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RESEARCH PAPER · Inorganic Chemistry Frontiers · 2023

A hybrid halide lead-free pseudo-perovskite with large birefringence

Weiqi Huang, Xiaolong Wu, Belal Ahmed, Yanqiang Li, Zhou Yang, Han Wang, Yipeng Song, Xiaojun Kuang, Junhua Luo, Sangen Zhao

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A hybrid halide lead-free pseudo-perovskite with large birefringenceOriginalC 3 N 6 H 7 SO 3 NH 2 : non-π-conjugated tetrahedra decoupling π-conjugated groups achieving large optical anisotropy and wide band gap29A Two‐Dimensional Hybrid Perovskite With Heat Switching Birefringence47A Two‐Dimensional Hybrid Perovskite With Heat Switching Birefringence7Designing a Hybrid Perovskite with Enlarged Birefringence and Bandgap for Modulation of Light Polarization32(C 3 N 6 H 7 )BF 4 ·H 2 O and (C 3 N 6 H 7 )SO 3 CH 3 ·H 2 O with large birefringence induced by coplanar π-conjugated [C 3 N 6 H 7 ] + groups33Broadband blue light emissions of one-dimensional hybrid Cu( i ) halides with ultrahigh anti -water stability12Research progress in optical materials with cationic organic planar π-conjugated groups containing CN bonds34Exceptional Optical Anisotropy Enhancement Achieved Through Dual‐Ions Cosubstitution Strategy in Novel Hybrid Bismuth Halides23Etude de stabilité des pérovskites aux halogénures mixtes plombate de Formamidinium FAPbX3 avec X={ Cl,Br,I}.01D Tin(II)‐Based Chiral Hybrid Perovskite Single Crystals with Extremely Distorted Inorganic Chains for Second Harmonic Generation38Na3K6(CO3)3(NO3)2X·6H2O (X = NO3, Cl, Br): Exploring High-Performance UV Birefringent Crystals Induced by Coplanar π-Conjugated CO3 and NO3 Groups15(C 8 H 7 N 2 O 2 ) 2 [Bi 2 Br 8 ]·2H 2 O and (C 8 H 7 N 2 O 2 ) 6 [Bi 2 Cl 10 ]Cl 2 ·2H 2 O: Exploring Birefringent Crystals in Hybrid Halide Systems5C9H7NBrX (X = Cl, Br, NO3): Three Excellent Birefringent Crystals with Distinct Optical Anisotropy Regulated by Anions34Zn(C6H4NO2)2·4H2O: A Solar-Blind Birefringent Crystal5A Highly Optical Anisotropic Hybrid Metal Halide for Modulation and Generation of Polarized Light44[C3H7N6]3[B3O5(OH)2] and [C3H8N6]4[B12O19(OH)6]: Two Melamine Borates with Large Birefringence13Strategically designed anisotropic organic–inorganic metal halides (OIMHs) with superior balance between bandgap and birefringence12(C 6 H 5 N 2 )HgCl 3 : Discovery of a Polar Hg‐Based Hybrid Halide as Preeminent Nonlinear Optical and Birefringent Material Activated by π‐Conjugated Organic Cation Substitution38(C 5 N 2 H 7 )IO 2 F 2 and (C 3 N 6 H 8 )(IO 2 F 2 ) 2 : two new organic–inorganic hybrid fluoroiodate birefringent crystals7Stable zero-dimensional hybrid indium-based halides with yellow to orange light emission4All-three-in-one: Pb2(H2PO4)2(C2O4) significantly enhanced birefringence in phosphate materials4A novel metal-free crystal demonstrating superior birefringence attributed to the synergistic interaction of dual π-conjugated units8Four Benzoguanamine-Based Birefringent Crystals with Excellent Optical Anisotropy5Exceptional Enhancement of Optical Anisotropy Achieved via the Strategy of Combining Rigid Groups with High Symmetry and π‐Conjugated Organic Groups in Hybrid Fluorides33Effect of Multiple Hydrogen Bonding on the π-Conjugated Groups and Optical Properties in Molecular Crystals5The condensation of π-conjugated units: a new paradigm for designing high-performance optical crystals4Truss bridge-like anhydrous stacking in hybrid crystals triggers ultra-high stability and robust birefringence0Protonation‐Triggered Structural Transformations in 4‐Hydroxypyridinium Halides for Solar‐Blind UV Functional Crystals3Protonation‐Triggered Structural Transformations in 4‐Hydroxypyridinium Halides for Solar‐Blind UV Functional Crystals8A 3.6–3.9 μm Mid-IR OPO with low pulse-to-pulse fluctuation pumped by a 1064 nm pulsed laser based on pre-biased transverse voltage-boosted EO Q-switching and BC filtering0Rare 3 × 3 Layering in High‐Pressure Pseudo‐Perovskite Sr 4 Te 4 O 150V-Shaped Pseudo-Chains Coupled with Lone-Pair-Distorted [GeX 3 ] − Units Enable Large Birefringence in Ge(II) Hybrid Halides2Noncovalent Assembly Engineering Achieves Excellent Birefringence in Crystals0Zero-dimensional hybrid indium halides with broadband orange emission for white light emitting diodes0Lateral‐Site Unblocking Enables Bilateral π ‐Chromophore Organization for Giant Birefringence in One‐Dimensional Lead Hybrids0Lateral‐Site Unblocking Enables Bilateral π ‐Chromophore Organization for Giant Birefringence in One‐Dimensional Lead Hybrids0Low-Dimensional Perovskites and Metal Halides across Structures and Functions: Connectivity, Dimensionality, and Emerging Principles1

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  1. C 3 N 6 H 7 SO 3 NH 2 : non-π-conjugated tetrahedra decoupling π-conjugated groups achieving large optical anisotropy and wide band gap

    Materials Chemistry Frontiers · 2023-01-01

    Danyang Dou, Qi Shi, Yunjie Bai, Cheng Chen, Bingbing Zhang, Ying Wang

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  2. A Two‐Dimensional Hybrid Perovskite With Heat Switching Birefringence

    Angewandte Chemie International Edition · 2023-09-28

    Ziyi Wang, Chen Xu, Yipeng Song, Zhipeng Du, Zhou Yang, Minjuan Li, Weiqi Huang, Qian-Ting Xu, Yanqiang Li, Sangen Zhao, Junhua Luo

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  3. A Two‐Dimensional Hybrid Perovskite With Heat Switching Birefringence

    Angewandte Chemie · 2023-09-28

    Ziyi Wang, Chen Xu, Yipeng Song, Zhipeng Du, Zhou Yang, Minjuan Li, Weiqi Huang, Qian-Ting Xu, Yanqiang Li, Sangen Zhao, Junhua Luo

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  4. Designing a Hybrid Perovskite with Enlarged Birefringence and Bandgap for Modulation of Light Polarization

    Small · 2023-10-20

    Weiqi Huang, Xianyu Song, Yanqiang Li, Zhou Yang, Qian-Ting Xu, Yipeng Song, Han Wang, Minjuan Li, Sangen Zhao, Junhua Luo

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  5. (C 3 N 6 H 7 )BF 4 ·H 2 O and (C 3 N 6 H 7 )SO 3 CH 3 ·H 2 O with large birefringence induced by coplanar π-conjugated [C 3 N 6 H 7 ] + groups

    Inorganic Chemistry Frontiers · 2024-01-01

    Hangwei Jia, Die Xu, Zi‐Jian Li, Muhammad Sharjeel Arif, Yansheng Jiang, Xueling Hou

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  6. Broadband blue light emissions of one-dimensional hybrid Cu( i ) halides with ultrahigh anti -water stability

    Dalton Transactions · 2024-01-01

    Na Lin, Yunxia Li, Yu Liu, Kai-Qi Sun, Hong-Yan Zhang, Xiao‐Wu Lei, Zhiwei Chen

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  7. Research progress in optical materials with cationic organic planar π-conjugated groups containing CN bonds

    Inorganic Chemistry Frontiers · 2024-01-01

    Hangwei Jia, Xueling Hou, Shilie Pan

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  8. Exceptional Optical Anisotropy Enhancement Achieved Through Dual‐Ions Cosubstitution Strategy in Novel Hybrid Bismuth Halides

    Small · 2024-01-17

    Zhiyong Bai, Kang Min Ok

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  9. Etude de stabilité des pérovskites aux halogénures mixtes plombate de Formamidinium FAPbX3 avec X={ Cl,Br,I}.

    Unknown journal · 2024-02-12

    Touré Abdoulaye

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  10. 1D Tin(II)‐Based Chiral Hybrid Perovskite Single Crystals with Extremely Distorted Inorganic Chains for Second Harmonic Generation

    Advanced Optical Materials · 2024-02-17

    Kezheng Tao, Qiang Li, Qingfeng Yan

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  11. Na3K6(CO3)3(NO3)2X·6H2O (X = NO3, Cl, Br): Exploring High-Performance UV Birefringent Crystals Induced by Coplanar π-Conjugated CO3 and NO3 Groups

    Inorganic Chemistry · 2024-04-23

    Wencong Li, Junbo Wang, Lili Liu, Chunmei Huang, Yanyan Ding, Mengmeng Zhu, Jindan Tian, Hai-Xin Qi, Yaoqing Chu, Jiayue Xu

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  12. (C 8 H 7 N 2 O 2 ) 2 [Bi 2 Br 8 ]·2H 2 O and (C 8 H 7 N 2 O 2 ) 6 [Bi 2 Cl 10 ]Cl 2 ·2H 2 O: Exploring Birefringent Crystals in Hybrid Halide Systems

    Inorganic Chemistry · 2024-05-10

    Mingliang Ding, Qiong Sen Wu, Yaoguo Shen, Jinquan Hong, Guofa Dong, Liang Ma

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  13. C9H7NBrX (X = Cl, Br, NO3): Three Excellent Birefringent Crystals with Distinct Optical Anisotropy Regulated by Anions

    Small · 2024-05-10

    Yaoguo Shen, Mingliang Ding, Gang Chen, Yingjie Luo, Sangen Zhao, Junhua Luo

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  14. Zn(C6H4NO2)2·4H2O: A Solar-Blind Birefringent Crystal

    Crystal Growth & Design · 2024-05-14

    Yaoguo Shen, Yu Wang, Zixiang Chen, Wencheng Lu

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  15. A Highly Optical Anisotropic Hybrid Metal Halide for Modulation and Generation of Polarized Light

    Advanced Functional Materials · 2024-10-10

    Qian-Ting Xu, Ziyi Wang, Zhou Yang, Weiqi Huang, Yipeng Song, Jieyu Zheng, Yanqiang Li, Linxi Hou, Junhua Luo, Sangen Zhao

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  16. [C3H7N6]3[B3O5(OH)2] and [C3H8N6]4[B12O19(OH)6]: Two Melamine Borates with Large Birefringence

    Inorganic Chemistry · 2024-11-18

    Ya-Lan Deng, Chun‐Li Hu, Jiang‐Gao Mao

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  17. Strategically designed anisotropic organic–inorganic metal halides (OIMHs) with superior balance between bandgap and birefringence

    Inorganic Chemistry Frontiers · 2024-12-16

    Mingchang Wang, Huaiyu Wu, Miao‐Bin Xu, Jiajia Li, Ke‐Zhao Du, Jin Chen

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  18. (C 6 H 5 N 2 )HgCl 3 : Discovery of a Polar Hg‐Based Hybrid Halide as Preeminent Nonlinear Optical and Birefringent Material Activated by π‐Conjugated Organic Cation Substitution

    Advanced Optical Materials · 2024-12-30

    Ru‐Ling Tang, Die‐Xue Yang, Liang Ma, Yi‐Lei Lv, Wenlong Liu, Sheng‐Ping Guo

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  19. (C 5 N 2 H 7 )IO 2 F 2 and (C 3 N 6 H 8 )(IO 2 F 2 ) 2 : two new organic–inorganic hybrid fluoroiodate birefringent crystals

    Dalton Transactions · 2025-01-01

    Si Yuan, Chun‐Li Hu, Jiang‐Gao Mao

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  20. Stable zero-dimensional hybrid indium-based halides with yellow to orange light emission

    Dalton Transactions · 2025-01-01

    Hong-Zhao Zan, Xiaozhong Wang, Haixin Zhao, S. G. Wang, Lei Chen, Hao‐Yuan Wang, Lai-Zhi Zhao, Xiao-De Zhang, Xiangwen Kong

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  21. All-three-in-one: Pb2(H2PO4)2(C2O4) significantly enhanced birefringence in phosphate materials

    Science China Chemistry · 2025-05-28

    Qingpeng Shao, Qingran Ding, Yanqiu Zhang, Weiqi Huang, Zihao Yu, Yipeng Song, Chengmin Ji, Ziyi Wang, Sangen Zhao, Junhua Luo

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  22. A novel metal-free crystal demonstrating superior birefringence attributed to the synergistic interaction of dual π-conjugated units

    Science China Materials · 2025-07-07

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  23. Four Benzoguanamine-Based Birefringent Crystals with Excellent Optical Anisotropy

    Inorganic Chemistry · 2025-07-19

    Yaoguo Shen, Lingxin Yan, Xin‐Yi Wang, Zhifeng Tang, Liang Ma, Guofa Dong

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  24. Exceptional Enhancement of Optical Anisotropy Achieved via the Strategy of Combining Rigid Groups with High Symmetry and π‐Conjugated Organic Groups in Hybrid Fluorides

    Advanced Science · 2025-10-06

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  25. Effect of Multiple Hydrogen Bonding on the π-Conjugated Groups and Optical Properties in Molecular Crystals

    Inorganic Chemistry · 2025-11-03

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  26. The condensation of π-conjugated units: a new paradigm for designing high-performance optical crystals

    Chemical Society Reviews · 2026-01-01

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  27. Truss bridge-like anhydrous stacking in hybrid crystals triggers ultra-high stability and robust birefringence

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    Ping Wang, Qiya Huang, Xiaoli Meng, Lehui Liu, Qi Wu, Hongming Liu

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  28. Protonation‐Triggered Structural Transformations in 4‐Hydroxypyridinium Halides for Solar‐Blind UV Functional Crystals

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  29. Protonation‐Triggered Structural Transformations in 4‐Hydroxypyridinium Halides for Solar‐Blind UV Functional Crystals

    Angewandte Chemie International Edition · 2026-01-04

    Jing Lu, Xin Liu, Shuangxiong Zhao, Xuebing Deng, Qundong Fu, Jingyu Guo, Zheng Liu, Li‐Ming Wu, Ling Chen

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  30. A 3.6–3.9 μm Mid-IR OPO with low pulse-to-pulse fluctuation pumped by a 1064 nm pulsed laser based on pre-biased transverse voltage-boosted EO Q-switching and BC filtering

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  31. Rare 3 × 3 Layering in High‐Pressure Pseudo‐Perovskite Sr 4 Te 4 O 15

    ChemistryOpen · 2026-02-01

    Benjamin J. Pullicino, Armin Penz, Martina Tribus, Thomas S. Hofer, Günter Heymann

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  32. V-Shaped Pseudo-Chains Coupled with Lone-Pair-Distorted [GeX 3 ] − Units Enable Large Birefringence in Ge(II) Hybrid Halides

    Crystal Growth & Design · 2026-02-28

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  33. Noncovalent Assembly Engineering Achieves Excellent Birefringence in Crystals

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  34. Zero-dimensional hybrid indium halides with broadband orange emission for white light emitting diodes

    Journal of Luminescence · 2026-05-21

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  35. Lateral‐Site Unblocking Enables Bilateral π ‐Chromophore Organization for Giant Birefringence in One‐Dimensional Lead Hybrids

    Angewandte Chemie International Edition · 2026-08-07

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  36. Lateral‐Site Unblocking Enables Bilateral π ‐Chromophore Organization for Giant Birefringence in One‐Dimensional Lead Hybrids

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  37. Low-Dimensional Perovskites and Metal Halides across Structures and Functions: Connectivity, Dimensionality, and Emerging Principles

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