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RESEARCH PAPER · Chemistry of Materials · 2015

PbGa2MSe6 (M = Si, Ge): Two Exceptional Infrared Nonlinear Optical Crystals

Zhong‐Zhen Luo, Chensheng Lin, Hong‐Hua Cui, Weilong Zhang, Hao Zhang, Hong Chen, Zhangzhen He, Wen‐Dan Cheng

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PbGa2MSe6 (M = Si, Ge): Two Exceptional Infrared Nonlinear Optical CrystalsOriginalBaGa 2 SnSe 6 : a new phase-matchable IR nonlinear optical material with strong second harmonic generation response58ChemInform Abstract: PbGa2MSe6 (M: Si, Ge): Two Exceptional Infrared Nonlinear Optical Crystals.0Preparation of Porous Three‐Dimensional Quaternary Thioantimonates(III) ACuSb2S4 (A=Rb, Cs) through a Surfactant‐Thermal Method29Metal Thiophosphates with Good Mid-infrared Nonlinear Optical Performances: A First-Principles Prediction and Analysis441Pb 5 Ga 6 ZnS 15 : a noncentrosymmetric framework with chains of T2-supertetrahedra41First principle calculation of physical properties of barium based chalcogenides BaM 4 S 7 (M = Ga, Al); a DFT, DFT-D and hybrid functional HSE06 study37Na 2 Hg 3 M 2 S 8 (M = Si, Ge, and Sn): New Infrared Nonlinear Optical Materials with Strong Second Harmonic Generation Effects and High Laser-Damage Thresholds186Na 2 BaMQ 4 (M=Ge, Sn; Q=S, Se): Infrared Nonlinear Optical Materials with Excellent Performances and that Undergo Structural Transformations202Na2BaMQ4 (M=Ge, Sn; Q=S, Se): Infrared Nonlinear Optical Materials with Excellent Performances and that Undergo Structural Transformations44A High Laser Damage Threshold and a Good Second-Harmonic Generation Response in a New Infrared NLO Material: LiSm3SiS725Non‐centrosymmetric Selenides AZn4In5Se12 (A=Rb, Cs): Synthesis, Characterization and Nonlinear Optical Properties47Crystal structure, electronic structure and physical properties of the new quaternary chalcogenides Tl 2 NdAg 3 Se 4 and Tl 2 NdAg 3 Te 48Infrared SHG Materials CsM3Se6 (M = Ga/Sn, In/Sn): Phase Matchability Controlled by Dipole Moment of the Asymmetric Building Unit102Recent achievements on middle and far-infrared second-order nonlinear optical materials433Ba 6 Li 2 CdSn 4 S 16 : lithium substitution simultaneously enhances band gap and SHG intensity44BaCu 2 M IV Q 4 (M IV = Si, Ge, and Sn; Q = S, Se): synthesis, crystal structures, optical performances and theoretical calculations54Na 6 Si 3 S 8 O: the first example of a sulfide silicate exhibiting unusual tri-polymerized [Si 3 S 8 O] 6− units without S–O bonds8Screening novel candidates for mid-IR nonlinear optical materials from I 3 –V–VI 4 compounds51Tailored synthesis of nonlinear optical quaternary chalcohalides: Ba 4 Ge 3 S 9 Cl 2 , Ba 4 Si 3 Se 9 Cl 2 and Ba 4 Ge 3 Se 9 Cl 252The first quaternary diamond-like semiconductor with 10-membered LiS 4 rings exhibiting excellent nonlinear optical performances104Two excellent phase-matchable infrared nonlinear optical materials based on 3D diamond-like frameworks: RbGaSn 2 Se 6 and RbInSn 2 Se 639Superpolyhedron-Built Second Harmonic Generation Materials Exhibit Large Mid-Infrared Conversion Efficiencies and High Laser-Induced Damage Thresholds101Mid-Infrared Nonlinear Optical Materials Based on Metal Chalcogenides: Structure–Property Relationship338Li2HgMS4 (M = Si, Ge, Sn): New Quaternary Diamond-Like Semiconductors for Infrared Laser Frequency Conversion64Pb0.65Mn2.85Ga3S8 and Pb0.72Mn2.84Ga2.95Se8: Two Quaternary Metal Chalcognides with Open-Tunnel-Framework Structures Displaying Intense Second Harmonic Generation Responses and Interesting Magnetic Properties17New Compressed Chalcopyrite-like Li2BaMIVQ4 (MIV = Ge, Sn; Q = S, Se): Promising Infrared Nonlinear Optical Materials245Large Second-Harmonic Generation Responses Achieved by the Dimeric [Ge2Se4(μ-Se2)]4– Functional Motif in Polar Polyselenides A4Ge4Se12 (A = Rb, Cs)49A Polyselenide with a Novel Se78– Unit: the Structure of Sr19–xPbxGe11Se44 with x = 5.0 and 6.44Experimental and theoretical studies on the NLO properties of two quaternary non-centrosymmetric chalcogenides: BaAg 2 GeS 4 and BaAg 2 SnS 468PbGa2GeS6: An Infrared Nonlinear Optical Material Synthesized by an Intermediate-Temperature Self-Fluxing Method42Four alkali metal molybdates with two types of Mo–O chains, ABMo 3 O 10 (A = Li, B = Rb; A = Li, Na, K, B = Cs): synthesis, structure comparison and optical properties10NaBaM III Q 3 (M III = Al, Ga; Q = S, Se): first quaternary chalcogenides with isolated edge-sharing (MIII2Q 6 ) 6− dimers8New strategy for designing promising mid-infrared nonlinear optical materials: narrowing the band gap for large nonlinear optical efficiencies and reducing the thermal effect for a high laser-induced damage threshold142Optimized oriented seed growth and optical properties of high-quality LiInSe 2 crystals13Remarkable multimember-ring configurations in a new family of Na 7 M II Sb 5 S 12 (M II = Zn, Cd, Hg) exhibiting various three-dimensional tunnel structures25A Member of Fluorooxoborates: Li2Na0.9K0.1B5O8F2 with the Fundamental Building Block B5O10F2 and a Short Cutoff Edge27PbGa2GeS6 crystal as a novel nonlinear optical material: Band structure aspects36Theoretical Evaluation on Terahertz Source Generators from Ternary Metal Chalcogenides of PbM6Te10 (M = Ga, In)30Four two-dimensional ternary selenides based on group 13 and 14 metals: Syntheses, crystal structures, and electrochemical properties6Nonbonding Electrons Driven Strong SHG Effect in Hg2GeSe4: Experimental and Theoretical Investigations61Structure and Optical Properties of the Li2In2GeSe6 Crystal13Module-Guided Design Scheme for Deep-Ultraviolet Nonlinear Optical Materials195Synthesis, Crystal Structure, and Optical Properties of Noncentrosymmetric Na2ZnSnS434V-doping in a potential nonlinear optical material Sr2Nb2O7 for increasing the SHG response: A first-principles study2Modifying Disordered Sites with Rational Cations to Regulate Band-Gaps and Second Harmonic Generation Responses Markedly: Ba6Li2ZnSn4S16 vs Ba6Ag2ZnSn4S16 vs Ba6Li2.67Sn4.33S1625Adduct-Type IR Nonlinear-Optical Crystal SbI 3 ·(S 8 ) 3 with a Large Second-Harmonic Generation and a High Laser-Induced Damage Threshold59A review on structure-performance relationship toward the optimal design of infrared nonlinear optical materials with balanced performances253A 2 SrM IV S 4 (A = Li, Na; M IV = Ge, Sn) concurrently exhibiting wide bandgaps and good nonlinear optical responses as new potential infrared nonlinear optical materials78A homo-chiral helical coordination polymer constructed from an achiral ligand with excellent photo-physical properties and cell imaging application7Ag 7 TaSe 6 : a new noncentrosymmetric selenide with fascinating “three in one” coordination modes and a strong second harmonic generation response13Growth and Characterization of PbGa2GeSе6: A New Quaternary Chalcogenide Nonlinear Crystal for the Mid-IR0Investigation on two new antimony-based quaternary chalcogenides: Na 6 CdSb 4 S 10 and Na 3 CdSbSe 41Li 2 ZnGeS 4 : a promising diamond-like infrared nonlinear optical material with high laser damage threshold and outstanding second-harmonic generation response43Mn-Based tin sulfide Sr 3 MnSn 2 S 8 with a wide band gap and strong nonlinear optical response30Rational design of a new chalcogenide with good infrared nonlinear optical performance: SrZnSnS 452SnGa 2 GeSe 6 , a benign addition to the AMIII2M IV Q 6 family: synthesis, crystal structure and nonlinear optical performance20Three new phosphates, Cs8Pb4(P2O7)4, CsLi7(P2O7)2 and LiCa(PO3)3: structural comparison, characterization and theoretical calculation23Theoretical Design of Layered AlGaS3 as a New Nonlinear Optical Material with a Strong Second Harmonic Generation Response5Balanced Second-Order Nonlinear Optical Properties of Adducts CHI3·(S8)3 and AsI3·(S8)3: A Systematic Survey48Growth and Characterization of PbGa 2 GeSe 6 : A New Quaternary Chalcogenide Nonlinear Crystal for the Mid-IR0Mixed-Anion Inorganic Compounds: A Favorable Candidate for Infrared Nonlinear Optical Materials140Crystal Growth and Characterization of a New Quaternary Chalcogenide Nonlinear Crystal for the Mid-Infrared: PbGa2GeSe611AHgSnQ4 (A = Sr, Ba; Q = S, Se): A Series of Hg-Based Infrared Nonlinear-Optical Materials with Strong Second-Harmonic-Generation Response and Good Phase Matchability76Sn 2 Ga 2 S 5 : A Polar Semiconductor with Exceptional Infrared Nonlinear Optical Properties Originating from the Combined Effect of Mixed Asymmetric Building Motifs81Ba 8 SrPb 24 O 24 Cl 18 : the first alkali-earth metal lead( ii ) oxyhalide with an intriguing multimember-ring layer9Sn2Ga2S5: A Type of IR Nonlinear-Optical Material22Atom-Resolved Analysis of Birefringence of Nonlinear Optical Crystals by Bader Charge Integration57A new family of quaternary thiosilicates SrA 2 SiS 4 (A = Li, Na, Cu) as promising infrared nonlinear optical crystals48Rational design of infrared nonlinear optical chalcogenides by chemical substitution287A review of the AI2B II C IV DVI4 family as infrared nonlinear optical materials: the effect of each site on the structure and optical properties59Coordinated regulation on critical physiochemical performances activated from mixed tetrahedral anionic ligands in new series of Sr 6 A 4 M 4 S 16 (A = Ag, Cu; M = Ge, Sn) nonlinear optical materials28Infrared Nonlinear Optical Polymorphs α- and β-SrCu 2 SnS 4 Exhibiting Large Second Harmonic Generation Responses with Requisite Phase-Matching Behavior44One-Dimensional Double Chains in Sodium-Based Quaternary Chalcogenides Displaying Intriguing Red Emission and Large Optical Anisotropy17Raman and Infrared Phonon Spectra of Novel Nonlinear Optical Materials PbGa 2 GeS 6 and PbGa 2 GeSe 6 : Experiment and Theory4AGaSnS4 (A = Rb, Cs): Three sulfides and their structure diversity8Molecular Construction from AgGaS 2 to CuZnPS 4 : Defect-Induced Second Harmonic Generation Enhancement and Cosubstitution-Driven Band Gap Enlargement97Highly anisotropic layered selenophosphate AgSbP2Se6: The electronic structure and optical properties by experimental measurements and first-principles calculations9A review on phase transition and structure-performance relationship of second-order nonlinear optical polymorphs107Chalcophosphates: A Treasure House of Infrared Nonlinear Optical Materials75Phase Matching, Strong Frequency Doubling, and Outstanding Laser-Induced Damage Threshold in the Biaxial, Quaternary Diamond-like Semiconductor Li 4 CdSn 2 S 779Recent Achievements in Lone-Pair Cation-Based Infrared Second-Order Nonlinear Optical Materials95Photoconductivity of the Single Crystals Pb4Ga4GeS12 and Pb4Ga4GeSe120A review on the recently developed promising infrared nonlinear optical materials103M 2 As 2 Q 5 (M = Ba, Pb; Q = S, Se): a source of infrared nonlinear optical materials with excellent overall performance activated by multiple discrete arsenate anions70Role of lone-pair electrons in determining the thermal transport behavior of LiAsS 2 : first-principles investigation5Na 6 MQ 4 (M=Zn, Cd; Q=S, Se): Promising New Ternary Infrared Nonlinear Optical Materials24Halonitrides Zn 2 NX (X=Cl,Br): Novel Mid-Infrared Nonlinear Optical Materials30Introduction of Li into Ag-Based Noncentrosymmetric Sulfides for High-Performance Infrared Nonlinear Optical Materials40Three-in-One Strategy Constructing a Series of Hybrid Tetrahedral Motif-Based Selenides with Balanced Second-Order Nonlinear Optical Performance12Inorganic Chalcogenides: From Zero‐Dimensional Clusters to Three‐Dimensional Frameworks5Solvothermal Syntheses of Three-Dimensional Open-Framework Thioantimonates Displaying Nonlinear Optical Responses5Stepwise Li Substitution Induced Structure Evolution and Improved Nonlinear Optical Performance for Diamond-like Sulfides28Synthesis, structure, linear and nonlinear optical properties of noncentrosymmetric quaternary diamond-like semiconductors, Cu2ZnGeSe4 (CZGSe) and the novel Cu4ZnGe2Se720SnPQ3 (Q = S, Se, S/Se): A Series of Lone-Pair Cationic Chalcogenophosphates Exhibiting Balanced NLO Activity Originating from SnQ8 Units49Noncentrosymmetric chalcohalide K2Ba3Ge3S9Cl2: A new nonlinear optical material with remarkable laser-induced damage threshold17Na+/Ag+ substitution induced birefringence enhancement from AgGaS2 to NaGaS218Noncentrosymmetric (KBa0.5)In2Se4 and (K0.58Ba0.71)(Ga0.89In1.11)Se4 derived from centrosymmetric BaIn2Se4 via partial cation substitution: structural chemistry and nonlinear optical activity9Sn7Br10S2: The First Ternary Halogen‐Rich Chalcohalide Exhibiting a Chiral Structure and Pronounced Nonlinear Optical Properties24Sn7Br10S2: The First Ternary Halogen‐Rich Chalcohalide Exhibiting a Chiral Structure and Pronounced Nonlinear Optical Properties146Rational combination of multiple structural groups on regulating nonlinear optical property in hexagonal Ln3MGeS7 polar crystals10Pb 4 SeBr 6 : A Congruently Melting Mid‐Infrared Nonlinear Optical Material with Excellent Comprehensive Performance39Growth of a novel K0.4Rb0.6Pb2Cl5 crystal and theoretical and experimental studies of its electronic and optical properties5Infrared nonlinear optical performances of a new sulfide β-PbGa2S415Impact of structure complexity on optoelectronic and non-linear optical properties in quaternary Ag(Pb)–Ga(In)–Si(Ge)–S(Se) systems13RbBiP2S6: A Promising IR Nonlinear Optical Material with a Giant Second-Harmonic Generation Response Designed by Aliovalent Substitution80A comprehensive review on metal chalcogenides with three-dimensional frameworks for infrared nonlinear optical applications115Recent developments on Bi-based oxychalcogenide materials with thermoelectric and optoelectronic applications: an overview33Component Interaction in the Quasi-Ternary System PbSe–Ga2Se3–GeSe21Revisiting two thiophosphate compounds constituting d 0 transition metal HfP 2 S 6 and d 10 transition metal α-Ag 4 P 2 S 6 as multifunctional materials for combining second harmonic generation response and photocurrent response12Synthesis, Crystal Structure, and Nonlinear-Optical Properties of a Diamond-Like Chalcogenide Cu 2 GeS 313Ga-based IR nonlinear optical materials: Synthesis, structures, and properties65Pb 6 Ba 3 Si 2 S 8 I 10 : a new thiohalide with a quasi-two-dimensional structure and wide band gap2RbPbPS 4 : a promising IR nonlinear optical material achieved by lone-pair-cation-substitution-induced structure transformation23Thermo-Mechanical Properties of Orthorhombic PbGa2GeSe60Vacancy‐Induced Extraordinary Second Harmonic Generation Response for Diamond‐Like Cu3PS49β-Pb3P2S8: A new optical crystal with exceptional birefringence effect12Design of a high-performance infrared birefringent crystal Ba 4 HgP 2 Se 10 via a low-dimensional motif intercalation strategy2Cd5As2Br4: A Ternary Arsenide with Nonlinear Optical Property3[K2PbI][Ga7Se12]: A New Lead-Containing Nonlinear Optical Material with Moderate Second-Harmonic Generation Response and Large Birefringence5Thermo-Mechanical Characterization of the Orthorhombic Nonlinear Optical Crystal PbGa2GeSe60Structure-property relationships in IR nonlinear optical chalcogenides with stereochemically active lone pairs29Vacancy-driven tetrahedral distortion leading to exceptional second harmonic generation3Modulating Nonlinear Optical Performances in α/β-SnGa2GeS6 Polymorphs via Atomic Coordination Engineering1CsGaGe₃Se₈: Enhanced optical anisotropy and bandgap via cation-substitution-driven dimensionality reduction0Maximizing the second-harmonic generation response via coordination-induced localization of nonbonding electrons12Pressure and composition tuning of structural and electronic properties of the ternary chalcohalide Pb4SeBr61KHg 4 Ga 5 S 12 : A Diamond-like Tetrahedral Chalcogenide Exhibiting Giant Phase-Matching Second Harmonic Generation6A Rigid‐Flexible Cooperative Bond‐Engineering Strategy for the Rational Design of Advanced Infrared Nonlinear Optical Crystals2From KBa 4 Ge 3 S 10 Cl to ABa 3 EuGe 3 S 11 (A = Na, K) Synthesized by Reactive Flux Assisted Metal Oxide-Boron-Chalcogen (MOBQ) Method: Effect of Cation/Anion Cosubstitution on Crystal Structure and Nonlinear Optical Properties0Heterometallic Ge–O–Sn-Bridged Oxychalcogenides Sr3GeSnO4Q3 (Q = S, Se) with Wide Band Gaps and Moderate Infrared Nonlinear Optical Responses0Mixed‐Valence Engineering in Ge 2+ Chalcogenides: Structural Modulation for Balanced Infrared Nonlinear Optics0

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  1. BaGa 2 SnSe 6 : a new phase-matchable IR nonlinear optical material with strong second harmonic generation response

    Journal of Materials Chemistry C · 2015-01-01

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  2. ChemInform Abstract: PbGa2MSe6 (M: Si, Ge): Two Exceptional Infrared Nonlinear Optical Crystals.

    ChemInform · 2015-04-01

    Zhong‐Zhen Luo, Chensheng Lin, Hong‐Hua Cui, Weilong Zhang, Hao Zhang, Hong Chen, Zhangzhen He, Wen‐Dan Cheng

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  3. Preparation of Porous Three‐Dimensional Quaternary Thioantimonates(III) ACuSb2S4 (A=Rb, Cs) through a Surfactant‐Thermal Method

    Chemistry - An Asian Journal · 2015-09-18

    Yaying Shen, Chang Liu, Peipei Hou, Mingjia Zhi, Chunmei Zhou, Wen‐Xiang Chai, Jian‐Wen Cheng, Yi Liu, Qichun Zhang

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  4. Metal Thiophosphates with Good Mid-infrared Nonlinear Optical Performances: A First-Principles Prediction and Analysis

    Journal of the American Chemical Society · 2015-09-23

    Lei Kang, Molin Zhou, Jiyong Yao, Zheshuai Lin, Yicheng Wu, Chuangtian Chen

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  5. Pb 5 Ga 6 ZnS 15 : a noncentrosymmetric framework with chains of T2-supertetrahedra

    Dalton Transactions · 2016-01-01

    Ruihuan Duan, Ju‐Song Yu, Hua Lin, Yujun Zheng, Hua‐Jun Zhao, Shangxiong Huangfu, Muhammad Ali Khan, Ling Chen, Li‐Ming Wu

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  6. First principle calculation of physical properties of barium based chalcogenides BaM 4 S 7 (M = Ga, Al); a DFT, DFT-D and hybrid functional HSE06 study

    Optical Materials · 2016-02-27

    Ali Benghia, Tahar Dahame, Bachir Bentria

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  7. Na 2 Hg 3 M 2 S 8 (M = Si, Ge, and Sn): New Infrared Nonlinear Optical Materials with Strong Second Harmonic Generation Effects and High Laser-Damage Thresholds

    Chemistry of Materials · 2016-04-05

    Kui Wu, Zhihua Yang, Shilie Pan

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  8. Na 2 BaMQ 4 (M=Ge, Sn; Q=S, Se): Infrared Nonlinear Optical Materials with Excellent Performances and that Undergo Structural Transformations

    Angewandte Chemie International Edition · 2016-04-21

    Kui Wu, Zhihua Yang, Shilie Pan

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  9. Na2BaMQ4 (M=Ge, Sn; Q=S, Se): Infrared Nonlinear Optical Materials with Excellent Performances and that Undergo Structural Transformations

    Angewandte Chemie · 2016-04-21

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  10. A High Laser Damage Threshold and a Good Second-Harmonic Generation Response in a New Infrared NLO Material: LiSm3SiS7

    Crystals · 2016-09-23

    Ni Zhen, Leyan Nian, Guangmao Li, Kui Wu, Shilie Pan

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  11. Non‐centrosymmetric Selenides AZn4In5Se12 (A=Rb, Cs): Synthesis, Characterization and Nonlinear Optical Properties

    Chemistry - An Asian Journal · 2016-12-01

    Hua Lin, Yu‐Jun Zheng, Xiaoning Hu, Hong Chen, Ju‐Song Yu, Li‐Ming Wu

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  12. Crystal structure, electronic structure and physical properties of the new quaternary chalcogenides Tl 2 NdAg 3 Se 4 and Tl 2 NdAg 3 Te 4

    Inorganic Chemistry Frontiers · 2016-12-14

    Abdeljalil Assoud, Quansheng Guo, Cheriyedath Raj Sankar, Holger Kleinke

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  13. Infrared SHG Materials CsM3Se6 (M = Ga/Sn, In/Sn): Phase Matchability Controlled by Dipole Moment of the Asymmetric Building Unit

    Chemistry of Materials · 2016-12-26

    Hua Lin, Ling Chen, Ju‐Song Yu, Hong Chen, Li‐Ming Wu

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  14. Recent achievements on middle and far-infrared second-order nonlinear optical materials

    Coordination Chemistry Reviews · 2016-12-27

    Sheng‐Ping Guo, Yang Chi, Guo‐Cong Guo

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  15. Ba 6 Li 2 CdSn 4 S 16 : lithium substitution simultaneously enhances band gap and SHG intensity

    Journal of Materials Chemistry C · 2017-01-01

    Ruihuan Duan, Pengfei Liu, Hua Lin, Yi‐Wen Zheng, Ju‐Song Yu, Xin‐Tao Wu, Shangxiong Huangfu, Ling Chen

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  16. BaCu 2 M IV Q 4 (M IV = Si, Ge, and Sn; Q = S, Se): synthesis, crystal structures, optical performances and theoretical calculations

    RSC Advances · 2017-01-01

    Leyan Nian, Junben Huang, Kui Wu, Zhi Su, Zhihua Yang, Shilie Pan

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  17. Na 6 Si 3 S 8 O: the first example of a sulfide silicate exhibiting unusual tri-polymerized [Si 3 S 8 O] 6− units without S–O bonds

    Dalton Transactions · 2017-01-01

    Kui Wu, Zhihua Yang, Shilie Pan

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  18. Screening novel candidates for mid-IR nonlinear optical materials from I 3 –V–VI 4 compounds

    Journal of Materials Chemistry C · 2017-01-01

    Zuju Ma, Jinyu Hu, Rongjian Sa, Qiaohong Li, Yongfan Zhang, Kechen Wu

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  19. Tailored synthesis of nonlinear optical quaternary chalcohalides: Ba 4 Ge 3 S 9 Cl 2 , Ba 4 Si 3 Se 9 Cl 2 and Ba 4 Ge 3 Se 9 Cl 2

    Dalton Transactions · 2017-01-01

    Pengfei Liu, Yanyan Li, Yujun Zheng, Ju‐Song Yu, Ruihuan Duan, Hong Chen, Hua Lin, Ling Chen, Li‐Ming Wu

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  20. The first quaternary diamond-like semiconductor with 10-membered LiS 4 rings exhibiting excellent nonlinear optical performances

    Chemical Communications · 2017-01-01

    Kui Wu, Zhihua Yang, Shilie Pan

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  21. Two excellent phase-matchable infrared nonlinear optical materials based on 3D diamond-like frameworks: RbGaSn 2 Se 6 and RbInSn 2 Se 6

    Dalton Transactions · 2017-01-01

    Hua Lin, Hong Chen, Yujun Zheng, Ju‐Song Yu, Xin‐Tao Wu, Li‐Ming Wu

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  22. Superpolyhedron-Built Second Harmonic Generation Materials Exhibit Large Mid-Infrared Conversion Efficiencies and High Laser-Induced Damage Thresholds

    Chemistry of Materials · 2017-01-30

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  23. Mid-Infrared Nonlinear Optical Materials Based on Metal Chalcogenides: Structure–Property Relationship

    Crystal Growth & Design · 2017-03-15

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  24. Li2HgMS4 (M = Si, Ge, Sn): New Quaternary Diamond-Like Semiconductors for Infrared Laser Frequency Conversion

    Crystals · 2017-04-12

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  25. Pb0.65Mn2.85Ga3S8 and Pb0.72Mn2.84Ga2.95Se8: Two Quaternary Metal Chalcognides with Open-Tunnel-Framework Structures Displaying Intense Second Harmonic Generation Responses and Interesting Magnetic Properties

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  26. New Compressed Chalcopyrite-like Li2BaMIVQ4 (MIV = Ge, Sn; Q = S, Se): Promising Infrared Nonlinear Optical Materials

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  27. Large Second-Harmonic Generation Responses Achieved by the Dimeric [Ge2Se4(μ-Se2)]4– Functional Motif in Polar Polyselenides A4Ge4Se12 (A = Rb, Cs)

    Chemistry of Materials · 2017-10-05

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  28. A Polyselenide with a Novel Se78– Unit: the Structure of Sr19–xPbxGe11Se44 with x = 5.0 and 6.4

    European Journal of Inorganic Chemistry · 2017-11-09

    Abdeljalil Assoud, Holger Kleinke

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  29. Experimental and theoretical studies on the NLO properties of two quaternary non-centrosymmetric chalcogenides: BaAg 2 GeS 4 and BaAg 2 SnS 4

    Dalton Transactions · 2017-11-27

    Hong Chen, Pei-Fei Liu, Bingxuan Li, Hua Lin, Li‐Ming Wu, Xin‐Tao Wu

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  30. PbGa2GeS6: An Infrared Nonlinear Optical Material Synthesized by an Intermediate-Temperature Self-Fluxing Method

    Crystal Growth & Design · 2017-12-28

    Yi‐Zhi Huang, Hao Zhang, Chensheng Lin, Wen‐Dan Cheng, Zhengxiao Guo, Guoliang Chai

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  31. Four alkali metal molybdates with two types of Mo–O chains, ABMo 3 O 10 (A = Li, B = Rb; A = Li, Na, K, B = Cs): synthesis, structure comparison and optical properties

    New Journal of Chemistry · 2018-01-01

    Shujuan Han, Bingbing Zhang, Tinghao Tong, Zhihua Yang, Shilie Pan

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  32. NaBaM III Q 3 (M III = Al, Ga; Q = S, Se): first quaternary chalcogenides with isolated edge-sharing (MIII2Q 6 ) 6− dimers

    Dalton Transactions · 2018-01-01

    Ailijiang Abudurusuli, Kui Wu, Yilimiranmu Rouzhahong, Zhihua Yang, Shilie Pan

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  33. New strategy for designing promising mid-infrared nonlinear optical materials: narrowing the band gap for large nonlinear optical efficiencies and reducing the thermal effect for a high laser-induced damage threshold

    Chemical Science · 2018-01-01

    Shu‐Fang Li, Xiao‐Ming Jiang, Yuhang Fan, Bin‐Wen Liu, Hui‐Yi Zeng, Guo‐Cong Guo

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  34. Optimized oriented seed growth and optical properties of high-quality LiInSe 2 crystals

    CrystEngComm · 2018-01-01

    Ning Jia, Xixi Xiong, Shanpeng Wang, Tongtong Yu, Bing Q. Han, Jie Qiao, Chenning Li, Xutang Tao

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  35. Remarkable multimember-ring configurations in a new family of Na 7 M II Sb 5 S 12 (M II = Zn, Cd, Hg) exhibiting various three-dimensional tunnel structures

    Chemical Communications · 2018-01-01

    Kui Wu, Bingbing Zhang, Zhihua Yang, Shilie Pan

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  36. A Member of Fluorooxoborates: Li2Na0.9K0.1B5O8F2 with the Fundamental Building Block B5O10F2 and a Short Cutoff Edge

    Inorganic Chemistry · 2018-01-02

    Shujuan Han, Ying Wang, Bingbing Zhang, Zhihua Yang, Shilie Pan

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  37. PbGa2GeS6 crystal as a novel nonlinear optical material: Band structure aspects

    Journal of Alloys and Compounds · 2018-01-02

    A.O. Fedorchuk, O.V. Parasyuk, Oleksandr Cherniushok, Bohdan V. Andriyevsky, G.L. Myronchuk, Oleg Yu Khyzhun, Gandham Lakshminarayana, Jarosław Jedryka, Ivan V. Kityk, Ahmed M. El-Naggar, A.A. Albassam, Michał Piasecki

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  38. Theoretical Evaluation on Terahertz Source Generators from Ternary Metal Chalcogenides of PbM6Te10 (M = Ga, In)

    The Journal of Physical Chemistry C · 2018-02-03

    Wen‐Dan Cheng, Chensheng Lin, Hao Zhang, Guoliang Chai

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  39. Four two-dimensional ternary selenides based on group 13 and 14 metals: Syntheses, crystal structures, and electrochemical properties

    Journal of Solid State Chemistry · 2018-04-16

    Jingrui Wang, Peng Li, Ting Cai, Dandan Yang, Wei‐Wei Xiong

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  40. Nonbonding Electrons Driven Strong SHG Effect in Hg2GeSe4: Experimental and Theoretical Investigations

    Inorganic Chemistry · 2018-06-06

    Yangwu Guo, Fei Liang, Jiyong Yao, Zheshuai Lin, Wenlong Yin, Yicheng Wu, Chuangtian Chen

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  43. Synthesis, Crystal Structure, and Optical Properties of Noncentrosymmetric Na2ZnSnS4

    Inorganic Chemistry · 2018-08-03

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  44. V-doping in a potential nonlinear optical material Sr2Nb2O7 for increasing the SHG response: A first-principles study

    Chemical Physics Letters · 2018-08-06

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  45. Modifying Disordered Sites with Rational Cations to Regulate Band-Gaps and Second Harmonic Generation Responses Markedly: Ba6Li2ZnSn4S16 vs Ba6Ag2ZnSn4S16 vs Ba6Li2.67Sn4.33S16

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  46. Adduct-Type IR Nonlinear-Optical Crystal SbI 3 ·(S 8 ) 3 with a Large Second-Harmonic Generation and a High Laser-Induced Damage Threshold

    Inorganic Chemistry · 2018-08-23

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  47. A review on structure-performance relationship toward the optimal design of infrared nonlinear optical materials with balanced performances

    Coordination Chemistry Reviews · 2018-09-20

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  48. A 2 SrM IV S 4 (A = Li, Na; M IV = Ge, Sn) concurrently exhibiting wide bandgaps and good nonlinear optical responses as new potential infrared nonlinear optical materials

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  49. A homo-chiral helical coordination polymer constructed from an achiral ligand with excellent photo-physical properties and cell imaging application

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  50. Ag 7 TaSe 6 : a new noncentrosymmetric selenide with fascinating “three in one” coordination modes and a strong second harmonic generation response

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