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RESEARCH PAPER · Inorganic Chemistry Frontiers · 2017

Recent progress in crystalline metal chalcogenides as efficient photocatalysts for organic pollutant degradation

Lina Nie, Qichun Zhang

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Recent progress in crystalline metal chalcogenides as efficient photocatalysts for organic pollutant degradationOriginalDesign of two isoreticular Cd-biphenyltetracarboxylate frameworks for dye adsorption, separation and photocatalytic degradation50A series of new hybrid selenidostannates with metal complexes prepared in alkylol amines13Ethanol–water ambient precipitation of {111} facets exposed Ag 3 PO 4 tetrahedra and its hybrid with graphene oxide for outstanding photoactivity and stability13New synthetic strategies to prepare metal–organic frameworks306[CH3NH3]4Ga4SbS9S0.28O0.72H: A Three‐Dimensionally Open‐Framework Heterometallic Chalcogenidoantimonate Exhibiting Ni2+ Ion‐Exchange Property19Surface Decorated Zn0.15Cd0.85S Nanoflowers with P25 for Enhanced Visible Light Driven Photocatalytic Degradation of Rh-B and Stability7Exploring the Surfactant–Thermal Synthesis of Crystalline Functional Thioarsenates48Crystal Chemistry and Photocatalytic Properties of RE 4 S 4 Te 3 (RE = Gd, Ho, Er, Tm): Experimental and Theoretical Investigations29Enhanced photocatalytic activity in hybrid composite combined BiOBr nanosheets and Bi2S3 nanoparticles54Hybrid Assembly of Different-Sized Supertetrahedral Clusters into a Unique Non-Interpenetrated Mn–In–S Open Framework with Large Cavity17Phase Tuned Originated Dual Properties of Cobalt Sulfide Nanostructures as Photocatalyst and Adsorbent for Removal of Dye Pollutants75Supramolecular Organic Photocatalyst Containing a Cubanelike Water Cluster and Donor–Acceptor Stacks: Hydrogen Evolution and Dye Degradation under Visible Light28Cu doped cubic pyrite-type CoS2 ball like superstructures as heterogeneous photocatalyst9Chemical vapor deposition of tin sulfide from diorganotin(IV) dixanthates29Self-templated synthesis of CoS2 hollow polyhedron with superior performance for removal of dye and heavy metal ion15Adsorptive removal of phenol by single and double network composite hydrogels based on hydroxypropyl cellulose and graphene oxide21Anti-Site Defects-Assisted Enhancement of Electrogenerated Chemiluminescence from in Situ Mn2+-Doped Supertetrahedral Chalcogenide Nanoclusters20Rational construction of direct Z-scheme LaMnO3/g-C3N4 hybrid for improved visible-light photocatalytic tetracycline degradation118Photocatalysis of Graphene and Carbon Nitride-Based Functional Carbon Quantum Dots52CuSbSe 2 /TiO 2 : novel type-II heterojunction nano-photocatalyst39A new cluster-based chalcogenide zeolite analogue with a large inter-cluster bridging angle15Interlinking supertetrahedral chalcogenolate clusters with bipyridines to form two-dimensional coordination polymers for photocatalytic degradation of organic dye27One-step, high-yield synthesis of g-C 3 N 4 nanosheets for enhanced visible light photocatalytic activity73Two rare-earth-based quaternary chalcogenides EuCdGeQ 4 (Q = S, Se) with strong second-harmonic generation66Effective photocatalytic salicylic acid removal under visible light irradiation using Ag2S/AgI-Bi2S3/BiOI with Z-scheme heterojunctions33Dual-Functional Photocatalysis for Simultaneous Hydrogen Production and Oxidation of Organic Substances298Boosting charge transfer and hydrogen evolution performance of CdS nanocrystals hybridized with MoS2 nanosheets under visible light irradiation47Solution-Based Synthesis and Processing of Metal Chalcogenides for Thermoelectric Applications23New 2D Assemblage of Supertetrahedral Chalcogenide Clusters with Tetravalent-Metal-Induced Interrupted Sites17Stepwise Conversion from GeO2 to [MGe4S10]n3n– (M = Cu, Ag) Polymer via Isolatable [Ge2S6]4– and [Ge4S10]4– Anions by Virtue of Templating Technique21Conjugated polymers for visible-light-driven photocatalysis687Tuning crystal phase and morphology of copper selenide nanostructures and their visible-light photocatalytic applications to degrade organic pollutants36The facile soft-template-morphology-controlled (STMC) synthesis of ZnIn 2 S 4 nanostructures and their excellent morphology-dependent adsorption properties22Chalcogenide semiconductor photocatalysis for the photocatalytic degradation of organic pollutants in water0From isolated Ti-oxo clusters to infinite Ti-oxo chains and sheets: recent advances in photoactive Ti-based MOFs260In situ fabrication of self-assembled BiOBr x I 1−x coated on carbon nanofibers for efficient solar light-driven photocatalytic nitrogen fixation15One-pot synthesis of MoS 2(1−x) Se 2x on N-doped reduced graphene oxide: tailoring chemical and structural properties for photoenhanced hydrogen evolution reaction8Photocatalytic Conversion of Carbon Dioxide into Hydrocarbons6Recent advances in 0D nanostructure-functionalized low-dimensional nanomaterials for chemiresistive gas sensors59Surface defect engineering of mesoporous Cu/ZnS nanocrystal-linked networks for improved visible-light photocatalytic hydrogen production41Two new layered metal chalcogenide frameworks as photocatalysts for highly efficient and selective dye degradation6Visible-light-driven photocatalytic selective organic oxidation reactions102Metal Chalcogenides Based Heterojunctions and Novel Nanostructures for Photocatalytic Hydrogen Evolution80Assembly of Discrete Chalcogenolate Clusters into a One-Dimensional Coordination Polymer with Enhanced Photocatalytic Activity and Stability32Mild solvothermal syntheses and characterizations of two layered sulfides Ba2Cu2Cd2S5 and Ba3Cu4Hg4S915Synthesis, structure and physical properties of a new two-dimensional polymer based on tri(imidazole) and dicarboxylate as co-ligands2Chalcogenides: Solid‐State Chemistry11Unique Two-Dimensional Indium Telluride Templated by a Rare Wheel-Shaped Heterobimetallic Mn/In Cluster4Using thiol-amine solvent mixture to prepare main group heterometallic chalcogenides8A serial of 2D Co‐Zn isomorphous metal–organic frameworks for photodegradation and luminescent detection properties20Recent Progress in Metal‐Free Covalent Organic Frameworks as Heterogeneous Catalysts372Two Copper-Rich Open-Framework Chalcogenides Built from Unusual [Cu5(SnxM1–x)Se10] Clusters and [(SnxM1–x)2Se6] Dimeric Linkers (M = In and Ga)4Biosensors Based on Advanced Sulfur-Containing Nanomaterials39Recent advances in homojunction-based photocatalysis for sustainable environmental remediation and clean energy generation93Tandem Synthesis of High Yield MoS2 Nanosheets and Enzyme Peroxidase Mimicking Properties17Effect of CeO2-ZnO Nanocomposite for Photocatalytic and Antibacterial Activities60Metal and Carbon Quantum Dot Photocatalysts for Water Purification16Three-dimensional metal-halide open frameworks56Z-scheme-based heterostructure photocatalysts for organic pollutant degradation3Metal chalcogenide/oxide-based quantum dots decorated functional materials for energy-related applications: Synthesis and preservation12A 3 Mn 2 Sb 3 S 8 (A = K and Rb): a new type of multifunctional infrared nonlinear optical material based on unique three-dimensional open frameworks53Advances in chalcogenides and chalcogenides-based nanomaterials such as sulfides, selenides, and tellurides26Chalcogenides as well as chalcogenides-based nanomaterials and its importance in photocatalysis19Challenges, novel applications, and future prospects of chalcogenides and chalcogenide-based nanomaterials for photocatalysis21CO2 photoreduction by MOF-derived carbon nanomaterials: A review12Core–shell Cu 2 S:NiS 2 @C hybrid nanostructure derived from a metal–organic framework with graphene oxide for photocatalytic synthesis of N-substituted derivatives43Efficient Cr( vi ) photoreduction under natural solar irradiation using a novel step-scheme ZnS/SnIn 4 S 8 nanoheterostructured photocatalysts30Facile syntheses of silver thioantimonates exhibiting second-harmonic generation responses and large birefringence18Recent advances in the “on–off” approaches for on-demand liquid-phase hydrogen evolution78Synthesis methods for chalcogenides and chalcogenides-based nanomaterials for photocatalysis5Three-dimensional ordered macroporous materials for photocatalysis: design and applications67Unveiling the impurity-modulated photoluminescence from Mn 2+ -containing metal chalcogenide semiconductors via Fe 2+ doping10Two 3D metal(II)–organic coordination polymers constructed by semi-rigid imidazolium carboxylate ligand: synthesis, crystal structure and property3Halide perovskite composites for photocatalysis: A mini review114Preparation of magnetic double network nanocomposite hydrogel for adsorption of phenol and p-nitrophenol from aqueous solution78Visible Light-Driven Photocatalytic Rhodamine B Degradation Using CdS Nanorods63Hierarchical fibrous bimetallic electrocatalyst based on ZnO-MoS2 composite nanostructures as high performance for hydrogen evolution reaction44Modification of TiO 2 with metal chalcogenide nanoclusters for hydrogen evolution10Quaternary Chalcohalides CdSnSX2 (X = Cl or Br) with Neutral Layers: Syntheses, Structures, and Photocatalytic Properties18Transformation synthesis of heterostructured SnS2/ZnS microspheres for ultrafast triethylamine detection51Using highly reactive tellurium precursors to synthesize organic hybrid indium-tellurides4Photocatalytic and Photoelectrochemical Overall Water Splitting8Mixed 1T-2H phase MoSe2 as interfacial charge-transfer-bridge to boosting photocatalytic activity of dual Z-scheme AgI/1T-2H MoSe2/Bi4O5Br2 heterojunction31Pristine and Janus monolayers of vanadium dichalcogenides: potential materials for overall water splitting and solar energy conversion13Atomically precise metal chalcogenide supertetrahedral clusters: frameworks to molecules, and structure to function79Ionothermal Synthesis of Two New Thioantimonates with Transition Metal Regulation4Photocatalysis Driven by Near-Infrared Light: Materials Design and Engineering for Environmentally Friendly Photoreactions96MoS 2 Nanosheet/ZnS Composites for the Visible-Light-Assisted Photocatalytic Degradation of Oxytetracycline99Dual-plasmon-induced photocatalytic performance enhancement in Au-PbS-CdS nanodumbbells with double Au caps on the ends11Density functional theory studies of oxygen reduction reaction for hydrogen peroxide generation on Graphene-Based catalysts6Fabrication of Highly Textured 2D SnSe Layers with Tunable Electronic Properties for Hydrogen Evolution13Rb2CuSb7S12: Quaternary Antimony-Rich Semiconductor Featuring a Three-Dimensional Open Framework and Exhibiting an Intriguing Photocurrent Response31An Organic Hybrid Indium–Telluride Incorporating Binuclear Complexes [In2(ea)4]2+ with a Bridging Oxygen Donor1Green processes and sustainable materials for renewable energy production via water splitting25Highly Active Electrochemiluminescence of Ruthenium Complex Co-assembled Chalcogenide Nanoclusters and the Application for Label-Free Detection of Alkaline Phosphatase33Boosting Photocatalytic Activity Using Carbon Nitride Based 2D/2D van der Waals Heterojunctions143Photo-assisted degradation of organic pollutant by CuFeS2 powder in RGB-LED reactors: A comprehensive study of band gap values and the relation between wavelength and electron-hole recombination30Open-Framework Chalcogenide Materials - from isolated clusters to highly ordered structures - and their photocalytic applications25Cs 3 CuAs 4 Q 8 (Q = S, Se): unique two-dimensional layered inorganic thioarsenates with the lowest Cu-to-As ratio and remarkable photocurrent responses17Photochemical deposition of SnS2 on graphitic carbon nitride for photocatalytic aqueous Cr(VI) reduction17Recent Progress and Prospects in Catalytic Water Treatment379Enhancing interfacial charge transfer in mesoporous MoS 2 /CdS nanojunction architectures for highly efficient visible-light photocatalytic water splitting17Ba 3 Zr 2 Cu 4 S 9 : the first quaternary phase of the Ba–Zr–Cu–S system5Interesting dimensional transition through changing cations as the trigger in multinary thioarsenates displaying variable photocurrent response and optical anisotropy22Molecular surface modification of silver chalcogenolate clusters1Recent advances in various applications of nickel cobalt sulfide-based materials55Sensing and photocatalytic properties of a new 3D Co( ii ) coordination polymer based on 1,1′-di( p -carboxybenzyl)-2,2′-biimidazole4Ultra-fast 137 Cs sequestration via a layered inorganic indium thioantimonate7First-principles calculation of chalcogen-doped Sr2M2O7 (M=Nb and Ta) for visible light photocatalysis5Microbe-mediated transformation of metal sulfides: Mechanisms and environmental significance69Photocatalytic degradation of organic textile dyes using tellurium-based metal alloy14Integration of CdS with a Fiber-Based Cadmium Coordination Polymer for Turning On Photocatalytic Oxidative Coupling Reactions15Transition Metal Dichalcogenide-based Membranes for Water Desalination, Gas Separation, and Energy Storage53Light-Harvesting Novel Hierarchical Porous Cu9S5–MnWO4 Hybrid Structures in Photocatalytic Oxidative Homocoupling of Alkynes and Amines17Electrocatalysts for Oxygen/Hydrogen-Involved Reactions0Application of perovskite oxides and their composites for degrading organic pollutants from wastewater using advanced oxidation processes: Review of the recent progress104Growth and exploration of visible-light-driven enhanced photocatalytic activity of Cu1–XCrxS/CdS heterojunction thin film for active dye degradation23Review of 3D printing in photocatalytic substrates and catalysts66A four-fold three-dimensional zinc(II) coordination polymer based on 4,4′-bis(2-methyl-imidazolyl)biphenyl and 5-sulfoisophthalate ligands: synthesis, structure and properties1Etude expérimentale et théorique d’un nouveau composé halogène pnicture Hg 12 Sb 6 ( Br 5 , 186 I 6 , 814 )0Role of Surface Defects and Optical Band-gap Energy on Photocatalytic Activities of Titanate-based Perovskite Nanomaterial5Structural studies and photocatalytic degradation of brilliant green by dodecylamine capped tin sulphide nanocrystals14The Solvothermal Synthesis and Properties of Thioantimonates Rb(1,4-DABH)Sb4S7 and Cs2ZnSb2S5: 1D Anion Chains and 2D Anion Layer2Influence of precursors and formation of heterostructures towards the enhanced photocatalytic activity of ZnO thin films deposited by spray pyrolysis7Capturing Solar Energy for Cathodic Protection of Metals: The Life of Photoexcited Charge Carriers23Metal chalcogenide materials: Synthesis, structure and properties1Selective fluorescent sensing and photocatalytic properties of a new 2D Co coordination polymer based on 1,1′-di(p-carbonylbenzyl)-2,2′-biimidazoline5Two new gallium(III)-thioantimonates TM(tren)GaSbS4 (TM = Mn, Fe): Syntheses, crystal structure and properties9Phase-controlled 1T/2H-MoS2 interaction with reduced TiO2 for highly stable photocatalytic CO2 reduction into CO36M–Sn–Q (M = Zn, Cd; Q = S, Se) Compounds Templated by (Alkyl)ammonium Species: Synthesis, Crystal Structure, and Sr2+ Adsorption Property12A wheel-shaped gallium-sulfide molecular ring with enhanced photocatalytic activity via indium alloying11CaIn 2 S 4 –In 2 O 3 hybrid nanofibers with expedited photocarrier separation for fast photocatalytic bacterial inactivation under visible light7Fabrication of a Sm 2 O 3 /In 2 S 3 photocatalyst for boosting ciprofloxacin oxidation and the Cr( vi ) reduction: process parameters and degradation mechanism11Magnetic field effects on the crystal structure, morphology, energy gap, and magnetic properties of manganese selenide nanoparticles synthesized by hydrothermal method11Magnetically retrievable graphitic carbon nitride-based nanocomposites1Photocatalytic properties of iodometallates with in situ -generated organic bases as countercations6Transition Metal Chalcogenides-Based Nanocomposite for the Photocatalytic Degradation of Hazardous Chemicals2Applications of Transition Metal Oxides and Chalcogenides and their Composites in Water Treatment: a review97Review on Metal Chalcogenides and Metal Chalcogenide-Based Nanocomposites in Photocatalytic Applications27Graphitic Carbon Nitride (g‐CN) for Sustainable Hydrogen Production2Bifunctional Supertetrahedral Chalcogenolate Cluster-Based Assembly Materials Constructed by a Photoactive Ligand4Influência do método de síntese nas propriedades físico-químicas e no desempenho fotocatalítico do Nb2O50Small Molecules, Great Powers: Chemistry of Small Organo‐Chalcogenide Molecules in Rechargeable Li‐Sulfur Batteries23Room-Temperature Synthesis of Carbon Dot/TiO2 Composites with High Photocatalytic Activity38Two-dimensional layered organic hybrid selenidostannate coupled with polyaniline for high efficient photocatalytic Cr(VI) reduction72Metal-organic frameworks derived porous MoS2/CdS heterostructure for efficient photocatalytic performance towards hydrogen evolution and organic pollutants34Construction of metal chalcogenolate cluster linked organic frameworks4Synergistic effect of stirring and marigold shaped Cu2FeSnS4 nanostructure for the enhanced performance of Rhodamine B degradation under visible light13ZnS–MoS2 nano-heterostructure: efficient photocatalyst for dye removal under sunlight6Fabrication and characterization of ( PVDF / PEO )/ AgBiSe2 polymeric membrane with enhanced visible light photocatalytic performance20

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  3. Ethanol–water ambient precipitation of {111} facets exposed Ag 3 PO 4 tetrahedra and its hybrid with graphene oxide for outstanding photoactivity and stability

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  5. [CH3NH3]4Ga4SbS9S0.28O0.72H: A Three‐Dimensionally Open‐Framework Heterometallic Chalcogenidoantimonate Exhibiting Ni2+ Ion‐Exchange Property

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  6. Surface Decorated Zn0.15Cd0.85S Nanoflowers with P25 for Enhanced Visible Light Driven Photocatalytic Degradation of Rh-B and Stability

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  8. Crystal Chemistry and Photocatalytic Properties of RE 4 S 4 Te 3 (RE = Gd, Ho, Er, Tm): Experimental and Theoretical Investigations

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  9. Enhanced photocatalytic activity in hybrid composite combined BiOBr nanosheets and Bi2S3 nanoparticles

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  10. Hybrid Assembly of Different-Sized Supertetrahedral Clusters into a Unique Non-Interpenetrated Mn–In–S Open Framework with Large Cavity

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  11. Phase Tuned Originated Dual Properties of Cobalt Sulfide Nanostructures as Photocatalyst and Adsorbent for Removal of Dye Pollutants

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  12. Supramolecular Organic Photocatalyst Containing a Cubanelike Water Cluster and Donor–Acceptor Stacks: Hydrogen Evolution and Dye Degradation under Visible Light

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  13. Cu doped cubic pyrite-type CoS2 ball like superstructures as heterogeneous photocatalyst

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  14. Chemical vapor deposition of tin sulfide from diorganotin(IV) dixanthates

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  15. Self-templated synthesis of CoS2 hollow polyhedron with superior performance for removal of dye and heavy metal ion

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  16. Adsorptive removal of phenol by single and double network composite hydrogels based on hydroxypropyl cellulose and graphene oxide

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  17. Anti-Site Defects-Assisted Enhancement of Electrogenerated Chemiluminescence from in Situ Mn2+-Doped Supertetrahedral Chalcogenide Nanoclusters

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  18. Rational construction of direct Z-scheme LaMnO3/g-C3N4 hybrid for improved visible-light photocatalytic tetracycline degradation

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  21. A new cluster-based chalcogenide zeolite analogue with a large inter-cluster bridging angle

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  22. Interlinking supertetrahedral chalcogenolate clusters with bipyridines to form two-dimensional coordination polymers for photocatalytic degradation of organic dye

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  30. Stepwise Conversion from GeO2 to [MGe4S10]n3n– (M = Cu, Ag) Polymer via Isolatable [Ge2S6]4– and [Ge4S10]4– Anions by Virtue of Templating Technique

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  32. Tuning crystal phase and morphology of copper selenide nanostructures and their visible-light photocatalytic applications to degrade organic pollutants

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  33. The facile soft-template-morphology-controlled (STMC) synthesis of ZnIn 2 S 4 nanostructures and their excellent morphology-dependent adsorption properties

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  34. Chalcogenide semiconductor photocatalysis for the photocatalytic degradation of organic pollutants in water

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  35. From isolated Ti-oxo clusters to infinite Ti-oxo chains and sheets: recent advances in photoactive Ti-based MOFs

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  36. In situ fabrication of self-assembled BiOBr x I 1−x coated on carbon nanofibers for efficient solar light-driven photocatalytic nitrogen fixation

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  37. One-pot synthesis of MoS 2(1−x) Se 2x on N-doped reduced graphene oxide: tailoring chemical and structural properties for photoenhanced hydrogen evolution reaction

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  38. Photocatalytic Conversion of Carbon Dioxide into Hydrocarbons

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  40. Surface defect engineering of mesoporous Cu/ZnS nanocrystal-linked networks for improved visible-light photocatalytic hydrogen production

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  41. Two new layered metal chalcogenide frameworks as photocatalysts for highly efficient and selective dye degradation

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  42. Visible-light-driven photocatalytic selective organic oxidation reactions

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  43. Metal Chalcogenides Based Heterojunctions and Novel Nanostructures for Photocatalytic Hydrogen Evolution

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