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RESEARCH PAPER · Crystal Growth & Design · 2015

New Developments in the Synthesis, Structure, and Applications of Borophosphates and Metalloborophosphates

Min Li, Anja Verena‐Mudring

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New Developments in the Synthesis, Structure, and Applications of Borophosphates and MetalloborophosphatesOriginalChemInform Abstract: New Developments in the Synthesis, Structure, and Applications of Borophosphates and Metalloborophosphates0Crystal structure and spin-trimer magnetism of Rb 2.3 (H 2 O) 0.8 Mn 3 [B 4 P 6 O 24 (O,OH) 2 ]6Enhancing optical anisotropy of crystals by optimizing bonding electron distribution in anionic groups237Low-temperature-flux syntheses of ultraviolet-transparent borophosphates Na 4 MB 2 P 3 O 13 (M = Rb, Cs) exhibiting a second-harmonic generation response23Electronic, bond order, linear optical properties of series of alkalimetal P-O-P linkage borophosphates11Porous Uranyl Borophosphates with Unique Three-Dimensional Open-Framework Structures36Effects of Ce+Gd on the structural features and thermal stability of iron-boron-phosphate glasses5Centrosymmetric (Hdima)2[Ge5B3O15(OH)] and Noncentrosymmetric Na4Ga3B4O12(OH): Solvothermal/Surfactant-Thermal Synthesis of Open-Framework Borogermanate and Galloborate34Divergent Structural Chemistry of Uranyl Borates Obtained from Solid State and Hydrothermal Conditions19Synthesis and Study of the First Zeolitic Uranium Borate22Photoluminescence investigation of novel reddish-orange phosphor Li2NaBP2O8:Sm3+ with high CP and low CCT100Amorphous N-Doped Cobalt Borophosphate Nanoparticles as Robust and Durable Electrocatalyst for Water Oxidation25Ionothermal Synthesis, Structures, and Magnetism of Three New Open Framework Iron Halide-Phosphates14(K,Na)2[AsB6O12]2[B3O3(OH)3], a New Microporous Material, and Its Comparison to Teruggite0Solution combustion synthesis of new metal borophosphates (Fe1-Cr )2B(PO4)3: Structural, thermal, surface, and magnetic properties6Liquid phase oxidation of benzyl alcohol to benzaldehyde over chromium borophosphate catalyst synthesized by solution combustion method using different types of fuel5Influence of Iron Doped on Structural and Optical Absorption Studies of Calcium Borophosphate (CaBP) Nanophosphors5TOPOLOGICAL FEATURES OF BOROPHOSPHATES WITH MIXED FRAMEWORKS: SYNTHESIS, CRYSTAL STRUCTURE OF FIRST ALUMINUM AND LITHIUM BOROPHOSPHATE Li3{Al2[BP4O16]}·2H2O AND COMPARATIVE CRYSTAL CHEMISTRY14Sr[B2(SO4)3(S2O7)]: A Borosulfate with an Unprecedented Chain Structure Comprising Disulfate Groups18M3B6O10NO3 (M = K, Rb): Two New Alkali Metal Borate‐Nitrates with Noncentrosymmetric Structures20Near-UV-excited photoluminescence of terbium (Ⅲ)-activated lithium sodium borophosphate phosphor18Pink-emitting RbBaBP2O8:Sm phosphor with diamondoid structure and high thermostability47Ultraviolet A-induced down conversion photoluminescence of lanthanum borophosphate doped with erbium (Ⅲ) for solid state lighting5Polytypism of Compounds with the General Formula Cs{Al2[TP6O20]} (T = B, Al): OD (Order-Disorder) Description, Topological Features, and DFT-Calculations9Modularity and Twinning in Mineral Crystal Structures0NUV-pumped luminescence of thermally stable samarium-activated alkali metal borophosphate phosphor44Thermally stable orange-red luminescence of samarium (Ⅲ)-activated KSrBP2O8 borophosphate13Efficient degradation of reactive brilliant red on the first open-framework borate-rich cadmium borophosphate8Polymorphism and topological features of compounds with the general formula A1−x+Bx2+ { Mx2+M1−x3+ [BP2O8(OH)]} (where x = 0, 1): Synthesis and structure refinement of Rb{V[BP2O8(OH)]}, analysis of the ion-migration paths, and comparative crystal chemistry of vanadium borophosphates6Ionic liquids and deep eutectics as a transformative platform for the synthesis of nanomaterials106Two lead borate-nitrates with anion-centered [OPb 4 ] tetrahedra and two types of π-conjugated planar units showing large birefringence20A new salt-inclusion compound, |Ag4Br|@[B7O12], with a novel type of the porous double-layered borate anion and strong anharmonicity of the “guest” sublattice11Vanadate Encapsulated Polyoxoborate Framework with [V12B18] Clusters: An Efficient Bifunctional Electrocatalyst for Oxygen and Hydrogen Evolution Reactions28Targeting Diverse Bridging Motifs within Actinide Borosulfates and Establishing an Unconventional Structural Hierarchy1RbBaBP2O8:Gd3+ phosphor with narrowband ultraviolet B-emitting and excellent heat-resistant performance2The missing link between zeolites and polyoxometalates4Borate-Based Compounds as Mixed Polyanion Cathode Materials for Advanced Batteries22The crystal chemistry of plutonium( iv ) borophosphate1Structure and Characterization of K2Na3B2P3O13, a New Nonlinear Optical Borophosphate with One-Dimensional Chain Structure and Short Ultraviolet Cutoff Edge13Modularity, polytypism, topology, and complexity of crystal structures of inorganic compounds (Review)32Synthesis, bright red-emitting and low thermal quenching behavior of europium(Ⅲ)-activated sodium borophosphate phosphor2Na3[Al2B6P4O22(OH)3](H2O)6 and Na3[Al2BP2O11](H2O)0.5: Two Remarkable Complex Aluminum Borophosphates8Electrochemical Na+/K+ Ion Exchange in Zeolitic Vanadium(IV) Borophosphate K1.33Na0.67[VO(B2O)(PO4)2(HPO4)]·1.63H2O as Cathode Material for Sodium-Ion Batteries8Synthesis of ordered mesoporous crystalline boron phosphate scaffold with double diamond surface structure4Die ersten Antimon‐Borosulfate offenbaren das Baukastensystem M III M I [B(SO 4 ) 2 ] 4 (M III =Bi 3+ , Sb 3+ , Lu 3+ ; M I =H 3 O + , NO 2 + , Li + , Na + , K + , Rb + , Cs + )0The First Antimony Borosulfates Unveil a Modular System M III M I [B(SO 4 ) 2 ] 4 (M III =Bi 3+ , Sb 3+ , Lu 3+ ; M I =H 3 O + , NO 2 + , Li + , Na + , K + , Rb + , Cs + )7Structural and Vibrational Properties of Calcium, Strontium, Barium, and Lead Borophosphates from First Principles2DFT investigation of elastic anisotropy and piezoelectric response of trigonal borophosphates ABPO5 (A=Ca, Sr, Pb, Ba) under hydrostatic pressure1Syntheses, structural characterization, and nonlinear optical properties of mixed alkaline/alkaline earth metal borophosphates1First-principles study of structural, electronic and nonlinear optical properties under pressure for trigonal borophosphatesABPO5 (A=Ca, Sr, Pb, Ba)1Enhanced Ion-Exchange Properties of a Complex Microporous Uranyl Borophosphate0Mössbauer Spectroscopy on Antimony Borosulfates Reveals Weak Coordination Behavior1Mößbauer‐Spektroskopie an Antimon‐Borosulfaten belegt deren schwache Koordinationskraft1The adsorption features, surface polarity and enantioselectivity of the chiral zeolite-like material cobalt borophosphate0(NH 4 )[B 4 O 5 (PO 4 )] – A Boron Rich Three-Dimensional Borophosphate1Organic–inorganic hybrid graphite/h-BN composite coating enables effective lubrication and microstructure uniformity during pure titanium hot extrusion under elevated temperatures0Borophosphate-based second-order nonlinear optical materials: Advances in structural diversity and optical performance0

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  1. ChemInform Abstract: New Developments in the Synthesis, Structure, and Applications of Borophosphates and Metalloborophosphates

    ChemInform · 2016-04-01

    Min Li, Anja Verena‐Mudring

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  2. Crystal structure and spin-trimer magnetism of Rb 2.3 (H 2 O) 0.8 Mn 3 [B 4 P 6 O 24 (O,OH) 2 ]

    Dalton Transactions · 2017-01-01

    Olga V. Yakubovich, Larisa Victorovna Shvanskaya, Galina V. Kiriukhina, Anatoly S. Volkov, Olga V. Dimitrova, E. A. Ovchenkov, Alexander A. Tsirlin, A. Shakin, О. С. Волкова, Alexander N. Vasiliev

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  3. Enhancing optical anisotropy of crystals by optimizing bonding electron distribution in anionic groups

    Chemical Communications · 2017-01-01

    Bing‐Hua Lei, Zhihua Yang, Shilie Pan

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  4. Low-temperature-flux syntheses of ultraviolet-transparent borophosphates Na 4 MB 2 P 3 O 13 (M = Rb, Cs) exhibiting a second-harmonic generation response

    Dalton Transactions · 2017-01-01

    Chao Wu, Longhua Li, Gang Yang, Jun‐Ling Song, Bing Yan, Mark Graeme Humphrey, Long Zhang, Jianda Shao, Chi Zhang

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  5. Electronic, bond order, linear optical properties of series of alkalimetal P-O-P linkage borophosphates

    Journal of Alloys and Compounds · 2017-02-25

    Dianwei Hou, Zhihua Yang, Shilie Pan

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  6. Porous Uranyl Borophosphates with Unique Three-Dimensional Open-Framework Structures

    Inorganic Chemistry · 2017-07-18

    Yucheng Hao, Gabriel L. Murphy, Dirk Bosbach, Giuseppe Modolo, Thomas E. Albrecht‐Schmitt, Evgeny V. Alekseev

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  7. Effects of Ce+Gd on the structural features and thermal stability of iron-boron-phosphate glasses

    Materials Chemistry and Physics · 2017-08-23

    Fu Wang, Zhiwei Fang, Hong Wang, Qilong Liao, Hanzhen Zhu

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  8. Centrosymmetric (Hdima)2[Ge5B3O15(OH)] and Noncentrosymmetric Na4Ga3B4O12(OH): Solvothermal/Surfactant-Thermal Synthesis of Open-Framework Borogermanate and Galloborate

    Inorganic Chemistry · 2017-10-18

    Sujuan Yu, Xiang-Yu Gu, Tingting Deng, Jianhao Huang, Jian‐Wen Cheng, Guo‐Yu Yang

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  9. Divergent Structural Chemistry of Uranyl Borates Obtained from Solid State and Hydrothermal Conditions

    Crystal Growth & Design · 2017-10-20

    Yucheng Hao, Philip Kegler, Dirk Bosbach, Thomas E. Albrecht‐Schmitt, Shuao Wang, Evgeny V. Alekseev

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  10. Synthesis and Study of the First Zeolitic Uranium Borate

    Crystal Growth & Design · 2017-11-28

    Yucheng Hao, Vladislav V. Klepov, Philip Kegler, Giuseppe Modolo, Dirk Bosbach, Thomas E. Albrecht‐Schmitt, Shuao Wang, Evgeny V. Alekseev

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  11. Photoluminescence investigation of novel reddish-orange phosphor Li2NaBP2O8:Sm3+ with high CP and low CCT

    Ceramics International · 2018-12-28

    Jiyun Xiang, Meihua Yang, Yi Che, Jing Zhu, Yong Mao, Kai Xiong, Heyun Zhao

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  12. Amorphous N-Doped Cobalt Borophosphate Nanoparticles as Robust and Durable Electrocatalyst for Water Oxidation

    ACS Sustainable Chemistry & Engineering · 2019-07-22

    Bin Wang, Wen-Xiu Lu, Zhao‐Qian Huang, Weijun Chen, Jie‐Ling Xie, Dong‐Sheng Pan, Lingli Zhou, Jun‐Ling Song

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  13. Ionothermal Synthesis, Structures, and Magnetism of Three New Open Framework Iron Halide-Phosphates

    Inorganic Chemistry · 2019-09-20

    Guangmei Wang, Martin Valldor, Stefanie Siebeneichler, Magdalena Wilk-Kozubek, Volodymyr Smetana, Anja‐Verena Mudring

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  14. (K,Na)2[AsB6O12]2[B3O3(OH)3], a New Microporous Material, and Its Comparison to Teruggite

    Minerals · 2019-12-13

    Yulia A. Pankova, Sergey V. Krivovichev

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  15. Solution combustion synthesis of new metal borophosphates (Fe1-Cr )2B(PO4)3: Structural, thermal, surface, and magnetic properties

    Ceramics International · 2020-01-30

    Demet Özer, Telem Şimşek, Şadan Özcan, Nurşen Altuntaş Öztaş

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  16. Liquid phase oxidation of benzyl alcohol to benzaldehyde over chromium borophosphate catalyst synthesized by solution combustion method using different types of fuel

    Research on Chemical Intermediates · 2020-04-22

    Demet Özer

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  17. Influence of Iron Doped on Structural and Optical Absorption Studies of Calcium Borophosphate (CaBP) Nanophosphors

    Macromolecular Symposia · 2020-10-01

    Rajesh Yadav Mudi, P. Radha K. Pambi, Venkata L. K. Ganti, R.V.S.S.N. Ravikumar

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  18. TOPOLOGICAL FEATURES OF BOROPHOSPHATES WITH MIXED FRAMEWORKS: SYNTHESIS, CRYSTAL STRUCTURE OF FIRST ALUMINUM AND LITHIUM BOROPHOSPHATE Li3{Al2[BP4O16]}·2H2O AND COMPARATIVE CRYSTAL CHEMISTRY

    Journal of Structural Chemistry · 2020-11-01

    Sergey M. Aksenov, N. A. Yamnova, E. Yu. Borovikova, Sergey Yu. Stefanovich, Anatoly S. Volkov, Д. В. Дейнеко, Olga V. Dimitrova, О.А. Гурбанова, Amy E. Hixon, Sergey V. Krivovichev

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  19. Sr[B2(SO4)3(S2O7)]: A Borosulfate with an Unprecedented Chain Structure Comprising Disulfate Groups

    Inorganic Chemistry · 2020-11-26

    Philip Netzsch, Henning A. Höppe

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  20. M3B6O10NO3 (M = K, Rb): Two New Alkali Metal Borate‐Nitrates with Noncentrosymmetric Structures

    European Journal of Inorganic Chemistry · 2021-02-13

    Qiqi Zhang, Fangfang Zhang, Fuming Li, Shujuan Han, Zhihua Yang, Shilie Pan

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  21. Near-UV-excited photoluminescence of terbium (Ⅲ)-activated lithium sodium borophosphate phosphor

    Optik · 2021-04-21

    Jing Zhu, Jiyun Xiang, Yong Mao

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  22. Pink-emitting RbBaBP2O8:Sm phosphor with diamondoid structure and high thermostability

    Ceramics International · 2021-04-22

    Dan Yang, Zhenyu Fang, Youkui Zheng, Yuefei Xiang, Ruitong Song, Tongsheng Yang, Jialiang Song, Jing Zhu

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  23. Ultraviolet A-induced down conversion photoluminescence of lanthanum borophosphate doped with erbium (Ⅲ) for solid state lighting

    Journal of Solid State Chemistry · 2021-06-04

    Youkui Zheng, Zhigang Cai, Zhuohui Zhang, Dan Yang, Zhenyu Fang, Jing Zhu

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  24. Polytypism of Compounds with the General Formula Cs{Al2[TP6O20]} (T = B, Al): OD (Order-Disorder) Description, Topological Features, and DFT-Calculations

    Minerals · 2021-06-30

    Sergey M. Aksenov, Alexey N. Kuznetsov∥, Andrey A. Antonov, N. A. Yamnova, Sergey V. Krivovichev, Stefanο Merlino

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  25. Modularity and Twinning in Mineral Crystal Structures

    MDPI eBooks · 2021-09-13

    Giovanni Ferraris

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  26. NUV-pumped luminescence of thermally stable samarium-activated alkali metal borophosphate phosphor

    Journal of Advanced Ceramics · 2021-09-15

    Zhenyu Fang, Dan Yang, Youkui Zheng, Jialiang Song, Tongsheng Yang, Ruitong Song, Yuefei Xiang, Jing Zhu

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  27. Thermally stable orange-red luminescence of samarium (Ⅲ)-activated KSrBP2O8 borophosphate

    Journal of Physics and Chemistry of Solids · 2021-09-27

    Dan Yang, Mingyang Li, Youkui Zheng, Zhenyu Fang, Jialiang Song, Tongsheng Yang, Yuefei Xiang, Ruitong Song, Jing Zhu

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  28. Efficient degradation of reactive brilliant red on the first open-framework borate-rich cadmium borophosphate

    CrystEngComm · 2021-12-13

    Yuquan Feng, LV Lin-xia, Dongqin Bi, Zhiguo Zhong, Jing Li, Zi-Long Yue, Zhaoge Zeng, Shuhan Zhang, Zhaohui Meng

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  29. Polymorphism and topological features of compounds with the general formula A1−x+Bx2+ { Mx2+M1−x3+ [BP2O8(OH)]} (where x = 0, 1): Synthesis and structure refinement of Rb{V[BP2O8(OH)]}, analysis of the ion-migration paths, and comparative crystal chemistry of vanadium borophosphates

    Journal of Solid State Chemistry · 2021-12-29

    Sergey M. Aksenov, Julia S. Mironova, N. A. Yamnova, Anatoly S. Volkov, Olga V. Dimitrova, О.А. Гурбанова, Dina V. Deyneko, Vladislav A. Blatov, Sergey V. Krivovichev

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  30. Ionic liquids and deep eutectics as a transformative platform for the synthesis of nanomaterials

    Chemical Communications · 2022-01-01

    Oliver S. Hammond, Anja‐Verena Mudring

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  31. Two lead borate-nitrates with anion-centered [OPb 4 ] tetrahedra and two types of π-conjugated planar units showing large birefringence

    Dalton Transactions · 2022-01-01

    Shuo Bai, Daqing Yang, Bingbing Zhang, Ling Li, Ying Wang

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  32. A new salt-inclusion compound, |Ag4Br|@[B7O12], with a novel type of the porous double-layered borate anion and strong anharmonicity of the “guest” sublattice

    Solid State Sciences · 2022-01-31

    Sergey N. Volkov, Dmitri O. Charkin, Lev S. Manelis, M. Yu. Arsent’ev, Valentina A. Yukhno, Alexey V. Povolotskiy, В. Л. Уголков, Maria Georgievna Krzhizhanovskaya, Vera A. Firsova, Sergey M. Aksenov, Р. С. Бубнова

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  33. Vanadate Encapsulated Polyoxoborate Framework with [V12B18] Clusters: An Efficient Bifunctional Electrocatalyst for Oxygen and Hydrogen Evolution Reactions

    Crystal Growth & Design · 2022-07-11

    Tanmay Rom, Rathindranath Biswas, Krishna Kanta Haldar, Uttam Kumar Saha, Sudhindra Rayaprol, Avijit Kumar Paul

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  34. Targeting Diverse Bridging Motifs within Actinide Borosulfates and Establishing an Unconventional Structural Hierarchy

    Inorganic Chemistry · 2022-09-01

    Teagan F. M. Sweet, Daniel E. Felton, Jennifer E. S. Szymanowski, Peter Carman Burns

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  35. RbBaBP2O8:Gd3+ phosphor with narrowband ultraviolet B-emitting and excellent heat-resistant performance

    Materials Today Communications · 2022-10-28

    Dan Yang, Youkui Zheng, Zhenyu Fang, Jing Zhu

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  36. The missing link between zeolites and polyoxometalates

    Science Advances · 2022-11-16

    Guangmei Wang, Katharina V. Dorn, Stefanie Siebeneichler, Martin Valldor, Volodymyr Smetana, Anja‐Verena Mudring

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  37. Borate-Based Compounds as Mixed Polyanion Cathode Materials for Advanced Batteries

    Molecules · 2022-11-19

    Giancarlo Dominador D. Sanglay, Jayson S. Garcia, Mecaelah S. Palaganas, Maurice Sorolla, Sean Benson A. See, Lawrence A. Limjuco, Joey Duran Ocon

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  38. The crystal chemistry of plutonium( iv ) borophosphate

    Dalton Transactions · 2023-01-01

    Ginger E. Sigmon, Nicole A. DiBlasi, Amy E. Hixon

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  39. Structure and Characterization of K2Na3B2P3O13, a New Nonlinear Optical Borophosphate with One-Dimensional Chain Structure and Short Ultraviolet Cutoff Edge

    Inorganic Chemistry · 2023-01-25

    Wenhao Liu, Ming‐Hsien Lee, Ruixin Guo, Jiyong Yao

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  40. Modularity, polytypism, topology, and complexity of crystal structures of inorganic compounds (Review)

    Journal of Structural Chemistry · 2023-10-01

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  41. Synthesis, bright red-emitting and low thermal quenching behavior of europium(Ⅲ)-activated sodium borophosphate phosphor

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  42. Na3[Al2B6P4O22(OH)3](H2O)6 and Na3[Al2BP2O11](H2O)0.5: Two Remarkable Complex Aluminum Borophosphates

    Inorganic Chemistry · 2024-05-08

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  43. Electrochemical Na+/K+ Ion Exchange in Zeolitic Vanadium(IV) Borophosphate K1.33Na0.67[VO(B2O)(PO4)2(HPO4)]·1.63H2O as Cathode Material for Sodium-Ion Batteries

    Inorganic Chemistry · 2024-08-06

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  44. Synthesis of ordered mesoporous crystalline boron phosphate scaffold with double diamond surface structure

    Science China Chemistry · 2024-09-03

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  45. Die ersten Antimon‐Borosulfate offenbaren das Baukastensystem M III M I [B(SO 4 ) 2 ] 4 (M III =Bi 3+ , Sb 3+ , Lu 3+ ; M I =H 3 O + , NO 2 + , Li + , Na + , K + , Rb + , Cs + )

    Angewandte Chemie · 2025-02-12

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  46. The First Antimony Borosulfates Unveil a Modular System M III M I [B(SO 4 ) 2 ] 4 (M III =Bi 3+ , Sb 3+ , Lu 3+ ; M I =H 3 O + , NO 2 + , Li + , Na + , K + , Rb + , Cs + )

    Angewandte Chemie International Edition · 2025-02-12

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  47. Structural and Vibrational Properties of Calcium, Strontium, Barium, and Lead Borophosphates from First Principles

    Journal of Structural Chemistry · 2025-06-01

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  48. DFT investigation of elastic anisotropy and piezoelectric response of trigonal borophosphates ABPO5 (A=Ca, Sr, Pb, Ba) under hydrostatic pressure

    Journal of Physics and Chemistry of Solids · 2025-07-29

    Yu. N. Zhuravlev, Ziad Y. Khattari

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  49. Syntheses, structural characterization, and nonlinear optical properties of mixed alkaline/alkaline earth metal borophosphates

    Journal of Solid State Chemistry · 2025-08-19

    Yang Pan, Jian Qiu Deng, Yucheng Hao, Xi Zhao, Yuanyuan Bao, Zixuan Fang, Chonghai Deng, Kunhong Hu, Wei Cheng, Yuan Hua Lin

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  50. First-principles study of structural, electronic and nonlinear optical properties under pressure for trigonal borophosphatesABPO5 (A=Ca, Sr, Pb, Ba)

    Physica B Condensed Matter · 2025-08-27

    Yu. N. Zhuravlev, Ziad Y. Khattari

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