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RESEARCH PAPER · Coordination Chemistry Reviews · 2016

Synthesis of heterometallic chalcogenides containing lanthanide and group 13–15 metal elements

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Synthesis of heterometallic chalcogenides containing lanthanide and group 13–15 metal elementsOriginalBaCdSnS 4 and Ba 3 CdSn 2 S 8 : syntheses, structures, and non-linear optical and photoluminescence properties97Na 9 Sb(Ge 2 Q 6 ) 2 (Q = S, Se): two new antimony( iii ) quaternary chalcogenides with ethane-like [Ge 2 Q 6 ] 6− ligands12Quaternary chalcogenides BaRE 2 In 2 Ch 7 (RE = La–Nd; Ch = S, Se) containing InCh 5 trigonal bipyramids12Solvothermal Syntheses and Characterization of a Series of New Selenidostannates with Lanthanide Complexes as Counterions5Synthesis, Crystal Structures and Properties of a Series of Lanthanide Adipates [Ln 2(ad)3(H2O)4] (Ln = Y3+, Ho3+, Er3+, Tm3+)7Incorporation of manganese complexes into thioarsenates(V), displaying a new structural motif5Main group metal chalcogenidometalates with transition metal complexes of 1,10-phenanthroline and 2,2′-bipyridine59A unique dysprosium selenoarsenate( iii ) exhibiting a photocurrent response and slow magnetic relaxation behavior13A novel 2-D Mn selenidostannate( iv ) incorporating high-nuclear Mn clusters with spin canting behavior8Flexibility and lability of a phenyl ligand in hetero-organometallic 3d metal–Sn( iv ) compounds and their catalytic activity in Baeyer–Villiger oxidation of cyclohexanone22Na 6 Si 3 S 8 O: the first example of a sulfide silicate exhibiting unusual tri-polymerized [Si 3 S 8 O] 6− units without S–O bonds8Structural transformation of selenidostannates from 1D to 0D and 2D via a stepwise amine-templated assembly strategy4Syntheses, structures and properties of a series of new lanthanide chalcoarsenates(III) containing crown-shaped [As3Q6]3− (Q = S, Se) clusters11Lanthanide(III) complexes with μ-SnSe4 and μ-Sn2Se6 linkers: solvothermal syntheses and properties of new Ln(III) selenidostannates decorated with linear polyamine3A Series of Dimeric Selenidogermanates with Lanthanide Complexes of Multidentate Chelating Amines3Catalytic N−N bond cleavage of hydrazine by thiolate-bridged iron-ruthenium heteronuclear complexes10Solvothermal Syntheses, Crystal Structures and Optical Properties of New Members of Transition Metal Complexes Based on Hexaselenidobistannate Ligand4Synthesis and characterization of two lead-containing metal chalcogenides: Ba5Pb2Sn3S13 and Ba6PbSn3Se137Synthesis, density functional theory calculations and luminescence of lanthanide complexes with 2,6‐bis[(3‐methoxybenzylidene)hydrazinocarbonyl] pyridine Schiff base ligand16Hydrothermal Syntheses and Crystal Structure of a New Organic Hybrid Holmium–Germanate Oxo-Cluster5Understanding the polychalcogenides as building blocks to solid state materials: Speciation of polychalcogenides in solutions10A series of new hybrid selenidostannates with metal complexes prepared in alkylol amines13Facile synthesis of highly monodisperse EuSe nanocubes with size-dependent optical/magnetic properties and their electrochemiluminescence performance12Hydrazine-solvothermal methods to synthesize polymeric thioarsenates from one-dimensional chains to a three-dimensional framework8NaBaM III Q 3 (M III = Al, Ga; Q = S, Se): first quaternary chalcogenides with isolated edge-sharing (MIII2Q 6 ) 6− dimers8Remarkable multimember-ring configurations in a new family of Na 7 M II Sb 5 S 12 (M II = Zn, Cd, Hg) exhibiting various three-dimensional tunnel structures25Structural insights into T 2 -cluster-containing chalcogenides with vertex-, edge- and face-sharing connection modes of NaQ 6 ligands: Na 3 ZnM III Q 4 (M III = In, Ga; Q = S, Se)13The structures, water stabilities and photoluminescence properties of two types of iodocuprate( i )-based hybrids35A Series of Lanthanide Selenidogermanates: The First Coexistence of Three Types of Selenidogermanate Units in the Same Architecture10A new 3-D cuprous thiogermanate with rare 3-D [Cu-S-Cu]n network7Two new 1-D lanthanide selenidogermanates with the [Ge2Se6]4− anion as a bridging ligand to a lanthanide complex cation1Supertetrahedral Cluster-Based In–Se Open Frameworks with Unique Polyselenide Ion as Linker9Synthesis, Crystal Structures, Optical Properties and Theoretical Calculations of Two Metal Chalcogenides Ba2AlSbS5 and Ba2GaBiSe59A Series of Lanthanide Chalcogenidogermanates Displaying Two Types of 1-D Polymeric Chains4Introduction of selenium and tellurium into reaction systems8Synthesis and characterization of three-coordinated Tin(II) chalcogenide compounds from chlorostannylene supported by β-diketiminato ligand14A series of new hybrid chalcogenogermanates: the rare examples of chalcogenogermanates combined with trivalent vanadium complexes6A series of new vanadium( iii ) chalcogenido-antimonates: an unusual seven-coordinate nitro-selenidovanadium( iii ) complex8New layered chromium chalcogenides CsLiCrSe 2 , RbLiCrS 2 and CsLiCrS 2 : structures and properties9Tris(ethylenediamine)nickel(II) thio-hydroxogermanate monohydrate: Synthesis, crystal structure, 1H NMR, EPR, optical and magnetic properties18Neodymium–Dysprosium and Neodymium–Ytterbium Iodide–Sulfide–Nitride Clusters: Synthesis and Luminescence3Solvothermal syntheses, characterizations and semiconducting properties of four quaternary thioargentates Ba2AgInS4, Ba3Ag2Sn2S8, BaAg2MS4 (M = Sn, Ge)21Recent advances in heterometallic polyoxotitanium clusters81Investigation of structural, mechanical, dynamic, electronic and optical properties of seleno-germanates A 2 GeSe 4 (A = Mg, Ca and γ -Sr) from first principles7Synthesis and crystal structure of catena-poly[[bis[(2,2′;6′,2′′-terpyridine)manganese(II)]-μ4-pentathiodiantimonato] tetrahydrate] showing a 1D MnSbS network5Synthesis and crystal structure of (1,4,7,10-tetraazacyclododecane-κ4 N)(tetrasulfido-κ2 S 1,S 4)manganese(II)2A Coordination Polymer based on Interconnection of Thioantimonate(III) and [Mn(terpy)]2+ Complexes: Synthesis, Crystal Structure, and Properties of {[(Mn(terpy))2Sb4S8]·0.5H2O}n4Study of the Possibility of Using Salt Metathesis Reactions for the Synthesis of the Neodymium and Samarium β-Diketiminate Chalcogenide Complexes. Unexpected Reduction of Sm(III) to Sm(II)11Unique Two-Dimensional Indium Telluride Templated by a Rare Wheel-Shaped Heterobimetallic Mn/In Cluster4Heteroleptic Samarium(III) Chalcogenide Complexes: Opportunities for Giant Exchange Coupling in Bridging σ- and π-Radical Lanthanide Dichalcogenides22Syntheses and luminescent properties of a series of new lanthanide azelates13A pillar-layered chalcogenide framework assembled by [Mn 5 S 12 N 12 ] n layers and [Sb 2 S 5 ] inorganic pillars6Facile syntheses of silver thioantimonates exhibiting second-harmonic generation responses and large birefringence18Solvothermal Syntheses, Structures, and Characterizations of Four Thioarsenates A 7Cu 4As 3S 13 (A = Rb, Cs), Rb 2Cu 5As 3S 8, and CsCu 2AsS 30Temperature controlling valance changes of crystalline thioarsenates and thioantimonates21A Copper(I)-Thioarsenate(III) Inorganic Framework Directed by [Ni(en)3]2+13The chain-shaped coordination polymers based on the bowl-like Ln18Ni24(23.5) clusters exhibiting favorable low-field magnetocaloric effect17Multinary Thioantimonates(III) with d10 Transition Metals: Ionothermal Synthesis, Crystal Structures and Physical Properties0Solvothermal Syntheses of Three-Dimensional Open-Framework Thioantimonates Displaying Nonlinear Optical Responses5An Organic Hybrid Indium–Telluride Incorporating Binuclear Complexes [In2(ea)4]2+ with a Bridging Oxygen Donor1The first selenidostannate directed by low-valent vanadium(II) complex: Photocurrent response and magnetic properties8Two Organic Hybrid Manganese Selenoarsenates: The Discovery of One-Dimensional Low-Valent Selenoarsenate(II)10Stable 3D neutral gallium thioantimonate frameworks decorated with transition metal complexes for a tunable photocatalytic hydrogen evolution9MII···Cl Interaction Supported Heterometallic {NiIISnII}{SnIV} and {NiIISnII}{SnII} Complex Salts: Possibility of Ion-Pair-Assisted Tetrel Bonds7Lanthanide thioborates, an emerging class of nonlinear optical materials, efficiently synthesized using the boron–chalcogen mixture method23Synthesis and crystal structure of poly[[di-μ3-tetrathioantimonato-tris[(cyclam)cobalt(II)]] acetonitrile disolvate dihydrate] (cyclam = 1,4,8,11-tetraazacyclotetradecane)2Solvothermal syntheses, characterizations and photocatalytic properties of two copper-rich thiostannates4A series of new lanthanide benzoates: Syntheses, crystal structures, and luminescent properties17Lanthanide Iodide Nitride Sulfide Clusters0Solvothermal syntheses, structures, and characterizations of four thioarsenates A7Cu4As3S13 (A = Rb, Cs), Rb2Cu5As3S8, and CsCu2AsS35Crystal structure of μ3-tetrathioantimonato-tris[(cyclam)zinc(II)] tetrathioantimonate acetonitrile disolvate dihydrate showing Zn disorder over the cyclam ring planes (cyclam = 1,4,8,11-tetraazacyclotetradecane)2Strong Photocurrent Response of Selenoarsenates With Different Transition Metal Complexes as Structure-Directing Agents3A series of new luminescent lanthanide naphthalates: The discovery of rare multi−responsive sensor for acetone, Fe3+, CrO42− and Cr2O72−16Solvothermal synthesis, crystal structure and properties of selenidostannate containing zero-dimensional cluster structure0Insights of metal 8-hydroxylquinolinol complexes as the potential anticancer drugs31Directed Dehydration of Na4Sn2S6 ⋅ 5H2O Generates the New Compound Na4Sn2S6: Crystal Structure and Selected Properties6One-Dimensional Selenidostannates Based on an Infrequent Tetrameric Cluster [Sn4Se12] Exhibiting Electro-Catalytic Properties8Solvothermal syntheses and characterization of one-dimensional (1,4-dabH2)Cu1.72Ag0.28SnSe4 (1) and (1,4-dabH2)Cu2SnSe4 (2)0Alkali halide flux synthesis, crystal structure, and photoelectric response of quaternary thiosilicates K 3 Ga 3 Si 7 S 20 and K 2 ZnSi 3 S 81Rare-earth chalcogenidotetrachloride clusters (RE3ECl4, RE = Dy, Gd, Y; E = S, Se, Te): syntheses and materials properties4Two Electrocatalytic Selenoarsenates with Manganese Complex Cations as Counterions6A Luminescent Sensing Experiment of Cage-like Europium-Germanate Oxo Cluster for Advanced Undergraduate Students2Three new organic hybrid lanthanide antimony selenides with photocurrent response and photocatalytic properties4Synthesis, crystal structure and properties of μ-tetrathioantimonato-bis[(cyclam)zinc(II)] perchlorate 0.8-hydrate0Solvothermal syntheses, structures and properties of quaternary alkaline earth metal sulfides BaCu6Ge2S8 and BaCuAsS33An Infrequent 1D Manganese–Tin Selenide with Bifunctional Catalytic Properties3Two structural types of lanthanide MOFs based on long-chain flexible sebacic acid: synthesis, luminescence, sensing, and magnetic properties4Structure‐Property Relationship of Heterometallic Coordination Systems Based on Lanthanides/Pincer Ligands1The hitherto-unknown coexistence of different types of luminescent lanthanide nicotinates: the development of new bi-functional sensor for uric acid and aniline detection0New members of the lanthanide titanium cluster family: Janus nanoclusters and their applications in optical imaging and photodynamic therapy2Solvothermal Syntheses, Characterization, and Properties of Five Quaternary Thioarsenates and Thioantimonates0A series of new lanthanide 2,2′-bipyridine-4,4′-dicarboxylates with free pyridyl sites: The discovery of double-responsive sensor for Cu2+ and Cr2O72–0Structural, Polymorph and Property Investigations of Realgar for Undergraduate Education0

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  1. BaCdSnS 4 and Ba 3 CdSn 2 S 8 : syntheses, structures, and non-linear optical and photoluminescence properties

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  2. Na 9 Sb(Ge 2 Q 6 ) 2 (Q = S, Se): two new antimony( iii ) quaternary chalcogenides with ethane-like [Ge 2 Q 6 ] 6− ligands

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  3. Quaternary chalcogenides BaRE 2 In 2 Ch 7 (RE = La–Nd; Ch = S, Se) containing InCh 5 trigonal bipyramids

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  4. Solvothermal Syntheses and Characterization of a Series of New Selenidostannates with Lanthanide Complexes as Counterions

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  5. Synthesis, Crystal Structures and Properties of a Series of Lanthanide Adipates [Ln 2(ad)3(H2O)4] (Ln = Y3+, Ho3+, Er3+, Tm3+)

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  6. Incorporation of manganese complexes into thioarsenates(V), displaying a new structural motif

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  7. Main group metal chalcogenidometalates with transition metal complexes of 1,10-phenanthroline and 2,2′-bipyridine

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  8. A unique dysprosium selenoarsenate( iii ) exhibiting a photocurrent response and slow magnetic relaxation behavior

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  9. A novel 2-D Mn selenidostannate( iv ) incorporating high-nuclear Mn clusters with spin canting behavior

    Dalton Transactions · 2017-01-01

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  10. Flexibility and lability of a phenyl ligand in hetero-organometallic 3d metal–Sn( iv ) compounds and their catalytic activity in Baeyer–Villiger oxidation of cyclohexanone

    Dalton Transactions · 2017-01-01

    Susanta Hazra, Nuno M. R. Martins, Maxim L. Kuznetsov, Maria Fátima C. Guedes da Silva, Armando J. L. Pombeiro

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  11. Na 6 Si 3 S 8 O: the first example of a sulfide silicate exhibiting unusual tri-polymerized [Si 3 S 8 O] 6− units without S–O bonds

    Dalton Transactions · 2017-01-01

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  12. Structural transformation of selenidostannates from 1D to 0D and 2D via a stepwise amine-templated assembly strategy

    Dalton Transactions · 2017-01-01

    Dandan Hu, Yingying Zhang, Huajun Yang, Jian Lin, Tao Wu

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  13. Syntheses, structures and properties of a series of new lanthanide chalcoarsenates(III) containing crown-shaped [As3Q6]3− (Q = S, Se) clusters

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  14. Lanthanide(III) complexes with μ-SnSe4 and μ-Sn2Se6 linkers: solvothermal syntheses and properties of new Ln(III) selenidostannates decorated with linear polyamine

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  15. A Series of Dimeric Selenidogermanates with Lanthanide Complexes of Multidentate Chelating Amines

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  16. Catalytic N−N bond cleavage of hydrazine by thiolate-bridged iron-ruthenium heteronuclear complexes

    Inorganic Chemistry Communications · 2017-06-16

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  17. Solvothermal Syntheses, Crystal Structures and Optical Properties of New Members of Transition Metal Complexes Based on Hexaselenidobistannate Ligand

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  18. Synthesis and characterization of two lead-containing metal chalcogenides: Ba5Pb2Sn3S13 and Ba6PbSn3Se13

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  19. Synthesis, density functional theory calculations and luminescence of lanthanide complexes with 2,6‐bis[(3‐methoxybenzylidene)hydrazinocarbonyl] pyridine Schiff base ligand

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  20. Hydrothermal Syntheses and Crystal Structure of a New Organic Hybrid Holmium–Germanate Oxo-Cluster

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  21. Understanding the polychalcogenides as building blocks to solid state materials: Speciation of polychalcogenides in solutions

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  22. A series of new hybrid selenidostannates with metal complexes prepared in alkylol amines

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  23. Facile synthesis of highly monodisperse EuSe nanocubes with size-dependent optical/magnetic properties and their electrochemiluminescence performance

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  24. Hydrazine-solvothermal methods to synthesize polymeric thioarsenates from one-dimensional chains to a three-dimensional framework

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  25. NaBaM III Q 3 (M III = Al, Ga; Q = S, Se): first quaternary chalcogenides with isolated edge-sharing (MIII2Q 6 ) 6− dimers

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  27. Structural insights into T 2 -cluster-containing chalcogenides with vertex-, edge- and face-sharing connection modes of NaQ 6 ligands: Na 3 ZnM III Q 4 (M III = In, Ga; Q = S, Se)

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  28. The structures, water stabilities and photoluminescence properties of two types of iodocuprate( i )-based hybrids

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  29. A Series of Lanthanide Selenidogermanates: The First Coexistence of Three Types of Selenidogermanate Units in the Same Architecture

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  30. A new 3-D cuprous thiogermanate with rare 3-D [Cu-S-Cu]n network

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  31. Two new 1-D lanthanide selenidogermanates with the [Ge2Se6]4− anion as a bridging ligand to a lanthanide complex cation

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  32. Supertetrahedral Cluster-Based In–Se Open Frameworks with Unique Polyselenide Ion as Linker

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  33. Synthesis, Crystal Structures, Optical Properties and Theoretical Calculations of Two Metal Chalcogenides Ba2AlSbS5 and Ba2GaBiSe5

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  34. A Series of Lanthanide Chalcogenidogermanates Displaying Two Types of 1-D Polymeric Chains

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  35. Introduction of selenium and tellurium into reaction systems

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  36. Synthesis and characterization of three-coordinated Tin(II) chalcogenide compounds from chlorostannylene supported by β-diketiminato ligand

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  37. A series of new hybrid chalcogenogermanates: the rare examples of chalcogenogermanates combined with trivalent vanadium complexes

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  38. A series of new vanadium( iii ) chalcogenido-antimonates: an unusual seven-coordinate nitro-selenidovanadium( iii ) complex

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  39. New layered chromium chalcogenides CsLiCrSe 2 , RbLiCrS 2 and CsLiCrS 2 : structures and properties

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  40. Tris(ethylenediamine)nickel(II) thio-hydroxogermanate monohydrate: Synthesis, crystal structure, 1H NMR, EPR, optical and magnetic properties

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  41. Neodymium–Dysprosium and Neodymium–Ytterbium Iodide–Sulfide–Nitride Clusters: Synthesis and Luminescence

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  42. Solvothermal syntheses, characterizations and semiconducting properties of four quaternary thioargentates Ba2AgInS4, Ba3Ag2Sn2S8, BaAg2MS4 (M = Sn, Ge)

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  43. Recent advances in heterometallic polyoxotitanium clusters

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  44. Investigation of structural, mechanical, dynamic, electronic and optical properties of seleno-germanates A 2 GeSe 4 (A = Mg, Ca and γ -Sr) from first principles

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  45. Synthesis and crystal structure of catena-poly[[bis[(2,2′;6′,2′′-terpyridine)manganese(II)]-μ4-pentathiodiantimonato] tetrahydrate] showing a 1D MnSbS network

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  46. Synthesis and crystal structure of (1,4,7,10-tetraazacyclododecane-κ4 N)(tetrasulfido-κ2 S 1,S 4)manganese(II)

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  47. A Coordination Polymer based on Interconnection of Thioantimonate(III) and [Mn(terpy)]2+ Complexes: Synthesis, Crystal Structure, and Properties of {[(Mn(terpy))2Sb4S8]·0.5H2O}n

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  48. Study of the Possibility of Using Salt Metathesis Reactions for the Synthesis of the Neodymium and Samarium β-Diketiminate Chalcogenide Complexes. Unexpected Reduction of Sm(III) to Sm(II)

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  49. Unique Two-Dimensional Indium Telluride Templated by a Rare Wheel-Shaped Heterobimetallic Mn/In Cluster

    Inorganic Chemistry · 2020-04-17

    Yao Fu, Jian Zhou, Hua-Hong Zou, Filipe A. Almeida Paz, Xing Liu, Lianshe Fu

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  50. Heteroleptic Samarium(III) Chalcogenide Complexes: Opportunities for Giant Exchange Coupling in Bridging σ- and π-Radical Lanthanide Dichalcogenides

    Inorganic Chemistry · 2020-05-18

    Conrad A. P. Goodwin, Benjamin L. L. Réant, Gianni F. Vettese, Jon G. C. Kragskow, Marcus J. Giansiracusa, Ida M. DiMucci, Kyle M. Lancaster, David Paul Mills, Stephen A. Sproules

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