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RESEARCH PAPER · Inorganic Chemistry Frontiers · 2014

An outstanding second-harmonic generation material BiB 2 O 4 F: exploiting the electron-withdrawing ability of fluorine

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An outstanding second-harmonic generation material BiB 2 O 4 F: exploiting the electron-withdrawing ability of fluorineOriginalChemInform Abstract: An Outstanding Second‐Harmonic Generation Material BiB2O4F: Exploiting the Electron‐Withdrawing Ability of Fluorine.0Recent development of metal borate halides: Crystal chemistry and application in second-order NLO materials340Alkali metal–alkaline earth metal borate crystal LiBa 3 (OH)(B 9 O 16 )[B(OH) 4 ] as a new deep-UV nonlinear optical material34Frequency-Doubling Oxide Fluorides, Borate Fluorides, and Fluorooxoborates9A Deep-Ultraviolet Nonlinear Optical Crystal: Strontium Beryllium Borate Fluoride with Planar Be(O/F)3 Groups49BiFSeO 3 : An Excellent SHG Material Designed by Aliovalent Substitution207The plane-wave DFT investigations into the structure and the 11B solid-state NMR parameters of lithium fluorooxoborates5Ba n+2 Zn n (BO 3 ) n (B 2 O 5 )F n (n = 1, 2): new members of the zincoborate fluoride series with two kinds of isolated B–O units33Na2B6O9F2: A Fluoroborate with Short Cutoff Edge and Deep-Ultraviolet Birefringent Property Prepared by an Open High-Temperature Solution Method106A new method for the preparation of a [Sn 2 (H 2 PO 2 ) 3 ]Br SHG-active polar crystal via surfactant-induced strategy12Li 6 Zn 3 (BO 3 ) 4 : a new zincoborate featuring vertex-, edge- and face-sharing LiO 4 tetrahedra and exhibiting reversible phase transitions18Solvent-controlled syntheses of mixed-alkali-metal borates exhibiting UV nonlinear optical properties23The activity of lone pair contributing to SHG response in bismuth borates: a combination investigation from experiment and DFT calculation28The structural diversity of halogen-centered secondary building units: two new mixed-metal borate halides with deep-ultraviolet cut-off edges16Bi(IO3)F2: The First Metal Iodate Fluoride with a Very Strong Second Harmonic Generation Effect238Bi(IO3)F2: The First Metal Iodate Fluoride with a Very Strong Second Harmonic Generation Effect71Fluorooxoborates: Beryllium‐Free Deep‐Ultraviolet Nonlinear Optical Materials without Layered Growth892Fluorooxoborates: Beryllium‐Free Deep‐Ultraviolet Nonlinear Optical Materials without Layered Growth99DFT-Based Comparative Study about the Influence of Fluorine and Hydroxyl Anions on Opto-Electric Properties of Borate Crystals: Choice for Better Anion13CsB 4 O 6 F: A Congruent‐Melting Deep‐Ultraviolet Nonlinear Optical Material by Combining Superior Functional Units184CsB4O6F: A Congruent‐Melting Deep‐Ultraviolet Nonlinear Optical Material by Combining Superior Functional Units895The First Alkaline‐Earth Fluorooxoborate Ba[B4O6F2]—Characterisation and Doping with Eu2+95BaBOF 3 : a new aurivillius-like borate containing two types of F atoms32First principle study of nonlinear optical crystals15Flexible coordination of Pb atoms and variable zinc–borate frameworks to construct three Pb 5 Zn 4 B 6 O 18 polymorphs8Ion-induced structural and optical performance evolution in LBO-like crystals: experimental and theoretical investigation13Cation‐Tuned Synthesis of Fluorooxoborates: Towards Optimal Deep‐Ultraviolet Nonlinear Optical Materials191Cation‐Tuned Synthesis of Fluorooxoborates: Towards Optimal Deep‐Ultraviolet Nonlinear Optical Materials714K3B6O9F3: A New Fluorooxoborate with Four Different Anionic Units42Recent advances in ultraviolet and deep-ultraviolet second-order nonlinear optical crystals257CaB5O7F3: A Beryllium-Free Alkaline-Earth Fluorooxoborate Exhibiting Excellent Nonlinear Optical Performances192Polar Fluorooxoborate, NaB4O6F: A Promising Material for Ionic Conduction and Nonlinear Optics494Polar Fluorooxoborate, NaB4O6F: A Promising Material for Ionic Conduction and Nonlinear Optics67A Fluorooxosilicophosphate with an Unprecedented SiO2F4 Species56A Fluorooxosilicophosphate with an Unprecedented SiO2F4 Species5Designing Deep‐UV Birefringent Crystals by Cation Regulation57Sn[B2O3F2]—The First Tin Fluorooxoborate as Possible NLO Material102Two Novel Deep‐Ultraviolet Nonlinear Optical Crystals with Shorter Phase‐Matching Second Harmonic Generation than KBe2BO3F2: A First‐Principles Prediction20Advantageous Units in Antimony Sulfides: Exploration and Design of Infrared Nonlinear Optical Materials95Fluorooxoborates: Ushering in a New Era of Deep Ultraviolet Nonlinear Optical Materials102Second-order nonlinear optical crystals with mixed anions250Synthesis and Characterization of the First Tin Fluoride Borate Sn3[B3O7]F with Second Harmonic Generation Response28Li2BaSc(BO3)2F and LiBa2Pb(BO3)2F with Layered Structures featuring Special Li−O/F Configurations11BaB8O12F2: a promising deep-UV birefringent material60A new barium fluorooxoborate BaB 5 O 8 F· x H 2 O with large birefringence and a wide UV transparency window25M 2 (SeO 3 )F 2 (M = Zn, Cd): understanding the structure directing effect of [SeO 3 ] 2− groups on constructing ordered oxyfluorides14Tb(HSO 4 )(SO 4 ) – a green emitting hydrogensulfate sulfate with second harmonic generation response21Designing Three Fluorooxoborates with a Wide Transmittance Window by Anionic Group Substitution15BaB 2 O 3 F 2 : A Barium Fluorooxoborate with a Unique [B 2 O 3 F] − Layer and Short Cutoff Edge38Nonlinear optical crystals K7CaR2(B5O10)3 (R = Nd, Yb), growth and properties27KBiCl2SO4: The First Bismuth Chloride Sulfate Being Second-Order Nonlinear Optical Active44Emergent Deep‐Ultraviolet Nonlinear Optical Candidates324Neue Kandidaten für die nichtlineare Optik im Tief‐UV‐Bereich43Lone pair electron effect induced differences in linear and nonlinear optical properties of bismuth borates12[O 2 Pb 3 ] 2 (BO 3 )I: a new lead borate iodide with 1∞[O 2 Pb 3 ] double chains6Ba(B 2 OF 3 (OH) 2 ) 2 with well-ordered OH/F anions and a unique B 2 OF 3 (OH) 2 dimer30From BaAl 2 (BO 3 ) 2 O to SnAl 2 (BO 3 ) 2 F 2 : structure transformation based on ion regulation3Inorganic planar π-conjugated groups in nonlinear optical crystals: review and outlook145A Promising Fluorooxoborate Framework with Flexibile Capability for Diverse Cations to Enhance the Second Harmonic Generation14Noncentrosymmetric Fluorooxoborates A10B13O15F19 (A = K and Rb) with Unexpected [B10O12F13]7– Units and Deep-Ultraviolet Cutoff Edges26Rational Design of the Nonlinear Optical Response in a Tin Iodate Fluoride Sn(IO3)2F290Two Pyrophosphates with Large Birefringences and Second‐Harmonic Responses as Ultraviolet Nonlinear Optical Materials137Two Pyrophosphates with Large Birefringences and Second‐Harmonic Responses as Ultraviolet Nonlinear Optical Materials29Sr5[BO2(OH)]3(OH)3F: First hydroxyborate fluoride with the [BO2(OH)]2− unit2Intense d ‑ p Hybridization Induced a Vast SHG Response Disparity between Tetrahedral Vanadates and Arsenates13Borates: A Rich Source for Optical Materials1089Sn3B8O15: A Ternary Tin(II) Borate with Flexible [B8O18]12– Fundamental Building Block Formed by [B7O16]11– and [BO3]3– Groups10BaB 4 O 5 F 4 with reversible phase transition featuring unprecedented fundamental building blocks of [B 16 O 21 F 16 ] in the α -phase and [B 4 O 6 F 4 ] in the β -phase19NaKB 6 O 9 F 2 : a new complex alkali metal fluorooxoborate with puckered layers10Recent advances of oxyfluorides for nonlinear optical applications69The tin sulfates Sn(SO 4 ) 2 and Sn2(SO4)3: crystal structures, optical and thermal properties10Na4B8O9F10: A Deep‐Ultraviolet Transparent Nonlinear Optical Fluorooxoborate with Unexpected Short Phase‐Matching Wavelength Induced by Optimized Chromatic Dispersion133Na4B8O9F10: A Deep‐Ultraviolet Transparent Nonlinear Optical Fluorooxoborate with Unexpected Short Phase‐Matching Wavelength Induced by Optimized Chromatic Dispersion13Ba 10 LuB 18 O 32 F 13 : the first example of borate in the Lu–B–O–F system with the unprecedented FBB [B 9 O 22 ]12The Role of the Bi3+ Lone Pair Effect in Bi(H3O)(SO4)2, Bi(HSO4)3, and Bi2(SO4)39Cs2Bi2OSi2O7: A Promising Bismuth Silicate Nonlinear Optical Crystal with Face-Sharing BiO5 Polyhedra Exhibiting Strengthened Second Harmonic Generation Response and Birefringence43LiNaB6O9F2: A Promising UV NLO Crystal Having Fluorine‐Directed Optimal Performances and Double Interpenetrating 3[B6O9F2]∞ Networks33Rb 3 B 5 O 8 F 2 and K 0.6 Rb 2.4 B 5 O 8 F 2 : two new deep-ultraviolet transparent nonlinear optical fluorooxoborates designed by cation regulation13A Cation-Driven Approach toward Deep-Ultraviolet Nonlinear Optical Materials17Ce 3 F 4 (SO 4 ) 4 : cationic framework assembly for designing polar nonlinear optical material through fluorination degree modulation23Nickel sulfate solution fluoride separation with hydrous zirconium oxide6New antimony fluorooxoborates with strong birefringence and unprecedented structural characterisation19Fluorine-driven materials design of novel deep-ultraviolet nonlinear optical crystal materials: Research progress and challenges6Constructing Ultraviolet Nonlinear Optical Crystals with Superior Thermal Stability Based on Organic π-Conjugated [HCOO] Groups6From B 3 O 3 (OH) 3 to B 3 O 3 F 3 : Uncovering Series of New Functional Units Based on [BO 2 F] Beneficial for Deep‐Ultraviolet Birefringence1Effect of pressure on the structure, elasticity and optical properties of AgGaSe2 crystal3Expanding silver fluorooxoborate crystal chemistry: Ag 2 B 5 O 8 F with 3D double interpenetrating frameworks and Ag 3 B 5 O 8 F 2 with 2D layers5Structural chemistry of antimony( iii ) oxalates with lone pairs: polyhedral distortion [SbO 4 F 2 ], π-conjugation [C 2 O 4 ], and birefringence tuning1A multi-scale birefringence modulation strategy in DUV/UV crystals induced by organic cations1Targeted hydroxyl fluorination for first-principles design of deep-ultraviolet nonlinear optical crystals: multi-property optimization & chromatic dispersion modulation in Li 2 CsB 7 O 10 F 41Topological structural chemistry of fluorooxoborates: From fundamental building blocks to macroscopic optical performance regulation0Toward the vacuum-ultraviolet frontier in nonlinear optical frequency conversion: phase-matching mechanisms across dimensions and architectures2

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  1. ChemInform Abstract: An Outstanding Second‐Harmonic Generation Material BiB2O4F: Exploiting the Electron‐Withdrawing Ability of Fluorine.

    ChemInform · 2015-04-01

    Rihong Cong, Ying Wang, Lei Kang, Zhengyang Zhou, Zheshuai Lin, Tao Yang

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  2. Recent development of metal borate halides: Crystal chemistry and application in second-order NLO materials

    Coordination Chemistry Reviews · 2015-12-30

    Ying Wang, Shilie Pan

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  3. Alkali metal–alkaline earth metal borate crystal LiBa 3 (OH)(B 9 O 16 )[B(OH) 4 ] as a new deep-UV nonlinear optical material

    Journal of Materials Chemistry C · 2016-01-01

    Chao Wu, Jun‐Ling Song, Longhua Li, Mark Graeme Humphrey, Chi Zhang

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  4. Frequency-Doubling Oxide Fluorides, Borate Fluorides, and Fluorooxoborates

    Elsevier eBooks · 2016-01-01

    Shilie Pan, Y. Wang, Kenneth Reinhard Poeppelmeier

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  5. A Deep-Ultraviolet Nonlinear Optical Crystal: Strontium Beryllium Borate Fluoride with Planar Be(O/F)3 Groups

    Chemistry of Materials · 2016-06-02

    Na Yu, Shichao Wang, Ning Ye, Fei Liang, Zheshuai Lin, Min Luo, Kenneth Reinhard Poeppelmeier

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  6. BiFSeO 3 : An Excellent SHG Material Designed by Aliovalent Substitution

    Journal of the American Chemical Society · 2016-07-18

    Mingli Liang, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao

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  7. The plane-wave DFT investigations into the structure and the 11B solid-state NMR parameters of lithium fluorooxoborates

    Chemical Physics Letters · 2016-10-28

    Jiřı́ Czernek, Jiřı́ Brus

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  8. Ba n+2 Zn n (BO 3 ) n (B 2 O 5 )F n (n = 1, 2): new members of the zincoborate fluoride series with two kinds of isolated B–O units

    Inorganic Chemistry Frontiers · 2016-12-01

    Miriding Mutailipu, Xin Su, Min Zhang, Zhihua Yang, Shilie Pan

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  9. Na2B6O9F2: A Fluoroborate with Short Cutoff Edge and Deep-Ultraviolet Birefringent Property Prepared by an Open High-Temperature Solution Method

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  10. A new method for the preparation of a [Sn 2 (H 2 PO 2 ) 3 ]Br SHG-active polar crystal via surfactant-induced strategy

    Dalton Transactions · 2017-01-01

    Jie‐Ling Xie, Yu-Hua Zhou, Long-Hua Li, Jian‐Han Zhang, Jun‐Ling Song

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  11. Li 6 Zn 3 (BO 3 ) 4 : a new zincoborate featuring vertex-, edge- and face-sharing LiO 4 tetrahedra and exhibiting reversible phase transitions

    Inorganic Chemistry Frontiers · 2017-01-01

    Yanna Chen, Donghai An, Min Zhang, Cong Hu, Miriding Mutailipu, Zhihua Yang, Xiaoquan Lu, Shilie Pan

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  12. Solvent-controlled syntheses of mixed-alkali-metal borates exhibiting UV nonlinear optical properties

    Inorganic Chemistry Frontiers · 2017-01-01

    Chao Wu, Longhua Li, Jun‐Ling Song, Gang Yang, Mark Graeme Humphrey, Chi Zhang

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  13. The activity of lone pair contributing to SHG response in bismuth borates: a combination investigation from experiment and DFT calculation

    Physical Chemistry Chemical Physics · 2017-01-01

    Cong Hu, Miriding Mutailipu, Ying Wang, Fengjiao Guo, Zhihua Yang, Shilie Pan

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  14. The structural diversity of halogen-centered secondary building units: two new mixed-metal borate halides with deep-ultraviolet cut-off edges

    Dalton Transactions · 2017-01-01

    Miriding Mutailipu, Min Zhang, Yanna Chen, Xiaoquan Lu, Shilie Pan

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  15. Bi(IO3)F2: The First Metal Iodate Fluoride with a Very Strong Second Harmonic Generation Effect

    Angewandte Chemie International Edition · 2017-01-16

    Fei‐Fei Mao, Chun‐Li Hu, Xiang Xu, Dong Yan, Bing‐Ping Yang, Jiang‐Gao Mao

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  16. Bi(IO3)F2: The First Metal Iodate Fluoride with a Very Strong Second Harmonic Generation Effect

    Angewandte Chemie · 2017-01-16

    Fei‐Fei Mao, Chun‐Li Hu, Xiang Xu, Dong Yan, Bing‐Ping Yang, Jiang‐Gao Mao

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  17. Fluorooxoborates: Beryllium‐Free Deep‐Ultraviolet Nonlinear Optical Materials without Layered Growth

    Angewandte Chemie International Edition · 2017-03-02

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  18. Fluorooxoborates: Beryllium‐Free Deep‐Ultraviolet Nonlinear Optical Materials without Layered Growth

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  19. DFT-Based Comparative Study about the Influence of Fluorine and Hydroxyl Anions on Opto-Electric Properties of Borate Crystals: Choice for Better Anion

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  20. CsB 4 O 6 F: A Congruent‐Melting Deep‐Ultraviolet Nonlinear Optical Material by Combining Superior Functional Units

    Angewandte Chemie · 2017-09-12

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  21. CsB4O6F: A Congruent‐Melting Deep‐Ultraviolet Nonlinear Optical Material by Combining Superior Functional Units

    Angewandte Chemie International Edition · 2017-09-12

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  22. The First Alkaline‐Earth Fluorooxoborate Ba[B4O6F2]—Characterisation and Doping with Eu2+

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  23. BaBOF 3 : a new aurivillius-like borate containing two types of F atoms

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  24. First principle study of nonlinear optical crystals

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  25. Flexible coordination of Pb atoms and variable zinc–borate frameworks to construct three Pb 5 Zn 4 B 6 O 18 polymorphs

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  26. Ion-induced structural and optical performance evolution in LBO-like crystals: experimental and theoretical investigation

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  27. Cation‐Tuned Synthesis of Fluorooxoborates: Towards Optimal Deep‐Ultraviolet Nonlinear Optical Materials

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  28. Cation‐Tuned Synthesis of Fluorooxoborates: Towards Optimal Deep‐Ultraviolet Nonlinear Optical Materials

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  29. K3B6O9F3: A New Fluorooxoborate with Four Different Anionic Units

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  30. Recent advances in ultraviolet and deep-ultraviolet second-order nonlinear optical crystals

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  31. CaB5O7F3: A Beryllium-Free Alkaline-Earth Fluorooxoborate Exhibiting Excellent Nonlinear Optical Performances

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  32. Polar Fluorooxoborate, NaB4O6F: A Promising Material for Ionic Conduction and Nonlinear Optics

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  33. Polar Fluorooxoborate, NaB4O6F: A Promising Material for Ionic Conduction and Nonlinear Optics

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  34. A Fluorooxosilicophosphate with an Unprecedented SiO2F4 Species

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  35. A Fluorooxosilicophosphate with an Unprecedented SiO2F4 Species

    Angewandte Chemie · 2018-06-05

    Guopeng Han, Bing‐Hua Lei, Zhihua Yang, Ying Wang, Shilie Pan

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  36. Designing Deep‐UV Birefringent Crystals by Cation Regulation

    Chemistry - A European Journal · 2018-06-25

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  37. Sn[B2O3F2]—The First Tin Fluorooxoborate as Possible NLO Material

    Advanced Optical Materials · 2018-06-25

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  38. Two Novel Deep‐Ultraviolet Nonlinear Optical Crystals with Shorter Phase‐Matching Second Harmonic Generation than KBe2BO3F2: A First‐Principles Prediction

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  39. Advantageous Units in Antimony Sulfides: Exploration and Design of Infrared Nonlinear Optical Materials

    ACS Applied Materials & Interfaces · 2018-07-12

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  40. Fluorooxoborates: Ushering in a New Era of Deep Ultraviolet Nonlinear Optical Materials

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  41. Second-order nonlinear optical crystals with mixed anions

    Coordination Chemistry Reviews · 2018-08-06

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  42. Synthesis and Characterization of the First Tin Fluoride Borate Sn3[B3O7]F with Second Harmonic Generation Response

    Chemistry - A European Journal · 2018-08-07

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  43. Li2BaSc(BO3)2F and LiBa2Pb(BO3)2F with Layered Structures featuring Special Li−O/F Configurations

    Chemistry - A European Journal · 2018-09-19

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  44. BaB8O12F2: a promising deep-UV birefringent material

    Inorganic Chemistry Frontiers · 2018-12-25

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  45. A new barium fluorooxoborate BaB 5 O 8 F· x H 2 O with large birefringence and a wide UV transparency window

    Dalton Transactions · 2019-01-01

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  46. M 2 (SeO 3 )F 2 (M = Zn, Cd): understanding the structure directing effect of [SeO 3 ] 2− groups on constructing ordered oxyfluorides

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  47. Tb(HSO 4 )(SO 4 ) – a green emitting hydrogensulfate sulfate with second harmonic generation response

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  48. Designing Three Fluorooxoborates with a Wide Transmittance Window by Anionic Group Substitution

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  49. BaB 2 O 3 F 2 : A Barium Fluorooxoborate with a Unique [B 2 O 3 F] − Layer and Short Cutoff Edge

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  50. Nonlinear optical crystals K7CaR2(B5O10)3 (R = Nd, Yb), growth and properties

    Journal of Crystal Growth · 2019-05-09

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