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RESEARCH PAPER · Journal of Alloys and Compounds · 2002

Structure determination of La3CuGeS7 and La3CuGeSe7

Kristin M. Poduska, Francis J. DiSalvo, K. Min, P. Shiv Halasyamani

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Structure determination of La3CuGeS7 and La3CuGeSe7OriginalChemInform Abstract: Structure Determination of La3CuGeS7 and La3CuGeSe7.0Crystal structure of trilanthanum monosilver monosilicon heptasulfide, La3AgSiS76Crystal structures of the Y3CuSiS7 and Y3CuSiSe7 compounds24Crystal structures of the R3CuGeSe7 (R=Ce, Pr, Nd, Sm, Gd, Tb and Ho) compounds26Crystal structures of the R3Mg0.5GeS7 (R=Y, Ce, Pr, Nd, Sm, Gd, Tb, Dy, Ho and Er) compounds28The crystal structures of R3CuGeS7 (R=Ce–Nd, Sm, Gd–Dy and Er)25Crystal structures of the compounds R3CuSiS7 (R=Ce, Pr, Nd, Sm, Tb, Dy and Er) and R3CuSiSe7 (R=La, Ce, Pr, Nd, Sm, Gd, Tb and Dy)26Syntheses and single-crystal structures of La3AgSnS7, Ln3MxMS7 (Ln=La, Ho, Er; M=Ge, Sn; 1/4≤x≤1/2)31A Series of New Infrared NLO Semiconductors, ZnY6Si2S14, AlxDy3(SiyAl1−y)S7, and Al0.33Sm3SiS7134Crystal structure and magnetic properties of Sm3CuGeS7 and Sm3CuGeSe721Ternary and Quaternary Chalcogenides of Si, Ge, Sn, Pb, and In10Structure Change Induced by Terminal Sulfur in Noncentrosymmetric La 2 Ga 2 GeS 8 and Eu 2 Ga 2 GeS 7 and Nonlinear-Optical Responses in Middle Infrared80Pressure induced silver ion displacement in La3Ag0.82SnS710Large Crystal Growth and New Crystal Exploration of Mid-Infrared Second-Order Nonlinear Optical Materials56Ln3FeGaQ7: A new series of transition-metal rare-earth chalcogenides30Rare-earth transition-metal indium sulphides RE3FeInS7 (RE=La–Pr), RE3CoInS7 (RE=La, Ce), and La3NiInS731Rare-earth transition-metal gallium chalcogenides RE3MGaCh7 (M=Fe, Co, Ni; Ch=S, Se)33Layered Compounds BaM2Ge4Ch6 (M = Rh, Ir and Ch = S, Se) with Pyrite-Type Building Blocks and Ge–Ch Heteromolecule-Like Anions5Synthesis, structure, magnetic and photo response properties of La3CuGaSe723Alkali-Metal Thiogermanates: Sodium Channels and Variations on the La3CuSiS7 Structure Type27Synthesis, structure, magnetic and photoelectric properties of Ln 3 M 0.5 M′Se 7 (Ln = La, Ce, Sm; M = Fe, Mn; M′ = Si, Ge) and La 3 MnGaSe 734Strongest Second Harmonic Generation in the Polar R3MTQ7 Family: Atomic Distribution Induced Nonlinear Optical Cooperation86Synthesis, Crystal and Electronic Structure, and Optical Property of the Quaternary Selenide: La3Sb0.33SiSe75Syntheses, crystal structures, and NLO properties of the quaternary sulfides RE3Sb0.33SiS7 (RE=La, Pr)24Synthesis, crystal and electronic structure of the quaternary sulfides Ln2CuMS5 (Ln=La, Ce; M=Sb, Bi)14Syntheses, structures, physical and electronic properties of quaternary semiconductors: Cs[RE 9 Cd 4 Se 18 ] (RE = Tb–Tm)14Synthesis of heterometallic chalcogenides containing lanthanide and group 13–15 metal elements94Metal ion displacements in noncentrosymmetric chalcogenides La3Ga1.67S7, La3Ag0.6GaCh7 (Ch=S, Se), and La3MGaSe7 (M=Zn, Cd)14A High Laser Damage Threshold and a Good Second-Harmonic Generation Response in a New Infrared NLO Material: LiSm3SiS725Mid-Infrared Nonlinear Optical Materials Based on Metal Chalcogenides: Structure–Property Relationship338A Series of Lanthanide Selenidogermanates: The First Coexistence of Three Types of Selenidogermanate Units in the Same Architecture10Composés inorganiques innovants par manipulation et diversification du sous-réseau anionique0Rational design of infrared nonlinear optical chalcogenides by chemical substitution287Applying band gap engineering to tune the linear optical and nonlinear optical properties of noncentrosymmetric chalcogenides La 4 Ge 3 Se x S 12− x ( x = 0, 2, 4, 6, 8, 10)21La 6 Cd 0.75 Ga 2 Q 11.5 Cl 2.5 (Q = S and Se): two new nonlinear optical chalcohalides with a large laser-induced damage threshold15Recent advances in nonlinear optical rare earth structures63Transition-metal-based chalcogenides: A rich source of infrared nonlinear optical materials184Synthesis, Crystal Growth, Electronic Properties and Optical Properties of Y6IV2.5S14 (IV=Si, Ge)9Homovalent Cation Substitutions Leading to New Lithium-Containing La3cusis7 Family Members Having Chiral, Uniaxial Structures and Exhibiting Second- and Third-Harmonic Generation7Non‐Linear Optical Properties of the (RE)3CuGeS7 Family of Compounds16КРИСТАЛІЧНА СТРУКТУРА Ce1.5Tb1.5Ga1.67S70Crystal Structures and Property Measurements of Rare Earth Magnesium Thiosilicates Synthesized via Flux Crystal Growth Utilizing the Boron Chalcogen Mixture (BCM) Method15Ga-based IR nonlinear optical materials: Synthesis, structures, and properties65Rare-earth-based chalcogenides and their derivatives: an encouraging IR nonlinear optical material candidate70[Na2PbI][Ga7S12]: Combining Diamond-Like Anionic Framework with Polycationic Chain toward Achieving Remarkable Nonlinear Optical Response21Magnetic triple Weyl semimetals that are robust against spin-orbit coupling4Structural Investigation of Six Quinary Sulfides Synthesized via the Flux-Assisted Boron-Chalcogen Mixture (BCM) Method: Eu2+ Containing Members of the RE3MTQ7 (M and T = Transition or Main Group Metals, Q = Chalcogens) Family8Optical, Photoelectric, and Electrocatalytic Properties of Quaternary Sulfides RE 3 M 1– x SnS 7 ( RE = La–Nd; M = Ti–Cu, Cd)1

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  1. ChemInform Abstract: Structure Determination of La3CuGeS7 and La3CuGeSe7.

    ChemInform · 2002-05-14

    Kristin M. Poduska, Francis J. DiSalvo, K. Min, P. Shiv Halasyamani

    Read original paper ↗ ·

  2. Crystal structure of trilanthanum monosilver monosilicon heptasulfide, La3AgSiS7

    Zeitschrift für Kristallographie - New Crystal Structures · 2005-04-01

    Liwei Wu, Fuqiang Huang

    Read original paper ↗ ·

  3. Crystal structures of the Y3CuSiS7 and Y3CuSiSe7 compounds

    Journal of Alloys and Compounds · 2005-06-27

    Lubomir D. Gulay, O. S. Lychmanyuk, J. Stępień‐Damm, A. Pietraszko, Ivan D. Olekseyuk

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  4. Crystal structures of the R3CuGeSe7 (R=Ce, Pr, Nd, Sm, Gd, Tb and Ho) compounds

    Journal of Alloys and Compounds · 2006-01-24

    Lubomir D. Gulay, O. S. Lychmanyuk, Ivan D. Olekseyuk, A. Pietraszko

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  5. Crystal structures of the R3Mg0.5GeS7 (R=Y, Ce, Pr, Nd, Sm, Gd, Tb, Dy, Ho and Er) compounds

    Journal of Alloys and Compounds · 2006-02-04

    M. R. Huch, Lubomir D. Gulay, Ivan D. Olekseyuk

    Read original paper ↗ ·

  6. The crystal structures of R3CuGeS7 (R=Ce–Nd, Sm, Gd–Dy and Er)

    Journal of Alloys and Compounds · 2006-03-03

    Lubomir D. Gulay, O. S. Lychmanyuk, Marek Wołcyrz, A. Pietraszko, Ivan D. Olekseyuk

    Read original paper ↗ ·

  7. Crystal structures of the compounds R3CuSiS7 (R=Ce, Pr, Nd, Sm, Tb, Dy and Er) and R3CuSiSe7 (R=La, Ce, Pr, Nd, Sm, Gd, Tb and Dy)

    Journal of Alloys and Compounds · 2006-07-26

    Lubomir D. Gulay, O. S. Lychmanyuk, Ivan D. Olekseyuk, Marek Daszkiewicz, J. Stępień‐Damm, A. Pietraszko

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  8. Syntheses and single-crystal structures of La3AgSnS7, Ln3MxMS7 (Ln=La, Ho, Er; M=Ge, Sn; 1/4≤x≤1/2)

    Journal of Alloys and Compounds · 2007-04-25

    Hui‐Yi Zeng, Fa‐Kun Zheng, Guo‐Cong Guo, Jin‐Shun Huang

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  9. A Series of New Infrared NLO Semiconductors, ZnY6Si2S14, AlxDy3(SiyAl1−y)S7, and Al0.33Sm3SiS7

    Inorganic Chemistry · 2009-07-09

    Sheng‐Ping Guo, Guo‐Cong Guo, Ming‐Sheng Wang, Jian‐Ping Zou, Gang Xu, Guojian Wang, Xifa Long, Jin‐Shun Huang

    Read original paper ↗ ·

  10. Crystal structure and magnetic properties of Sm3CuGeS7 and Sm3CuGeSe7

    Journal of Alloys and Compounds · 2010-01-05

    O. M. Strok, Marek Daszkiewicz, Lubomir D. Gulay, D. Kaczorowski

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  11. Ternary and Quaternary Chalcogenides of Si, Ge, Sn, Pb, and In

    Elsevier eBooks · 2010-10-20

    Lubomir D. Gulay, Marek Daszkiewicz

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  12. Structure Change Induced by Terminal Sulfur in Noncentrosymmetric La 2 Ga 2 GeS 8 and Eu 2 Ga 2 GeS 7 and Nonlinear-Optical Responses in Middle Infrared

    Inorganic Chemistry · 2011-11-16

    Mei‐Chun Chen, Peng Li, Liujiang Zhou, Long-Hua Li, Ling Chen

    Read original paper ↗ ·

  13. Pressure induced silver ion displacement in La3Ag0.82SnS7

    Materials Research Bulletin · 2011-11-20

    Marek Daszkiewicz, Lubomir D. Gulay

    Read original paper ↗ ·

  14. Large Crystal Growth and New Crystal Exploration of Mid-Infrared Second-Order Nonlinear Optical Materials

    Structure and bonding · 2012-01-01

    Xiao‐Ming Jiang, Sheng‐Ping Guo, Hui‐Yi Zeng, Ming‐Jian Zhang, Guo‐Cong Guo

    Read original paper ↗ ·

  15. Ln3FeGaQ7: A new series of transition-metal rare-earth chalcogenides

    Journal of Solid State Chemistry · 2013-03-28

    Wenlong Yin, Wendong Wang, Lei Kang, Zheshuai Lin, Kai Feng, Youguo Shi, Wenyu Hao, Jiyong Yao, Yicheng Wu

    Read original paper ↗ ·

  16. Rare-earth transition-metal indium sulphides RE3FeInS7 (RE=La–Pr), RE3CoInS7 (RE=La, Ce), and La3NiInS7

    Journal of Solid State Chemistry · 2013-10-01

    Brent W. Rudyk, Stanislav S. Stoyko, A. Mar

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  17. Rare-earth transition-metal gallium chalcogenides RE3MGaCh7 (M=Fe, Co, Ni; Ch=S, Se)

    Journal of Solid State Chemistry · 2013-11-12

    Brent W. Rudyk, Stanislav S. Stoyko, Anton O. Oliynyk, A. Mar

    Read original paper ↗ ·

  18. Layered Compounds BaM2Ge4Ch6 (M = Rh, Ir and Ch = S, Se) with Pyrite-Type Building Blocks and Ge–Ch Heteromolecule-Like Anions

    Inorganic Chemistry · 2014-05-09

    Hechang Lei, Jun‐ichi Yamaura, Jiangang Guo, Yanpeng Qi, Yoshitake Toda, Hideo Hosono

    Read original paper ↗ ·

  19. Synthesis, structure, magnetic and photo response properties of La3CuGaSe7

    Journal of Alloys and Compounds · 2014-05-21

    Xian Zhang, Wei Chen, Dajiang Mei, Chong Zheng, Fuhui Liao, Yanting Li, Jianhua Lin, Fuqiang Huang

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  20. Alkali-Metal Thiogermanates: Sodium Channels and Variations on the La3CuSiS7 Structure Type

    Inorganic Chemistry · 2014-11-20

    Amitava Choudhury, Peter K. Dorhout

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  21. Synthesis, structure, magnetic and photoelectric properties of Ln 3 M 0.5 M′Se 7 (Ln = La, Ce, Sm; M = Fe, Mn; M′ = Si, Ge) and La 3 MnGaSe 7

    RSC Advances · 2015-01-01

    Jianqiao He, Zhe Wang, Xian Zhang, Cheng Ye, Yu Gong, Xiaofang Lai, Chong Zheng, Jianhua Lin, Fuqiang Huang

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  22. Strongest Second Harmonic Generation in the Polar R3MTQ7 Family: Atomic Distribution Induced Nonlinear Optical Cooperation

    Chemistry of Materials · 2015-02-16

    Yong‐Fang Shi, Yukun Chen, Mei‐Chun Chen, Li‐Ming Wu, Hua Lin, Liujiang Zhou, Ling Chen

    Read original paper ↗ ·

  23. Synthesis, Crystal and Electronic Structure, and Optical Property of the Quaternary Selenide: La3Sb0.33SiSe7

    Zeitschrift für anorganische und allgemeine Chemie · 2015-03-18

    Hua‐Jun Zhao

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  24. Syntheses, crystal structures, and NLO properties of the quaternary sulfides RE3Sb0.33SiS7 (RE=La, Pr)

    Journal of Solid State Chemistry · 2015-04-02

    Hua‐Jun Zhao

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  25. Synthesis, crystal and electronic structure of the quaternary sulfides Ln2CuMS5 (Ln=La, Ce; M=Sb, Bi)

    Journal of Solid State Chemistry · 2015-10-30

    Ardak M. Kusainova, Lev Akselrud, Nian‐Tzu Suen, Leonard Voss, Stanislav S. Stoyko, Svilen Bobev

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  26. Syntheses, structures, physical and electronic properties of quaternary semiconductors: Cs[RE 9 Cd 4 Se 18 ] (RE = Tb–Tm)

    Dalton Transactions · 2016-01-01

    Hua Lin, Hong Chen, Pengfei Liu, Ju‐Song Yu, Yujun Zheng, Khan Muhammad Ali, Ling Chen, Li‐Ming Wu

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  27. Synthesis of heterometallic chalcogenides containing lanthanide and group 13–15 metal elements

    Coordination Chemistry Reviews · 2016-02-19

    Jian Zhou

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  28. Metal ion displacements in noncentrosymmetric chalcogenides La3Ga1.67S7, La3Ag0.6GaCh7 (Ch=S, Se), and La3MGaSe7 (M=Zn, Cd)

    Journal of Solid State Chemistry · 2016-08-25

    Abishek K. Iyer, Wenlong Yin, Brent W. Rudyk, Xinsong Lin, Tom Nilges, A. Mar

    Read original paper ↗ ·

  29. A High Laser Damage Threshold and a Good Second-Harmonic Generation Response in a New Infrared NLO Material: LiSm3SiS7

    Crystals · 2016-09-23

    Ni Zhen, Leyan Nian, Guangmao Li, Kui Wu, Shilie Pan

    Read original paper ↗ ·

  30. Mid-Infrared Nonlinear Optical Materials Based on Metal Chalcogenides: Structure–Property Relationship

    Crystal Growth & Design · 2017-03-15

    Fei Liang, Lei Kang, Zheshuai Lin, Yicheng Wu

    Read original paper ↗ ·

  31. A Series of Lanthanide Selenidogermanates: The First Coexistence of Three Types of Selenidogermanate Units in the Same Architecture

    Inorganic Chemistry · 2018-01-10

    Shimei Tang, Jian Zhou, Hua‐Hong Zou, Xing Liu, Li Zhang

    Read original paper ↗ ·

  32. Composés inorganiques innovants par manipulation et diversification du sous-réseau anionique

    Unknown journal · 2018-12-14

    Sarah Nicoud

    Read original paper ↗ ·

  33. Rational design of infrared nonlinear optical chalcogenides by chemical substitution

    Coordination Chemistry Reviews · 2019-12-21

    Hua Lin, Wenbo Wei, Hong Chen, Xintao Wu, Qi‐Long Zhu

    Read original paper ↗ ·

  34. Applying band gap engineering to tune the linear optical and nonlinear optical properties of noncentrosymmetric chalcogenides La 4 Ge 3 Se x S 12− x ( x = 0, 2, 4, 6, 8, 10)

    Inorganic Chemistry Frontiers · 2021-01-01

    Gary Cicirello, Kui Wu, Bingbing Zhang, Jian Wang

    Read original paper ↗ ·

  35. La 6 Cd 0.75 Ga 2 Q 11.5 Cl 2.5 (Q = S and Se): two new nonlinear optical chalcohalides with a large laser-induced damage threshold

    CrystEngComm · 2021-01-01

    Feng Lin, Mengjia Luo, Ruiqi Wang, Xiangli Che, Fuqiang Huang

    Read original paper ↗ ·

  36. Recent advances in nonlinear optical rare earth structures

    Journal of Rare Earths · 2021-07-15

    Jun Zhao, Dajiang Mei, Weikang Wang, Yuandong Wu, Dongfeng Xue

    Read original paper ↗ ·

  37. Transition-metal-based chalcogenides: A rich source of infrared nonlinear optical materials

    Coordination Chemistry Reviews · 2021-08-26

    Hong Chen, Wenbo Wei, Hua Lin, Xintao Wu

    Read original paper ↗ ·

  38. Synthesis, Crystal Growth, Electronic Properties and Optical Properties of Y6IV2.5S14 (IV=Si, Ge)

    Zeitschrift für anorganische und allgemeine Chemie · 2021-12-06

    Zhengyang Ye, Stefano Bardelli, Kui Wu, Arka Sarkar, Andrew Swindle, Jian Wang

    Read original paper ↗ ·

  39. Homovalent Cation Substitutions Leading to New Lithium-Containing La3cusis7 Family Members Having Chiral, Uniaxial Structures and Exhibiting Second- and Third-Harmonic Generation

    SSRN Electronic Journal · 2022-01-01

    Andrew J. Craig, Jeong Bin Cho, Seung Han Shin, Seung Heon Ha, Stanislav S. Stoyko, Joon Ik Jang, Jennifer A. Aitken

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  40. Non‐Linear Optical Properties of the (RE)3CuGeS7 Family of Compounds

    Zeitschrift für anorganische und allgemeine Chemie · 2022-04-05

    Georgiy Akopov, Nethmi W. Hewage, Gayatri Viswanathan, Philip Yox, Kui Wu, Kirill A. Kovnir

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  41. КРИСТАЛІЧНА СТРУКТУРА Ce1.5Tb1.5Ga1.67S7

    Проблеми хімії та сталого розвитку · 2023-02-28

    N.M. Blashko, О.V. Marchuk, A.O. Fedorchuk, Ярослав РОМАНЮК

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  42. Crystal Structures and Property Measurements of Rare Earth Magnesium Thiosilicates Synthesized via Flux Crystal Growth Utilizing the Boron Chalcogen Mixture (BCM) Method

    Inorganic Chemistry · 2023-05-03

    Adam A. King, Logan S. Breton, Gregory W. Morrison, Mark D. Smith, Mingli Liang, P. Shiv Halasyamani, Hans‐Conrad zur Loye

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  43. Ga-based IR nonlinear optical materials: Synthesis, structures, and properties

    Coordination Chemistry Reviews · 2023-12-21

    Jiaxiang Zhang, Ping Feng, Mao‐Yin Ran, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  44. Rare-earth-based chalcogenides and their derivatives: an encouraging IR nonlinear optical material candidate

    Chemical Science · 2024-01-01

    Ping Feng, Jiaxiang Zhang, Mao‐Yin Ran, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  45. [Na2PbI][Ga7S12]: Combining Diamond-Like Anionic Framework with Polycationic Chain toward Achieving Remarkable Nonlinear Optical Response

    Chemistry of Materials · 2024-03-27

    Zixuan Wu, Wen‐Fa Chen, Xiao‐Ming Jiang, Bin‐Wen Liu, Guo‐Cong Guo

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  46. Magnetic triple Weyl semimetals that are robust against spin-orbit coupling

    Physical review. B./Physical review. B · 2024-10-25

    Guang Liu, Peiyao Qin, Junfeng Ren, Zhongjia Chen, Guanghui Zhou, Hu Xu

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  47. Structural Investigation of Six Quinary Sulfides Synthesized via the Flux-Assisted Boron-Chalcogen Mixture (BCM) Method: Eu2+ Containing Members of the RE3MTQ7 (M and T = Transition or Main Group Metals, Q = Chalcogens) Family

    Inorganic Chemistry · 2025-09-08

    Habiba Binte Kashem, Hunter B. Tisdale, Hans‐Conrad zur Loye

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  48. Optical, Photoelectric, and Electrocatalytic Properties of Quaternary Sulfides RE 3 M 1– x SnS 7 ( RE = La–Nd; M = Ti–Cu, Cd)

    Chemistry of Materials · 2026-07-02

    Trinanjan Dey, Zhongqi Lin, Dundappa Mumbaraddi, Taek Rim Kim, Seung Han Shin, Khushveer Kaur, Dmitry Vrublevskiy, Elisa Fontaine, Andrew P. Grosvenor, Lingzi Sang, Joon Ik Jang, A. Mar

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