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RESEARCH PAPER · RSC Advances · 2015

Synthesis, structure, magnetic and photoelectric properties of Ln 3 M 0.5 M′Se 7 (Ln = La, Ce, Sm; M = Fe, Mn; M′ = Si, Ge) and La 3 MnGaSe 7

Jianqiao He, Zhe Wang, Xian Zhang, Cheng Ye, Yu Gong, Xiaofang Lai, Chong Zheng, Jianhua Lin, Fuqiang Huang

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Synthesis, structure, magnetic and photoelectric properties of Ln 3 M 0.5 M′Se 7 (Ln = La, Ce, Sm; M = Fe, Mn; M′ = Si, Ge) and La 3 MnGaSe 7OriginalBaGa 2 SnSe 6 : a new phase-matchable IR nonlinear optical material with strong second harmonic generation response58ChemInform Abstract: Synthesis, Structure, Magnetic and Photoelectric Properties of Ln3M0.5M′Se7 (Ln: La, Ce, Sm; M: Fe, Mn; M′: Si, Ge) and La3MnGaSe7.0Quaternary rare-earth sulfides RE 3 M 0.5 GeS 7 (RE=La–Nd, Sm; M=Co, Ni) and Y 3 Pd 0.5 SiS 725Quaternary Chalcogenides La3Sn0.5InS7 and La3Sn0.5InSe73NaBaM III Q 3 (M III = Al, Ga; Q = S, Se): first quaternary chalcogenides with isolated edge-sharing (MIII2Q 6 ) 6− dimers8New quaternary chalcogenide Ba 4 HgAs 2 S 10 originating from the combination of linear [HgS 2 ] 2− and tetrahedral [AsS 4 ] 3− modules8STRUCTURE INVESTIGATION OF CHALCOGENIDES Ce0,5R1,5PbSi2S8 AND Pr1,5R0,5PbSi2S8 (R' – Tb, Y, Er)0Synthesis-enabled exploration of chiral and polar multivalent quaternary sulfides37Recent Developments on Molten Salt Synthesis of Inorganic Nanomaterials: A Review207Synthesis, structure, and magnetic properties of the quaternary oxysulfides Ln 5V3O7S6 (Ln = La, Ce)1CRYSTAL STRUCTURE OF SULFIDES R3Co(Ni)0.5SiS7 (R – Ce, Pr)0Synthesis, Crystal Growth, Electronic Properties and Optical Properties of Y6IV2.5S14 (IV=Si, Ge)9Ba6(CuxZy)Sn4S16 (Z = Mg, Mn, Zn, Cd, In, Bi, Sn): High Chemical Flexibility Resulting in Good Nonlinear-Optical Properties12Ti0.85Eu3SiS7: The rare-earth/Ti based quaternary sulfide containing two variable valence elements4New Quaternary Compounds R3Ni0.5SiS7 (R – Y, Sm, La) with the La3Mn0.5SiS7 Structure1Melilite oxychalcogenide Sr 2 FeGe 2 OS 6 : a phase-matching IR nonlinear optical material realized by isomorphous substitution30Y3Fe0.5SiSe7: A new cation-deficient quaternary mixed transition metal chalcogenide with extremely low thermal conductivity3Crystal Structures and Property Measurements of Rare Earth Magnesium Thiosilicates Synthesized via Flux Crystal Growth Utilizing the Boron Chalcogen Mixture (BCM) Method15Eu 2 MGe 2 OS 6 (M = Mn, Fe, Co): Three Melilite-Type Rare-Earth Oxythiogermanates Exhibiting Balanced Nonlinear-Optical Behaviors21Boron Chalcogen Mixture Method-Assisted Alkali Halide Flux Crystal Growth of an Extensive Family of Quaternary Rare Earth Transition-Metal Thiosilicates: Investigation of Their Structures and Magnetic Properties9High-throughput screening of stable sulfide semiconductors for solar cell conversion3Advanced Computational Insights Into the Optical, Electronic, and Thermoelectric Characteristics of Novel Rare‐Earth Ternary Chalcogenides0Synthesis of a series of rare-earth-based multi-anion chalcogenide iodides RE 3 Si 2 Se x S 8− x I (RE = La, Ce, Pr, and Nd) using the flux-assisted boron–chalcogen mixture method14Synthesis, Crystal, and Electronic Structures, and Second Harmonic Generation of La4Ge3S121Non-centrosymmetric Y3FeGaSe7 and Y3Mn0·5SiSe7 with extremely low thermal conductivities2Noncentrosymmetric Mixed Chalcogenide Semiconductors La3Ga1.67(S1–xSex)71Crystal Growth of Quaternary Rare Earth Selenosilicates by Using the Flux-Assisted Boron Chalcogen Mixture Method: Investigation of Their Magnetic and Optical Properties10Structural Investigation of Six Quinary Sulfides Synthesized via the Flux-Assisted Boron-Chalcogen Mixture (BCM) Method: Eu2+ Containing Members of the RE3MTQ7 (M and T = Transition or Main Group Metals, Q = Chalcogens) Family8Flux-Assisted Boron Chalcogen Mixture (BCM) Method for Synthesizing Mixed Chalcogenide Semiconductors (AkRE 2 Si 2 Se x S 8– x and CaRE 2 Si 2 Se 8 ) ( Ak = Ca and Sr; RE = La, Ce, Pr, Nd, and Sm): Investigation of Their Magnetic and Optical Properties0K 3 Mg 2 [K 6 MgCl 3 ][Ga 20 S 36 ]: A Diamond-like Framework Based on Mixed-Type Supertetrahedra for Excellent Nonlinear Optical Property1Flux-Assisted Growth and Characterization of Noncentrosymmetric Quaternary Rare-Earth Selenides CsRESiSe 4 (RE = La, Pr, Nd, Sm, Gd, Tb): Crystal Structure, Magnetism, and Theoretical Studies0Optical, Photoelectric, and Electrocatalytic Properties of Quaternary Sulfides RE 3 M 1– x SnS 7 ( RE = La–Nd; M = Ti–Cu, Cd)1Crystal Chemistry, Optical Properties and Electronic Structure of R3Fe0.1Ga1.6S7 (R – La, Ce, Pr, Nd, Tb) Sulfides03 d Transition Metal Contribution to the Magnetic Behavior of Chiral Y6 M x Si2S14 and Tb6CoSi2S140

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  1. BaGa 2 SnSe 6 : a new phase-matchable IR nonlinear optical material with strong second harmonic generation response

    Journal of Materials Chemistry C · 2015-01-01

    Xiaoshuang Li, Chao Li, Pifu Gong, Zheshuai Lin, Jiyong Yao, Yicheng Wu

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  2. ChemInform Abstract: Synthesis, Structure, Magnetic and Photoelectric Properties of Ln3M0.5M′Se7 (Ln: La, Ce, Sm; M: Fe, Mn; M′: Si, Ge) and La3MnGaSe7.

    ChemInform · 2015-08-01

    Jianqiao He, Zhe Wang, Xian Zhang, Cheng Ye, Yu Gong, Xiaofang Lai, Chong Zheng, Jianhua Lin, Fuqiang Huang

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  3. Quaternary rare-earth sulfides RE 3 M 0.5 GeS 7 (RE=La–Nd, Sm; M=Co, Ni) and Y 3 Pd 0.5 SiS 7

    Journal of Solid State Chemistry · 2017-03-07

    Abishek K. Iyer, Wenlong Yin, Emma J. Lee, Xinsong Lin, Arthur Mar

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  4. Quaternary Chalcogenides La3Sn0.5InS7 and La3Sn0.5InSe7

    Zeitschrift für anorganische und allgemeine Chemie · 2017-09-01

    Abishek K. Iyer, Wenlong Yin, Emma J. Lee, Guy M. Bernard, Vladimir K. Michaelis, Arthur Mar

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  5. NaBaM III Q 3 (M III = Al, Ga; Q = S, Se): first quaternary chalcogenides with isolated edge-sharing (MIII2Q 6 ) 6− dimers

    Dalton Transactions · 2018-01-01

    Ailijiang Abudurusuli, Kui Wu, Yilimiranmu Rouzhahong, Zhihua Yang, Shilie Pan

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  6. New quaternary chalcogenide Ba 4 HgAs 2 S 10 originating from the combination of linear [HgS 2 ] 2− and tetrahedral [AsS 4 ] 3− modules

    Dalton Transactions · 2020-01-01

    Wenhao Xing, Naizheng Wang, Zhuang Li, Wenhao Liu, Jian Tang, Wenlong Yin, Zheshuai Lin, Bin Kang, Jiyong Yao

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  7. STRUCTURE INVESTIGATION OF CHALCOGENIDES Ce0,5R1,5PbSi2S8 AND Pr1,5R0,5PbSi2S8 (R' – Tb, Y, Er)

    Scientific Bulletin of the Uzhhorod University Series «Chemistry» · 2020-06-25

    Kh.O. Melnychuk, Олександр Вікторович Смітюх, О.V. Marchuk, N. V. Mazur, V.О. Yukhymchuk

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  8. Synthesis-enabled exploration of chiral and polar multivalent quaternary sulfides

    Chemical Science · 2021-01-01

    Georgiy Akopov, Nethmi W. Hewage, Philip Yox, Gayatri Viswanathan, Shannon Lee, Liam Hulsebosch, Sarah D. Cady, Alexander L. Paterson, Frédéric A. Perras, Wenqian Xu, Kui Wu, Yaroslav Mudryk, Kirill A. Kovnir

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  9. Recent Developments on Molten Salt Synthesis of Inorganic Nanomaterials: A Review

    The Journal of Physical Chemistry C · 2021-02-23

    Santosh K. Gupta, Yuanbing Mao

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  10. Synthesis, structure, and magnetic properties of the quaternary oxysulfides Ln 5V3O7S6 (Ln = La, Ce)

    Zeitschrift für Naturforschung B · 2021-09-21

    Chong Zheng, Roald Hoffmann, Timothy S. Perkins, Frank Calvagna, Roxanna Fotovat, Crystal Ferels, Alyssa Mohr, Reinhard Karl Kremer, Jürgen Köhler, Arndt Simon, Kejun Bu, Fuqiang Huang

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  11. CRYSTAL STRUCTURE OF SULFIDES R3Co(Ni)0.5SiS7 (R – Ce, Pr)

    Proceedings of the Shevchenko Scientific Society Series Сhemical sciences · 2021-09-30

    О.V. Marchuk, Олександр Вікторович Смітюх

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  12. Synthesis, Crystal Growth, Electronic Properties and Optical Properties of Y6IV2.5S14 (IV=Si, Ge)

    Zeitschrift für anorganische und allgemeine Chemie · 2021-12-06

    Zhengyang Ye, Stefano Bardelli, Kui Wu, Arka Sarkar, Andrew Swindle, Jian Wang

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  13. Ba6(CuxZy)Sn4S16 (Z = Mg, Mn, Zn, Cd, In, Bi, Sn): High Chemical Flexibility Resulting in Good Nonlinear-Optical Properties

    Inorganic Chemistry · 2022-01-26

    Bingheng Ji, Kui Wu, Yunhua Chen, Fei Wang, Aaron J. Rossini, Bingbing Zhang, Jian Wang

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  14. Ti0.85Eu3SiS7: The rare-earth/Ti based quaternary sulfide containing two variable valence elements

    Journal of Solid State Chemistry · 2022-03-19

    Sihan Yang, Xiaohui Li, Xiao Fen Huang, Wenlong Liu, Sheng‐Ping Guo

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  15. New Quaternary Compounds R3Ni0.5SiS7 (R – Y, Sm, La) with the La3Mn0.5SiS7 Structure

    Physics and Chemistry of Solid State · 2022-11-02

    Олександр Вікторович Смітюх, О.V. Marchuk

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  16. Melilite oxychalcogenide Sr 2 FeGe 2 OS 6 : a phase-matching IR nonlinear optical material realized by isomorphous substitution

    Inorganic Chemistry Frontiers · 2023-01-01

    Hedi Yang, Shenghua Zhou, Mao‐Yin Ran, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  17. Y3Fe0.5SiSe7: A new cation-deficient quaternary mixed transition metal chalcogenide with extremely low thermal conductivity

    Solid State Sciences · 2023-02-21

    Gopabandhu Panigrahi, Sweta Yadav, Subhendu Jana, Muthukumaran Sundaramoorthy, S. Arumugam, Manish K. Niranjan, Jai Prakash

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  18. Crystal Structures and Property Measurements of Rare Earth Magnesium Thiosilicates Synthesized via Flux Crystal Growth Utilizing the Boron Chalcogen Mixture (BCM) Method

    Inorganic Chemistry · 2023-05-03

    Adam A. King, Logan S. Breton, Gregory W. Morrison, Mark D. Smith, Mingli Liang, P. Shiv Halasyamani, Hans‐Conrad zur Loye

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  19. Eu 2 MGe 2 OS 6 (M = Mn, Fe, Co): Three Melilite-Type Rare-Earth Oxythiogermanates Exhibiting Balanced Nonlinear-Optical Behaviors

    Inorganic Chemistry · 2023-09-28

    Nan Zhang, Xiao Fen Huang, Wen‐Dong Yao, Yao Chen, Zheng-Rui Pan, Bingxuan Li, Wenlong Liu, Sheng‐Ping Guo

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  20. Boron Chalcogen Mixture Method-Assisted Alkali Halide Flux Crystal Growth of an Extensive Family of Quaternary Rare Earth Transition-Metal Thiosilicates: Investigation of Their Structures and Magnetic Properties

    Inorganic Chemistry · 2023-10-23

    Adam A. King, Logan S. Breton, Gregory W. Morrison, Mark D. Smith, Hans‐Conrad zur Loye

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  21. High-throughput screening of stable sulfide semiconductors for solar cell conversion

    Materials Advances · 2024-01-01

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  22. Advanced Computational Insights Into the Optical, Electronic, and Thermoelectric Characteristics of Novel Rare‐Earth Ternary Chalcogenides

    International Journal of Quantum Chemistry · 2024-09-20

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  23. Synthesis of a series of rare-earth-based multi-anion chalcogenide iodides RE 3 Si 2 Se x S 8− x I (RE = La, Ce, Pr, and Nd) using the flux-assisted boron–chalcogen mixture method

    Dalton Transactions · 2025-01-01

    Gopabandhu Panigrahi, Habiba Binte Kashem, Gregory W. Morrison, Hans‐Conrad zur Loye

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  24. Synthesis, Crystal, and Electronic Structures, and Second Harmonic Generation of La4Ge3S12

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    Hiroya Ohtsuki, Suguru Nakata, Yu Yamane, Ryunosuke Takahashi, Koichi Kusakabe, Hiroki Wadati

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  25. Non-centrosymmetric Y3FeGaSe7 and Y3Mn0·5SiSe7 with extremely low thermal conductivities

    Journal of Physics and Chemistry of Solids · 2025-04-19

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  26. Noncentrosymmetric Mixed Chalcogenide Semiconductors La3Ga1.67(S1–xSex)7

    Inorganic Chemistry · 2025-05-07

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  27. Crystal Growth of Quaternary Rare Earth Selenosilicates by Using the Flux-Assisted Boron Chalcogen Mixture Method: Investigation of Their Magnetic and Optical Properties

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  28. Structural Investigation of Six Quinary Sulfides Synthesized via the Flux-Assisted Boron-Chalcogen Mixture (BCM) Method: Eu2+ Containing Members of the RE3MTQ7 (M and T = Transition or Main Group Metals, Q = Chalcogens) Family

    Inorganic Chemistry · 2025-09-08

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  29. Flux-Assisted Boron Chalcogen Mixture (BCM) Method for Synthesizing Mixed Chalcogenide Semiconductors (AkRE 2 Si 2 Se x S 8– x and CaRE 2 Si 2 Se 8 ) ( Ak = Ca and Sr; RE = La, Ce, Pr, Nd, and Sm): Investigation of Their Magnetic and Optical Properties

    Inorganic Chemistry · 2025-11-05

    Gopabandhu Panigrahi, Manish Kumar, Gregory W. Morrison, Christopher A. Sutton, Hans‐Conrad zur Loye

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  30. K 3 Mg 2 [K 6 MgCl 3 ][Ga 20 S 36 ]: A Diamond-like Framework Based on Mixed-Type Supertetrahedra for Excellent Nonlinear Optical Property

    Chemistry of Materials · 2026-04-22

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  31. Flux-Assisted Growth and Characterization of Noncentrosymmetric Quaternary Rare-Earth Selenides CsRESiSe 4 (RE = La, Pr, Nd, Sm, Gd, Tb): Crystal Structure, Magnetism, and Theoretical Studies

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  32. Optical, Photoelectric, and Electrocatalytic Properties of Quaternary Sulfides RE 3 M 1– x SnS 7 ( RE = La–Nd; M = Ti–Cu, Cd)

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  33. Crystal Chemistry, Optical Properties and Electronic Structure of R3Fe0.1Ga1.6S7 (R – La, Ce, Pr, Nd, Tb) Sulfides

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  34. 3 d Transition Metal Contribution to the Magnetic Behavior of Chiral Y6 M x Si2S14 and Tb6CoSi2S14

    Chemistry of Materials · 2026-10-06

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