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RESEARCH PAPER · Journal of Solid State Chemistry · 2003

Syntheses, structures, and second-harmonic generating properties in new quaternary tellurites: A2TeW3O12 (A=K, Rb, or Cs)

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Syntheses, structures, and second-harmonic generating properties in new quaternary tellurites: A2TeW3O12 (A=K, Rb, or Cs)OriginalFine particle formation using supercritical fluids189Synthesis, structure and characterization of two new antimony oxides–LaSb 3 O 9 and LaSb 5 O 12 : Formation of LaSb 5 O 12 from the reaction of LaSb 3 O 9 with Sb 2 O 318Asymmetric Cation Coordination in Oxide Materials: Influence of Lone-Pair Cations on the Intra-octahedral Distortion in d0 Transition Metals660Syntheses, Crystal Structures, and Properties of Six New Lanthanide(III) Transition Metal Tellurium(IV) Oxyhalides with Three Types of Structures37Synthesis, crystal structure and magnetic property of a new nickel selenite chloride: Ni5(SeO3)4Cl221Syntheses and Structural Characterization of New Mixed-Valent Tellurium Oxides, A4[Te56+Te34+]O23 (A = Rb and K)13[Cd2(Te6O13)][Cd2Cl6] and Cd7Cl8(Te7O17): Novel Tellurium(IV) Oxide Slabs and Unusual Cadmium Chloride Architectures35Na2Te3Mo3O16: A New Molybdenum Tellurite with Second-Harmonic Generating and Pyroelectric Properties232Syntheses, crystal structures and characterizations of BaZn(SeO3)2 and BaZn(TeO3)Cl222LiMoO3(IO3): A new molybdenyl iodate based on WO3-type sheets with large SHG response75Syntheses, Structural Studies, and Magnetic Properties of Divalent Cu and Co Selenites with Organic Constituents31Synthesis, Crystal Structure and Characterization of the Barium Zinc Tellurate Disilicate: Ba3Zn6[TeO6][Si2O7]210New Layered Uranium Phosphate Fluorides: Syntheses, Structures, Characterizations, and Ion-Exchange Properties of A(UO2)F(HPO4)·xH2O (A = Cs+, Rb+, K+; x = 0−1)88Synthesis, crystal and band structures, and optical properties of a new lanthanide–alkaline earth tellurium(IV) oxide: La2Ba(Te3O8)(TeO3)230Ni3(Mo2O8)(XO3) (X = Se, Te): The First Nickel Selenite- and Tellurite-Containing Mo4 Clusters36New Luminescent Solids in the Ln−W(Mo)−Te−O−(Cl) Systems35Two New Noncentrosymmetric Polar Oxides: Synthesis, Characterization, Second-Harmonic Generating, and Pyroelectric Measurements on TlSeVO5 and TlTeVO5115(NH4)2Te2WO8: A New Polar Oxide with Second-Harmonic Generating, Ferroelectric, and Pyroelectric Properties88Bulk Growth and Characterization of a Novel Nonlinear Optical Crystal BaTeMo2O9125ZnVSe2O7 and Cd6V2Se5O21: New d10 Transition-Metal Selenites with V(IV) or V(V) Cations54Polar Hexagonal Tungsten Bronze-Type Oxides: KNbW2O9, RbNbW2O9, and KTaW2O973Structures and Properties of Functional Metal Selenites and Tellurites164Elastic, dielectric, and piezoelectric properties of BaTeMo2O9 single crystal62Explorations of new second-order NLO materials in the AgI-MoVI/WVI-TeIV-O systems62Rb2W3[TeO3]O90New Polar Oxides: Synthesis, Characterization, Calculations, and Structure−Property Relationships in RbSe2V3O12 and TlSe2V3O12125Structure and Thermal Properties of the Nonlinear Optical Crystal BaTeMo2O965Polar or Nonpolar? A+ Cation Polarity Control in A2Ti(IO3)6(A = Li, Na, K, Rb, Cs, Tl)306A Series of New Infrared NLO Semiconductors, ZnY6Si2S14, AlxDy3(SiyAl1−y)S7, and Al0.33Sm3SiS7134New Noncentrosymmetric Material - [N(CH3)4]ZnCl3: Polar Chains of Aligned ZnCl4 Tetrahedra63Syntheses, Crystal Structures, and Properties of Five New Transition Metal Molybdenum(VI) Selenites and Tellurites54Explorations of new quaternary phases in the LnIII–VV(d0)–SeIV–O (Ln = Nd, Eu, Gd, Tb) systems23Crystal growth of a new series of non-centrosymmetric oxides, Ln3FeO6 (Ln = La, Nd, Sm, Eu and Gd)14Polar Hexagonal Tungsten Oxide (HTO) Materials: (1) Synthesis, Characterization, Functional Properties, and Structure−Property Relationships in A2(MoO3)3(SeO3) (A = Rb+ and Tl+) and (2) Classification, Structural Distortions, and Second-Harmonic Generating Properties of Known Polar HTOs104Noncentrosymmetric Inorganic Oxide Materials: Synthetic Strategies and Characterisation Techniques8Syntheses, crystal structures, and properties of three new metal selenites Na2Co2(SeO3)3, Na2Co1.67Ni0.33(SeO3)3, and Na2Ni2(SeO3)315Top-Seeded Solution Crystal Growth and Functional Properties of a Polar Material—Na2TeW2O956Anisotropic Thermal Properties of the Nonlinear Optical and Polar Oxide Material Na2TeW2O931Polymorphism of BaTeMo 2 O 9 : A New Polar Polymorph and the Phase Transformation186Compositionally controlled rhombohedral to cubic phase transition in CsTe2−xWxO6 related to pyrochlore structure11Centrosymmetric [N(CH3)4]2TiF6 vs. noncentrosymmetric polar [C(NH2)3]2TiF6: A hydrogen-bonding effect on the out-of-center distortion of TiF6 octahedra31New Vanadium Selenites: Centrosymmetric Ca2(VO2)2(SeO3)3(H2O)2, Sr2(VO2)2(SeO3)3, and Ba(V2O5)(SeO3), and Noncentrosymmetric and Polar A4(VO2)2(SeO3)4(Se2O5) (A = Sr2+ or Pb2+)50New mixed metal selenites and tellurites containing Pd 2+ ions in a square planar geometry14Anisotropic thermal properties of the polar crystal Cs2TeMo3O1224Crystal growth and optical properties of a noncentrosymmetric molybdenum tellurite, Na2Te3Mo3O1641Second-Order Nonlinear Optical Materials Based on Metal Iodates, Selenites, and Tellurites60Structural Designs and Property Characterizations for Second-Harmonic Generation Materials1Top‐seeded growth, optical properties and theoretical studies of noncentrosymmetric Te2V2O914Synthesis, crystal structure and properties of a new lead fluoride borate, Pb3OBO3F17Influence of the Cation Size on the Framework Structures and Space Group Centricities in AMo2O5(SeO3)2 (A = Sr, Pb, and Ba)93Synthesis, crystal structure and properties of a new congruently melting compound, K3ZnB5O1016Noncentrosymmetric salt inclusion oxides: Role of salt lattices and counter ions in bulk polarity52Effect of the Framework Flexibility on the Centricities in Centrosymmetric In2Zn(SeO3)4 and Noncentrosymmetric Ga2Zn(TeO3)450Investigation of the dielectric, elastic, and piezoelectric properties of Cs2TeMo3O12 crystals22Synthesis, Structure, and Characterization of New Li+ – d0 –Lone-Pair – Oxides: Noncentrosymmetric Polar Li6(Mo2O5)3(SeO3)6 and Centrosymmetric Li2(MO3)(TeO3) (M = Mo6+ or W6+)47Structure–Property Relationships in Solid Solutions of Noncentrosymmetric Aurivillius Phases, Bi4–xLaxTi3O12 (x = 0–0.75)33Chemistry of Polar Transition-Metal Oxides1Top-seeded solution growth and characterization of a novel nonlinear optical crystal MnTeMoO637Synthesis, Structure, and Characterization of Two New Polar Sodium Tungsten Selenites: Na2(WO3)3(SeO3)·2H2O and Na6(W6O19)(SeO3)247New Alkali-Metal Gallium Selenites, AGa(SeO3)2 (A = Li, Na, K, and Cs): Effect of Cation Size on the Framework Structures and Macroscopic Centricities76Heat capacity and thermodynamic functions of cadmium tellurites in the range of 298.15–673 K4Na1.4InTe3.6O9.4: New Variant of a Hexagonal Tungsten Oxide (HTO)-Like Layered Framework Containing Both a Main-Group Cation, In3+, and a Lone-Pair Cation, Te4+14From an Open Framework to a Layered and a Hexagonal Tungsten Oxide Structure: Controlled Transformation Reactions of an Extended Solid-State Material, Cs3Ga7(SeO3)12 to Ga(OH)(SeO3) and KGa3(SeO4)2(OH)613VSb(SeO3)4, First Selenite Containing V3+ Cation: Synthesis, Structure, Characterization, Magnetic Properties, and Calculations15Noncentrosymmetric YVSe2O8 and Centrosymmetric YVTe2O8: Macroscopic Centricities Influenced by the Size of Lone Pair Cation Linkers63Noncentrosymmetric versus Centrosymmetric: Influence of the Na+ Substitution on Structural Transition and Second-Harmonic Generation Property50Variable Framework Structures and Centricities in Alkali Metal Yttrium Selenites, AY(SeO3)2 (A = Na, K, Rb, and Cs)51Effect of polarizable lone pair cations on the second-harmonic generation (SHG) properties of noncentrosymmetric (NCS) Bi 2−x Y x TeO 5 (x = 0–0.2)24Dimensional and Coordination Number Reductions in a Large Family of Lanthanide Tellurite Sulfates21A series of novel mercury( i ) selenites and tellurites containing SOJT Mo 6+ cations18Heat capacity and thermodynamic functions of cerium tellurites in the range of 298.15–673 K2Macroscopic polarity control with alkali metal cation size and coordination environment in a series of tin iodates82Second-harmonic generation (SHG) and photoluminescence properties of noncentrosymmetric (NCS) layered perovskite solid solutions, CsBi 1−x Eu x Nb 2 O 7 (x = 0, 0.1, and 0.2)30Dinuclear Face‐Sharing Bi‐octahedral Tungsten(VI) Core and Unusual Thermal Behavior in Complex Th Tungstates12Cs(TaO 2 ) 3 (SeO 3 ) 2 and Cs(TiOF) 3 (SeO 3 ) 2 : Structural and Second Harmonic Generation Changes Induced by the Different d 0 -TM Coordination Octahedra67Modulation of Framework and Centricity: Cation Size Effect in New Quaternary Selenites, ASc(SeO3)2 (A = Na, K, Rb, and Cs)41Effects of Te(IV) Oxo-Anion Incorporation into Thorium Molybdates and Tungstates14Top-Seeded Solution Growth, Structure, Morphology, and Functional Properties of a New Polar Crystal — Cs2TeW3O1238Topological Analysis of Void Spaces in Tungstate Frameworks: Assessing Storage Properties for the Environmentally Important Guest Molecules and Ions: CO2, UO2, PuO2, U, Pu, Sr2+, Cs+, CH4, and H23Structure–Property Correlations in the Heterobimetallic 4f/3d Materials Ln2M(TeO3)2(SO4) (Ln = Y, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, or Lu; M = Co or Zn)25Structure-Directing Effect of Alkali Metal Cations in New Molybdenum Selenites, Na2Mo2O5(SeO3)2, K2Mo2O5(SeO3)2, and Rb2Mo3O7(SeO3)315Crystal growth and anisotropic thermal properties of the nonlinear and polar oxide Cs2TeW3O1213Nonlinear optical (NLO) properties and temperature-dependent photoluminescence in activator-doped noncentrosymmetric (NCS) bismuth tellurite solid solutions, Bi2−Ln TeO5 (Ln = Ce and Eu)8A review of the structural architecture of tellurium oxycompounds170Ag 3 I[(MoO 3 ) 2 (IO 3 ) 2 ]: a new polar material synthesized from the structural modulation of molybdenyl iodate architectures by polarizable cation (Ag + ) and anion (I − )6Thorium Chemistry in Oxo-Tellurium System under Extreme Conditions10Synthesis, second-harmonic generations (SHG), and photoluminescence (PL) properties of Ca 4 Bi 6-x Ln x O 13 (Ln=La and Eu) solid solutions3A first–principles study on polar hexagonal Cs 2 Te M 3 O 12 ( M = W, Mo): New visible–light responsive photocatalyst7Structural motifs in heteroleptic copper and cadmium selenites7Supercritical Fluid Technology: An Emphasis on Drug Delivery and Related Biomedical Applications283Li7(TeO3)3F: A Lithium Fluoride Tellurite with Large Second Harmonic Generation Responses and a Short Ultraviolet Cutoff Edge39A(VO 2 F)(SeO 3 ) (A = Sr, Ba) and Ba(MOF 2 )(TeO 4 ) (M = Mo, W): first examples of alkali-earth selenites/tellurites with a fluorinated d 0 -TM octahedron33A cation size effect on the framework structures in ABi 2 SeO 3 F 5 (A = K and Rb): first examples of alkali metal bismuth selenite fluorides14Four alkali metal molybdates with two types of Mo–O chains, ABMo 3 O 10 (A = Li, B = Rb; A = Li, Na, K, B = Cs): synthesis, structure comparison and optical properties10Role of Bis(triphenylphosphine)iminium Cation [PNP]+ on the Crystal Packing of [PNP]+[HSeO3]− Solvate Salt2Investigations into anisotropic properties of the nonlinear optical material CdTeMoO6 with quasi-two-dimensional structure16Investigation into the optimized growth, anisotropic properties and theoretical calculations of the polar material Cs 2 TeW 3 O 128Crystal structure and second harmonic generation in Bi2TeO5: An X-N study from synchrotron and neutron diffraction data8A high-pressure phase with a non-centrosymmetric crystal structure in the PbSe–PbBr2 system8AE2[Ni(Te4O10)Cl2] (AE = Ca, Sr, Ba, Pb): A New Type of Inorganic Compound Synthesized through the Recombination of Tellurium(IV) Oxide Anion Fragments by Introducing Post-transition-metal Halide NiCl22Crystal structure features of the mixed-valence tellurium β-pyrochlores: CsTe1.625W0.375O6 and RbTe1.5W0.5O621Transition-Metal Monofluorophosphate Ba2M2(PO3F)F6 (M = Mn, Co, and Ni): Varied One-Dimensional Transition-Metal Chains and Antiferromagnetism19A powder method for the high-efficacy evaluation of electro-optic crystals28AGa 3 F 6 (SeO 3 ) 2 (A = Rb, Cs): A New Type of Phase-Matchable Hexagonal Tungsten Oxide Material with Strong Second-Harmonic Generation Responses63Structure analysis and electronic properties of ATe4+0.5Te6+1.5-xM6+xO6 (A=Rb, Cs, M6+=Mo, W) solid solutions with β-pyrochlore structure28A2(TeO)P2O7 (A = K, Rb, Cs): Three new tellurite-pyrophosphates with large birefringence17New Solids in As-O-Mo, As(P)-O-Mo(W) and As(P)-O-Nb(W) Systems That Exhibit Nonlinear Optical Properties0Structural characterization of quaternary selenites of tungsten(VI), A 2W3SeO12 (A = NH4, Cs, Rb, K or Tl)1Supercritical fluid (SCF)-assisted fabrication of carrier-free drugs: An eco-friendly welcome to active pharmaceutical ingredients (APIs)85KIn0.33IIITe0.67VITe2IVO7: Zirconolite-like Mixed-Valent Metal Oxide with a 3D Framework2A New Nonlinear Optical Material with N(CN)2− Anion2Recent advances in tellurite molybdate/tungstate crystals15One-Side Capping in Two-Dimensional WO 3 -Type Materials Leading to Strong Second-Harmonic Response29Open-Framework Iron Fluoride Phosphates Based on Chain, Trinuclear, and Tetranuclear Chain FeIII Building Units: Crystal Structures and Magnetic Properties8Cd2Nb2Te4O15: A Novel Pseudo‐Aurivillius‐Type Tellurite with Unprecedented Nonlinear Optical Properties and Excellent Stability40Large Difference in Nonlinear Optical Activity of Rare Earth Ion Substitution of Bi3+ in A3TeBO9 (A = Bi, La, Pr, Nd, Sm-Dy)6Structural Type of β-Pyrochlore Oxides AM2O60Hydrated and fluorinated potassium scandium phosphates: topology symmetry analysis and structure prediction1Second Harmonic Generation in β-K2TeW3O12: An Acentric Crystal Designed from Centric Phase via Pressure Modulation4Recent progress in nonlinear optical molybdenum/tungsten tellurites: Structures, crystal growth and characterizations34Enhanced Birefringence and Excellent Thermal Stability in Two Tellurium(IV) Vanadates: KTeOVO4 and Ca2TeV2O95Recent achievements of d0 transition-metal-based oxyfluorides: Crystal chemistry and application in second-order NLO materials10One-step hydrothermal synthesis of ZnSnO 3 clustered nanorods: the effect of Zn 2+ /urea ratio, reaction conditions, and optimized mineralizer concentration0Rational design of a quasi-0D tungsten tellurite nonlinear optical crystal with exceptionally balanced properties1

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  2. Synthesis, structure and characterization of two new antimony oxides–LaSb 3 O 9 and LaSb 5 O 12 : Formation of LaSb 5 O 12 from the reaction of LaSb 3 O 9 with Sb 2 O 3

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  3. Asymmetric Cation Coordination in Oxide Materials: Influence of Lone-Pair Cations on the Intra-octahedral Distortion in d0 Transition Metals

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  4. Syntheses, Crystal Structures, and Properties of Six New Lanthanide(III) Transition Metal Tellurium(IV) Oxyhalides with Three Types of Structures

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  5. Synthesis, crystal structure and magnetic property of a new nickel selenite chloride: Ni5(SeO3)4Cl2

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  6. Syntheses and Structural Characterization of New Mixed-Valent Tellurium Oxides, A4[Te56+Te34+]O23 (A = Rb and K)

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  7. [Cd2(Te6O13)][Cd2Cl6] and Cd7Cl8(Te7O17): Novel Tellurium(IV) Oxide Slabs and Unusual Cadmium Chloride Architectures

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  8. Na2Te3Mo3O16: A New Molybdenum Tellurite with Second-Harmonic Generating and Pyroelectric Properties

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  9. Syntheses, crystal structures and characterizations of BaZn(SeO3)2 and BaZn(TeO3)Cl2

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  10. LiMoO3(IO3): A new molybdenyl iodate based on WO3-type sheets with large SHG response

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  11. Syntheses, Structural Studies, and Magnetic Properties of Divalent Cu and Co Selenites with Organic Constituents

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  12. Synthesis, Crystal Structure and Characterization of the Barium Zinc Tellurate Disilicate: Ba3Zn6[TeO6][Si2O7]2

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  13. New Layered Uranium Phosphate Fluorides: Syntheses, Structures, Characterizations, and Ion-Exchange Properties of A(UO2)F(HPO4)·xH2O (A = Cs+, Rb+, K+; x = 0−1)

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  14. Synthesis, crystal and band structures, and optical properties of a new lanthanide–alkaline earth tellurium(IV) oxide: La2Ba(Te3O8)(TeO3)2

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  16. New Luminescent Solids in the Ln−W(Mo)−Te−O−(Cl) Systems

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  25. Rb2W3[TeO3]O9

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  27. Structure and Thermal Properties of the Nonlinear Optical Crystal BaTeMo2O9

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  33. Crystal growth of a new series of non-centrosymmetric oxides, Ln3FeO6 (Ln = La, Nd, Sm, Eu and Gd)

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  34. Polar Hexagonal Tungsten Oxide (HTO) Materials: (1) Synthesis, Characterization, Functional Properties, and Structure−Property Relationships in A2(MoO3)3(SeO3) (A = Rb+ and Tl+) and (2) Classification, Structural Distortions, and Second-Harmonic Generating Properties of Known Polar HTOs

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  35. Noncentrosymmetric Inorganic Oxide Materials: Synthetic Strategies and Characterisation Techniques

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  36. Syntheses, crystal structures, and properties of three new metal selenites Na2Co2(SeO3)3, Na2Co1.67Ni0.33(SeO3)3, and Na2Ni2(SeO3)3

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  37. Top-Seeded Solution Crystal Growth and Functional Properties of a Polar Material—Na2TeW2O9

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  38. Anisotropic Thermal Properties of the Nonlinear Optical and Polar Oxide Material Na2TeW2O9

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  39. Polymorphism of BaTeMo 2 O 9 : A New Polar Polymorph and the Phase Transformation

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  40. Compositionally controlled rhombohedral to cubic phase transition in CsTe2−xWxO6 related to pyrochlore structure

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