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RESEARCH PAPER · Angewandte Chemie · 2016

Na2BaMQ4 (M=Ge, Sn; Q=S, Se): Infrared Nonlinear Optical Materials with Excellent Performances and that Undergo Structural Transformations

Kui Wu, Zhihua Yang, Shilie Pan

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Na2BaMQ4 (M=Ge, Sn; Q=S, Se): Infrared Nonlinear Optical Materials with Excellent Performances and that Undergo Structural TransformationsOriginalCrystal and electronic structures, and photoluminescence and photocatalytic properties of α-EuZrS 326Na 9 Sb(Ge 2 Q 6 ) 2 (Q = S, Se): two new antimony( iii ) quaternary chalcogenides with ethane-like [Ge 2 Q 6 ] 6− ligands12Pb 5 Ga 6 ZnS 15 : a noncentrosymmetric framework with chains of T2-supertetrahedra41A High Laser Damage Threshold and a Good Second-Harmonic Generation Response in a New Infrared NLO Material: LiSm3SiS725Non‐centrosymmetric Selenides AZn4In5Se12 (A=Rb, Cs): Synthesis, Characterization and Nonlinear Optical Properties47Recent achievements on middle and far-infrared second-order nonlinear optical materials433Ba 6 Li 2 CdSn 4 S 16 : lithium substitution simultaneously enhances band gap and SHG intensity44Na 2 CdGe 2 Q 6 (Q = S, Se): two metal-mixed chalcogenides with phase-matching abilities and large second-harmonic generation responses78Tailored synthesis of nonlinear optical quaternary chalcohalides: Ba 4 Ge 3 S 9 Cl 2 , Ba 4 Si 3 Se 9 Cl 2 and Ba 4 Ge 3 Se 9 Cl 252The first quaternary diamond-like semiconductor with 10-membered LiS 4 rings exhibiting excellent nonlinear optical performances104First-principles study lone-pair effects of Sb (III)-S chromophore influence on SHG response in quaternary potassium containing silver antimony sulfides12Li3VO4: A Promising Mid-Infrared Nonlinear Optical Material with Large Laser Damage Threshold51Li2HgMS4 (M = Si, Ge, Sn): New Quaternary Diamond-Like Semiconductors for Infrared Laser Frequency Conversion64Growth, Properties, and Theoretical Analysis of M2LiVO4 (M = Rb, Cs) Crystals: Two Potential Mid-Infrared Nonlinear Optical Materials36Ba 6 Zn 7 Ga 2 S 16 : A Wide Band Gap Sulfide with Phase-Matchable Infrared NLO Properties111Coexistence of Strong Second Harmonic Generation Response and Wide Band Gap in AZn4Ga5S12 (A=K, Rb, Cs) with 3D Diamond‐like Frameworks65AgGa2PS6: A New Mid‐Infrared Nonlinear Optical Material with a High Laser Damage Threshold and a Large Second Harmonic Generation Response78Synthesis and characterization of two lead-containing metal chalcogenides: Ba5Pb2Sn3S13 and Ba6PbSn3Se137New Compressed Chalcopyrite-like Li2BaMIVQ4 (MIV = Ge, Sn; Q = S, Se): Promising Infrared Nonlinear Optical Materials245LiGaGe2S6: A Chalcogenide with Good Infrared Nonlinear Optical Performance and Low Melting Point56A Polyselenide with a Novel Se78– Unit: the Structure of Sr19–xPbxGe11Se44 with x = 5.0 and 6.44Remarkable multimember-ring configurations in a new family of Na 7 M II Sb 5 S 12 (M II = Zn, Cd, Hg) exhibiting various three-dimensional tunnel structures25Structural insights into T 2 -cluster-containing chalcogenides with vertex-, edge- and face-sharing connection modes of NaQ 6 ligands: Na 3 ZnM III Q 4 (M III = In, Ga; Q = S, Se)13Intriguing Structural Transition Inducing Variable Birefringences in ABa2MS4Cl (A = Rb, Cs; M = Ge, Sn)32Rational design of a new chalcogenide with good infrared nonlinear optical performance: SrZnSnS 452[Ge2S5(S2)]4−, A NLO‐Active Unit Leading to an Asymmetric Structure Discovered in Li2Cs4Ge2S5(S2)Cl2: An Experimental and Theoretical study18Large Second Harmonic Generation (SHG) Effect and High Laser‐Induced Damage Threshold (LIDT) Observed Coexisting in Gallium Selenide188Large Second Harmonic Generation (SHG) Effect and High Laser‐Induced Damage Threshold (LIDT) Observed Coexisting in Gallium Selenide48Li[LiCs2Cl][Ga3S6]: A Nanoporous Framework of GaS4 Tetrahedra with Excellent Nonlinear Optical Performance172Li[LiCs2Cl][Ga3S6]: A Nanoporous Framework of GaS4 Tetrahedra with Excellent Nonlinear Optical Performance40A review of the AI2B II C IV DVI4 family as infrared nonlinear optical materials: the effect of each site on the structure and optical properties59Li 2 CdSiS 4 , a promising IR NLO material with a balanced E g and SHG response originating from the effect of Cd with d 10 configuration36A2SnS5: A Structural Incommensurate Modulation Exhibiting Strong Second‐Harmonic Generation and a High Laser‐Induced Damage Threshold (A=Ba, Sr)30A2SnS5: A Structural Incommensurate Modulation Exhibiting Strong Second‐Harmonic Generation and a High Laser‐Induced Damage Threshold (A=Ba, Sr)86Structural diversities in centrosymmetric La 8 S 4 Cl 8 La 12 S 8 Cl 4 [SbS 3 ] 8 and non-centrosymmetric Ln 12 S 8 Cl 8 [SbS 3 ] 4 (Ln = La and Ce): syntheses, crystal and electronic structures, and optical properties10Li 4 MgGe 2 S 7 : The First Alkali and Alkaline‐Earth Diamond‐Like Infrared Nonlinear Optical Material with Exceptional Large Band Gap214Li4MgGe2S7: The First Alkali and Alkaline‐Earth Diamond‐Like Infrared Nonlinear Optical Material with Exceptional Large Band Gap16A Congruent‐Melting Mid‐Infrared Nonlinear Optical Vanadate Exhibiting Strong Second‐Harmonic Generation22A Congruent‐Melting Mid‐Infrared Nonlinear Optical Vanadate Exhibiting Strong Second‐Harmonic Generation64β-BaGa 4 Se 7 : a promising IR nonlinear optical crystal designed by predictable structural rearrangement46Na+/Ag+ substitution induced birefringence enhancement from AgGaS2 to NaGaS218(Na0.74Ag1.26)BaSnS4: A New AgGaS2‐Type Nonlinear Optical Sulfide with a Wide Band Gap and High Laser Induced Damage Threshold14Synthesis, Crystal Structure, and Optical Properties of a New Quaternary Tin Polychalcogenide K2BaSnSe50Topology‐Preserving Ionic‐Unit Substitution Enables Sphalerite‐Like Phosphides Achieving Superior Infrared Optical Nonlinearity0

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  1. Crystal and electronic structures, and photoluminescence and photocatalytic properties of α-EuZrS 3

    New Journal of Chemistry · 2016-01-01

    Sheng‐Ping Guo, Yang Chi, Jian‐Ping Zou, Huaiguo Xue

    Read original paper ↗ ·

  2. Na 9 Sb(Ge 2 Q 6 ) 2 (Q = S, Se): two new antimony( iii ) quaternary chalcogenides with ethane-like [Ge 2 Q 6 ] 6− ligands

    RSC Advances · 2016-01-01

    Xiaowen Wu, Yi Hu, Hui Pan, Zhi Su

    Read original paper ↗ ·

  3. Pb 5 Ga 6 ZnS 15 : a noncentrosymmetric framework with chains of T2-supertetrahedra

    Dalton Transactions · 2016-01-01

    Ruihuan Duan, Ju‐Song Yu, Hua Lin, Yujun Zheng, Hua‐Jun Zhao, Shangxiong Huangfu, Muhammad Ali Khan, Ling Chen, Li‐Ming Wu

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  4. A High Laser Damage Threshold and a Good Second-Harmonic Generation Response in a New Infrared NLO Material: LiSm3SiS7

    Crystals · 2016-09-23

    Ni Zhen, Leyan Nian, Guangmao Li, Kui Wu, Shilie Pan

    Read original paper ↗ ·

  5. Non‐centrosymmetric Selenides AZn4In5Se12 (A=Rb, Cs): Synthesis, Characterization and Nonlinear Optical Properties

    Chemistry - An Asian Journal · 2016-12-01

    Hua Lin, Yu‐Jun Zheng, Xiaoning Hu, Hong Chen, Ju‐Song Yu, Li‐Ming Wu

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  6. Recent achievements on middle and far-infrared second-order nonlinear optical materials

    Coordination Chemistry Reviews · 2016-12-27

    Sheng‐Ping Guo, Yang Chi, Guo‐Cong Guo

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  7. Ba 6 Li 2 CdSn 4 S 16 : lithium substitution simultaneously enhances band gap and SHG intensity

    Journal of Materials Chemistry C · 2017-01-01

    Ruihuan Duan, Pengfei Liu, Hua Lin, Yi‐Wen Zheng, Ju‐Song Yu, Xin‐Tao Wu, Shangxiong Huangfu, Ling Chen

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  8. Na 2 CdGe 2 Q 6 (Q = S, Se): two metal-mixed chalcogenides with phase-matching abilities and large second-harmonic generation responses

    Dalton Transactions · 2017-01-01

    Guangmao Li, Qiong Liu, Kui Wu, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·

  9. Tailored synthesis of nonlinear optical quaternary chalcohalides: Ba 4 Ge 3 S 9 Cl 2 , Ba 4 Si 3 Se 9 Cl 2 and Ba 4 Ge 3 Se 9 Cl 2

    Dalton Transactions · 2017-01-01

    Pengfei Liu, Yanyan Li, Yujun Zheng, Ju‐Song Yu, Ruihuan Duan, Hong Chen, Hua Lin, Ling Chen, Li‐Ming Wu

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  10. The first quaternary diamond-like semiconductor with 10-membered LiS 4 rings exhibiting excellent nonlinear optical performances

    Chemical Communications · 2017-01-01

    Kui Wu, Zhihua Yang, Shilie Pan

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  11. First-principles study lone-pair effects of Sb (III)-S chromophore influence on SHG response in quaternary potassium containing silver antimony sulfides

    Journal of Solid State Chemistry · 2017-03-06

    Junben Huang, Xin Su, Dianwei Hou, Bing‐Hua Lei, Zhihua Yang, Shilie Pan

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  12. Li3VO4: A Promising Mid-Infrared Nonlinear Optical Material with Large Laser Damage Threshold

    Crystal Growth & Design · 2017-03-30

    Zhaohui Chen, Zhizhong Zhang, Xiaoyu Dong, Yunjing Shi, Yaqin Liu, Qun Jing

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  13. Li2HgMS4 (M = Si, Ge, Sn): New Quaternary Diamond-Like Semiconductors for Infrared Laser Frequency Conversion

    Crystals · 2017-04-12

    Kui Wu, Shilie Pan

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  14. Growth, Properties, and Theoretical Analysis of M2LiVO4 (M = Rb, Cs) Crystals: Two Potential Mid-Infrared Nonlinear Optical Materials

    Scientific Reports · 2017-05-09

    Guopeng Han, Ying Wang, Xin Su, Zhihua Yang, Shilie Pan

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  15. Ba 6 Zn 7 Ga 2 S 16 : A Wide Band Gap Sulfide with Phase-Matchable Infrared NLO Properties

    Chemistry of Materials · 2017-05-31

    Yanyan Li, Pengfei Liu, Li‐Ming Wu

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  16. Coexistence of Strong Second Harmonic Generation Response and Wide Band Gap in AZn4Ga5S12 (A=K, Rb, Cs) with 3D Diamond‐like Frameworks

    Chemistry - A European Journal · 2017-06-03

    Hua Lin, Hong Chen, Yu‐Jun Zheng, Ju‐Song Yu, Xin‐Tao Wu, Li‐Ming Wu

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  17. AgGa2PS6: A New Mid‐Infrared Nonlinear Optical Material with a High Laser Damage Threshold and a Large Second Harmonic Generation Response

    Chemistry - A European Journal · 2017-07-07

    Jiang‐He Feng, Chun‐Li Hu, Xiang Xu, Bingxuan Li, Mingjian Zhang, Jiang‐Gao Mao

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  18. Synthesis and characterization of two lead-containing metal chalcogenides: Ba5Pb2Sn3S13 and Ba6PbSn3Se13

    Journal of Solid State Chemistry · 2017-08-16

    Ailijiang Abudurusuli, Hanqin Ding, Kui Wu

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  19. New Compressed Chalcopyrite-like Li2BaMIVQ4 (MIV = Ge, Sn; Q = S, Se): Promising Infrared Nonlinear Optical Materials

    Journal of the American Chemical Society · 2017-09-25

    Kui Wu, Bingbing Zhang, Zhihua Yang, Shilie Pan

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  20. LiGaGe2S6: A Chalcogenide with Good Infrared Nonlinear Optical Performance and Low Melting Point

    Inorganic Chemistry · 2017-10-19

    Dajiang Mei, Shiyan Zhang, Fei Liang, Sangen Zhao, Jian‐Qiao Jiang, Junbo Zhong, Zheshuai Lin, Yuandong Wu

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  21. A Polyselenide with a Novel Se78– Unit: the Structure of Sr19–xPbxGe11Se44 with x = 5.0 and 6.4

    European Journal of Inorganic Chemistry · 2017-11-09

    Abdeljalil Assoud, Holger Kleinke

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  22. Remarkable multimember-ring configurations in a new family of Na 7 M II Sb 5 S 12 (M II = Zn, Cd, Hg) exhibiting various three-dimensional tunnel structures

    Chemical Communications · 2018-01-01

    Kui Wu, Bingbing Zhang, Zhihua Yang, Shilie Pan

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  23. Structural insights into T 2 -cluster-containing chalcogenides with vertex-, edge- and face-sharing connection modes of NaQ 6 ligands: Na 3 ZnM III Q 4 (M III = In, Ga; Q = S, Se)

    Dalton Transactions · 2018-01-01

    Ruijiao Chen, Xiaowen Wu, Zhi Su

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  24. Intriguing Structural Transition Inducing Variable Birefringences in ABa2MS4Cl (A = Rb, Cs; M = Ge, Sn)

    Inorganic Chemistry · 2018-08-24

    Yu Chu, Kui Wu, Xin Su, Jian Wei Han, Zhihua Yang, Shilie Pan

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  25. Rational design of a new chalcogenide with good infrared nonlinear optical performance: SrZnSnS 4

    Journal of Materials Chemistry C · 2019-01-01

    Yiling Zhang, Dajiang Mei, Yi Jin Yang, Wangzhu Cao, Yuandong Wu, Jie Lü, Zheshuai Lin

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  26. [Ge2S5(S2)]4−, A NLO‐Active Unit Leading to an Asymmetric Structure Discovered in Li2Cs4Ge2S5(S2)Cl2: An Experimental and Theoretical study

    Chemistry - A European Journal · 2019-03-06

    Guangmao Li, Kui Wu, Yi Huang, Zhihua Yang, Shilie Pan

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  27. Large Second Harmonic Generation (SHG) Effect and High Laser‐Induced Damage Threshold (LIDT) Observed Coexisting in Gallium Selenide

    Angewandte Chemie International Edition · 2019-04-19

    Sheng‐Ping Guo, Xiyue Cheng, Zongdong Sun, Yang Chi, Bin‐Wen Liu, Xiao‐Ming Jiang, Shu‐Fang Li, Huaiguo Xue, Shuiquan Deng, Viola Düppel, Jürgen Köhler, Guo‐Cong Guo

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  28. Large Second Harmonic Generation (SHG) Effect and High Laser‐Induced Damage Threshold (LIDT) Observed Coexisting in Gallium Selenide

    Angewandte Chemie · 2019-04-19

    Sheng‐Ping Guo, Xiyue Cheng, Zongdong Sun, Yang Chi, Bin‐Wen Liu, Xiao‐Ming Jiang, Shu‐Fang Li, Huaiguo Xue, Shuiquan Deng, Viola Düppel, Jürgen Köhler, Guo‐Cong Guo

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  29. Li[LiCs2Cl][Ga3S6]: A Nanoporous Framework of GaS4 Tetrahedra with Excellent Nonlinear Optical Performance

    Angewandte Chemie International Edition · 2019-10-26

    Bin‐Wen Liu, Xiao‐Ming Jiang, Bingxuan Li, Hui‐Yi Zeng, Guo‐Cong Guo

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  30. Li[LiCs2Cl][Ga3S6]: A Nanoporous Framework of GaS4 Tetrahedra with Excellent Nonlinear Optical Performance

    Angewandte Chemie · 2019-10-26

    Bin‐Wen Liu, Xiao‐Ming Jiang, Bingxuan Li, Hui‐Yi Zeng, Guo‐Cong Guo

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  31. A review of the AI2B II C IV DVI4 family as infrared nonlinear optical materials: the effect of each site on the structure and optical properties

    Chemical Communications · 2020-01-01

    Guangmao Li, Zhihua Yang, Junjie Li, Shilie Pan

    Read original paper ↗ ·

  32. Li 2 CdSiS 4 , a promising IR NLO material with a balanced E g and SHG response originating from the effect of Cd with d 10 configuration

    Dalton Transactions · 2020-01-01

    Guangmao Li, Yu Chu, Jun Li, Zhongxiang Zhou

    Read original paper ↗ ·

  33. A2SnS5: A Structural Incommensurate Modulation Exhibiting Strong Second‐Harmonic Generation and a High Laser‐Induced Damage Threshold (A=Ba, Sr)

    Angewandte Chemie · 2020-04-17

    Rui‐An Li, Zhengyang Zhou, Yu‐Kun Lian, Fei Jia, Xingxing Jiang, Mingcong Tang, Li‐Ming Wu, Junliang Sun, Ling Chen

    Read original paper ↗ ·

  34. A2SnS5: A Structural Incommensurate Modulation Exhibiting Strong Second‐Harmonic Generation and a High Laser‐Induced Damage Threshold (A=Ba, Sr)

    Angewandte Chemie International Edition · 2020-04-17

    Rui‐An Li, Zhengyang Zhou, Yu‐Kun Lian, Fei Jia, Xingxing Jiang, Mingcong Tang, Li‐Ming Wu, Junliang Sun, Ling Chen

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  35. Structural diversities in centrosymmetric La 8 S 4 Cl 8 La 12 S 8 Cl 4 [SbS 3 ] 8 and non-centrosymmetric Ln 12 S 8 Cl 8 [SbS 3 ] 4 (Ln = La and Ce): syntheses, crystal and electronic structures, and optical properties

    Dalton Transactions · 2021-01-01

    Hua‐Jun Zhao, Pengfei Liu, Li‐Ming Wu

    Read original paper ↗ ·

  36. Li 4 MgGe 2 S 7 : The First Alkali and Alkaline‐Earth Diamond‐Like Infrared Nonlinear Optical Material with Exceptional Large Band Gap

    Angewandte Chemie International Edition · 2021-07-24

    Ailijiang Abudurusuli, Junben Huang, Peng Wang, Zhihua Yang, Shilie Pan, Junjie Li

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  37. Li4MgGe2S7: The First Alkali and Alkaline‐Earth Diamond‐Like Infrared Nonlinear Optical Material with Exceptional Large Band Gap

    Angewandte Chemie · 2021-07-24

    Ailijiang Abudurusuli, Junben Huang, Peng Wang, Zhihua Yang, Shilie Pan, Junjie Li

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  38. A Congruent‐Melting Mid‐Infrared Nonlinear Optical Vanadate Exhibiting Strong Second‐Harmonic Generation

    Angewandte Chemie · 2021-08-04

    Chao Wu, Xingxing Jiang, Lin Lin, Yilei Hu, Tianhui Wu, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  39. A Congruent‐Melting Mid‐Infrared Nonlinear Optical Vanadate Exhibiting Strong Second‐Harmonic Generation

    Angewandte Chemie International Edition · 2021-08-04

    Chao Wu, Xingxing Jiang, Lin Lin, Yilei Hu, Tianhui Wu, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  40. β-BaGa 4 Se 7 : a promising IR nonlinear optical crystal designed by predictable structural rearrangement

    Journal of Materials Chemistry C · 2021-11-29

    Zhen Qian, Qiang Bian, Hongping Wu, Hongwei Yu, Zheshuai Lin, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  41. Na+/Ag+ substitution induced birefringence enhancement from AgGaS2 to NaGaS2

    Journal of Alloys and Compounds · 2021-12-04

    Yihan Yun, Wenlong Xie, Zhihua Yang, Guangmao Li, Shilie Pan

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  42. (Na0.74Ag1.26)BaSnS4: A New AgGaS2‐Type Nonlinear Optical Sulfide with a Wide Band Gap and High Laser Induced Damage Threshold

    Chemistry - A European Journal · 2022-08-10

    Wenfeng Zhou, Wenlong Liu, Sheng‐Ping Guo

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  43. Synthesis, Crystal Structure, and Optical Properties of a New Quaternary Tin Polychalcogenide K2BaSnSe5

    Zeitschrift für anorganische und allgemeine Chemie · 2024-08-08

    Jinlong Shi, Mengran Sun, Chunxiao Li, Jiyong Yao

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  44. Topology‐Preserving Ionic‐Unit Substitution Enables Sphalerite‐Like Phosphides Achieving Superior Infrared Optical Nonlinearity

    Angewandte Chemie · 2026-08-26

    Qichao Zhao, Bingxuan Li, Guang Peng, Ning Ye, Jindong Chen

    Read original paper ↗ ·
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