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RESEARCH PAPER · Advanced Optical Materials · 2018

Strong SHG Response via High Orientation of Tetrahedral Functional Motifs in Polyselenide A2Ge4Se10 (A = Rb, Cs)

Bin‐Wen Liu, Chun‐Li Hu, Hui‐Yi Zeng, Xiao‐Ming Jiang, Guo‐Cong Guo

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Strong SHG Response via High Orientation of Tetrahedral Functional Motifs in Polyselenide A2Ge4Se10 (A = Rb, Cs)OriginalSyntheses, crystal structures and optical properties of two one-dimensional germanophosphates: HRb3Ge2(HPO4)6 and CsGe(HPO4)2(OH)2BaMnSnS 4 and BaCdGeS 4 : infrared nonlinear optical sulfides containing highly distorted motifs with centers of moderate electronegativity48Balanced Second-Order Nonlinear Optical Properties of Adducts CHI3·(S8)3 and AsI3·(S8)3: A Systematic Survey48Sn 2 Ga 2 S 5 : A Polar Semiconductor with Exceptional Infrared Nonlinear Optical Properties Originating from the Combined Effect of Mixed Asymmetric Building Motifs81Li4HgSn2Se7: The First Second-Order Nonlinear Optical-Active Selenide in the I4–II–IV2–VI7 Diamond-like Family32Li[LiCs2Cl][Ga3S6]: A Nanoporous Framework of GaS4 Tetrahedra with Excellent Nonlinear Optical Performance172Li[LiCs2Cl][Ga3S6]: A Nanoporous Framework of GaS4 Tetrahedra with Excellent Nonlinear Optical Performance40Ba 13 In 12 Zn 7 S 38 and Ba 12 In 12 Zn 8 Se 38 : infrared nonlinear optical chalcogenides designed by zinc-induced non-centrosymmetry transformation22LiGa0.54In0.46S2: A new infrared nonlinear optical material with large laser damage threshold designed by gallium substitution in LiInS223LiBa4Ga5Q12 (Q = S, Se): Noncentrosymmetric Metal Chalcogenides with a Cesium Chloride Topological Structure Displaying a Remarkable Laser Damage Threshold32[ABa2Cl][Ga4S8] (A = Rb, Cs): Wide-Spectrum Nonlinear Optical Materials Obtained by Polycation-Substitution-Induced Nonlinear Optical (NLO)-Functional Motif Ordering269Inherent laws between tetrahedral arrangement pattern and optical performance in tetrahedron-based mid-infrared nonlinear optical materials130Evaluation of nonlinear optical properties of quaternary chalcogenide halides Ba4Si3Se9Br2 and Ba4Ge3Se9Br222Chalcophosphates: A Treasure House of Infrared Nonlinear Optical Materials75AMnAs3S6 (A = Cs, Rb): Phase-Matchable Infrared Nonlinear Optical Functional Motif [As3S6]3– Obtained via Surfactant–Thermal Method32α-CdP2: Large SHG Effect Originating from the Synergism of Parallel ∞1[P–] Polyanion Chains and Distorted CdP4 Tetrahedra21A novel promising infrared nonlinear optical selenide KAg 3 Ga 8 Se 14 designed from benchmark AgGaQ 2 (Q = S, Se)55Balanced infrared nonlinear optical performance achieved by modulating the covalency and ionicity distributions in the electron localization function map42Na 6 MQ 4 (M=Zn, Cd; Q=S, Se): Promising New Ternary Infrared Nonlinear Optical Materials24Uncovering a Functional Motif of Nonlinear Optical Materials by In Situ Electron Density and Wavefunction Studies Under Laser Irradiation39Uncovering a Functional Motif of Nonlinear Optical Materials by In Situ Electron Density and Wavefunction Studies Under Laser Irradiation1Ionothermal Synthesis of Two New Thioantimonates with Transition Metal Regulation4AXHg3P2S8 (A = Rb, Cs; X = Cl, Br): New Excellent Infrared Nonlinear Optical Materials with Mixed‐Anion Chalcohalide Groups of Trigonal Planar [HgS2X]3− and Tetrahedral [HgS3X]5−58Superior Infrared Nonlinear Optical Performance Achieved by Synergetic Functional Motif and Vacancy Site Modulations48Material research from the viewpoint of functional motifs103(Na0.74Ag1.26)BaSnS4: A New AgGaS2‐Type Nonlinear Optical Sulfide with a Wide Band Gap and High Laser Induced Damage Threshold14Enhanced Second-Harmonic Generation of van der Waals CuInP 2 S 6 via Pressure-Regulated Cationic Displacement61d6versus d10, Which Is Better for Second Harmonic Generation Susceptibility? A Case Study of K2TGe3Ch8 (T = Fe, Cd; Ch = S, Se)18“Three‐in‐One”: A New Hg‐Based Selenide Hg 7 P 2 Se 12 Exhibiting Wide Infrared Transparency Range and Strong Nonlinear Optical Effect80Optical second harmonic generation in anisotropic multilayers with complete multireflection of linear and nonlinear waves using ♯SHAARP.ml package12Ae3[TO3][SnOQ3] (Ae = Sr, Ba; T = Si, Ge; Q = S, Se) and Ba3[CO3][MQ4] (M = Ge, Sn; Q = S, Se): Design and Syntheses of a Series of Heteroanionic Antiperovskite-Type Oxychalcogenides29

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  1. Syntheses, crystal structures and optical properties of two one-dimensional germanophosphates: HRb3Ge2(HPO4)6 and CsGe(HPO4)2(OH)

    Acta Crystallographica Section C Structural Chemistry · 2018-09-26

    Jun-Ling Song, Wen-Xiu Lu, Tian-Shuo Guo, Yu-Hua Zhou

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  2. BaMnSnS 4 and BaCdGeS 4 : infrared nonlinear optical sulfides containing highly distorted motifs with centers of moderate electronegativity

    Inorganic Chemistry Frontiers · 2019-01-01

    Yang-Jie Lin, Run Ye, Long‐Qi Yang, Xiao‐Ming Jiang, Bin‐Wen Liu, Hui‐Yi Zeng, Guo‐Cong Guo

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  3. Balanced Second-Order Nonlinear Optical Properties of Adducts CHI3·(S8)3 and AsI3·(S8)3: A Systematic Survey

    Inorganic Chemistry · 2019-03-15

    Zhen‐Tao Lu, Zongdong Sun, Yang Chi, Huaiguo Xue, Sheng‐Ping Guo

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  4. Sn 2 Ga 2 S 5 : A Polar Semiconductor with Exceptional Infrared Nonlinear Optical Properties Originating from the Combined Effect of Mixed Asymmetric Building Motifs

    Chemistry of Materials · 2019-07-26

    Mengyue Li, Bingxuan Li, Hua Lin, Zuju Ma, Li‐Ming Wu, Xin‐Tao Wu, Qi‐Long Zhu

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  5. Li4HgSn2Se7: The First Second-Order Nonlinear Optical-Active Selenide in the I4–II–IV2–VI7 Diamond-like Family

    Crystal Growth & Design · 2019-09-09

    Yangwu Guo, Fei Liang, Zhuang Li, Wenhao Xing, Zheshuai Lin, Jiyong Yao, Yicheng Wu

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  6. Li[LiCs2Cl][Ga3S6]: A Nanoporous Framework of GaS4 Tetrahedra with Excellent Nonlinear Optical Performance

    Angewandte Chemie International Edition · 2019-10-26

    Bin‐Wen Liu, Xiao‐Ming Jiang, Bingxuan Li, Hui‐Yi Zeng, Guo‐Cong Guo

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  7. Li[LiCs2Cl][Ga3S6]: A Nanoporous Framework of GaS4 Tetrahedra with Excellent Nonlinear Optical Performance

    Angewandte Chemie · 2019-10-26

    Bin‐Wen Liu, Xiao‐Ming Jiang, Bingxuan Li, Hui‐Yi Zeng, Guo‐Cong Guo

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  8. Ba 13 In 12 Zn 7 S 38 and Ba 12 In 12 Zn 8 Se 38 : infrared nonlinear optical chalcogenides designed by zinc-induced non-centrosymmetry transformation

    Journal of Materials Chemistry C · 2020-01-01

    Long‐Qi Yang, Run Ye, Xiao‐Ming Jiang, Bin‐Wen Liu, Hui‐Yi Zeng, Guo‐Cong Guo

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  9. LiGa0.54In0.46S2: A new infrared nonlinear optical material with large laser damage threshold designed by gallium substitution in LiInS2

    Inorganic Chemistry Communications · 2020-02-21

    Long‐Qi Yang, Xiao‐Ming Jiang, Guo‐Cong Guo

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  10. LiBa4Ga5Q12 (Q = S, Se): Noncentrosymmetric Metal Chalcogenides with a Cesium Chloride Topological Structure Displaying a Remarkable Laser Damage Threshold

    Inorganic Chemistry · 2020-04-04

    Ailijiang Abudurusuli, Junjie Li, Tinghao Tong, Zhihua Yang, Shilie Pan

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  11. [ABa2Cl][Ga4S8] (A = Rb, Cs): Wide-Spectrum Nonlinear Optical Materials Obtained by Polycation-Substitution-Induced Nonlinear Optical (NLO)-Functional Motif Ordering

    Journal of the American Chemical Society · 2020-05-29

    Bin‐Wen Liu, Xiao‐Ming Jiang, Hui‐Yi Zeng, Guo‐Cong Guo

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  12. Inherent laws between tetrahedral arrangement pattern and optical performance in tetrahedron-based mid-infrared nonlinear optical materials

    Coordination Chemistry Reviews · 2020-06-29

    Weikang Wang, Dajiang Mei, Fei Liang, Jun Zhao, Yuandong Wu, Zheshuai Lin

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  13. Evaluation of nonlinear optical properties of quaternary chalcogenide halides Ba4Si3Se9Br2 and Ba4Ge3Se9Br2

    Journal of Alloys and Compounds · 2020-07-19

    Wenhao Xing, Naizheng Wang, Abishek K. Iyer, Wenlong Yin, Zheshuai Lin, Jiyong Yao, Bin Kang, A. Mar

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  14. Chalcophosphates: A Treasure House of Infrared Nonlinear Optical Materials

    Crystal Growth & Design · 2020-10-23

    Zhuang Li, Jiyong Yao, Yicheng Wu

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  15. AMnAs3S6 (A = Cs, Rb): Phase-Matchable Infrared Nonlinear Optical Functional Motif [As3S6]3– Obtained via Surfactant–Thermal Method

    ACS Applied Materials & Interfaces · 2020-11-10

    Run Ye, Bin‐Wen Liu, Xiao‐Ming Jiang, Jian Lü, Hui‐Yi Zeng, Guo‐Cong Guo

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  16. α-CdP2: Large SHG Effect Originating from the Synergism of Parallel ∞1[P–] Polyanion Chains and Distorted CdP4 Tetrahedra

    Chemistry of Materials · 2020-11-25

    Jindong Chen, Chensheng Lin, Feng Xu, Shunda Yang, Yingshuang Sun, Xin Lei Zhao, Xiaotian Jiang, Bingxuan Li, Tao Yan, Ning Ye

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  17. A novel promising infrared nonlinear optical selenide KAg 3 Ga 8 Se 14 designed from benchmark AgGaQ 2 (Q = S, Se)

    Chemical Communications · 2020-12-17

    Jia-Nuo Li, Wen‐Dong Yao, Xiaohui Li, Wenlong Liu, Huaiguo Xue, Sheng‐Ping Guo

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  18. Balanced infrared nonlinear optical performance achieved by modulating the covalency and ionicity distributions in the electron localization function map

    Materials Horizons · 2021-01-01

    Bin‐Wen Liu, Xiao‐Ming Jiang, Shao‐Min Pei, Wen‐Fa Chen, Long‐Qi Yang, Guo‐Cong Guo

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  19. Na 6 MQ 4 (M=Zn, Cd; Q=S, Se): Promising New Ternary Infrared Nonlinear Optical Materials

    Chemistry - A European Journal · 2021-01-27

    Yi Huang, Le Gao, Haohai Yu, Zhihua Yang, Junjie Li, Shilie Pan

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  20. Uncovering a Functional Motif of Nonlinear Optical Materials by In Situ Electron Density and Wavefunction Studies Under Laser Irradiation

    Angewandte Chemie International Edition · 2021-03-22

    Xiao‐Ming Jiang, Shujuan Lin, Chao He, Bin‐Wen Liu, Guo‐Cong Guo

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  21. Uncovering a Functional Motif of Nonlinear Optical Materials by In Situ Electron Density and Wavefunction Studies Under Laser Irradiation

    Angewandte Chemie · 2021-03-22

    Xiao‐Ming Jiang, Shujuan Lin, Chao He, Bin‐Wen Liu, Guo‐Cong Guo

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  22. Ionothermal Synthesis of Two New Thioantimonates with Transition Metal Regulation

    Journal of Cluster Science · 2021-04-29

    Gang Yang, Chao Wu, Jinfang Zhang, Chi Zhang

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  23. AXHg3P2S8 (A = Rb, Cs; X = Cl, Br): New Excellent Infrared Nonlinear Optical Materials with Mixed‐Anion Chalcohalide Groups of Trigonal Planar [HgS2X]3− and Tetrahedral [HgS3X]5−

    Advanced Optical Materials · 2021-05-20

    Wenhao Xing, Chunlan Tang, Naizheng Wang, Chunxiao Li, Ece Uykur, Jieyun Wu, Zheshuai Lin, Jiyong Yao, Wenlong Yin, Bin Kang

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  24. Superior Infrared Nonlinear Optical Performance Achieved by Synergetic Functional Motif and Vacancy Site Modulations

    Chemistry of Materials · 2021-11-03

    Shao‐Min Pei, Bin‐Wen Liu, Xiao‐Ming Jiang, Ya-Qian Zou, Wen‐Fa Chen, Qiu-Nan Yan, Guo‐Cong Guo

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  25. Material research from the viewpoint of functional motifs

    National Science Review · 2022-02-10

    Xiao‐Ming Jiang, Shuiquan Deng, Myung‐Hwan Whangbo, Guo‐Cong Guo

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  26. (Na0.74Ag1.26)BaSnS4: A New AgGaS2‐Type Nonlinear Optical Sulfide with a Wide Band Gap and High Laser Induced Damage Threshold

    Chemistry - A European Journal · 2022-08-10

    Wenfeng Zhou, Wenlong Liu, Sheng‐Ping Guo

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  27. Enhanced Second-Harmonic Generation of van der Waals CuInP 2 S 6 via Pressure-Regulated Cationic Displacement

    Chemistry of Materials · 2022-12-16

    Kejun Bu, Tonghuan Fu, Ziwan Du, Xinliang Feng, Dong Wang, Zhongyang Li, Songhao Guo, Zongdong Sun, Hui Luo, Gang Liu, Yang Ding, Tianyou Zhai, Qian Li, Xujie Lü

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  28. d6versus d10, Which Is Better for Second Harmonic Generation Susceptibility? A Case Study of K2TGe3Ch8 (T = Fe, Cd; Ch = S, Se)

    Inorganic Chemistry · 2022-12-27

    Bingheng Ji, Fei Wang, Kui Wu, Bingbing Zhang, Jian Wang

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  29. “Three‐in‐One”: A New Hg‐Based Selenide Hg 7 P 2 Se 12 Exhibiting Wide Infrared Transparency Range and Strong Nonlinear Optical Effect

    Advanced Functional Materials · 2023-12-28

    Yu Chu, Hongshan Wang, Quan Chen, Xin Su, Zuxin Chen, Zhihua Yang, Junjie Li, Shilie Pan

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  30. Optical second harmonic generation in anisotropic multilayers with complete multireflection of linear and nonlinear waves using ♯SHAARP.ml package

    npj Computational Materials · 2024-03-29

    Rui Zu, Bo Wang, Jingyang He, Lincoln Weber, Akash Saha, Long‐Qing Chen, Venkatraman Gopalan

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  31. Ae3[TO3][SnOQ3] (Ae = Sr, Ba; T = Si, Ge; Q = S, Se) and Ba3[CO3][MQ4] (M = Ge, Sn; Q = S, Se): Design and Syntheses of a Series of Heteroanionic Antiperovskite-Type Oxychalcogenides

    Journal of the American Chemical Society · 2024-09-16

    Yuanding Yu, Shiyi Zhang, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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