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RESEARCH PAPER · Advanced Functional Materials · 2021

Noncentrosymmetric Tetrel Pnictides RuSi4P4 and IrSi3P3: Nonlinear Optical Materials with Outstanding Laser Damage Threshold

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Noncentrosymmetric Tetrel Pnictides RuSi4P4 and IrSi3P3: Nonlinear Optical Materials with Outstanding Laser Damage ThresholdOriginalBalanced infrared nonlinear optical performance achieved by modulating the covalency and ionicity distributions in the electron localization function map42Synthesis-enabled exploration of chiral and polar multivalent quaternary sulfides37Mg 2 In 3 Si 2 P 7 : A Quaternary Diamond-like Phosphide Infrared Nonlinear Optical Material Derived from ZnGeP 2130Predictive Synthesis53The Rise of Infrared Nonlinear Optical Pnictides: Advances and Outlooks36Design of metal silicide nanoparticles in molten salts : electrocatalytic and magnetic properties0Add a Pinch of Tetrel: The Transformation of a Centrosymmetric Metal into a Nonsymmorphic and Chiral Semiconductor8Broad transparency and wide band gap achieved in a magnetic infrared nonlinear optical chalcogenide by suppressing d–d transitions41First polar quaternary sulphide CsLiGa 6 S 10 with mixed ordered alkali cations displaying excellent infrared nonlinear optical properties16Methylpiperazine based 0D chiral hybrid lead halides for second harmonic generation21Semiconducting silicon–phosphorus frameworks for caging exotic polycations10Pd and octahedra do not get along: Square planar [PdS4] units in non-centrosymmetric La6PdSi2S1419Phosphogermanate Crystal: A New Ultraviolet–Infrared Nonlinear Optical Crystal with Excellent Optical Performances16Non‐Linear Optical Properties of the (RE)3CuGeS7 Family of Compounds16BaSi7P10 and SrSi7P10: Two Infrared Nonlinear Optical Phosphides with T2 Supertetrahedra Exhibiting Strong Second‐Harmonic Generation Effects22Machine Learning-Guided Discovery of Ternary Compounds Containing La, P, and Group 14 Elements14AIn 3 Si 4 P 9 (A = Ca, Sr): quaternary phosphides with double-helix structures exhibiting high laser-induced damage thresholds19Breaking the bottleneck of simultaneously wide band gap and large nonlinear optical coefficient by a “pore reconstruction” strategy in a salt-inclusion chalcogenide26Enhancement of birefringence and refractive index dispersion optimization from iodates to fluorooxoiodates1IrSi 3 As 3 : a first transition metal arsenide non-linear optical material10Open honeycomb frameworks of sulphides AHg 4 Ga 5 S 12 (A = Rb, Cs) exhibiting infrared nonlinear optical properties12Synthesis of chiral high-entropy sulfides for non-linear optical applications13Universal Method for Determining the Principal Optical Indicatrix Axes in Triclinic Crystals1ε-La(IO3)3: A Polar Iodate with High Thermal Stability and a Large Second-Harmonic-Generation Response Obtained by a Supercritical Hydrothermal Method8Inherent law of SHG and phase-matching in 0D NLO materials: Permutation tetra-coordinated groups2Excellent Nonlinear Optical M[M4Cl][Ga11S20] (M = A/Ba, A = K, Rb) Achieved by Unusual Cationic Substitution Strategy20Direct Band Gap Semiconductors with Two‐ and Three‐Dimensional Triel‐Phosphide Frameworks (Triel=Al, Ga, In)3Computer-aided screening of bismuth molybdates nonlinear optical crystals γ -Bi 2 MoO 63Multi-step cation substitution facilitating the exploration of potential infrared nonlinear optical materials6Novel Laser Crystal Nd:LiY(MoO4)2: Crystal Growth, Characterization, and Orthogonally Polarized Dual-Wavelength Laser13EuSi7P10: An Inorganic Supramolecular Nonlinear Optical Crystal Exhibiting Strong Second-Harmonic Generation Response4A new neutral organic material DMPO with ultra-strong second-order nonlinear response and excellent anti-deliquescence2FeSi4P4 and CoSi3P3: Hidden Gems of Ternary Tetrel Pnictides with Outstanding Nonlinear Optical Properties11Breaking Symmetry for SHG Response: Lanthanide Acetate Crystals via Water Molecule Regulation Strategy5Achieving strong optical nonlinearity and wide bandgap of pnictides via ionic motif–driven directed assembly of covalent groups39Enhancement of Crystal Growth in Molten Salts by a Cocrystallization Agent: Synthesis and Luminescent Properties of Ce3+- and Eu2+-Doped La3(SiS4)2I4Reinforced Nonlinear Optical Performances Induced by P‐P Homoatomic Bond in Phosphide SrIn 3 Si 4 P 1131Reinforced Nonlinear Optical Performances Induced by P‐P Homoatomic Bond in Phosphide SrIn 3 Si 4 P 116In and Out: Shuttling Atoms in Covalent Nanocrystals, from Synthesis in Molten Salts to Water-Splitting Electrocatalysis5Pnictides: An Overview of Crystal Structures, Properties and Applications5Developing a neural network machine learning interatomic potential for molecular dynamics simulations of La–Si–P systems4CaM 3 Si 4 As 11 (M = Ga, In): arsenide infrared nonlinear optical crystals enforced by novel [As 2 ] linear motifs0Topology-Guided Discovery of BaIn 2 Si 7 P 12 : A Quaternary Diamond-like Framework Phosphide with Giant Second-Harmonic Generation and High Laser-Induced Damage Threshold22Design of a High-Performance Infrared Nonlinear Optical Crystal via a Multiple Flexible-Group Synergistic Polarization Strategy10Salt-Inclusion Rare-Earth Chalcogenides: Exploring Infrared Nonlinear Optical Crystals via a Guest-Framework Modulation Strategy0Mid‐ to Far‐Infrared Nonlinear Optical Crystals: Design Strategies, Structure–Property Relationships and Engineering Prospects0CaM 3 Si 4 P 11 (M = Al, Ga): [P 2 ] Motifs‐Modified Quasi‐T 3 Supertetrahedra Drive Superior Infrared Nonlinear Optical Performances1

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  2. Synthesis-enabled exploration of chiral and polar multivalent quaternary sulfides

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  3. Mg 2 In 3 Si 2 P 7 : A Quaternary Diamond-like Phosphide Infrared Nonlinear Optical Material Derived from ZnGeP 2

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  4. Predictive Synthesis

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  5. The Rise of Infrared Nonlinear Optical Pnictides: Advances and Outlooks

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  6. Design of metal silicide nanoparticles in molten salts : electrocatalytic and magnetic properties

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  7. Add a Pinch of Tetrel: The Transformation of a Centrosymmetric Metal into a Nonsymmorphic and Chiral Semiconductor

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  8. Broad transparency and wide band gap achieved in a magnetic infrared nonlinear optical chalcogenide by suppressing d–d transitions

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  9. First polar quaternary sulphide CsLiGa 6 S 10 with mixed ordered alkali cations displaying excellent infrared nonlinear optical properties

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  10. Methylpiperazine based 0D chiral hybrid lead halides for second harmonic generation

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  11. Semiconducting silicon–phosphorus frameworks for caging exotic polycations

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  12. Pd and octahedra do not get along: Square planar [PdS4] units in non-centrosymmetric La6PdSi2S14

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  13. Phosphogermanate Crystal: A New Ultraviolet–Infrared Nonlinear Optical Crystal with Excellent Optical Performances

    ACS Applied Materials & Interfaces · 2022-02-16

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  14. Non‐Linear Optical Properties of the (RE)3CuGeS7 Family of Compounds

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  15. BaSi7P10 and SrSi7P10: Two Infrared Nonlinear Optical Phosphides with T2 Supertetrahedra Exhibiting Strong Second‐Harmonic Generation Effects

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  16. Machine Learning-Guided Discovery of Ternary Compounds Containing La, P, and Group 14 Elements

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  17. AIn 3 Si 4 P 9 (A = Ca, Sr): quaternary phosphides with double-helix structures exhibiting high laser-induced damage thresholds

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  18. Breaking the bottleneck of simultaneously wide band gap and large nonlinear optical coefficient by a “pore reconstruction” strategy in a salt-inclusion chalcogenide

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  19. Enhancement of birefringence and refractive index dispersion optimization from iodates to fluorooxoiodates

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  20. IrSi 3 As 3 : a first transition metal arsenide non-linear optical material

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  21. Open honeycomb frameworks of sulphides AHg 4 Ga 5 S 12 (A = Rb, Cs) exhibiting infrared nonlinear optical properties

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  22. Synthesis of chiral high-entropy sulfides for non-linear optical applications

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  23. Universal Method for Determining the Principal Optical Indicatrix Axes in Triclinic Crystals

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  24. ε-La(IO3)3: A Polar Iodate with High Thermal Stability and a Large Second-Harmonic-Generation Response Obtained by a Supercritical Hydrothermal Method

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  25. Inherent law of SHG and phase-matching in 0D NLO materials: Permutation tetra-coordinated groups

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  26. Excellent Nonlinear Optical M[M4Cl][Ga11S20] (M = A/Ba, A = K, Rb) Achieved by Unusual Cationic Substitution Strategy

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  27. Direct Band Gap Semiconductors with Two‐ and Three‐Dimensional Triel‐Phosphide Frameworks (Triel=Al, Ga, In)

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  28. Computer-aided screening of bismuth molybdates nonlinear optical crystals γ -Bi 2 MoO 6

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  29. Multi-step cation substitution facilitating the exploration of potential infrared nonlinear optical materials

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  30. Novel Laser Crystal Nd:LiY(MoO4)2: Crystal Growth, Characterization, and Orthogonally Polarized Dual-Wavelength Laser

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  32. A new neutral organic material DMPO with ultra-strong second-order nonlinear response and excellent anti-deliquescence

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