Andrey V. Prosvirin, Jiang‐Gao Mao, Kim R. Dunbar

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  13. New Members in the Nin+1(QO3)nX2 Family: Unusual 3D Network Based on Ni4ClO3 Cubane-like Clusters in Ni7(TeO3)6Cl2

    Inorganic Chemistry · 2006-08-16

    Hai‐Long Jiang, Jiang‐Gao Mao

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  14. Synthesis, Crystal Structure and Characterization of the Barium Zinc Tellurate Disilicate: Ba3Zn6[TeO6][Si2O7]2

    Zeitschrift für anorganische und allgemeine Chemie · 2006-08-23

    Hai‐Long Jiang, Jiang‐Gao Mao

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  15. Synthesis, structure, and characterization of a new two-dimensional lead(II) vanadate, Ba3PbV4O14

    Solid State Sciences · 2007-03-22

    T. Sivakumar, Hong Chang, P. Shiv Halasyamani

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  16. Synthesis, crystal and band structures, and optical properties of a new lanthanide–alkaline earth tellurium(IV) oxide: La2Ba(Te3O8)(TeO3)2

    Journal of Solid State Chemistry · 2007-04-11

    Hai‐Long Jiang, Fang Kong, Jiang‐Gao Mao

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  17. Ni3(Mo2O8)(XO3) (X = Se, Te): The First Nickel Selenite- and Tellurite-Containing Mo4 Clusters

    Inorganic Chemistry · 2007-06-30

    Hai‐Long Jiang, Zhi Xie, Jiang‐Gao Mao

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  18. New Luminescent Solids in the Ln−W(Mo)−Te−O−(Cl) Systems

    Inorganic Chemistry · 2007-07-11

    Hai‐Long Jiang, En Ma, Jiang‐Gao Mao

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  19. Two New Noncentrosymmetric Polar Oxides: Synthesis, Characterization, Second-Harmonic Generating, and Pyroelectric Measurements on TlSeVO5 and TlTeVO5

    Chemistry of Materials · 2007-08-21

    T. Sivakumar, Hong Chang, Jaewook Baek, P. Shiv Halasyamani

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  20. New Organically Templated Copper(I) Sulfites: the Role of Sulfite Anion as Both Soft and Hard Ligand

    Inorganic Chemistry · 2007-08-25

    Pei-Xin Li, Hai‐Long Jiang, Mei‐Ling Feng, Jiang‐Gao Mao

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  21. (NH4)2Te2WO8: A New Polar Oxide with Second-Harmonic Generating, Ferroelectric, and Pyroelectric Properties

    Chemistry of Materials · 2007-10-09

    Junho Kim, Jaewook Baek, P. Shiv Halasyamani

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  22. Explorations of New Types of Second‐Order Nonlinear Optical Materials in Cd(Zn)‐VV‐TeIV‐O Systems

    Chemistry - A European Journal · 2007-12-11

    Hai‐Long Jiang, Shuping Huang, Yang Fan, Jiang‐Gao Mao, Wen‐Dan Cheng

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  23. Syntheses, crystal structures and optical properties of the first strontium selenium(IV) and tellurium(IV) oxychlorides: Sr3(SeO3)(Se2O5)Cl2 and Sr4(Te3O8)Cl4

    Journal of Solid State Chemistry · 2007-12-18

    Hai‐Long Jiang, Jiang‐Gao Mao

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  24. New Organically Templated Ln(III)−Cu(I) Heteronuclear Sulfite Bromides

    Crystal Growth & Design · 2008-07-18

    Pei-Xin Li, Jiang‐Gao Mao

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  25. Organic–inorganic hybrid based on the molybdenum tellurite

    Journal of Molecular Structure · 2008-12-31

    Ying Liu, Yuxin Li, Shiwei Zhang, Hongmei Ji, Ruige Cao, Shuxia Liu

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  26. Explorations of new phases in the GaIII/InIII–MoVI–SeIV/TeIV–O systems

    Dalton Transactions · 2009-01-01

    Fang Kong, Chun‐Li Hu, Ting Hu, Yong Lian Zhou, Jiang‐Gao Mao

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  27. New Polar Oxides: Synthesis, Characterization, Calculations, and Structure−Property Relationships in RbSe2V3O12 and TlSe2V3O12

    Chemistry of Materials · 2009-03-24

    Hong Chang, Sang‐Hwan Kim, Kang Min Ok, P. Shiv Halasyamani

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  28. Explorations of New Phases in the GaIII/InIII-CuII-SeIV-O System

    Inorganic Chemistry · 2009-06-18

    Fang Kong, Qipu Lin, Fei‐Yan Yi, Jiang‐Gao Mao

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  29. BaNbO(IO3)5: A New Polar Material with a Very Large SHG Response

    Journal of the American Chemical Society · 2009-06-22

    Chuan‐Fu Sun, Chun‐Li Hu, Xiang Xu, Ji‐Bei Ling, Ting Hu, Fang Kong, Xifa Long, Jiang‐Gao Mao

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  30. Syntheses and characterization of two oxoborates, (Pb3O)2(BO3)2MO4 (M=Cr, Mo)

    Journal of Solid State Chemistry · 2009-07-29

    Xuean Chen, Fang-Ping Song, Xinan Chang, Hegui Zang, Weiqiang Xiao

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  31. Synthesis, Structure, and Characterization of a Layered Mixed Metal Oxychloride, PbVO3Cl

    Bulletin of the Korean Chemical Society · 2009-09-20

    Vinna Jo

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  32. Hydrothermal syntheses, crystal structures and magnetic properties of two new mixed metal copper( i ) sulfites

    Dalton Transactions · 2009-11-02

    Pei-Xin Li, Jiang‐Gao Mao

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  33. Syntheses, Crystal Structures, and Properties of Five New Transition Metal Molybdenum(VI) Selenites and Tellurites

    Inorganic Chemistry · 2009-11-17

    Suyun Zhang, Hai‐Long Jiang, Chuan‐Fu Sun, Jiang‐Gao Mao

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  34. Explorations of new quaternary phases in the LnIII–VV(d0)–SeIV–O (Ln = Nd, Eu, Gd, Tb) systems

    Dalton Transactions · 2010-01-01

    Pei-Xin Li, Suyun Zhang, Jiang‐Gao Mao

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  35. Hydrothermal syntheses, crystal structures and physicochemical properties of 2-D and 3-D inorganic coordination cobalt(ii)-sulfite polymers

    Dalton Transactions · 2010-01-01

    George I. Chilas, Nikolia Lalioti, Tiverios Vaimakis, Maciej Kubicki, Themistoklis A. Kabanos

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  36. The Role of Stereoactive Lone Pairs in Templated Vanadium Tellurite Charge Density Matching

    Inorganic Chemistry · 2010-05-11

    Kelvin B. Chang, Desmond J. Hubbard, Mat­thias Zeller, Joshua Schrier, Alexander J. Norquist

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  37. A Series of New Phases Containing Three Different Asymmetric Building Units

    Inorganic Chemistry · 2010-06-07

    Pei-Xin Li, Fang Kong, Chun‐Li Hu, Na Zhao, Jiang‐Gao Mao

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  38. Syntheses, crystal structures, and properties of three new metal selenites Na2Co2(SeO3)3, Na2Co1.67Ni0.33(SeO3)3, and Na2Ni2(SeO3)3

    Journal of Solid State Chemistry · 2010-07-06

    Xiaoqing Yuan, Mei‐Ling Feng, Jian‐Rong Li, Xiao‐Ying Huang

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  39. A Series of New Ternary and Quaternary Compounds in the LiI−GaIII−TeIV−O System

    Inorganic Chemistry · 2010-11-15

    Fang Kong, Xiang Xu, Jiang‐Gao Mao

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  40. Syntheses and Crystal Structures of a Series of Alkaline Earth Vanadium Selenites and Tellurites

    Inorganic Chemistry · 2010-11-23

    Suyun Zhang, Chun‐Li Hu, Chuan‐Fu Sun, Jiang‐Gao Mao

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  41. A series of new phases in the alkali metal–NbV/TaV–SeIV/TeIV–O systems

    Dalton Transactions · 2011-01-01

    Qian-Hua Gu, Chun‐Li Hu, Jian‐Han Zhang, Jiang‐Gao Mao

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  42. [R-C7H16N2][V2Te2O10] and [S-C7H16N2][V2Te2O10]; new polar templated vanadium tellurite enantiomers

    Journal of Solid State Chemistry · 2011-04-20

    Ethan C. Glor, Samuel M. Blau, Jeongho Yeon, Mat­thias Zeller, P. Shiv Halasyamani, Joshua Schrier, Alexander J. Norquist

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  43. Syntheses, Crystal Structures, Magnetic and Luminescent Properties of two Classes of Molybdenum(VI) Rich Quaternary Lanthanide Selenites

    Inorganic Chemistry · 2011-04-28

    Suyun Zhang, Jiang‐Gao Mao

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  44. PbMSeO6 (M = Mo and W): New quaternary mixed metal selenites with asymmetric cationic coordination environments

    Dalton Transactions · 2012-01-01

    Seung‐Jin Oh, Dong Woo Lee, Kang Min Ok

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  45. Second-Order Nonlinear Optical Materials Based on Metal Iodates, Selenites, and Tellurites

    Structure and bonding · 2012-01-01

    Fang Kong, Chuan‐Fu Sun, Bing‐Ping Yang, Jiang‐Gao Mao

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  46. Syntheses, crystal structures and SHG properties of a series of polar alkali-metal molybdenum(vi) selenites based on strandberg-type [Mo5O15(SeO3)2]4− polyanion

    Dalton Transactions · 2012-01-01

    Fang Kong, Chun‐Li Hu, Xiang Xu, Tianhua Zhou, Jiang‐Gao Mao

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  47. Single-crystal oxoborate (Pb3O)2(BO3)2WO4: Growth and characterization

    Materials Research Bulletin · 2012-05-04

    A.H. Reshak, Xuean Chen, S. Auluck, Hussin Kamarudin

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  48. Unusual Coordination for Plutonium(IV), Cerium(IV), and Zirconium(IV) in the Cationic Layered Materials [M2Te4O11]X2 (M = Pu, Ce, Zr; X = Cl, Br)

    Inorganic Chemistry · 2012-10-17

    Jian Hung Lin, Justin N. Cross, Juan Diwu, Matthew J. Polinski, Eric M. Villa, Thomas E. Albrecht‐Schmitt

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  49. Na1.4InTe3.6O9.4: New Variant of a Hexagonal Tungsten Oxide (HTO)-Like Layered Framework Containing Both a Main-Group Cation, In3+, and a Lone-Pair Cation, Te4+

    Inorganic Chemistry · 2013-05-15

    Dong Woo Lee, Kang Min Ok

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  50. Y2MoSe3O12 and Y2MoTe3O12: Solid-state synthesis, structure determination, and characterization of two new quaternary mixed metal oxides containing asymmetric coordination environment

    Journal of Solid State Chemistry · 2013-10-10

    Seong‐eun Bang, Zhi Quan Pan, Yeong Hun Kim, Dong Woo Lee, Kang Min Ok

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