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RESEARCH PAPER · Advanced Optical Materials · 2024

1D Tin(II)‐Based Chiral Hybrid Perovskite Single Crystals with Extremely Distorted Inorganic Chains for Second Harmonic Generation

Kezheng Tao, Qiang Li, Qingfeng Yan

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1D Tin(II)‐Based Chiral Hybrid Perovskite Single Crystals with Extremely Distorted Inorganic Chains for Second Harmonic GenerationOriginalAmine-directed synthesis, valence state control, and optical properties of two new organic–inorganic tin chlorides7Chemically driven dimensionality modulation of hybrid tin( ii ) halide perovskite microcrystals11Tuning the dimensionality in chiral and racemic organic/tin hybrids with halides2Chiral Organic Cations and Distorted Inorganic Polyhedra Composing Metal Halide Nonlinear Optical Materials22Phase Transition of a Chiral Lead‐Free Hybrid Antimony(III) Halide Crystal2Synthesis and growth of solution-processed chiral perovskites12l -Homoproline-Directed Synthesis of Organic–Inorganic Metal Iodides for Second Harmonic Generation14Single Crystal Sn-Based Halide Perovskites10Chirality‐Dependent Anisotropic Nonlinear Optical Effect in Low‐Dimensional Hybrid Metal Halides10(C 6 H 5 N 2 )HgCl 3 : Discovery of a Polar Hg‐Based Hybrid Halide as Preeminent Nonlinear Optical and Birefringent Material Activated by π‐Conjugated Organic Cation Substitution38Chiral perovskites with a unique 1D chain structure: impact of chiral ligand geometry on local inversion asymmetry and chiral-induced spin selectivity17From (C6H5N2)2CdCl4 to (C6H5N2)2ZnCl4, Chirality Transformation to Realize a Nonlinear Optical Organic–Inorganic Hybrid Halide with Balanced Comprehensive Performance19Nonlinear Optical Properties of 0D Chiral Hybrid Bismuth Iodides35Chiral Ligand-Induced Second-Harmonic Generation Response in Helical One-Dimensional Hybrid Lead Bromides9Chiral Perovskite Single Crystals: Toward Promising Design and Application7Femtosecond Laser Breaks the Lattice Symmetry and Induces Broadband Second Harmonic Generation in 3D Halide Perovskites6Engineering the Electronic Structure and Optoelectronic Properties of Chiral Metal Halides through Cation Design0Controlling d10 Metal in Phenylthiourea‐Based Hybrid Metal Halides to Actualize Dimensional Transformation and Significantly Improve the Birefringence11Achieving large birefringence in oxalate crystals by a hydrogen bond-directed strategy1Chiral Molecules Induce Enantiomorphic Lattice Helicity in Chiral 0D Tin Bromide Crystals17Chiral Molecules Induce Enantiomorphic Lattice Helicity in Chiral 0D Tin Bromide Crystals6Second‐Harmonic‐Generation Circular‐Dichroism in Chiral Perovskite Single Crystals Enhanced by Self‐Trapped Excitonic State12Recent advances of theoretical investigation on lead-free metal halide perovskites4Achieving record birefringence in metal-free semiorganic sulfate crystals via tetrahedral anionic group substitution0Halogen-ion-driven polymorphs for high-performance nonlinear optical crystalline materials3Chirality Transfer in Metal Halide Semiconductors16Boosting Intrinsic Chirality of One‐dimensional Perovskite Single Crystals via Extended Cation Conjugation4Halogen Anion-Mediated Substitution of Nitrate: Toward Polar Materials with Intense Second-Harmonic Generation Effects3One-Dimensional Sb(III) Halides with Orange Emission and White-Light Conversion Capability1Engineering Chirality in the Solid State: Co‐Crystallization as a Strategy for Chiral Induction and Resolution3Chiral (R/S‐MPz)Ge 4 I 10 With Unique 2D [Ge 4 I 10 ] Layered Structure and Large Chirality‐Induced Nonlinear Optical Effect0Dual tuning of second-harmonic generation and Rashba-Dresselhaus spin-splitting in chiral hybrid perovskites via halogen-site engineering1Highly Stable Chiral Hybrid Bismuth Halides With Giant Anisotropy for Self‐Driven Circularly Polarized Light Detection0Low-Dimensional Perovskites and Metal Halides across Structures and Functions: Connectivity, Dimensionality, and Emerging Principles1HSAB‐Guided Design of Chiral Osmium Halides With Both Efficient Nonlinear Optical Properties and High Stability0HSAB‐Guided Design of Chiral Osmium Halides With Both Efficient Nonlinear Optical Properties and High Stability0Mixed‐Valence Engineering in Ge 2+ Chalcogenides: Structural Modulation for Balanced Infrared Nonlinear Optics0Room-temperature spin control in WS 2 enabled by chiral seeded lead-free chiral perovskites0

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    Dalton Transactions · 2024-01-01

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  2. Chemically driven dimensionality modulation of hybrid tin( ii ) halide perovskite microcrystals

    Journal of Materials Chemistry C · 2024-01-01

    Raúl Iván Sánchez Alarcón, Omar E. Solis, Cristina Momblona, Teresa S. Ripollés, Juan P. Martínez‐Pastor, Rafael Abargues, Pablo P. Boix

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  3. Tuning the dimensionality in chiral and racemic organic/tin hybrids with halides

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  4. Chiral Organic Cations and Distorted Inorganic Polyhedra Composing Metal Halide Nonlinear Optical Materials

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  5. Phase Transition of a Chiral Lead‐Free Hybrid Antimony(III) Halide Crystal

    European Journal of Inorganic Chemistry · 2024-07-26

    Jun‐Chao Qi, Zhang‐Tian Xia, Xin Shen, Hang Peng, Huiping Chen, Yong‐Ju Bai, Wei‐Qiang Liao

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  6. Synthesis and growth of solution-processed chiral perovskites

    Journal of Physics Energy · 2024-08-12

    Sander Driessen, Sevgi Sarıgül Özbek, Carolin M. Sutter‐Fella, Shuxia Tao

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  7. l -Homoproline-Directed Synthesis of Organic–Inorganic Metal Iodides for Second Harmonic Generation

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    Juan Cheng, Gangji Yi, Peiqi Qian, Jing Li, Ling Huang, Hongmei Zeng, Guohong Zou, Zhien Lin

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  8. Single Crystal Sn-Based Halide Perovskites

    Nanomaterials · 2024-09-04

    Aditya Bhardwaj, Daniela Marongiu, Valeria Demontis, Angelica Simbula, Francesco Quochi, Michele Saba, Andrea Mura, Giovanni Bongiovanni

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  9. Chirality‐Dependent Anisotropic Nonlinear Optical Effect in Low‐Dimensional Hybrid Metal Halides

    Chemistry - A European Journal · 2024-11-26

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  10. (C 6 H 5 N 2 )HgCl 3 : Discovery of a Polar Hg‐Based Hybrid Halide as Preeminent Nonlinear Optical and Birefringent Material Activated by π‐Conjugated Organic Cation Substitution

    Advanced Optical Materials · 2024-12-30

    Ru‐Ling Tang, Die‐Xue Yang, Liang Ma, Yi‐Lei Lv, Wenlong Liu, Sheng‐Ping Guo

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  11. Chiral perovskites with a unique 1D chain structure: impact of chiral ligand geometry on local inversion asymmetry and chiral-induced spin selectivity

    Chemical Science · 2025-01-01

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  12. From (C6H5N2)2CdCl4 to (C6H5N2)2ZnCl4, Chirality Transformation to Realize a Nonlinear Optical Organic–Inorganic Hybrid Halide with Balanced Comprehensive Performance

    Inorganic Chemistry · 2025-02-13

    Die-Xue Yang, Yi‐Lei Lv, Jiandong Guo, Wen-Ye Gao, Wenlong Liu, Ru‐Ling Tang

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  13. Nonlinear Optical Properties of 0D Chiral Hybrid Bismuth Iodides

    Advanced Materials · 2025-04-03

    Aman Chaturvedi, Parikshit Kumar Rajput, Shabnum Maqbool, Angshuman Nag, Pankaj K. Mandal

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  14. Chiral Ligand-Induced Second-Harmonic Generation Response in Helical One-Dimensional Hybrid Lead Bromides

    Inorganic Chemistry · 2025-06-02

    Qiao‐Feng Huang, Shufang Yan, Ying Fu, Wenlong Liu, Jiajing Wu, Sheng‐Ping Guo

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  15. Chiral Perovskite Single Crystals: Toward Promising Design and Application

    Materials · 2025-06-04

    Lin Wang, Jie Ren, Hanying Li

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  16. Femtosecond Laser Breaks the Lattice Symmetry and Induces Broadband Second Harmonic Generation in 3D Halide Perovskites

    Laser & Photonics Review · 2025-07-08

    Guan‐Feng Gao, Ze‐Lin Li, Ze‐Kai Chen, Lanlan Zhong, Nan Hou, Zhi‐Hao Yan, Jing Wang, Chenhui Li, F. R. Zeng, Xiaozhi Xu, Ieng-Wai Un, Yihang Chen, Jiadong Zhou, Lakshminarayana Polavarapu, Xiaowen Hu, Xiaofang Jiang

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  17. Engineering the Electronic Structure and Optoelectronic Properties of Chiral Metal Halides through Cation Design

    ACS Materials Letters · 2025-07-18

    Clarissa Coccia, Marco Moroni, Massimo Boiocchi, Marta Morana, M. Patrini, Doretta Capsoni, Alessio Porta, Andera Olivati, Giulia Folpini, Annamaria Petrozza, Luca Gregori, Edoardo Mosconi, Filippo De Angelis, Lorenzo Malavasi

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  18. Controlling d10 Metal in Phenylthiourea‐Based Hybrid Metal Halides to Actualize Dimensional Transformation and Significantly Improve the Birefringence

    Advanced Optical Materials · 2025-07-20

    Yi‐Lei Lv, Ru‐Ling Tang, Liang Ma, Cheng Chen, Wenlong Liu, Sheng‐Ping Guo

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  19. Achieving large birefringence in oxalate crystals by a hydrogen bond-directed strategy

    Science China Chemistry · 2025-08-08

    Yan-Zhen Xie, Hua Huang, Qingran Ding, Jian Lei, Yu-Ling Wang, Qing‐Yan Liu

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  20. Chiral Molecules Induce Enantiomorphic Lattice Helicity in Chiral 0D Tin Bromide Crystals

    Angewandte Chemie International Edition · 2025-08-31

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  21. Chiral Molecules Induce Enantiomorphic Lattice Helicity in Chiral 0D Tin Bromide Crystals

    Angewandte Chemie · 2025-08-31

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  22. Second‐Harmonic‐Generation Circular‐Dichroism in Chiral Perovskite Single Crystals Enhanced by Self‐Trapped Excitonic State

    Advanced Functional Materials · 2025-09-07

    Jinhui Yu, Min Li, Yicong Lv, Bowen Liao, Guangrong Tan, Jinyu Zou, Xitao Liu, Yibo Han, Liang Li

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  23. Recent advances of theoretical investigation on lead-free metal halide perovskites

    Coordination Chemistry Reviews · 2025-09-18

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  24. Achieving record birefringence in metal-free semiorganic sulfate crystals via tetrahedral anionic group substitution

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  25. Halogen-ion-driven polymorphs for high-performance nonlinear optical crystalline materials

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  26. Chirality Transfer in Metal Halide Semiconductors

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  27. Boosting Intrinsic Chirality of One‐dimensional Perovskite Single Crystals via Extended Cation Conjugation

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  28. Halogen Anion-Mediated Substitution of Nitrate: Toward Polar Materials with Intense Second-Harmonic Generation Effects

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  29. One-Dimensional Sb(III) Halides with Orange Emission and White-Light Conversion Capability

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    Mingyue Chen, Kunjie Liu, Yong Zhang, Ruonan Yao, Jing Zhao, Quanlin Liu

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  30. Engineering Chirality in the Solid State: Co‐Crystallization as a Strategy for Chiral Induction and Resolution

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  31. Chiral (R/S‐MPz)Ge 4 I 10 With Unique 2D [Ge 4 I 10 ] Layered Structure and Large Chirality‐Induced Nonlinear Optical Effect

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  32. Dual tuning of second-harmonic generation and Rashba-Dresselhaus spin-splitting in chiral hybrid perovskites via halogen-site engineering

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  33. Highly Stable Chiral Hybrid Bismuth Halides With Giant Anisotropy for Self‐Driven Circularly Polarized Light Detection

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  34. Low-Dimensional Perovskites and Metal Halides across Structures and Functions: Connectivity, Dimensionality, and Emerging Principles

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  35. HSAB‐Guided Design of Chiral Osmium Halides With Both Efficient Nonlinear Optical Properties and High Stability

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  36. HSAB‐Guided Design of Chiral Osmium Halides With Both Efficient Nonlinear Optical Properties and High Stability

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  37. Mixed‐Valence Engineering in Ge 2+ Chalcogenides: Structural Modulation for Balanced Infrared Nonlinear Optics

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  38. Room-temperature spin control in WS 2 enabled by chiral seeded lead-free chiral perovskites

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