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RESEARCH PAPER · Dalton Transactions · 2010

Hybrid materials through linkage of chalcogenide tetrahedral clusters

Paz Vaqueiro

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Hybrid materials through linkage of chalcogenide tetrahedral clustersOriginalChemInform Abstract: Hybrid Materials Through Linkage of Chalcogenide Tetrahedral Clusters0Observation of in Situ Ligand Reactions during the Assembly of Crystalline Zn−S Clusters11Self-assembly of d-penicillaminato M6M′8 (M = Niii, Pdii, Ptii; M′ = Cui, Agi) clusters and their organization into extended LaiiiM6M′8 supramolecular structures19Three‐Dimensional Covalent Co‐Assembly between Inorganic Supertetrahedral Clusters and Imidazolates104Three‐Dimensional Covalent Co‐Assembly between Inorganic Supertetrahedral Clusters and Imidazolates14ST= 22 [Mn10] Supertetrahedral Building-Block to Design Extended Magnetic Networks25Solvothermal synthesis of a bimetallic thiometallate containing germanium in two oxidation states20From Molecule to Materials: Crystalline Superlattices of Nanoscopic CdS Clusters12Two-dimensional assembly of tetrahedral chalcogenide clusters with tetrakis(imidazolyl)borate ligands22Modular Metal Chalcogenide Chemistry: Secondary Building Blocks as a Basis of the Silicate‐Type Framework Structure of CsLiU(PS4)213Inorganic–organic hybrid compounds based on novel lanthanide-antimony oxohalide nanoclusters13Largest discrete supertetrahedral clusters synthesized in ionic liquids121A 3-D chiral organic–inorganic hybrid zinc vanadate assembled from helical units20A new polymorph telluridoindate [In(en)3][In5Te9(en)2] with photocatalytic properties12Polymeric supertetrahedral InS clusters assembled by new linkages18Growing Crystalline Chalcogenidoarsenates in Surfactants: From Zero-Dimensional Cluster to Three-Dimensional Framework285Metal Chalcogenides Tetrahedral Molecular Clusters: Crystal Engineering and Properties1Synthesis of Complex Polymeric Telluridoindates from KInTe210Kinetically Controlling Phase Transformations of Crystalline Mercury Selenidostannates through Surfactant Media121Changes in the Structural Dimensionality of Selenidostannates in Ionic Liquids: Formation, Structures, Stability, and Photoconductivity50Solvothermal syntheses of three new one-dimensional ternary selenidostannates: [DBNH][M1/2Sn1/2Se2] (M=Mn, Zn, Hg)14Syntheses, crystal structures, and properties of two new one-dimensional heterometallic selenides: [DBNH]4[M3Sn4Se11(Se2)2] (M = Cd, Hg)14Synthesis of anST= 7 [Mn3] Mixed-Valence Complex Based on 1,3-Propanediol Ligand Derivatives and Its One-Dimensional Assemblies11An infinite square lattice of super-supertetrahedral T6-like tin oxyselenide clusters37New strategies to prepare crystalline chalcogenides165Atomically Precise Doping of Monomanganese Ion into Coreless Supertetrahedral Chalcogenide Nanocluster Inducing Unusual Red Shift in Mn2+ Emission172Ligand-Participated Formation of Covalent Superlattices Containing [Cd4(μ-SPh)6] Cores with Adamantane-Like Stereochemistry6Visible‐Light‐Driven, Tunable, Photoelectrochemical Performance of a Series of Metal‐Chelate, Dye‐Organized, Crystalline, CdS Nanoclusters27Mit Tetraedern zum Ziel1Construction of a series of zero-dimensional/one-dimensional crystalline Zn–S clusters – effect of the character of bridging organic ligands on structural diversity14Stepwise assembly of a semiconducting coordination polymer [Cd 8 S(SPh) 14 (DMF)(bpy)] n and its photodegradation of organic dyes21Mono and digallium selenide clusters as potential superhalogens8Controlled Solvothermal Routes to Hierarchical 3D Superparticles of Nanoscopic CdS23Synthese kristalliner Chalkogenide in ionischen Flüssigkeiten43Synthesis of Crystalline Chalcogenides in Ionic Liquids150Highly effective nanosegregation of dual dopants in a micron-sized nanocluster-based semiconductor molecular single crystal for targeting white-light emission23Large Metal Chalcogenide Clusters and Their Ordered Superstructures via Solvothermal and Ionothermal Syntheses8Octanuclear Silver Sulfide Cluster [Ag8(µ8‐S)(µ‐mimt)12](NO3)6 Containing the First Thione‐Stabilized Ag8 Cube Caging a Sulfide Anion2Unprecedented 3D and 2D Frameworks of Manganese Thioarsenates Based on Heterometallic Cubic Cluster [Mn6(µ6‐S)(AsS3)4] and Covalent Linker N2H46Synthesis, Crystal Structures and Properties of a Series of Lanthanide Adipates [Ln 2(ad)3(H2O)4] (Ln = Y3+, Ho3+, Er3+, Tm3+)7A new class of hybrid super-supertetrahedral cluster and its assembly into a five-fold interpenetrating network26Assembly of supertetrahedral clusters into a Cu–In–S superlattice via an unprecedented vertex–edge connection mode11Recent progress in crystalline metal chalcogenides as efficient photocatalysts for organic pollutant degradation179Luminescent CdSe Superstructures: A Nanocluster Superlattice and a Nanoporous Crystal30Silver–Sulfur Hybrid Supertetrahedral Clusters: The Hitherto Missing Members in the Metal–Chalcogenide Tetrahedral Clusters20Crystalline Superlattices of Nanoscopic CdS Molecular Clusters: An X-ray Crystallography and111Cd SSNMR Spectroscopy Study9Discrete Supertetrahedral T3 InQ Clusters (Q = S, S/Se, Se, Se/Te): Ionothermal Syntheses and Tunable Optical and Photodegradation Properties34Unusual Flexibility of Microporous Sulfides during Ion Exchange52Crystal-to-crystal interconversion of open and closed dicopper( ii ) paddle wheels in a heterotrimetallic coordination polymer8Interlinking supertetrahedral chalcogenolate clusters with bipyridines to form two-dimensional coordination polymers for photocatalytic degradation of organic dye27Germanite derivative materials : synthesis, crystallographic structure from multi-scale characterizations and thermoelectric properties0[Bmmim] 6 [In 10 Se 16 Cl 4 ]·(MIm) 2 : an organic-ligand free discrete T3 cluster for efficient hydrogen evolution under visible light irradiation12An unprecedented cobalt( ii )-containing Wells–Dawson-type tungstovanadate-based metal–organic framework as an efficient catalyst for ring-opening polymerization of ε-caprolactone15Controllable incorporation of 1,2,4-triazolate into cluster-based metal-chalcogenide frameworks5Assembly of Discrete Chalcogenolate Clusters into a One-Dimensional Coordination Polymer with Enhanced Photocatalytic Activity and Stability32Metal Chalcogenide Supertetrahedral Clusters: Synthetic Control over Assembly, Dispersibility, and Their Functional Applications124Discrete Supertetrahedral Tn Chalcogenido Clusters Synthesized in Ionic Liquids: Crystal Structures and Photocatalytic Activity13Atomically precise metal chalcogenide supertetrahedral clusters: frameworks to molecules, and structure to function79A Discrete Ligand-Free T3 Supertetrahedral Cluster of Gallium Sulfide3Open-Framework Chalcogenide Materials - from isolated clusters to highly ordered structures - and their photocalytic applications25Atomic precision in other nanocluster systems: Chalcogenides1Solvothermal and hydrothermal methods for preparative solid-state chemistry5Platonic and Archimedean solids in discrete metal-containing clusters138Selective and benign alkylation of sulfido-oxo stannate clusters with propyl, pentyl, or hexyl substituents3Bifunctional Supertetrahedral Chalcogenolate Cluster-Based Assembly Materials Constructed by a Photoactive Ligand4Synthesis and Assembly of Cadmium Chalcogenide Supertetrahedral Clusters0Ligand Influence on Indium–Sulfide Cluster Formation and Reactivity0Structure-property correlation in atomically precise Group-12 nanoclusters and their alloys with Group-11 coinage metals0

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  1. ChemInform Abstract: Hybrid Materials Through Linkage of Chalcogenide Tetrahedral Clusters

    ChemInform · 2010-10-07

    Paz Vaqueiro

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  2. Observation of in Situ Ligand Reactions during the Assembly of Crystalline Zn−S Clusters

    Crystal Growth & Design · 2010-12-17

    Jingli Xie, Stuart R. Batten, Yang Zou, Xiao‐Ming Ren

    Read original paper ↗ ·

  3. Self-assembly of d-penicillaminato M6M′8 (M = Niii, Pdii, Ptii; M′ = Cui, Agi) clusters and their organization into extended LaiiiM6M′8 supramolecular structures

    Dalton Transactions · 2011-01-01

    Nobuto Yoshinari, Takumi Konno

    Read original paper ↗ ·

  4. Three‐Dimensional Covalent Co‐Assembly between Inorganic Supertetrahedral Clusters and Imidazolates

    Angewandte Chemie International Edition · 2011-02-23

    Tao Wu, Ripsime Khazhakyan, Le Wang, Xianhui Bu, Shou‐Tian Zheng, Victoria Chau, Pingyun Feng

    Read original paper ↗ ·

  5. Three‐Dimensional Covalent Co‐Assembly between Inorganic Supertetrahedral Clusters and Imidazolates

    Angewandte Chemie · 2011-02-23

    Tao Wu, Ripsime Khazhakyan, Le Wang, Xianhui Bu, Shou‐Tian Zheng, Victoria Chau, Pingyun Feng

    Read original paper ↗ ·

  6. ST= 22 [Mn10] Supertetrahedral Building-Block to Design Extended Magnetic Networks

    Inorganic Chemistry · 2011-08-05

    Gang Wu, Jian Ping Huang, Linlin Sun, Jiaquan Bai, Guanghua Li, E. Cremades, Eliseo Ruíz, Rodolphe Clérac, Shilun Qiu

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  7. Solvothermal synthesis of a bimetallic thiometallate containing germanium in two oxidation states

    Journal of Solid State Chemistry · 2011-10-05

    Anthony V. Powell, Rosalyn Mackay

    Read original paper ↗ ·

  8. From Molecule to Materials: Crystalline Superlattices of Nanoscopic CdS Clusters

    Chemistry - A European Journal · 2011-11-18

    Tetyana I. Levchenko, Christian Kübel, Yining Huang, John F. Corrigan

    Read original paper ↗ ·

  9. Two-dimensional assembly of tetrahedral chalcogenide clusters with tetrakis(imidazolyl)borate ligands

    Dalton Transactions · 2011-12-12

    Ziyi Chen, Daibing Luo, Xiuchao Luo, Maoping Kang, Zhien Lin

    Read original paper ↗ ·

  10. Modular Metal Chalcogenide Chemistry: Secondary Building Blocks as a Basis of the Silicate‐Type Framework Structure of CsLiU(PS4)2

    Zeitschrift für anorganische und allgemeine Chemie · 2011-12-16

    Christine Neuhausen, Frank Rocker, Wolfgang Tremel

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  11. Inorganic–organic hybrid compounds based on novel lanthanide-antimony oxohalide nanoclusters

    Dalton Transactions · 2012-01-01

    Bing Hu, Guo‐Dong Zou, Mei‐Ling Feng, Xiao‐Ying Huang

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  12. Largest discrete supertetrahedral clusters synthesized in ionic liquids

    Chemical Science · 2012-01-01

    Wei‐Wei Xiong, Jian‐Rong Li, Bing Hu, Bin Tan, Renfu Li, Xiao‐Ying Huang

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  13. A 3-D chiral organic–inorganic hybrid zinc vanadate assembled from helical units

    Dalton Transactions · 2012-11-30

    Jian Zhou, Xing Liu, Rong Chen, Fei-Long Hu, Hua‐Hong Zou, Meixiao Wei

    Read original paper ↗ ·

  14. A new polymorph telluridoindate [In(en)3][In5Te9(en)2] with photocatalytic properties

    Inorganic Chemistry Communications · 2012-12-12

    Rong Chen, Jian Zhou, Xing Liu, Fei-Long Hu, Litao An, Yu‐He Kan, Chen‐jian Xue

    Read original paper ↗ ·

  15. Polymeric supertetrahedral InS clusters assembled by new linkages

    CrystEngComm · 2013-01-01

    Yuhong Wang, Jian-Bing Jiang, Peng Wang, Xiao-Lu Sun, Qin‐Yu Zhu, Jie Dai

    Read original paper ↗ ·

  16. Growing Crystalline Chalcogenidoarsenates in Surfactants: From Zero-Dimensional Cluster to Three-Dimensional Framework

    Journal of the American Chemical Society · 2013-01-11

    Wei‐Wei Xiong, Eashwer Athresh, Yu Ting Ng, Junfeng Ding, Tom Wu, Qichun Zhang

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  17. Metal Chalcogenides Tetrahedral Molecular Clusters: Crystal Engineering and Properties

    InTech eBooks · 2013-02-20

    Chun‐Chang Ou, Chung‐Sung Yang

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  18. Synthesis of Complex Polymeric Telluridoindates from KInTe2

    Inorganic Chemistry · 2013-03-27

    Johanna Heine, Silke Santner, Stefanie Dehnen

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  19. Kinetically Controlling Phase Transformations of Crystalline Mercury Selenidostannates through Surfactant Media

    Inorganic Chemistry · 2013-04-04

    Wei‐Wei Xiong, Pei‐Zhou Li, Tianhua Zhou, Alfred Iing Yoong Tok, Rong Qing Xu, Yanli Zhao, Qichun Zhang

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  20. Changes in the Structural Dimensionality of Selenidostannates in Ionic Liquids: Formation, Structures, Stability, and Photoconductivity

    Chemistry - A European Journal · 2013-05-15

    Yu‐Mei Lin, Dewang Xie, Werner Massa, Leonhard Mayrhofer, Sina Lippert, Benjamin Ewers, Alexey Chernikov, Martín Koch, Stefanie Dehnen

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  21. Solvothermal syntheses of three new one-dimensional ternary selenidostannates: [DBNH][M1/2Sn1/2Se2] (M=Mn, Zn, Hg)

    Journal of Solid State Chemistry · 2013-05-28

    Wei‐Wei Xiong, Pei‐Zhou Li, Tianhua Zhou, Yanli Zhao, Rong Qing Xu, Qichun Zhang

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  22. Syntheses, crystal structures, and properties of two new one-dimensional heterometallic selenides: [DBNH]4[M3Sn4Se11(Se2)2] (M = Cd, Hg)

    Inorganic Chemistry Communications · 2013-07-31

    Wei‐Wei Xiong, Kaiqi Ye, Ling Ye, Qichun Zhang

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  23. Synthesis of anST= 7 [Mn3] Mixed-Valence Complex Based on 1,3-Propanediol Ligand Derivatives and Its One-Dimensional Assemblies

    Inorganic Chemistry · 2013-09-12

    Jian Ping Huang, Gang Wu, Jiaquan Bai, Yuan Jiang, Guanghua Li, Shilun Qiu, Rodolphe Clérac

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  24. An infinite square lattice of super-supertetrahedral T6-like tin oxyselenide clusters

    Chemical Communications · 2014-01-01

    Qipu Lin, Xianhui Bu, Pingyun Feng

    Read original paper ↗ ·

  25. New strategies to prepare crystalline chalcogenides

    Inorganic Chemistry Frontiers · 2014-01-01

    Wei‐Wei Xiong, Guodong Zhang, Qichun Zhang

    Read original paper ↗ ·

  26. Atomically Precise Doping of Monomanganese Ion into Coreless Supertetrahedral Chalcogenide Nanocluster Inducing Unusual Red Shift in Mn2+ Emission

    Journal of the American Chemical Society · 2014-03-13

    Jian Lin, Qian Zhang, Le Wang, Xiaochun Liu, Wenbo Yan, Tao Wu, Xianhui Bu, Pingyun Feng

    Read original paper ↗ ·

  27. Ligand-Participated Formation of Covalent Superlattices Containing [Cd4(μ-SPh)6] Cores with Adamantane-Like Stereochemistry

    Journal of Cluster Science · 2014-03-31

    Chao Xu, Hua‐Tian Shi, Zhifeng Xin, Ai‐Quan Jia, Qian‐Feng Zhang

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  28. Visible‐Light‐Driven, Tunable, Photoelectrochemical Performance of a Series of Metal‐Chelate, Dye‐Organized, Crystalline, CdS Nanoclusters

    Chemistry - A European Journal · 2014-05-28

    Yang Liu, Qipu Lin, Qichun Zhang, Xianhui Bu, Pingyun Feng

    Read original paper ↗ ·

  29. Mit Tetraedern zum Ziel

    Nachrichten aus der Chemie · 2014-07-01

    Johanna Heine, Bastian Weinert, Stefanie Dehnen

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  30. Construction of a series of zero-dimensional/one-dimensional crystalline Zn–S clusters – effect of the character of bridging organic ligands on structural diversity

    Inorganic Chemistry Frontiers · 2014-12-19

    Xianghua Zeng, Xiaojing Yao, Junyong Zhang, Qi Zhang, Wenqian Wu, Aihua Chai, Jinlan Wang, Qingdao Zeng, Jingli Xie

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  31. Stepwise assembly of a semiconducting coordination polymer [Cd 8 S(SPh) 14 (DMF)(bpy)] n and its photodegradation of organic dyes

    Dalton Transactions · 2015-01-01

    Chao Xu, Niklas Hedin, Hua‐Tian Shi, Zhifeng Xin, Qian‐Feng Zhang

    Read original paper ↗ ·

  32. Mono and digallium selenide clusters as potential superhalogens

    Journal of Molecular Modeling · 2015-02-12

    Neelum Seeburrun, Edet F. Archibong, Ponnadurai Ramasami

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  33. Controlled Solvothermal Routes to Hierarchical 3D Superparticles of Nanoscopic CdS

    Chemistry of Materials · 2015-05-05

    Tetyana I. Levchenko, Christian Kübel, Di Wang, Bahareh Khalili Najafabadi, Yining Huang, John F. Corrigan

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  34. Synthese kristalliner Chalkogenide in ionischen Flüssigkeiten

    Angewandte Chemie · 2015-12-11

    Silke Santner, Johanna Heine, Stefanie Dehnen

    Read original paper ↗ ·

  35. Synthesis of Crystalline Chalcogenides in Ionic Liquids

    Angewandte Chemie International Edition · 2015-12-11

    Silke Santner, Johanna Heine, Stefanie Dehnen

    Read original paper ↗ ·

  36. Highly effective nanosegregation of dual dopants in a micron-sized nanocluster-based semiconductor molecular single crystal for targeting white-light emission

    Journal of Materials Chemistry C · 2016-01-01

    Jian Lin, Le Wang, Qian Zhang, Fei Bu, Tao Wu, Xianhui Bu, Pingyun Feng

    Read original paper ↗ ·

  37. Large Metal Chalcogenide Clusters and Their Ordered Superstructures via Solvothermal and Ionothermal Syntheses

    Structure and bonding · 2016-01-01

    Tetyana I. Levchenko, Yining Huang, John F. Corrigan

    Read original paper ↗ ·

  38. Octanuclear Silver Sulfide Cluster [Ag8(µ8‐S)(µ‐mimt)12](NO3)6 Containing the First Thione‐Stabilized Ag8 Cube Caging a Sulfide Anion

    European Journal of Inorganic Chemistry · 2016-07-01

    Yali Shen, Shuzhen Liu, Peipei Sun, Chunying Tang, Dingxian Jia

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  39. Unprecedented 3D and 2D Frameworks of Manganese Thioarsenates Based on Heterometallic Cubic Cluster [Mn6(µ6‐S)(AsS3)4] and Covalent Linker N2H4

    European Journal of Inorganic Chemistry · 2016-07-22

    Chunying Tang, Yali Shen, Peipei Sun, ShuZhen Liu, Jingyu Han, Yun Liu, Hui Sun, Dingxian Jia

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  40. Synthesis, Crystal Structures and Properties of a Series of Lanthanide Adipates [Ln 2(ad)3(H2O)4] (Ln = Y3+, Ho3+, Er3+, Tm3+)

    Journal of Cluster Science · 2016-08-26

    Xiao-Feng Tan, Jian Zhou, Hua‐Hong Zou, Hong‐Ping Xiao, Qiuling Tang, Tingting Jiang, Xiaoyan Zhang

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  41. A new class of hybrid super-supertetrahedral cluster and its assembly into a five-fold interpenetrating network

    Dalton Transactions · 2017-01-01

    Paz Vaqueiro, Sarah Makin, Y. Tong, Sarah J. Ewing

    Read original paper ↗ ·

  42. Assembly of supertetrahedral clusters into a Cu–In–S superlattice via an unprecedented vertex–edge connection mode

    CrystEngComm · 2017-01-01

    Hongxiang Wang, Huajun Yang, Wei Wang, Chaozhuang Xue, Yingying Zhang, Min Luo, Dandan Hu, Jian Lin, Dong‐Sheng Li, Tao Wu

    Read original paper ↗ ·

  43. Recent progress in crystalline metal chalcogenides as efficient photocatalysts for organic pollutant degradation

    Inorganic Chemistry Frontiers · 2017-01-01

    Lina Nie, Qichun Zhang

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  44. Luminescent CdSe Superstructures: A Nanocluster Superlattice and a Nanoporous Crystal

    Journal of the American Chemical Society · 2017-01-13

    Tetyana I. Levchenko, Christian Kübel, Bahareh Khalili Najafabadi, Paul D. Boyle, Carolyn Cadogan, Lyudmila V. Goncharova, Alexandre Garreau, François Lagugné‐Labarthet, Yining Huang, John F. Corrigan

    Read original paper ↗ ·

  45. Silver–Sulfur Hybrid Supertetrahedral Clusters: The Hitherto Missing Members in the Metal–Chalcogenide Tetrahedral Clusters

    Chemistry - A European Journal · 2017-09-06

    Geng‐Geng Luo, Hai‐Feng Su, An Xiao, Zhi Wang, Yang Zhao, Qiao‐Yu Wu, Jihuai Wu, Di Sun, Lan‐Sun Zheng

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  46. Crystalline Superlattices of Nanoscopic CdS Molecular Clusters: An X-ray Crystallography and111Cd SSNMR Spectroscopy Study

    Inorganic Chemistry · 2017-12-15

    Tetyana I. Levchenko, Bryan E. G. Lucier, John F. Corrigan, Yining Huang

    Read original paper ↗ ·

  47. Discrete Supertetrahedral T3 InQ Clusters (Q = S, S/Se, Se, Se/Te): Ionothermal Syntheses and Tunable Optical and Photodegradation Properties

    Crystal Growth & Design · 2018-01-09

    Nan‐Nan Shen, Bing Hu, Chuchu Cheng, Guo‐Dong Zou, Qianqian Hu, Cheng‐Feng Du, Jian‐Rong Li, Xiao‐Ying Huang

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  48. Unusual Flexibility of Microporous Sulfides during Ion Exchange

    Inorganic Chemistry · 2018-10-10

    Ren‐Chun Zhang, Jingchao Zhang, Zhi Min Cao, Junjie Wang, Shuangshuang Liang, Hong-Jing Cong, He-Jie Wang, Dao‐Jun Zhang, Yong‐Lin An

    Read original paper ↗ ·

  49. Crystal-to-crystal interconversion of open and closed dicopper( ii ) paddle wheels in a heterotrimetallic coordination polymer

    Chemical Communications · 2019-01-01

    Hayato Ohwaki, Nobuto Yoshinari, Takumi Konno

    Read original paper ↗ ·

  50. Interlinking supertetrahedral chalcogenolate clusters with bipyridines to form two-dimensional coordination polymers for photocatalytic degradation of organic dye

    Dalton Transactions · 2019-01-01

    Chao Xu, Ming-Ming Sheng, Hua‐Tian Shi, Maria Strømme, Qian‐Feng Zhang

    Read original paper ↗ ·
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