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RESEARCH PAPER · Materials Chemistry Frontiers · 2023

Recent progress in borate-based short-wavelength nonlinear optical crystals with boron–oxygen skeleton modification

Meng Cheng, Xueling Hou, Zhihua Yang, Shilie Pan

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Recent progress in borate-based short-wavelength nonlinear optical crystals with boron–oxygen skeleton modificationOriginalThe structural origin and boundaries of thermal transitions in stillwellite-type LnBSiO54Galloborates as ultraviolet nonlinear optical crystals: advances and perspectives8Shooting short-wavelength nonlinear optical materials with targeted balance performances in hydroxyborates through first-principles high-throughput screening4Toward the ultraviolet (UV) or deep-UV nonlinear optical crystals: The combination of π-conjugated planar [XY3] and tetrahedral [XY4]80Modulating Electron Density of Boron–Oxygen Groups in Borate via Metal Electronegativity for Propane Oxidative Dehydrogenation5Old tree blossoms anew: Research progress on the structures and optical properties of ultraviolet selenites56Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units66Unraveling Superior Elasticity and Controlled Thermal Expansion in Trigonal MBO3 (M=Al, Ga) with Isolated [BO3] Group: A Theoretical Perspective9Insight in to the properties of a UV nonlinear optical alkali pentaborate crystal2Li2NaB3S2O12: A Deep-UV Transparent Borosulfate with Moderate Birefringence Derived from the [B3S2O12]∞ Infinite Chain Designed by the High Boron-to-Sulfur Ratio Strategy6Learning From Nature: The Rational Non‐Centrosymmetric Structural Design in the Honeycomb‐Like Gaudefroyite Family23Thermal evolution of the Ca 2 B 2 O 5 crystal structure through γ ↔ β′ ↔ α phase transitions and the crystal structure of the incommensurately modulated β′-phase0Computational Identification of Four Promising Nonlinear Optical Materials for Near and Middle Ultraviolet Operation6A Promising Deep Ultraviolet Nonlinear Optical Crystal Activated by the Ordered Structure Design40A Promising Deep Ultraviolet Nonlinear Optical Crystal Activated by the Ordered Structure Design3Second-Harmonic Generation Response in Nitridophosphates MP2N4 (M = Ge, Sn, Pb) and the Role of Stereochemically Active Lone Pairs6Non-equivalent terminating roles of hydroxyl and fluorine in hydroxy/fluorooxo-borate optical functional materials2Influence of an alkali metal dopant Rb on the structural, mechanical and optical properties of an UV-transparent ammonium pentaborate crystal0Four zinc borates: From acentric chain to centric porous layer0Growth and Characterization of Novel SrB2O4 Crystals0Unit Symmetry‐Breaking and Layered Linear Ordering Enabling Superior Short‐Wave Ultraviolet Birefringent Crystal8Unit Symmetry‐Breaking and Layered Linear Ordering Enabling Superior Short‐Wave Ultraviolet Birefringent Crystal2NH 4 B 3 PO 6 (OH) 3 : A Hydroxyborophosphate with Short DUV Cutoff Edge and Large Birefringence2Minimizing Oscillator Strength: A Strategy for Engineering Deep-Ultraviolet Nonlinear Optical Crystals with Optimized Refractive-Index Dispersion0Effects of alkali metal (K+) cation substitution on the mechanical and nonlinear optical properties of ammonium pentaborate crystal0Prediction of deep-ultraviolet nonlinear optical material in borosilicate system: a case of RbSiB3O70D‐π‐A Type Pure Organic Small Molecular Nonlinear Optical Materials in Quantum Information Technology0Borophosphate-based second-order nonlinear optical materials: Advances in structural diversity and optical performance0

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  1. The structural origin and boundaries of thermal transitions in stillwellite-type LnBSiO5

    Optical Materials · 2023-12-08

    Maria Georgievna Krzhizhanovskaya, Олег Сергеевич Верещагин, Yu.O. Kopylova, Liudmila A. Gorelova, Dmitrii Vasil'evich Pankin, Valentina A. Yukhno, Natalia S. Vlasenko, Vladimir M. Bocharov, Sergey N. Britvin

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  2. Galloborates as ultraviolet nonlinear optical crystals: advances and perspectives

    Dalton Transactions · 2024-01-01

    Jingyi Lu, Yangfeifei Ou, Congcong Jin, Jian‐Wen Cheng

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  3. Shooting short-wavelength nonlinear optical materials with targeted balance performances in hydroxyborates through first-principles high-throughput screening

    Inorganic Chemistry Frontiers · 2024-01-01

    chenxu li, Abudukadi Tudi, Huanhuan Cheng, Qing‐Yu Liu, Zhihua Yang, Shilie Pan

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  4. Toward the ultraviolet (UV) or deep-UV nonlinear optical crystals: The combination of π-conjugated planar [XY3] and tetrahedral [XY4]

    Coordination Chemistry Reviews · 2024-02-02

    W. Zhang, Xueling Hou, Shujuan Han, Shilie Pan

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  5. Modulating Electron Density of Boron–Oxygen Groups in Borate via Metal Electronegativity for Propane Oxidative Dehydrogenation

    Materials · 2024-06-12

    Panpan Li, Yongbin Yao, Shanshan Chai, Zhijian Li, Fan Xue, Xi Wang

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  6. Old tree blossoms anew: Research progress on the structures and optical properties of ultraviolet selenites

    Coordination Chemistry Reviews · 2024-06-15

    Pengfei Li, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

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  7. Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units

    Coordination Chemistry Reviews · 2024-07-03

    Bo Zhang, Mao‐Yin Ran, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  8. Unraveling Superior Elasticity and Controlled Thermal Expansion in Trigonal MBO3 (M=Al, Ga) with Isolated [BO3] Group: A Theoretical Perspective

    European Journal of Inorganic Chemistry · 2024-07-24

    Dingfeng Yang, Yurou Tang, Hongxu Xia, Keman Yin, Yuanyuan Li, Yuanyuan Li

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  9. Insight in to the properties of a UV nonlinear optical alkali pentaborate crystal

    Journal of Materials Science Materials in Electronics · 2024-09-01

    A.N. Vigneshwaran, Chidambaram Ramachandra Raja

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  10. Li2NaB3S2O12: A Deep-UV Transparent Borosulfate with Moderate Birefringence Derived from the [B3S2O12]∞ Infinite Chain Designed by the High Boron-to-Sulfur Ratio Strategy

    Inorganic Chemistry · 2024-10-07

    Zichang Wang, Jianyi Zuo, Qing‐Yu Liu, Xueling Hou, Minqiang Gai

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  11. Learning From Nature: The Rational Non‐Centrosymmetric Structural Design in the Honeycomb‐Like Gaudefroyite Family

    Advanced Functional Materials · 2024-10-10

    Fanlu Bu, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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  12. Thermal evolution of the Ca 2 B 2 O 5 crystal structure through γ ↔ β′ ↔ α phase transitions and the crystal structure of the incommensurately modulated β′-phase

    CrystEngComm · 2025-01-01

    Yu. O. Kopylova, Sergey N. Volkov, Maria Georgievna Krzhizhanovskaya, A. M. Banaru, Valentina A. Yukhno, S. M. Aksenov, R. S. Bubnova

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  13. Computational Identification of Four Promising Nonlinear Optical Materials for Near and Middle Ultraviolet Operation

    Journal of Experimental and Theoretical Physics Letters · 2025-02-01

    Y. Alkabakibi, D. D. Barma, Dmitry V. Rybkovskiy, Abudukadi Tudi, Congwei Xie, Артем Ромаевич Оганов

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  14. A Promising Deep Ultraviolet Nonlinear Optical Crystal Activated by the Ordered Structure Design

    Angewandte Chemie International Edition · 2025-03-11

    Haonan Liu, Xuming Zhai, Xinru Li, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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  15. A Promising Deep Ultraviolet Nonlinear Optical Crystal Activated by the Ordered Structure Design

    Angewandte Chemie · 2025-03-11

    Haonan Liu, Xuming Zhai, Xinru Li, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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  16. Second-Harmonic Generation Response in Nitridophosphates MP2N4 (M = Ge, Sn, Pb) and the Role of Stereochemically Active Lone Pairs

    Chemistry of Materials · 2025-05-07

    Xiyue Cheng, Victor Trinquet, Bohan Ding, Gian‐Marco Rignanese, Xavier Gonze, Shuiquan Deng

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  17. Non-equivalent terminating roles of hydroxyl and fluorine in hydroxy/fluorooxo-borate optical functional materials

    Science China Chemistry · 2025-06-03

    Huanhuan Cheng, Shilie Pan, Zhihua Yang

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  18. Influence of an alkali metal dopant Rb on the structural, mechanical and optical properties of an UV-transparent ammonium pentaborate crystal

    Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy · 2025-08-05

    A.N. Vigneshwaran, Chidambaram Ramachandra Raja

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  19. Four zinc borates: From acentric chain to centric porous layer

    Chinese Journal of Structural Chemistry · 2025-10-22

    Juan Chen, Jin-Ni Zhao, Guo‐Yu Yang

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  20. Growth and Characterization of Novel SrB2O4 Crystals

    Crystals · 2025-10-25

    Magdalena Angelova, Rusi Rusew, Rositsa Nikolova, Boris Lubomirov Shivachev

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  21. Unit Symmetry‐Breaking and Layered Linear Ordering Enabling Superior Short‐Wave Ultraviolet Birefringent Crystal

    Angewandte Chemie International Edition · 2026-01-14

    Xin Wen, Dequan Kong, Jingyao Lu, Jindong Chen, Haohai Yu, Huaijin Zhang, Zhanggui Hu, Jiyang Wang, Ning Ye, Guang Peng

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  22. Unit Symmetry‐Breaking and Layered Linear Ordering Enabling Superior Short‐Wave Ultraviolet Birefringent Crystal

    Angewandte Chemie · 2026-01-14

    Xin Wen, Dequan Kong, Jingyao Lu, Jindong Chen, Haohai Yu, Huaijin Zhang, Zhanggui Hu, Jiyang Wang, Ning Ye, Guang Peng

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  23. NH 4 B 3 PO 6 (OH) 3 : A Hydroxyborophosphate with Short DUV Cutoff Edge and Large Birefringence

    Inorganic Chemistry · 2026-03-27

    Bailin Chen, Yansheng Jiang, Hangwei Jia, Shuai An, Xueling Hou, Shilie Pan

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  24. Minimizing Oscillator Strength: A Strategy for Engineering Deep-Ultraviolet Nonlinear Optical Crystals with Optimized Refractive-Index Dispersion

    Chemistry of Materials · 2026-04-13

    Paipai Zhang, Fh Li, Wenhu Wang, Zhihua Yang

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  25. Effects of alkali metal (K+) cation substitution on the mechanical and nonlinear optical properties of ammonium pentaborate crystal

    Inorganic Chemistry Communications · 2026-06-16

    A.N. Vigneshwaran, Chidambaram Ramachandra Raja

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  26. Prediction of deep-ultraviolet nonlinear optical material in borosilicate system: a case of RbSiB3O7

    Science China Materials · 2026-07-10

    Xiaoyu Wu, Olga Reutova, Linlin Liu, Wenqi Jin, Abudukadi Tudi, Jidong Zhang, Congwei Xie, Zhihua Yang

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  27. D‐π‐A Type Pure Organic Small Molecular Nonlinear Optical Materials in Quantum Information Technology

    Advanced Quantum Technologies · 2026-09-01

    Chuanxin Liao, Jialong Cui, D H Zhang, Qi Zhang, Xiaofu Zhang, Yunru Fan, 郭光灿, Qiang Zhou

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  28. Borophosphate-based second-order nonlinear optical materials: Advances in structural diversity and optical performance

    Coordination Chemistry Reviews · 2026-09-17

    Bo Zhao, Yaozu Li, Danyang Dou, Wenjing Zhang, Huiyi Zhang, Bingbing Zhang, Ying Wang

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