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RESEARCH PAPER · Russian Chemical Reviews · 2018

The structure and classification of complex borates

Anastasiya P. Topnikova, Elena L. Belokoneva

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The structure and classification of complex boratesOriginalK 2 [B 4 O 5 (OH) 4 ]·H 2 O and K 2 [B 4 O 5 (OH) 4 ]: two new hydrated potassium borates with isolated [B 4 O 5 (OH) 4 ] 2− units and different structural frameworks8Oxidopolyborate anions templated by transition-metal complex cations: Self-assembled syntheses and structural studies (XRD) of [Co(NH3)6]2[B4O5(OH)4]3·11H2O, [Ni(phen)3][B7O9(OH)5].9.5H2O and [Zn(dac)2(H2O)2][B7O9(OH)5]·H2O10Pentaborate(1-) Salts and a Tetraborate(2-) Salt Derived from C2- or C3-Linked Bis(alkylammonium) Dications: Synthesis, Characterization, and Structural (XRD) Studies5Crystal structure, theoretical studies and luminescent properties of a new borate Na 3 GdB 8 O 15 with one-dimensional broad-banded anionic framework13Synthesis, characterization and crystal structure of a new mixed alkali and alkaline-earth metal borate Rb 9 Ba 24 (BO 3 ) 196Synthesis, crystal structure and topological features of microporous “anti-zeolite” Yb3(BO3)(OH)6∙2.1H2O, a new cubic borate with isolated BO3 groups8Structural Diversity of Cationic Copper(II) Complexes with Neutral Nitrogen-Containing Organic Ligands in Compounds with Boron Cluster Anions and Their Derivatives (Review)36Formation of oxidopolyborates in destruction of the [B11H14]– anion promoted by transition metals18New double holmium borates: Rb3HoB6O12 and Rb3Ho2B3O910Ba3(BO3)(CO3)F: The First Borate Carbonate Fluoride Synthesized by the High‐Temperature Solution Method19Unprecedented Formation of Potassium Borate Based Carbonate from Chloral Hydrate, Potassium Carbonate and Boric Acid1Exploration of structural, thermal and vibrational properties of new noncentrosymmetric double borate Rb3Tm2B3O99Synthesis, crystal structure, and thermal stability of double borate Na3ErB2O62Guanidinium Fluorooxoborates as Efficient Metal-free Short-Wavelength Nonlinear Optical Crystals140DOUBLE BORATES OF POTASSIUM (RUBIDIUM) AND RARE-EARTH ELEMENTS1Formation of Polyborates during Dimerization of the closo-Decaborate Anion and Isomerization of the Octadecahydroeicosaborate Anion12A New Approach for the Synthesis of Powder Zinc Oxide and Zinc Borates with Desired Properties27Effect of Nature of Substituents on Coordination Properties of Mono- and Disubstituted Derivatives of Boron Cluster Anions [BnHn]2– (n = 10, 12) and Carboranes with exo-Polyhedral B–X Bonds (X = N, O, S, Hal)42Effects of Boron-Containing Compounds on Liposoluble Hormone Functions41Filling of Channels of the Zeolite Framework in Trigonal Polar Nonaborate Ва3Na0.9(OH)1.9[B9O16][B(OH)3]02D COSY 11B NMR spectroscopy in the interpretation of the structures of iso and trans isomers of the macropolyhedral boron cluster [B20H18]2–14Synthesis and Thermal Studies of Two Phosphonium Tetrahydroxidohexaoxidopentaborate(1-) Salts: Single-Crystal XRD Characterization of [iPrPPh3][B5O6(OH)4]·3.5H2O and [MePPh3][B5O6(OH)4]·B(OH)3·0.5H2O2Heterocyclic hexagonal B5O7− and B5O8− clusters: Inorganic benzenes and phenolate anions, dual 3c-4e hypervalent π bonds, and superhalogen anions5Preparation of novel silver borates by soft hydrothermal synthesis in sealed tubes: New representatives of larderellite and veatchite families17Boron Oxide B5o6 and B5o6− Clusters with a Hexagonal B3o3 Ring: Overturn of Potential Landscapes by One Electron†0Magnesium cations as templates for the self-assembly of supramolecular luminescent {Mg@[B 18 φ 34–35 ]}-clusters0The Further Development of the Borate Nitrate Family: Synthesis and Structural Characterization of Ag4(B3o6)(No3) with Unique Isolated B9o18 Clusters, 9b:6δ3□:3(<2δ□>–)<3□>0The local state of hydrogen atoms and proton transfer in the crystal structure of natural berborite, Be2(BO3)(OH)‧H2O: Low-temperature single crystal X-ray analysis, IR and 1H NMR spectroscopy, and crystal chemistry and structural complexity of beryllium borates8The further development of the borate nitrate family: Synthesis and characterization of Ag12(B9O18)(NO3)3 with unique isolated B9O18 clusters, 9B:6Δ3□:3(<2Δ□>–)<3□>6Tetrahydroxidohexaoxidopentaborate(1-) Salts of C6-Linked Substituted Diimidazolium and Dipyrrolidinium Cations: Synthesis, Characterization and XRD Studies0Boron oxide B5O6 and B5O6− clusters with a hexagonal B3O3 ring: Overturn of potential energy landscapes by one electron1Two Alkaline Metal Borates: from Layer to Layer-Pillared Framework8Structural Family of the CaMg[B2O5] Kurchatovite: Structure Features, Polytypical Complexity, DFT Analysis, and Comparative Crystal Chemistry of Divalent Cation Pyroborates3Aromatic compounds and their fascinating boron complexes as potential quorum sensing molecules13Crystal Chemistry of Silver Borates with Salt Inclusion Structure2[CON3H6BF4]: An Efficient Metal‐Free Borate with Optimized Birefringence Achieved by Structural Design Strategy15Studies on the melilite compound, Bi2ZnB2O7, as a host for new colored compounds and as a phosphor for rare-earth luminescence2Metal borates as emerging heterogeneous catalysts for organic transformations0Investigation on structural characteristics and properties of B7O60/− clusters: Four-, five-, and six-membered rings as key structural building blocks0Topological diversity of layered pentaborates: Synthesis, characterization, thermal behavior and optical properties of Ag2[B5O8(OH)] with a new type structure1Novel multifunctionalized transition metal borate materials in photo-electro catalysis, sensing and biobased applications1On the border between layered and framework motifs: Ag2[B8O12(OH)2], a novel silver borate with corrugated open-framework layers and unusual hydrogen bonding0Two transition metal borates built from unprecedented {B11} clusters with nonlinear optical properties0

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  1. K 2 [B 4 O 5 (OH) 4 ]·H 2 O and K 2 [B 4 O 5 (OH) 4 ]: two new hydrated potassium borates with isolated [B 4 O 5 (OH) 4 ] 2− units and different structural frameworks

    New Journal of Chemistry · 2019-01-01

    Tingting Shi, Fangfang Zhang, Abudukadi Tudi, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·

  2. Oxidopolyborate anions templated by transition-metal complex cations: Self-assembled syntheses and structural studies (XRD) of [Co(NH3)6]2[B4O5(OH)4]3·11H2O, [Ni(phen)3][B7O9(OH)5].9.5H2O and [Zn(dac)2(H2O)2][B7O9(OH)5]·H2O

    Journal of Molecular Structure · 2019-09-12

    Mohammed A. Altahan, Michael A. Beckett, Simon John Coles, Peter Neil Horton

    Read original paper ↗ ·

  3. Pentaborate(1-) Salts and a Tetraborate(2-) Salt Derived from C2- or C3-Linked Bis(alkylammonium) Dications: Synthesis, Characterization, and Structural (XRD) Studies

    Molecules · 2019-12-23

    Michael A. Beckett, Bashdar I. Meena, Thomas A. Rixon, Simon John Coles, Peter Neil Horton

    Read original paper ↗ ·

  4. Crystal structure, theoretical studies and luminescent properties of a new borate Na 3 GdB 8 O 15 with one-dimensional broad-banded anionic framework

    Dalton Transactions · 2020-01-01

    Dan Zhao, Yanan Li, Yan-Ping Fan, Baozhong Liu, Shirui Zhang, Ruijuan Zhang

    Read original paper ↗ ·

  5. Synthesis, characterization and crystal structure of a new mixed alkali and alkaline-earth metal borate Rb 9 Ba 24 (BO 3 ) 19

    New Journal of Chemistry · 2020-01-01

    Xiaowen Niu, Li Wang

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  6. Synthesis, crystal structure and topological features of microporous “anti-zeolite” Yb3(BO3)(OH)6∙2.1H2O, a new cubic borate with isolated BO3 groups

    Microporous and Mesoporous Materials · 2020-03-08

    A. P. Topnikova, Tatiana A. Eremina, Elena L. Belokoneva, Olga V. Dimitrova, Anatoly S. Volkov, Sergey M. Aksenov

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  7. Structural Diversity of Cationic Copper(II) Complexes with Neutral Nitrogen-Containing Organic Ligands in Compounds with Boron Cluster Anions and Their Derivatives (Review)

    Russian Journal of Inorganic Chemistry · 2020-04-01

    Varvara Vladimirovna Avdeeva, Еlena А. Malinina, Konstantin Yu. Zhizhin, Nikolay T. Kuznetsov

    Read original paper ↗ ·

  8. Formation of oxidopolyborates in destruction of the [B11H14]– anion promoted by transition metals

    Inorganica Chimica Acta · 2020-04-22

    Varvara Vladimirovna Avdeeva, Еlena А. Malinina, Anna Vladimirovna Vologzhanina, Igor B. Sivaev, Nikolay T. Kuznetsov

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  9. New double holmium borates: Rb3HoB6O12 and Rb3Ho2B3O9

    Solid State Sciences · 2020-04-22

    Alexey Karpovich Subanakov, Evgeniy V. Kovtunets, Баир Гармаевич Базаров, Sesegma G. Dorzhieva, Jibzema G. Bazarova

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  10. Ba3(BO3)(CO3)F: The First Borate Carbonate Fluoride Synthesized by the High‐Temperature Solution Method

    Chemistry - A European Journal · 2020-09-25

    Chunmei Huang, Fangfang Zhang, Shichao Cheng, Zhihua Yang, Hao Li, Shilie Pan

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  11. Unprecedented Formation of Potassium Borate Based Carbonate from Chloral Hydrate, Potassium Carbonate and Boric Acid

    X-ray Structure Analysis Online · 2021-08-09

    Mustafa Tombul, Elmas TÜRKMENOGLU, Onur Şahın

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  12. Exploration of structural, thermal and vibrational properties of new noncentrosymmetric double borate Rb3Tm2B3O9

    Solid State Sciences · 2021-09-03

    Alexey Karpovich Subanakov, Evgeniy V. Kovtunets, Баир Гармаевич Базаров, A. M. Pugachev, Dmitriy Sofich, Jibzema G. Bazarova

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  13. Synthesis, crystal structure, and thermal stability of double borate Na3ErB2O6

    Chimica Techno Acta · 2021-10-20

    Alexey Karpovich Subanakov, Evgeniy V. Kovtunets, Баир Гармаевич Базаров, Jibzema G. Bazarova

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  14. Guanidinium Fluorooxoborates as Efficient Metal-free Short-Wavelength Nonlinear Optical Crystals

    Chemistry of Materials · 2021-12-24

    Congcong Jin, Hao Zeng, Feng Zhang, Haotian Qiu, Zhihua Yang, Miriding Mutailipu, Shilie Pan

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  15. DOUBLE BORATES OF POTASSIUM (RUBIDIUM) AND RARE-EARTH ELEMENTS

    Journal of Structural Chemistry · 2022-07-01

    Alexey Karpovich Subanakov, Evgeniy V. Kovtunets, Баир Гармаевич Базаров, Jibzema G. Bazarova

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  16. Formation of Polyborates during Dimerization of the closo-Decaborate Anion and Isomerization of the Octadecahydroeicosaborate Anion

    Russian Journal of Inorganic Chemistry · 2022-07-01

    Alexey S. Kubasov, Ivan V. Novikov, Polina A. Starodubets, Varvara Vladimirovna Avdeeva, Konstantin Yu. Zhizhin, Nikolay T. Kuznetsov

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  17. A New Approach for the Synthesis of Powder Zinc Oxide and Zinc Borates with Desired Properties

    Inorganics · 2022-11-17

    Irina V. Kozerozhets, Varvara Vladimirovna Avdeeva, Grigorii A. Buzanov, Е. А. Семенов, Yu. V. Ioni, С. П. Губин

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  18. Effect of Nature of Substituents on Coordination Properties of Mono- and Disubstituted Derivatives of Boron Cluster Anions [BnHn]2– (n = 10, 12) and Carboranes with exo-Polyhedral B–X Bonds (X = N, O, S, Hal)

    Inorganics · 2022-12-02

    E. Yu. Matveev, Varvara Vladimirovna Avdeeva, Konstantin Yu. Zhizhin, Еlena А. Malinina, Nikolay T. Kuznetsov

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  19. Effects of Boron-Containing Compounds on Liposoluble Hormone Functions

    Inorganics · 2023-02-17

    Elizabeth Estevez-Fregoso, Ahmet Kılıç, Diana Rodríguez-Vera, Luis Eduardo Nicanor-Juárez, C. Elena M. Romero-Rizo, Eunice D. Farfán‐García, Marvin Antonio Soriano-Ursua

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  20. Filling of Channels of the Zeolite Framework in Trigonal Polar Nonaborate Ва3Na0.9(OH)1.9[B9O16][B(OH)3]

    Crystallography Reports · 2023-04-01

    A. P. Topnikova, Elena L. Belokoneva, Olga V. Dimitrova, Anatoly S. Volkov, Leokadiya V. Zorina

    Read original paper ↗ ·

  21. 2D COSY 11B NMR spectroscopy in the interpretation of the structures of iso and trans isomers of the macropolyhedral boron cluster [B20H18]2–

    Inorganica Chimica Acta · 2023-05-10

    Varvara Vladimirovna Avdeeva, Viktor I. Privalov, Alexey S. Kubasov, Svetlana E. Nikiforova, Еlena А. Malinina, Nikolay T. Kuznetsov

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  22. Synthesis and Thermal Studies of Two Phosphonium Tetrahydroxidohexaoxidopentaborate(1-) Salts: Single-Crystal XRD Characterization of [iPrPPh3][B5O6(OH)4]·3.5H2O and [MePPh3][B5O6(OH)4]·B(OH)3·0.5H2O

    Molecules · 2023-09-29

    Michael A. Beckett, Peter Neil Horton, Michael B. Hursthouse, James L. Timmis

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  23. Heterocyclic hexagonal B5O7− and B5O8− clusters: Inorganic benzenes and phenolate anions, dual 3c-4e hypervalent π bonds, and superhalogen anions

    Journal of Molecular Structure · 2023-10-03

    Shu‐Juan Gao, Peng-Fei Han, Jin‐Chang Guo, Hua‐Jin Zhai

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  24. Preparation of novel silver borates by soft hydrothermal synthesis in sealed tubes: New representatives of larderellite and veatchite families

    Solid State Sciences · 2023-12-15

    Sergey N. Volkov, Sergey M. Aksenov, Dmitri O. Charkin, A. M. Banaru, Daria A. Banaru, Yulia A. Vaitieva, Maria Georgievna Krzhizhanovskaya, N. A. Yamnova, Vadim E. Kireev, Alevtina N. Gosteva, Nikita Sergeyevich Tsvetov, Yevgeny E. Savchenko, Р. С. Бубнова

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  25. Boron Oxide B5o6 and B5o6− Clusters with a Hexagonal B3o3 Ring: Overturn of Potential Landscapes by One Electron†

    SSRN Electronic Journal · 2024-01-01

    Da Zhi Li, Qiuhong Xu, He Bian, Shu‐Juan Gao, Lijuan Zhang, Ling Pei, Hua‐Jin Zhai

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  26. Magnesium cations as templates for the self-assembly of supramolecular luminescent {Mg@[B 18 φ 34–35 ]}-clusters

    Dalton Transactions · 2024-01-01

    Sergey N. Volkov, Valentina A. Yukhno, A. M. Banaru, Dina V. Deyneko, Sergey M. Aksenov, Dmitri O. Charkin, Alexey V. Povolotskiy, Yevgeny E. Savchenko, Andrey A. Antonov, Maria Georgievna Krzhizhanovskaya, В. Л. Уголков, Vera A. Firsova, Yulia A. Vaitieva, Kirill N. Boldyrev, Р. С. Бубнова

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  27. The Further Development of the Borate Nitrate Family: Synthesis and Structural Characterization of Ag4(B3o6)(No3) with Unique Isolated B9o18 Clusters, 9b:6δ3□:3(<2δ□>–)<3□>

    SSRN Electronic Journal · 2024-01-01

    Sergey N. Volkov, Dmitri O. Charkin, Ivan A. Marsiy, Daria A. Banaru, Alexey V. Povolotskiy, Alevtina N. Gosteva, Maxim Yu. Arsent apos ev, Maria Georgievna Krzhizhanovskaya, Valeriy L. Ugolkov, Yevgeny E. Savchenko, Vadim E. Kireev, Sergey M. Aksenov, Р. С. Бубнова

    Read original paper ↗ ·

  28. The local state of hydrogen atoms and proton transfer in the crystal structure of natural berborite, Be2(BO3)(OH)‧H2O: Low-temperature single crystal X-ray analysis, IR and 1H NMR spectroscopy, and crystal chemistry and structural complexity of beryllium borates

    Journal of Physics and Chemistry of Solids · 2024-02-22

    Sergey M. Aksenov, Nikita V. Chukanov, Viktor P. Tarasov, Daria A. Banaru, Stephanie A. Mackley, A. M. Banaru, Sergey V. Krivovichev, Peter Carman Burns

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  29. The further development of the borate nitrate family: Synthesis and characterization of Ag12(B9O18)(NO3)3 with unique isolated B9O18 clusters, 9B:6Δ3□:3(<2Δ□>–)<3□>

    Journal of Crystal Growth · 2024-07-31

    Sergey N. Volkov, Dmitri O. Charkin, Ivan A. Marsiy, Daria A. Banaru, Alexey V. Povolotskiy, Alevtina N. Gosteva, M. Yu. Arsent’ev, Maria Georgievna Krzhizhanovskaya, В. Л. Уголков, Yevgeny E. Savchenko, Vadim E. Kireev, Sergey M. Aksenov, Р. С. Бубнова

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  30. Tetrahydroxidohexaoxidopentaborate(1-) Salts of C6-Linked Substituted Diimidazolium and Dipyrrolidinium Cations: Synthesis, Characterization and XRD Studies

    Inorganics · 2024-08-15

    Ahmad R. Al Dulayymi, Michael A. Beckett, Radek Bragança, Simon John Coles, Peter Neil Horton, Thomas A. Rixon

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  31. Boron oxide B5O6 and B5O6− clusters with a hexagonal B3O3 ring: Overturn of potential energy landscapes by one electron

    Computational and Theoretical Chemistry · 2024-12-01

    Dazhi Li, Qiuhong Xu, He Bian, Shu‐Juan Gao, Lijuan Zhang, Ling Pei, Hua‐Jin Zhai

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  32. Two Alkaline Metal Borates: from Layer to Layer-Pillared Framework

    Inorganic Chemistry · 2024-12-31

    Juan Chen, Dan Qin, Guo‐Yu Yang

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  33. Structural Family of the CaMg[B2O5] Kurchatovite: Structure Features, Polytypical Complexity, DFT Analysis, and Comparative Crystal Chemistry of Divalent Cation Pyroborates

    Journal of Structural Chemistry · 2025-02-01

    Sergey M. Aksenov, D. А. Banaru, A. M. Banaru, Andrey A. Antonov, Natalia A. Kabanova, Alexey N. Kuznetsov∥, Elena L. Belokoneva, N. A. Yamnova, Д. В. Дейнеко, Nadezhda A. Chervonnaya, Nikita V. Chukanov, Vladislav A. Blatov

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  34. Aromatic compounds and their fascinating boron complexes as potential quorum sensing molecules

    Vietnam Journal of Chemistry · 2025-04-01

    Valery M. Dembitsky, Alexander Olegovich Terent'ev, S. V. Baranin, Mikhail E. Gursky

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  35. Crystal Chemistry of Silver Borates with Salt Inclusion Structure

    Crystallography Reports · 2025-04-01

    S. N. Volkov, Dmitri O. Charkin, Sergey M. Aksenov, A. M. Banaru, Yu.O. Kopylova, Р. С. Бубнова

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  36. [CON3H6BF4]: An Efficient Metal‐Free Borate with Optimized Birefringence Achieved by Structural Design Strategy

    Small · 2025-05-23

    Muhammad Arif, Xu Liu, Hangwei Jia, Zhihua Yang, Xueling Hou, Shilie Pan

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  37. Studies on the melilite compound, Bi2ZnB2O7, as a host for new colored compounds and as a phosphor for rare-earth luminescence

    Journal of Chemical Sciences · 2025-08-13

    Indrani. G. Shanmugapriya, S A Shreenibasa, Srinivasan Natarajan

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  38. Metal borates as emerging heterogeneous catalysts for organic transformations

    Catalysis Science & Technology · 2026-01-01

    Yurong Sun, Yao Yang, Wenliang Gao, Tao Yang

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  39. Investigation on structural characteristics and properties of B7O60/− clusters: Four-, five-, and six-membered rings as key structural building blocks

    Computational and Theoretical Chemistry · 2026-03-14

    Huiqing Sun, Ziyan Guo, Rachel Sun, Wenjuan Tian

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  40. Topological diversity of layered pentaborates: Synthesis, characterization, thermal behavior and optical properties of Ag2[B5O8(OH)] with a new type structure

    Journal of Solid State Chemistry · 2026-04-02

    Yu.A. Vaitieva, A. M. Banaru, A.N. Gosteva, M. Yu. Arsent’ev, M.G. Krzhizhanovskaya, S. K. Volkov, Sergey M. Aksenov

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  41. Novel multifunctionalized transition metal borate materials in photo-electro catalysis, sensing and biobased applications

    Journal of the Iranian Chemical Society · 2026-04-27

    J.J. Umashankar, Jayachandran Hemalatha, Chennappan Senthamil, Chandrasekar Sakthivel, A. Nivetha, I. Prabha

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  42. On the border between layered and framework motifs: Ag2[B8O12(OH)2], a novel silver borate with corrugated open-framework layers and unusual hydrogen bonding

    Journal of Solid State Chemistry · 2026-08-05

    A. M. Banaru, Yu.A. Vaitieva, A. N. Gosteva, M. Yu. Arsent’ev, A. A. Kompanchenko, Y. E. Savchenko, Maria Georgievna Krzhizhanovskaya, S. N. Volkov, Sergey M. Aksenov

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  43. Two transition metal borates built from unprecedented {B11} clusters with nonlinear optical properties

    Science China Chemistry · 2026-09-22

    Juan Chen, Guo-Yu Yang

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