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RESEARCH PAPER · Inorganic Chemistry · 2016

Phase Transition and Second Harmonic Generation in Thiophosphates Ag2Cd(P2S6) and AgCd3(PS4)S2 Containing Two Second-Order Jahn–Teller Distorted Cations

Yuhang Fan, Xiao‐Ming Jiang, Bin‐Wen Liu, Shu‐Fang Li, Wei‐Huan Guo, Hui‐Yi Zeng, Guo‐Cong Guo, Jin‐Shun Huang

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Phase Transition and Second Harmonic Generation in Thiophosphates Ag2Cd(P2S6) and AgCd3(PS4)S2 Containing Two Second-Order Jahn–Teller Distorted CationsOriginalAgGa2PS6: A New Mid‐Infrared Nonlinear Optical Material with a High Laser Damage Threshold and a Large Second Harmonic Generation Response78Structural insights into T 2 -cluster-containing chalcogenides with vertex-, edge- and face-sharing connection modes of NaQ 6 ligands: Na 3 ZnM III Q 4 (M III = In, Ga; Q = S, Se)13Syntheses, crystal structures and optical properties of two one-dimensional germanophosphates: HRb3Ge2(HPO4)6 and CsGe(HPO4)2(OH)2ABaSbQ 3 (A = Li, Na; Q = S, Se): diverse arrangement modes of isolated SbQ 3 ligands regulating the magnitudes of birefringences50SrCdSnQ 4 (Q = S and Se): infrared nonlinear optical chalcogenides with mixed NLO-active and synergetic distorted motifs69Structural modulation induced by M IIIA metals in Ba 3 MQ 4 X (M = Al, Ga, In; Q = S, Se; X = Cl, Br): an experimental and computational analysis7Syntheses, structures, anomalous phase transition and optical properties of two new polymorphic α- and β-LiMoPO 611Balanced Second-Order Nonlinear Optical Properties of Adducts CHI3·(S8)3 and AsI3·(S8)3: A Systematic Survey48Ionothermal Synthesis of Metal Chalcogenides M2Ag3Sb3S7 (M = Rb, Cs) Displaying Nonlinear Optical Activity in the Infrared Region33First-principles investigation of the ferroelectric, piezoelectric and nonlinear optical properties of LiNbO3-type ZnTiO328Mixed-metal thiophosphate CuCd 3 PS 6 : an infrared nonlinear optical material activated by its three-in-one tetrahedra-stacking architecture33New polymorphism for BaTi(IO 3 ) 6 with two polymorphs crystallizing in the same space group11Bond-length distributions for ions bonded to oxygen: results for the transition metals and quantification of the factors underlying bond-length variation in inorganic solids128Chalcophosphates: A Treasure House of Infrared Nonlinear Optical Materials75Dimensional reduction upon calcium incorporation in Cs 0.3 (Ca 0.3 Ln 0.7 )PS 4 and Cs 0.5 (Ca 0.5 Ln 0.5 )PS 45Revisiting thiophosphate Pb 3 P 2 S 8 : a multifunctional material combining a nonlinear optical response and photocurrent response23Synthesis, crystal structure and physical properties of a new chalcogenides Rb3Ga3Ge7S208BaCdGeSe4: Synthesis, structure and nonlinear optical properties13A review of the structural diversity of [P x S y ] n − motifs and their potential application prospects in metal thiophosphates21Transition-metal-based chalcogenides: A rich source of infrared nonlinear optical materials184SnPQ3 (Q = S, Se, S/Se): A Series of Lone-Pair Cationic Chalcogenophosphates Exhibiting Balanced NLO Activity Originating from SnQ8 Units49Investigation into Structural Variation from 3D to 1D and Strong Second Harmonic Generation of the AHgPS4 (A+ = Na+, K+, Rb+, Cs+) Family26First-principles study of opto-electronic and thermoelectric properties of SrCdSnX4 (X=S, Se, Te) alkali metal chalcogenides35A 2 Zn 3 P 4 S 13 (A = Rb and Cs): First Infrared Nonlinear Optical Materials with Mixed Thiophosphate Functional Motifs PS 4 and P 2 S 621Two Nonlinear Optical Thiophosphates Cu 5 Hg 0.5 P 2 S 8 and AgHg 3 PS 6 Activated by Their Tetrahedra-Stacking Architecture12α- and β-Ag4P2S7: Two Semiconductors with Promising Photocatalytic Hydrogen Production Based on a Density Functional Theory Study6SrAgAsS4: A Noncentrosymmetric Sulfide with Good Infrared Nonlinear Optical Performance Induced by Aliovalent Substitution from Centrosymmetric SrGa2S412Hg2P2S6: A layered mercury hexathiodiphosphate (IV) with large birefringence11Synthesis, Crystal and Electronic Structures, Nonlinear Optical Properties, and Magnetic Properties of Two Thiophosphates: KInP2S7 and KCrP2S79Ag-based chalcogenides and derivatives as promising infrared nonlinear optical materials90DSC of Inorganic Materials3Na 6 Sn 3 P 4 S 16 : Sn( ii )-chelated PS 4 groups inspired an ultra-strong SHG response22Quaternary alkaline-earth metal thiophosphate SrAgPS 4 : syntheses, structures, and optical properties9Revisiting two thiophosphate compounds constituting d 0 transition metal HfP 2 S 6 and d 10 transition metal α-Ag 4 P 2 S 6 as multifunctional materials for combining second harmonic generation response and photocurrent response12HgB2S4: A d10 Metal Thioborate with Giant Birefringence and Wide Band Gap31AEAg7(PS4)3 (AE = Ba, Sr): The homovalent substitution of lead by alkaline earth metals achieves the separation of the two phases and enlarges the band gap1A two-fold interpenetrated mixed-ligands acentric 3D coordination polymer Zn(OBA)(DIB)·0.5H2O: Topological analysis, fluorescent and second-order NLO properties7Greatly enhanced optical anisotropy in thiophosphates inspired by rational coupling of tetrahedra and ethane-like [P 2 S 6 ] 4− groups7Infrared nonlinear optical materials with multiple strongly ionic cations5DFT‐Based Investigation of Electronic, Optical, and Thermoelectric Properties of TaCu 3 X 4 (X = S, Se, Te) Chalcogenides for Optoelectronic and Energy Applications5Phase transition engineering to break the symmetry of diamond-like chalcogenide for second-order nonlinear optics2Two-dimensional Ag2MP2S6 (M=Cd, Zn) chalcogenides: Structural, electro-optical features, and photocatalytic potential6In Situ Generation of Poly(3,4‐ethylenedioxythiophene)/Ag2SeO3 Nanohybrids at Hexane/Water Interface for Photodegradation of Organic Dyes6The physical origin of electric polarizations in two dimensional ferroelectric monolayer materials7Nonbonding Electron Inversion‐Driven Structural Engineering: Synergistic Enhancement of Linear and Nonlinear Optical Properties3Nonbonding Electron Inversion‐Driven Structural Engineering: Synergistic Enhancement of Linear and Nonlinear Optical Properties26Data-Enabled Discovery of Two-Dimensional van der Waals Layered Phosphochalcogenides3

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  1. AgGa2PS6: A New Mid‐Infrared Nonlinear Optical Material with a High Laser Damage Threshold and a Large Second Harmonic Generation Response

    Chemistry - A European Journal · 2017-07-07

    Jiang‐He Feng, Chun‐Li Hu, Xiang Xu, Bingxuan Li, Mingjian Zhang, Jiang‐Gao Mao

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  2. Structural insights into T 2 -cluster-containing chalcogenides with vertex-, edge- and face-sharing connection modes of NaQ 6 ligands: Na 3 ZnM III Q 4 (M III = In, Ga; Q = S, Se)

    Dalton Transactions · 2018-01-01

    Ruijiao Chen, Xiaowen Wu, Zhi Su

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  3. Syntheses, crystal structures and optical properties of two one-dimensional germanophosphates: HRb3Ge2(HPO4)6 and CsGe(HPO4)2(OH)

    Acta Crystallographica Section C Structural Chemistry · 2018-09-26

    Jun‐Ling Song, Wen-Xiu Lu, Tian-Shuo Guo, Yu-Hua Zhou

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  4. ABaSbQ 3 (A = Li, Na; Q = S, Se): diverse arrangement modes of isolated SbQ 3 ligands regulating the magnitudes of birefringences

    Chemical Communications · 2019-01-01

    Ailijiang Abudurusuli, Kui Wu, Abudukadi Tudi, Zhihua Yang, Shilie Pan

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  5. SrCdSnQ 4 (Q = S and Se): infrared nonlinear optical chalcogenides with mixed NLO-active and synergetic distorted motifs

    Journal of Materials Chemistry C · 2019-01-01

    Yang-Jie Lin, Bin‐Wen Liu, Run Ye, Xiao‐Ming Jiang, Long‐Qi Yang, Hui‐Yi Zeng, Guo‐Cong Guo

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  6. Structural modulation induced by M IIIA metals in Ba 3 MQ 4 X (M = Al, Ga, In; Q = S, Se; X = Cl, Br): an experimental and computational analysis

    Dalton Transactions · 2019-01-01

    Abudukadi Tudi, Shujuan Han, Ailijiang Abudurusuli, Haohai Yu, Zhihua Yang, Shilie Pan

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  7. Syntheses, structures, anomalous phase transition and optical properties of two new polymorphic α- and β-LiMoPO 6

    Dalton Transactions · 2019-01-01

    Haonan Liu, Hongping Wu, Hongwei Yu, Zhanggui Hu, Yicheng Wu

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  8. Balanced Second-Order Nonlinear Optical Properties of Adducts CHI3·(S8)3 and AsI3·(S8)3: A Systematic Survey

    Inorganic Chemistry · 2019-03-15

    Zhen‐Tao Lu, Zongdong Sun, Yang Chi, Huaiguo Xue, Sheng‐Ping Guo

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  9. Ionothermal Synthesis of Metal Chalcogenides M2Ag3Sb3S7 (M = Rb, Cs) Displaying Nonlinear Optical Activity in the Infrared Region

    Inorganic Chemistry · 2019-09-25

    Gang Yang, Long-Hua Li, Chao Wu, Mark Graeme Humphrey, Chi Zhang

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  10. First-principles investigation of the ferroelectric, piezoelectric and nonlinear optical properties of LiNbO3-type ZnTiO3

    Scientific Reports · 2019-11-26

    Jing Zhang, Bin Xu, Yusheng Wang, Zhen Qin, San-Huang Ke

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  11. Mixed-metal thiophosphate CuCd 3 PS 6 : an infrared nonlinear optical material activated by its three-in-one tetrahedra-stacking architecture

    Journal of Materials Chemistry C · 2020-01-01

    Zhuang Li, Shengzi Zhang, Wenhao Xing, Yangwu Guo, Chunxiao Li, Zheshuai Lin, Jiyong Yao, Yicheng Wu

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  12. New polymorphism for BaTi(IO 3 ) 6 with two polymorphs crystallizing in the same space group

    Dalton Transactions · 2020-01-01

    Zhen Qian, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  13. Bond-length distributions for ions bonded to oxygen: results for the transition metals and quantification of the factors underlying bond-length variation in inorganic solids

    IUCrJ · 2020-06-09

    Olivier Charles Gagné, Frank Christopher Hawthorne

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  14. Chalcophosphates: A Treasure House of Infrared Nonlinear Optical Materials

    Crystal Growth & Design · 2020-10-23

    Zhuang Li, Jiyong Yao, Yicheng Wu

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  15. Dimensional reduction upon calcium incorporation in Cs 0.3 (Ca 0.3 Ln 0.7 )PS 4 and Cs 0.5 (Ca 0.5 Ln 0.5 )PS 4

    CrystEngComm · 2020-12-09

    Vladislav V. Klepov, Vancho Kocevski, Theodore M. Besmann, Hans‐Conrad zur Loye

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  16. Revisiting thiophosphate Pb 3 P 2 S 8 : a multifunctional material combining a nonlinear optical response and photocurrent response

    Physical Chemistry Chemical Physics · 2021-01-01

    Bingheng Ji, Elizabeth Guderjahn, Kui Wu, Tajamul Hussain Syed, Wei Wei, Bingbing Zhang, Jian Wang

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  17. Synthesis, crystal structure and physical properties of a new chalcogenides Rb3Ga3Ge7S20

    Journal of Solid State Chemistry · 2021-01-07

    Shu‐Fang Li, Dong Yan

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  18. BaCdGeSe4: Synthesis, structure and nonlinear optical properties

    Journal of Solid State Chemistry · 2021-06-26

    Fang-Yu Yuan, Chensheng Lin, Yi‐Zhi Huang, Hao Zhang, Anyi Zhou, Guoliang Chai, Wen‐Dan Cheng

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  19. A review of the structural diversity of [P x S y ] n − motifs and their potential application prospects in metal thiophosphates

    Journal of Physics D Applied Physics · 2021-07-16

    Ya Yang, Miao Song, Xiaowen Wu, Kui Wu

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  20. Transition-metal-based chalcogenides: A rich source of infrared nonlinear optical materials

    Coordination Chemistry Reviews · 2021-08-26

    Hong Chen, Wenbo Wei, Hua Lin, Xintao Wu

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  21. SnPQ3 (Q = S, Se, S/Se): A Series of Lone-Pair Cationic Chalcogenophosphates Exhibiting Balanced NLO Activity Originating from SnQ8 Units

    Inorganic Chemistry · 2021-08-31

    Zhi‐Hui Shi, Mei Yang, Wen‐Dong Yao, Wenlong Liu, Sheng‐Ping Guo

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  22. Investigation into Structural Variation from 3D to 1D and Strong Second Harmonic Generation of the AHgPS4 (A+ = Na+, K+, Rb+, Cs+) Family

    Inorganic Chemistry · 2021-11-12

    Wenhao Xing, Chunlan Tang, Pifu Gong, Jieyun Wu, Zheshuai Lin, Jiyong Yao, Wenlong Yin, Bin Kang

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  23. First-principles study of opto-electronic and thermoelectric properties of SrCdSnX4 (X=S, Se, Te) alkali metal chalcogenides

    Computational Condensed Matter · 2021-12-13

    Muhammad Irfan, Sikander Azam, Alaa Dahshan, Issam El Bakkali, Khalid Nouneh

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  24. A 2 Zn 3 P 4 S 13 (A = Rb and Cs): First Infrared Nonlinear Optical Materials with Mixed Thiophosphate Functional Motifs PS 4 and P 2 S 6

    Journal of Materials Chemistry C · 2022-01-01

    Mingze Li, Lin‐Tao Jiang, Shao‐Min Pei, Bin‐Wen Liu, Xiao‐Ming Jiang, Guo‐Cong Guo

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  25. Two Nonlinear Optical Thiophosphates Cu 5 Hg 0.5 P 2 S 8 and AgHg 3 PS 6 Activated by Their Tetrahedra-Stacking Architecture

    Inorganic Chemistry · 2022-01-11

    Yang Wang, Yuqiang Fang, Yunzhen Cao, Fuqiang Huang

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  26. α- and β-Ag4P2S7: Two Semiconductors with Promising Photocatalytic Hydrogen Production Based on a Density Functional Theory Study

    Inorganic Chemistry · 2022-04-28

    Jianghe Feng, Long Fei Chen, Li-Jia Yao, Chun‐Li Hu, Jiang‐Gao Mao

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  27. SrAgAsS4: A Noncentrosymmetric Sulfide with Good Infrared Nonlinear Optical Performance Induced by Aliovalent Substitution from Centrosymmetric SrGa2S4

    Inorganic Chemistry · 2022-06-07

    Jian Tang, Fei Liang, Chunlan Tang, Wenhao Xing, Jieyun Wu, Wenlong Yin, Bin Kang, Jianguo Deng

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  28. Hg2P2S6: A layered mercury hexathiodiphosphate (IV) with large birefringence

    Journal of Solid State Chemistry · 2022-07-18

    Li-Jia Yao, Chun‐Li Hu, Zhi Gang Fang, Jiang‐Gao Mao

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  29. Synthesis, Crystal and Electronic Structures, Nonlinear Optical Properties, and Magnetic Properties of Two Thiophosphates: KInP2S7 and KCrP2S7

    Crystals · 2022-10-22

    Craig Cropek, Vivian Nguyen, Santosh Karki Chhetri, Jin Hu, Sheng‐Ping Guo, Jian Wang

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  30. Ag-based chalcogenides and derivatives as promising infrared nonlinear optical materials

    Coordination Chemistry Reviews · 2022-11-26

    Wenfeng Zhou, Jiajing Wu, Wenlong Liu, Sheng‐Ping Guo

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  31. DSC of Inorganic Materials

    Elsevier eBooks · 2023-01-01

    Katalin Mészáros Szécsényi, Joseph D. Menczel

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  32. Na 6 Sn 3 P 4 S 16 : Sn( ii )-chelated PS 4 groups inspired an ultra-strong SHG response

    Inorganic Chemistry Frontiers · 2023-01-01

    Chenyao Zhao, Bingbing Zhang, Xinyu Tian, Guoqiang Zhou, Jingjing Xu, Kui Wu

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  33. Quaternary alkaline-earth metal thiophosphate SrAgPS 4 : syntheses, structures, and optical properties

    Dalton Transactions · 2023-01-01

    Wenhao Xing, Jian Tang, Fei Liang, Chunlan Tang, Jieyun Wu, Wenlong Yin, Bin Kang, Jianguo Deng

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  34. Revisiting two thiophosphate compounds constituting d 0 transition metal HfP 2 S 6 and d 10 transition metal α-Ag 4 P 2 S 6 as multifunctional materials for combining second harmonic generation response and photocurrent response

    CrystEngComm · 2023-01-01

    Craig Cropek, Bingheng Ji, Arka Sarkar, Fei Wang, Tajamul Hussain Syed, Wei Wei, Sheng‐Ping Guo, Jian Wang

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  35. HgB2S4: A d10 Metal Thioborate with Giant Birefringence and Wide Band Gap

    Chemistry of Materials · 2023-05-24

    Yi Huang, Yong an Zhang, Dongdong Chu, Zhihua Yang, Guangmao Li, Shilie Pan

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  36. AEAg7(PS4)3 (AE = Ba, Sr): The homovalent substitution of lead by alkaline earth metals achieves the separation of the two phases and enlarges the band gap

    Journal of Solid State Chemistry · 2023-08-25

    Jian Tang, Wenhao Xing, Chunlan Tang, Jieyun Wu, Mingjun Xia, Wenlong Yin, Bin Kang, Jianguo Deng

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  37. A two-fold interpenetrated mixed-ligands acentric 3D coordination polymer Zn(OBA)(DIB)·0.5H2O: Topological analysis, fluorescent and second-order NLO properties

    Journal of Molecular Structure · 2023-09-05

    Jian‐Di Lin, Zhenfei Li, Zu‐Jin Lin, Fa‐Kun Zheng

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  38. Greatly enhanced optical anisotropy in thiophosphates inspired by rational coupling of tetrahedra and ethane-like [P 2 S 6 ] 4− groups

    Inorganic Chemistry Frontiers · 2024-01-01

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  39. Infrared nonlinear optical materials with multiple strongly ionic cations

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  40. DFT‐Based Investigation of Electronic, Optical, and Thermoelectric Properties of TaCu 3 X 4 (X = S, Se, Te) Chalcogenides for Optoelectronic and Energy Applications

    International Journal of Energy Research · 2025-01-01

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  41. Phase transition engineering to break the symmetry of diamond-like chalcogenide for second-order nonlinear optics

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  42. Two-dimensional Ag2MP2S6 (M=Cd, Zn) chalcogenides: Structural, electro-optical features, and photocatalytic potential

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  43. In Situ Generation of Poly(3,4‐ethylenedioxythiophene)/Ag2SeO3 Nanohybrids at Hexane/Water Interface for Photodegradation of Organic Dyes

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  44. The physical origin of electric polarizations in two dimensional ferroelectric monolayer materials

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  45. Nonbonding Electron Inversion‐Driven Structural Engineering: Synergistic Enhancement of Linear and Nonlinear Optical Properties

    Angewandte Chemie · 2025-04-28

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  46. Nonbonding Electron Inversion‐Driven Structural Engineering: Synergistic Enhancement of Linear and Nonlinear Optical Properties

    Angewandte Chemie International Edition · 2025-04-28

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  47. Data-Enabled Discovery of Two-Dimensional van der Waals Layered Phosphochalcogenides

    Chemistry of Materials · 2025-07-07

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