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RESEARCH PAPER · Inorganic Chemistry · 2023

Crystal Structures and Property Measurements of Rare Earth Magnesium Thiosilicates Synthesized via Flux Crystal Growth Utilizing the Boron Chalcogen Mixture (BCM) Method

Adam A. King, Logan S. Breton, Gregory W. Morrison, Mark D. Smith, Mingli Liang, P. Shiv Halasyamani, Hans‐Conrad zur Loye

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Crystal Structures and Property Measurements of Rare Earth Magnesium Thiosilicates Synthesized via Flux Crystal Growth Utilizing the Boron Chalcogen Mixture (BCM) MethodOriginalAn overview of Mg-based IR nonlinear optical materials23Boron Chalcogen Mixture Method-Assisted Alkali Halide Flux Crystal Growth of an Extensive Family of Quaternary Rare Earth Transition-Metal Thiosilicates: Investigation of Their Structures and Magnetic Properties9Li13YGe4O16: A Mid-infrared Rare-Earth Germanate Nonlinear Optical Crystal Featuring a Broad Transmission Range and an Enlarged Band Gap10Crystal Growth of Quaternary AkRE 2 Si 2 S 8 (Ak = Ca and Sr; RE = La–Tb) Thiosilicates Using Flux-Assisted Boron Chalcogen Mixture Method: Exploring X-ray Scintillation, Luminescence, and Magnetic Properties11Rare Bird: U+5 in Uranium Chalcogenides6Synthesis, Optical, and Magnetic Properties of the Mixed Chalcogenide Semiconductor Series Eu(II)2SiSexS4-x, Prepared via the Flux-Assisted Boron Chalcogen Mixture Method4Synthesis of a series of rare-earth-based multi-anion chalcogenide iodides RE 3 Si 2 Se x S 8− x I (RE = La, Ce, Pr, and Nd) using the flux-assisted boron–chalcogen mixture method14Synergistic Machine Learning Guided Discovery of ABa 3 (BSe 3 ) 2 X (A = Rb, Cs; X = Cl, Br, I): A Promising Family as Property‐Balanced IR Functional Materials10Crystal Growth of Quaternary Rare Earth Selenosilicates by Using the Flux-Assisted Boron Chalcogen Mixture Method: Investigation of Their Magnetic and Optical Properties10Structural Investigation of Six Quinary Sulfides Synthesized via the Flux-Assisted Boron-Chalcogen Mixture (BCM) Method: Eu2+ Containing Members of the RE3MTQ7 (M and T = Transition or Main Group Metals, Q = Chalcogens) Family8Tailoring ordered structures with distorted [TeO 3 ] and aligned [ScO 6 ] motifs for balanced nonlinear optical properties in rare-earth tellurate crystals5Lanthanide Cation Size-Driven Trigonal-to-Monoclinic-to-Orthorhombic Transition in a Series of Quaternary Zirconium Molybdates: Crystal Growth, Optical, and Magnetic Investigation4Flux-Assisted Growth and Characterization of Noncentrosymmetric Quaternary Rare-Earth Selenides CsRESiSe 4 (RE = La, Pr, Nd, Sm, Gd, Tb): Crystal Structure, Magnetism, and Theoretical Studies0Synthesis and Characterization of RE 3 LiSiSe 7 (RE = La–Nd, Sm, Gd, and Tb) Exhibiting Enhanced Nonlinear Optical (NLO) Properties03 d Transition Metal Contribution to the Magnetic Behavior of Chiral Y6 M x Si2S14 and Tb6CoSi2S140

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  1. An overview of Mg-based IR nonlinear optical materials

    Inorganic Chemistry Frontiers · 2023-01-01

    Jiaxiang Zhang, Mao‐Yin Ran, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  2. Boron Chalcogen Mixture Method-Assisted Alkali Halide Flux Crystal Growth of an Extensive Family of Quaternary Rare Earth Transition-Metal Thiosilicates: Investigation of Their Structures and Magnetic Properties

    Inorganic Chemistry · 2023-10-23

    Adam A. King, Logan S. Breton, Gregory W. Morrison, Mark D. Smith, Hans‐Conrad zur Loye

    Read original paper ↗ ·

  3. Li13YGe4O16: A Mid-infrared Rare-Earth Germanate Nonlinear Optical Crystal Featuring a Broad Transmission Range and an Enlarged Band Gap

    Inorganic Chemistry · 2024-02-15

    Jinmiao Jiao, Conggang Li, Yuheng She, Haiyan Shi, Wenhao Di, Ning Ye, Zhanggui Hu, Yicheng Wu

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  4. Crystal Growth of Quaternary AkRE 2 Si 2 S 8 (Ak = Ca and Sr; RE = La–Tb) Thiosilicates Using Flux-Assisted Boron Chalcogen Mixture Method: Exploring X-ray Scintillation, Luminescence, and Magnetic Properties

    Inorganic Chemistry · 2024-06-29

    Gopabandhu Panigrahi, Anna A. Berseneva, Gregory W. Morrison, Adam A. King, Robin L. Conner, Luiz Gustavo Jacobsohn, Hans‐Conrad zur Loye

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  5. Rare Bird: U+5 in Uranium Chalcogenides

    Chemistry of Materials · 2024-08-12

    Anna A. Berseneva, Vladislav V. Klepov, Habiba Binte Kashem, Alevtina A. Maksimova, Gregory W. Morrison, Joshua Wright, Joseph C. Schaeperkoetter, Scott T. Misture, Hans‐Conrad zur Loye

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  6. Synthesis, Optical, and Magnetic Properties of the Mixed Chalcogenide Semiconductor Series Eu(II)2SiSexS4-x, Prepared via the Flux-Assisted Boron Chalcogen Mixture Method

    Inorganic Chemistry · 2024-12-04

    Gopabandhu Panigrahi, Gregory W. Morrison, Mark D. Smith, Hans‐Conrad zur Loye

    Read original paper ↗ ·

  7. Synthesis of a series of rare-earth-based multi-anion chalcogenide iodides RE 3 Si 2 Se x S 8− x I (RE = La, Ce, Pr, and Nd) using the flux-assisted boron–chalcogen mixture method

    Dalton Transactions · 2025-01-01

    Gopabandhu Panigrahi, Habiba Binte Kashem, Gregory W. Morrison, Hans‐Conrad zur Loye

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  8. Synergistic Machine Learning Guided Discovery of ABa 3 (BSe 3 ) 2 X (A = Rb, Cs; X = Cl, Br, I): A Promising Family as Property‐Balanced IR Functional Materials

    Advanced Science · 2025-04-26

    Yihan Yun, Mengfan Wu, Zhihua Yang, Guangmao Li, Shilie Pan

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  9. Crystal Growth of Quaternary Rare Earth Selenosilicates by Using the Flux-Assisted Boron Chalcogen Mixture Method: Investigation of Their Magnetic and Optical Properties

    Crystal Growth & Design · 2025-05-20

    Habiba Binte Kashem, Gopabandhu Panigrahi, Gregory W. Morrison, Eric A. Gabilondo, P. Shiv Halasyamani, Pandu Wisesa, Theodore M. Besmann, Hans‐Conrad zur Loye

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  10. Structural Investigation of Six Quinary Sulfides Synthesized via the Flux-Assisted Boron-Chalcogen Mixture (BCM) Method: Eu2+ Containing Members of the RE3MTQ7 (M and T = Transition or Main Group Metals, Q = Chalcogens) Family

    Inorganic Chemistry · 2025-09-08

    Habiba Binte Kashem, Hunter B. Tisdale, Hans‐Conrad zur Loye

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  11. Tailoring ordered structures with distorted [TeO 3 ] and aligned [ScO 6 ] motifs for balanced nonlinear optical properties in rare-earth tellurate crystals

    Chemical Science · 2025-11-18

    Xiaoxu Wang, Tinghui Zhang, Huijian Zhao, Ning Jia, Hongjun Liu, Ning Ye, Zhanggui Hu, Conggang Li

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  12. Lanthanide Cation Size-Driven Trigonal-to-Monoclinic-to-Orthorhombic Transition in a Series of Quaternary Zirconium Molybdates: Crystal Growth, Optical, and Magnetic Investigation

    Crystal Growth & Design · 2026-01-19

    Abdullah Al Muhit, Habiba Binte Kashem, Buddhima K. P. Maldeni Kankanamalage, Gregory W. Morrison, Natalia B. Shustova, Hans‐Conrad zur Loye

    Read original paper ↗ ·

  13. Flux-Assisted Growth and Characterization of Noncentrosymmetric Quaternary Rare-Earth Selenides CsRESiSe 4 (RE = La, Pr, Nd, Sm, Gd, Tb): Crystal Structure, Magnetism, and Theoretical Studies

    Inorganic Chemistry · 2026-06-30

    Gopabandhu Panigrahi, Rachita Panigrahi, P. S. S. Dabare, Hope Eden Catalano, Hans‐Conrad zur Loye

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  14. Synthesis and Characterization of RE 3 LiSiSe 7 (RE = La–Nd, Sm, Gd, and Tb) Exhibiting Enhanced Nonlinear Optical (NLO) Properties

    Inorganic Chemistry · 2026-07-01

    Habiba Binte Kashem, Eric A. Gabilondo, Abdullah Al Muhit, Hope Eden Catalano, P. Shiv Halasyamani, Hans‐Conrad zur Loye

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  15. 3 d Transition Metal Contribution to the Magnetic Behavior of Chiral Y6 M x Si2S14 and Tb6CoSi2S14

    Chemistry of Materials · 2026-10-06

    Eranga H. Gamage, Ernesto Soto, Vasile Ovidiu Garlea, Nethmi W. Hewage, Feng Ye, Mohd Anas, Govind Sasi Kumar, Parashu Ram Kharel, Michael Shatruk, Yaroslav Mudryk, Georgiy Akopov, Kirill A. Kovnir

    Read original paper ↗ ·
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