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RESEARCH PAPER · Inorganic Chemistry · 2023

Structural Motif Cosubstitution Strategy for Designing Fluoroaluminoborate with the Sr2Be2B2O7-Type Double-Layered Structure

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Structural Motif Cosubstitution Strategy for Designing Fluoroaluminoborate with the Sr2Be2B2O7-Type Double-Layered StructureOriginal“One stone two birds” design of borates featuring edge-sharing [BO 4 ] and different B–O configurations in one structure utilizing covalent tetrahedra8Ca 3 Al 2 B 8 O 18 : borate with a graphene-like layer featuring two types of topological six-membered rings induced by [AlO 4 ] units7CsAlB 3 O 6 Cl: the rational construction of a KBBF-type structure with aligned 2 ∞ [AlB 3 O 6 Cl] layers via introducing unprecedented [AlO 3 Cl] tetrahedra5Recent advances in rational structure design for nonlinear optical crystals: leveraging advantageous templates153LiNa2Ca8B12O24F6Cl and Li1.2Na2.8B6O11: A Case of Cation-Induced Birefringence Enhancement via Dimensional Changes of Highly Polymerized [B12O24] Motifs10Simultaneous fluoridation strategies for achieving high thermionic emission and low melting point in aluminate impregnants for Ba-W cathodes3Influence of F-Doped 612 Impregnants on the Emission Properties of Dispenser Cathodes4NH4B5O7(OH)2 and CsRbB10O14(OH)4·H2O: Two Hydroxyborates Feature Significant Optical Anisotropy and Contain 1∞[B5O7(OH)2] Chains1Cation-modulated aligned arrangement of [B3O7] units in an unprecedented 2∞[B3O5] layer with remarkable birefringence10Studies on Three 3D Bimetallic Tellurates: Including a Second-Order NLO Material with d10-Zn2+ and SOJT-Effect Te4+/Mo6+ Cations2[Al(H 2 O) 6 ](NO 3 )Cl 2 : achieving parallel arrangement of functional units and birefringence enhancement through free halogen-mediated structural regulation0CsB(OH) 4 (H 2 O) 2 and Na(NH 4 ) 2 B 10 O 16 OH(H 2 O): a hydroxylation modification strategy regulates the borate structures and optical properties0K3Sr3Li2Ga4B6O20F: A Sr2Be2B2O7-Type Ultraviolet Nonlinear Optical Crystal0MAlB3O6F2 (M = Ca and Pb): Two New Fluoroaluminoborates Featuring π-Conjugated [BO3] and [AlO4F2] Units with Large Birefringence0

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  1. “One stone two birds” design of borates featuring edge-sharing [BO 4 ] and different B–O configurations in one structure utilizing covalent tetrahedra

    Journal of Materials Chemistry C · 2024-01-01

    Haoran Wang, Jiahao Jiao, Abudukadi Tudi, Shilie Pan, Min Zhang

    Read original paper ↗ ·
  2. Ca 3 Al 2 B 8 O 18 : borate with a graphene-like layer featuring two types of topological six-membered rings induced by [AlO 4 ] units

    Chemical Communications · 2024-01-01

    Ziting Yan, Dongdong Chu, Zhihua Yang, Shilie Pan, Min Zhang

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  3. CsAlB 3 O 6 Cl: the rational construction of a KBBF-type structure with aligned 2 ∞ [AlB 3 O 6 Cl] layers via introducing unprecedented [AlO 3 Cl] tetrahedra

    Chemical Communications · 2024-01-01

    Haoran Liu, Jiahao Jiao, Abudukadi Tudi, Qing‐Yu Liu, Zhihua Yang, Shilie Pan, Min Zhang

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  4. Recent advances in rational structure design for nonlinear optical crystals: leveraging advantageous templates

    Chemical Society Reviews · 2024-01-01

    Ziting Yan, Jinbin Fan, Shilie Pan, Min Zhang

    Read original paper ↗ ·
  5. LiNa2Ca8B12O24F6Cl and Li1.2Na2.8B6O11: A Case of Cation-Induced Birefringence Enhancement via Dimensional Changes of Highly Polymerized [B12O24] Motifs

    Inorganic Chemistry · 2024-08-21

    Ziting Yan, Jinbin Fan, Dongdong Chu, Zhihua Yang, Juanjuan Lu, Shilie Pan, Min Zhang

    Read original paper ↗ ·
  6. Simultaneous fluoridation strategies for achieving high thermionic emission and low melting point in aluminate impregnants for Ba-W cathodes

    Ceramics International · 2024-11-01

    Yongfeng Cai, Zichen Li, Yunfei Yang, Yong Hou, Junhao Sun, Zheng Liu, Hexiong Liu, Liran Dong, Xuewei Lv, Jinshu Wang

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  7. Influence of F-Doped 612 Impregnants on the Emission Properties of Dispenser Cathodes

    IEEE Transactions on Electron Devices · 2025-05-07

    Zichen Li, Yongfeng Cai, Yunfei Yang, Peng Liu, F R Liu, Junhao Sun, Jinshu Wang

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  8. NH4B5O7(OH)2 and CsRbB10O14(OH)4·H2O: Two Hydroxyborates Feature Significant Optical Anisotropy and Contain 1∞[B5O7(OH)2] Chains

    Inorganic Chemistry · 2025-07-17

    Xueli Du, Haoran Wang, Haoran Liu, Qingyu Liu, Wenhu Wang, Jiahao Jiao, Yuchen Yan, Xueyan Wu, Min Zhang

    Read original paper ↗ ·
  9. Cation-modulated aligned arrangement of [B3O7] units in an unprecedented 2∞[B3O5] layer with remarkable birefringence

    Science China Materials · 2025-07-28

    Ziting Yan, Dongdong Chu, Zhihua Yang, Shilie Pan, Min Zhang

    Read original paper ↗ ·
  10. Studies on Three 3D Bimetallic Tellurates: Including a Second-Order NLO Material with d10-Zn2+ and SOJT-Effect Te4+/Mo6+ Cations

    Inorganic Chemistry · 2025-08-14

    Yuquan Feng, Zhiguo Zhong, Shuyang Chen, Sujuan Jin, Zhaohui Meng, Hongwei Wang

    Read original paper ↗ ·
  11. [Al(H 2 O) 6 ](NO 3 )Cl 2 : achieving parallel arrangement of functional units and birefringence enhancement through free halogen-mediated structural regulation

    Inorganic Chemistry Frontiers · 2026-01-01

    Z B Zhang, Luyong Zhang, Ruyi Niu, Hussin Elkik, Xue Bai, Jin Li, Shujuan Han

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  12. CsB(OH) 4 (H 2 O) 2 and Na(NH 4 ) 2 B 10 O 16 OH(H 2 O): a hydroxylation modification strategy regulates the borate structures and optical properties

    Dalton Transactions · 2026-01-01

    Kelibinuer Wulamu, Ziting Yan, Dongdong Chu, Juanjuan Lu, Yanhui Zhang, Hong Du

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  13. K3Sr3Li2Ga4B6O20F: A Sr2Be2B2O7-Type Ultraviolet Nonlinear Optical Crystal

    Inorganic Chemistry · 2026-08-28

    Bing Li, Aoge Yao, Jianqiao Wang, Zhengyang Zhou, Hongrui Liu, Haochen Li, Haotian Tian, Qian Wu, Ying Zhao, Lei Kang, Shu Hai Guo, Mingjun Xia

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  14. MAlB3O6F2 (M = Ca and Pb): Two New Fluoroaluminoborates Featuring π-Conjugated [BO3] and [AlO4F2] Units with Large Birefringence

    Crystal Growth & Design · 2026-10-02

    Yaozu Li, Chao Wei, Wenjing Zhang, Huiyi Zhang, Bo Zhao, Bingbing Zhang, Ying Wang

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