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RESEARCH PAPER · Crystal Growth & Design · 2017

PbGa2GeS6: An Infrared Nonlinear Optical Material Synthesized by an Intermediate-Temperature Self-Fluxing Method

Yi‐Zhi Huang, Hao Zhang, Chensheng Lin, Wen‐Dan Cheng, Zhengxiao Guo, Guoliang Chai

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PbGa2GeS6: An Infrared Nonlinear Optical Material Synthesized by an Intermediate-Temperature Self-Fluxing MethodOriginalSynthesis, Crystal Structure, and Optical Properties of Noncentrosymmetric Na2ZnSnS434Ag 7 TaSe 6 : a new noncentrosymmetric selenide with fascinating “three in one” coordination modes and a strong second harmonic generation response13Growth and Characterization of PbGa2GeSе6: A New Quaternary Chalcogenide Nonlinear Crystal for the Mid-IR0Li 2 ZnGeS 4 : a promising diamond-like infrared nonlinear optical material with high laser damage threshold and outstanding second-harmonic generation response43Mn-Based tin sulfide Sr 3 MnSn 2 S 8 with a wide band gap and strong nonlinear optical response30SnGa 2 GeSe 6 , a benign addition to the AMIII2M IV Q 6 family: synthesis, crystal structure and nonlinear optical performance20Balanced Second-Order Nonlinear Optical Properties of Adducts CHI3·(S8)3 and AsI3·(S8)3: A Systematic Survey48Growth and Characterization of PbGa 2 GeSe 6 : A New Quaternary Chalcogenide Nonlinear Crystal for the Mid-IR0Crystal Growth and Characterization of a New Quaternary Chalcogenide Nonlinear Crystal for the Mid-Infrared: PbGa2GeSe611Sn2Ga2S5: A Type of IR Nonlinear-Optical Material22Partial Congener Substitution Induced Centrosymmetric to Noncentrosymmetric Transformation Witnessed by K3Ga3(Ge7–xMx)Se20 (M = Si, Sn) and Their Nonlinear Optical Properties51Rational design of infrared nonlinear optical chalcogenides by chemical substitution287Mixed-metal thiophosphate CuCd 3 PS 6 : an infrared nonlinear optical material activated by its three-in-one tetrahedra-stacking architecture33Raman and Infrared Phonon Spectra of Novel Nonlinear Optical Materials PbGa 2 GeS 6 and PbGa 2 GeSe 6 : Experiment and Theory4Cd4SiQ6 (Q = S, Se): Ternary Infrared Nonlinear Optical Materials with Mixed Functional Building Motifs21Highly anisotropic layered selenophosphate AgSbP2Se6: The electronic structure and optical properties by experimental measurements and first-principles calculations9Inherent laws between tetrahedral arrangement pattern and optical performance in tetrahedron-based mid-infrared nonlinear optical materials131A New Nonlinear Optical Selenide Crystal AgLiGa 2 Se 4 with Good Comprehensive Performance in Mid‐Infrared Region44Recent Achievements in Lone-Pair Cation-Based Infrared Second-Order Nonlinear Optical Materials95Photoconductivity of the Single Crystals Pb4Ga4GeS12 and Pb4Ga4GeSe120M 2 As 2 Q 5 (M = Ba, Pb; Q = S, Se): a source of infrared nonlinear optical materials with excellent overall performance activated by multiple discrete arsenate anions70Revisiting thiophosphate Pb 3 P 2 S 8 : a multifunctional material combining a nonlinear optical response and photocurrent response23Na 6 MQ 4 (M=Zn, Cd; Q=S, Se): Promising New Ternary Infrared Nonlinear Optical Materials24Noncentrosymmetric (KBa0.5)In2Se4 and (K0.58Ba0.71)(Ga0.89In1.11)Se4 derived from centrosymmetric BaIn2Se4 via partial cation substitution: structural chemistry and nonlinear optical activity9A novel 2-(aminomethyl)pyridineH 2 PO 4 crystal with second-order nonlinear optical performance8AAg 3 Ga 8 Se 14 (A = Rb, Cs): second-harmonic generation responses realized through the parallel arrangement of AgSe 4 and GaSe 4 tetrahedrons5Infrared nonlinear optical performances of a new sulfide β-PbGa2S415Impact of structure complexity on optoelectronic and non-linear optical properties in quaternary Ag(Pb)–Ga(In)–Si(Ge)–S(Se) systems13A comprehensive review on metal chalcogenides with three-dimensional frameworks for infrared nonlinear optical applications115Component Interaction in the Quasi-Ternary System PbSe–Ga2Se3–GeSe21Noncentrosymmetric Na6Pb3P4S16 and Centrosymmetric K2MIIP2S6 (MII = Mg and Zn) Displaying Multiple Membered-Ring Configurations and Strong Optical Anisotropy10Ga-based IR nonlinear optical materials: Synthesis, structures, and properties65Pb 3.5 GeS 4 Br 3 : the first phase-matching thiogermanate halide infrared nonlinear optical material12Infrared nonlinear optical materials with multiple strongly ionic cations5Five Transition Metal-Mixed Germanium Chalcogenide Materials: Solvothermal Syntheses, Crystal Structures, Photoelectric Response Properties, and Ion-Exchange Properties3[K2PbI][Ga7Se12]: A New Lead-Containing Nonlinear Optical Material with Moderate Second-Harmonic Generation Response and Large Birefringence5Thermo-Mechanical Characterization of the Orthorhombic Nonlinear Optical Crystal PbGa2GeSe60Structure-property relationships in IR nonlinear optical chalcogenides with stereochemically active lone pairs29Growth, structure and optical properties of PbBi3PO8 crystals0Modulating Nonlinear Optical Performances in α/β-SnGa2GeS6 Polymorphs via Atomic Coordination Engineering1Structural origins of the thermal properties of Ba2BiInSe50Achieving Excellent Nonlinear Optics in α ‑Ba 2 Ge 4 S 10 via Flux‑Induced Symmetry Breaking1

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  1. Synthesis, Crystal Structure, and Optical Properties of Noncentrosymmetric Na2ZnSnS4

    Inorganic Chemistry · 2018-08-03

    Jianqiao He, Yangwu Guo, Wenjuan Huang, Xian Zhang, Jiyong Yao, Tianyou Zhai, Fuqiang Huang

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  2. Ag 7 TaSe 6 : a new noncentrosymmetric selenide with fascinating “three in one” coordination modes and a strong second harmonic generation response

    Journal of Materials Chemistry C · 2019-01-01

    Zhuang Li, Shengzi Zhang, Wenlong Yin, Kaijin Kang, Yangwu Guo, Wenhao Xing, Zheshuai Lin, Jiyong Yao, Yicheng Wu

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  3. Growth and Characterization of PbGa2GeSе6: A New Quaternary Chalcogenide Nonlinear Crystal for the Mid-IR

    Conference on Lasers and Electro-Optics · 2019-01-01

    Valeriy V. Badikov, Dmitrii V. Badikov, Li Wang, Galina S. Shevyrdyaeva, Vladimir L. Panyutin, Anna A. Fintisova, Svetlana G. Sheina, Valentin P. Petrov

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  4. Li 2 ZnGeS 4 : a promising diamond-like infrared nonlinear optical material with high laser damage threshold and outstanding second-harmonic generation response

    Dalton Transactions · 2019-01-01

    Yi Huang, Kui Wu, Jianian Cheng, Yu Chu, Zhihua Yang, Shilie Pan

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  5. Mn-Based tin sulfide Sr 3 MnSn 2 S 8 with a wide band gap and strong nonlinear optical response

    Journal of Materials Chemistry C · 2019-01-01

    Chuang Liu, Dajiang Mei, Wangzhu Cao, Yi Jin Yang, Yuandong Wu, Guobao Li, Zheshuai Lin

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  6. SnGa 2 GeSe 6 , a benign addition to the AMIII2M IV Q 6 family: synthesis, crystal structure and nonlinear optical performance

    Dalton Transactions · 2019-01-01

    Zhuang Li, Shengzi Zhang, Yangwu Guo, Zheshuai Lin, Jiyong Yao, Yicheng Wu

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  7. Balanced Second-Order Nonlinear Optical Properties of Adducts CHI3·(S8)3 and AsI3·(S8)3: A Systematic Survey

    Inorganic Chemistry · 2019-03-15

    Zhen‐Tao Lu, Zongdong Sun, Yang Chi, Huaiguo Xue, Sheng‐Ping Guo

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  8. Growth and Characterization of PbGa 2 GeSe 6 : A New Quaternary Chalcogenide Nonlinear Crystal for the Mid-IR

    Conference on Lasers and Electro-Optics · 2019-05-05

    Valeriy V. Badikov, Dmitrii V. Badikov, Li Wang, Galina S. Shevyrdyaeva, Vladimir L. Panyutin, Anna A. Fintisova, Svetlana Sheina, Valentin P. Petrov

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  9. Crystal Growth and Characterization of a New Quaternary Chalcogenide Nonlinear Crystal for the Mid-Infrared: PbGa2GeSe6

    Crystal Growth & Design · 2019-07-02

    Valeriy V. Badikov, Dmitrii V. Badikov, Li Wang, Galina S. Shevyrdyaeva, Vladimir L. Panyutin, Anna A. Fintisova, Svetlana G. Sheina, Valentin P. Petrov

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  10. Sn2Ga2S5: A Type of IR Nonlinear-Optical Material

    Inorganic Chemistry · 2019-08-28

    Zhi‐Hui Shi, Yang Chi, Zongdong Sun, Wenlong Liu, Sheng‐Ping Guo

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  11. Partial Congener Substitution Induced Centrosymmetric to Noncentrosymmetric Transformation Witnessed by K3Ga3(Ge7–xMx)Se20 (M = Si, Sn) and Their Nonlinear Optical Properties

    Inorganic Chemistry · 2019-09-25

    Xiaohui Li, Nian‐Tzu Suen, Yang Chi, Yueling Sun, Anhua Gong, Huaiguo Xue, Sheng‐Ping Guo

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  12. Rational design of infrared nonlinear optical chalcogenides by chemical substitution

    Coordination Chemistry Reviews · 2019-12-21

    Hua Lin, Wenbo Wei, Hong Chen, Xintao Wu, Qi‐Long Zhu

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  13. Mixed-metal thiophosphate CuCd 3 PS 6 : an infrared nonlinear optical material activated by its three-in-one tetrahedra-stacking architecture

    Journal of Materials Chemistry C · 2020-01-01

    Zhuang Li, Shengzi Zhang, Wenhao Xing, Yangwu Guo, Chunxiao Li, Zheshuai Lin, Jiyong Yao, Yicheng Wu

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  14. Raman and Infrared Phonon Spectra of Novel Nonlinear Optical Materials PbGa 2 GeS 6 and PbGa 2 GeSe 6 : Experiment and Theory

    physica status solidi (b) · 2020-01-30

    Mykhailo Ya. Valakh, Volodymyr Dzhagan, Nazar V. Mazur, Yevhenii Havryliuk, Volodymyr Olexsandrovych Yukhymchuk, Л.В. Піскач, Yuri Kogut, Dietrich R. T. Zahn, Alexander P. Litvinchuk

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  15. Cd4SiQ6 (Q = S, Se): Ternary Infrared Nonlinear Optical Materials with Mixed Functional Building Motifs

    Crystal Growth & Design · 2020-03-11

    Jindong Chen, Chensheng Lin, Shunda Yang, Xiaotian Jiang, Shuangshuang Shi, Yingshuang Sun, Bingxuan Li, Shenghao Fang, Ning Ye

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  16. Highly anisotropic layered selenophosphate AgSbP2Se6: The electronic structure and optical properties by experimental measurements and first-principles calculations

    Chemical Physics · 2020-04-20

    Tuan V. Vu, Anatoliy A. Lavrentyev, B.V. Gabrelian, Dat Duy Vo, V.I. Sabov, M. Yu. Sabov, I. E. Barchiy, Michał Piasecki, Oleg Yu Khyzhun

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  17. Inherent laws between tetrahedral arrangement pattern and optical performance in tetrahedron-based mid-infrared nonlinear optical materials

    Coordination Chemistry Reviews · 2020-06-29

    Weikang Wang, Dajiang Mei, Fei Liang, Jun Zhao, Yuandong Wu, Zheshuai Lin

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  18. A New Nonlinear Optical Selenide Crystal AgLiGa 2 Se 4 with Good Comprehensive Performance in Mid‐Infrared Region

    Advanced Optical Materials · 2020-12-16

    Alexander Yèlisseyev, Sergei I. Lobanov, Мaxim S. Моlokeev, Shengzi Zhang, A. M. Pugachev, Zheshuai Lin, Vitaliy Nikolaevich Vedenyapin, Alexey Kurus, Avag Khamoyam, L. I. Isaenko

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  19. Recent Achievements in Lone-Pair Cation-Based Infrared Second-Order Nonlinear Optical Materials

    Crystal Growth & Design · 2020-12-22

    Mei Yan, Huaiguo Xue, Sheng‐Ping Guo

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  20. Photoconductivity of the Single Crystals Pb4Ga4GeS12 and Pb4Ga4GeSe12

    Unknown journal · 2020-12-31

    Hadj K. Bellagra, Oksana Nyhmatullina, Yuri Kogut, Halyna Myronchuk, Л.В. Піскач

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  21. M 2 As 2 Q 5 (M = Ba, Pb; Q = S, Se): a source of infrared nonlinear optical materials with excellent overall performance activated by multiple discrete arsenate anions

    Journal of Materials Chemistry C · 2021-01-01

    Man-Man Chen, Zuju Ma, Bingxuan Li, Wenbo Wei, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  22. Revisiting thiophosphate Pb 3 P 2 S 8 : a multifunctional material combining a nonlinear optical response and photocurrent response

    Physical Chemistry Chemical Physics · 2021-01-01

    Bingheng Ji, Elizabeth Guderjahn, Kui Wu, Tajamul Hussain Syed, Wei Wei, Bingbing Zhang, Jian Wang

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  23. Na 6 MQ 4 (M=Zn, Cd; Q=S, Se): Promising New Ternary Infrared Nonlinear Optical Materials

    Chemistry - A European Journal · 2021-01-27

    Yi Huang, Le Gao, Haohai Yu, Zhihua Yang, Junjie Li, Shilie Pan

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  24. Noncentrosymmetric (KBa0.5)In2Se4 and (K0.58Ba0.71)(Ga0.89In1.11)Se4 derived from centrosymmetric BaIn2Se4 via partial cation substitution: structural chemistry and nonlinear optical activity

    Journal of Alloys and Compounds · 2021-12-16

    Zi‐Xia Chen, Yanan Li, Wen‐Dong Yao, Wenlong Liu, Sheng‐Ping Guo

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  25. A novel 2-(aminomethyl)pyridineH 2 PO 4 crystal with second-order nonlinear optical performance

    CrystEngComm · 2022-01-01

    Duanliang Wang, Defu Sun, Shoubao Zhang, Jiancai Leng, Ruoxian Hou, Hanzhang Chen, Jie Sun, Yangyang Dang, Chuanying Shen

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  26. AAg 3 Ga 8 Se 14 (A = Rb, Cs): second-harmonic generation responses realized through the parallel arrangement of AgSe 4 and GaSe 4 tetrahedrons

    Dalton Transactions · 2022-01-01

    Zhi-Xin Qiu, Shao‐Min Pei, Wen‐Fa Chen, Xiao‐Ming Jiang, Bin‐Wen Liu, Guo‐Cong Guo

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  27. Infrared nonlinear optical performances of a new sulfide β-PbGa2S4

    Journal of Alloys and Compounds · 2022-02-02

    Wen‐Fa Chen, Bin‐Wen Liu, Xiao‐Ming Jiang, Guo‐Cong Guo

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  28. Impact of structure complexity on optoelectronic and non-linear optical properties in quaternary Ag(Pb)–Ga(In)–Si(Ge)–S(Se) systems

    Journal of Alloys and Compounds · 2022-03-18

    Michał Piasecki, G.L. Myronchuk, Oleg Yu Khyzhun, A.O. Fedorchuk, B. Andryievsky, I. Barchyi, M.G. Brik

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  29. A comprehensive review on metal chalcogenides with three-dimensional frameworks for infrared nonlinear optical applications

    Coordination Chemistry Reviews · 2022-07-19

    Hong Chen, Mao‐Yin Ran, Wenbo Wei, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  30. Component Interaction in the Quasi-Ternary System PbSe–Ga2Se3–GeSe2

    Journal of Phase Equilibria and Diffusion · 2022-12-06

    Hadj K. Bellagra, Yuri Kogut, Л.В. Піскач

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  31. Noncentrosymmetric Na6Pb3P4S16 and Centrosymmetric K2MIIP2S6 (MII = Mg and Zn) Displaying Multiple Membered-Ring Configurations and Strong Optical Anisotropy

    Inorganic Chemistry · 2023-12-06

    Chenyao Zhao, Dazhi Lu, Xinyu Tian, Jingjing Xu, Bingbing Zhang, Kui Wu, Haohai Yu, Huaijin Zhang

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  32. Ga-based IR nonlinear optical materials: Synthesis, structures, and properties

    Coordination Chemistry Reviews · 2023-12-21

    Jiaxiang Zhang, Ping Feng, Mao‐Yin Ran, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  33. Pb 3.5 GeS 4 Br 3 : the first phase-matching thiogermanate halide infrared nonlinear optical material

    Inorganic Chemistry Frontiers · 2024-01-01

    Jiazheng Zhou, Hongshan Wang, Junjie Liu, Xin Su, Yu Chu, Jiale Qu, Xiangzhan Jiang

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  34. Infrared nonlinear optical materials with multiple strongly ionic cations

    Progress in Solid State Chemistry · 2024-04-01

    Yang Wang, Yuqiang Fang, Ruiqi Wang, Fuqiang Huang

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  35. Five Transition Metal-Mixed Germanium Chalcogenide Materials: Solvothermal Syntheses, Crystal Structures, Photoelectric Response Properties, and Ion-Exchange Properties

    Inorganic Chemistry · 2025-03-05

    Hong Liang Pan, Li Wang, Gele Teri, Xin Liu, Menghe Baiyin

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  36. [K2PbI][Ga7Se12]: A New Lead-Containing Nonlinear Optical Material with Moderate Second-Harmonic Generation Response and Large Birefringence

    Crystal Growth & Design · 2025-05-22

    Jinlong Shi, Chunxiao Li, Pifu Gong, Jiyong Yao

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  37. Thermo-Mechanical Characterization of the Orthorhombic Nonlinear Optical Crystal PbGa2GeSe6

    Photonics · 2025-06-01

    Michael A. Susner, Jonathan T. Goldstein, Ginka K. Exner, Aleksandar Grigorov, Ryan Siebenaller, Kentaro Miyata, Valentin P. Petrov

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  38. Structure-property relationships in IR nonlinear optical chalcogenides with stereochemically active lone pairs

    Coordination Chemistry Reviews · 2025-09-03

    Hong Chen, Xin‐Tao Wu, Hua Lin

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  39. Growth, structure and optical properties of PbBi3PO8 crystals

    Journal of Solid State Chemistry · 2025-09-16

    Huatong Jiang, Jianfu Zhao, Chao Fu Li, Shengxuan Yang, Dongxiao Cai, Hechun Jiang, Xiulan Duan, Fapeng Yu

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  40. Modulating Nonlinear Optical Performances in α/β-SnGa2GeS6 Polymorphs via Atomic Coordination Engineering

    Inorganic Chemistry · 2025-09-20

    Jingjing Xu, Yan Xiao, Dazhi Lu, Bingbing Zhang, Kui Wu, Haohai Yu, Huaijin Zhang

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  41. Structural origins of the thermal properties of Ba2BiInSe5

    Materials Chemistry and Physics · 2026-05-25

    Wilarachchige D. C. B. Gunatilleke, George S. Nolas

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  42. Achieving Excellent Nonlinear Optics in α ‑Ba 2 Ge 4 S 10 via Flux‑Induced Symmetry Breaking

    Small · 2026-06-24

    Ying Guo, Guo‐Qiang Wang, Yan Guo, Xiao‐Ming Jiang, B C Liu, Guo‐Cong Guo

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