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RESEARCH PAPER · Chemistry of Materials · 2023

HgB2S4: A d10 Metal Thioborate with Giant Birefringence and Wide Band Gap

Yi Huang, Yong an Zhang, Dongdong Chu, Zhihua Yang, Guangmao Li, Shilie Pan

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HgB2S4: A d10 Metal Thioborate with Giant Birefringence and Wide Band GapOriginalBa 3 (BS 3 )(PS 4 ): the first alkaline-earth metal thioborate–thiophosphate with strong optical anisotropy originating from planar [BS 3 ] units8Na 6 Mg 3 P 4 S 16 and RbMg 2 PS 4 Cl 2 : two Mg-based thiophosphates with ultrawide bandgaps resulting from [MgS 6 ] and [MgS x Cl 6− x ] octahedra4C(NH2)3Cd(C2O4)Cl(H2O)·H2O and BaCd(C2O4)1.5Cl(H2O)2: Two Oxalate Chlorides Obtained by Chemical Scissors Strategy Exhibiting Low-Dimensional Structural Networks and Balanced Overall Optical Properties14Ba4Cd2Ge2Te9: A promising infrared functional crystal with large birefringent and photoluminescence properties2HgBr 2 : an easily growing wide-spectrum birefringent crystal38Partial substitution with a significant effect: coexistence of a wide band gap and large birefringence in the oxychalcogenide AEGe 2 O 4 Se (AE = Sr and Ba)17Mixed-anion square-pyramid [SbS3I2] units causing strong second-harmonic generation intensity and large birefringence8EuSi7P10: An Inorganic Supramolecular Nonlinear Optical Crystal Exhibiting Strong Second-Harmonic Generation Response4Structure‐Prediction‐Oriented Synthesis of Thiophosphates as Promising Infrared Nonlinear Optical Materials24Structure‐Prediction‐Oriented Synthesis of Thiophosphates as Promising Infrared Nonlinear Optical Materials1Na 2 B 12 Si 6 Se 18 : a novel B 12 -cluster-containing quaternary selenoborate framework material2Hg4InS2Cl5: Achieving Giant Optical Anisotropy by Introducing Well‐Aligned Linear [Hg2S2] Units14(C 6 H 5 N 2 )HgCl 3 : Discovery of a Polar Hg‐Based Hybrid Halide as Preeminent Nonlinear Optical and Birefringent Material Activated by π‐Conjugated Organic Cation Substitution38A π-conjugated organic molecule-modified strategy to achieve high-performance metal nitrate birefringent crystals9Selenoborates: a latent structure resource for infrared functional crystal materials1Stereochemically active lone pair-induced large optical anisotropy in a novel infrared birefringent crystal Ba 2 La 2 Sb 4 S 10 (S 2 )5Double Sb‐N Coordination Enables Record‐High Birefringence in UV‐Transparent Crystals71Double Sb‐N Coordination Enables Record‐High Birefringence in UV‐Transparent Crystals8Two-Step Substitutions of Square Pyramidal VO5 with CdO4Br to Achieve Higher Laser-Induced Damage Threshold from Polar Oxybromides Rb4CdV5O15Br to Rb3CdV4O12Br10Designed Metal‐Free Quasi‐1D Crystals with Giant Birefringence8Synergistic Machine Learning Guided Discovery of ABa 3 (BSe 3 ) 2 X (A = Rb, Cs; X = Cl, Br, I): A Promising Family as Property‐Balanced IR Functional Materials10Recent progress in structural design strategies of high-birefringence optical crystals54KYSiSe 4 : A Rare-Earth Selenide Infrared Nonlinear Optical Crystal with Wide Infrared Transparency and Well-Balanced E g and SHG Response9Cd 7 I 12 Q·As 4 Q n (Q = S, Se; n = 3, 4): In Situ Alteration of Functional Molecules in Polar Metal Inorganic Framework Tailoring High‐Performance Infrared Nonlinear Optical Crystals9Research progress and future prospect of chalcogenides with large optical anisotropy46Controlling d10 Metal in Phenylthiourea‐Based Hybrid Metal Halides to Actualize Dimensional Transformation and Significantly Improve the Birefringence11CsICl 2 : A Record-Birefringent Inorganic Crystal with Ultrawide Infrared Transparency Enabled by Linear Interhalogen ICl 2 – Units36CaYIIIS 4 (III = Ga, In): Two Olivine-Type Compounds Exhibiting Exceptional Birefringence Properties1Achieving giant optical anisotropy in the mid-far infrared region via ideal alignment of dual functional motifs0Optical anisotropy in Mo–Te–O frameworks constructed from distorted MoO 6 and TeO 3 units0Anion-Centered Engineering for Simultaneously Enhancing Birefringence and Band Gap in Chalcogenides1

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31 direct citing papers saved.

  1. Ba 3 (BS 3 )(PS 4 ): the first alkaline-earth metal thioborate–thiophosphate with strong optical anisotropy originating from planar [BS 3 ] units

    Dalton Transactions · 2023-01-01

    Jiazheng Zhou, Linan Wang, Hongshan Wang, Ling Luo, Junjie Li, Feng Yu

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  2. Na 6 Mg 3 P 4 S 16 and RbMg 2 PS 4 Cl 2 : two Mg-based thiophosphates with ultrawide bandgaps resulting from [MgS 6 ] and [MgS x Cl 6− x ] octahedra

    Dalton Transactions · 2023-12-05

    Yi Chu Huang, Dongdong Chu, Xueling Hou, Guangmao Li, Yong an Zhang

    Read original paper ↗ ·

  3. C(NH2)3Cd(C2O4)Cl(H2O)·H2O and BaCd(C2O4)1.5Cl(H2O)2: Two Oxalate Chlorides Obtained by Chemical Scissors Strategy Exhibiting Low-Dimensional Structural Networks and Balanced Overall Optical Properties

    Inorganic Chemistry · 2023-12-19

    Wei Xu, Liang Ma, Yi‐Lei Lv, Siyu Ma, Wenlong Liu, Sheng‐Ping Guo, Ru‐Ling Tang

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  4. Ba4Cd2Ge2Te9: A promising infrared functional crystal with large birefringent and photoluminescence properties

    Journal of Alloys and Compounds · 2023-12-29

    Mengran Sun, Haojian Su, Wenhao Liu, Jiyong Yao

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  5. HgBr 2 : an easily growing wide-spectrum birefringent crystal

    Chemical Science · 2024-01-01

    Ming‐Shu Zhang, Wen‐Dong Yao, Shao‐Min Pei, Bin‐Wen Liu, Xiao‐Ming Jiang, Guo‐Cong Guo

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  6. Partial substitution with a significant effect: coexistence of a wide band gap and large birefringence in the oxychalcogenide AEGe 2 O 4 Se (AE = Sr and Ba)

    Inorganic Chemistry Frontiers · 2024-01-01

    Mao‐Yin Ran, Shenghua Zhou, Wenbo Wei, A-Yang Wang, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  7. Mixed-anion square-pyramid [SbS3I2] units causing strong second-harmonic generation intensity and large birefringence

    Chinese Chemical Letters · 2024-03-08

    Yu Zhou, Lin‐Tao Jiang, Xiao‐Ming Jiang, Bin‐Wen Liu, Guo‐Cong Guo

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  8. EuSi7P10: An Inorganic Supramolecular Nonlinear Optical Crystal Exhibiting Strong Second-Harmonic Generation Response

    Inorganic Chemistry · 2024-05-30

    Yunxia Song, Chensheng Lin, Chao Wang, Yuqiao Zhou, Shenghao Fang, Pengxiang Dong, Bingxuan Li, Ning Ye, Xin Lei Zhao, Min Luo

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  9. Structure‐Prediction‐Oriented Synthesis of Thiophosphates as Promising Infrared Nonlinear Optical Materials

    Angewandte Chemie International Edition · 2024-06-03

    Yi Bo Huang, Dongdong Chu, Yong an Zhang, Congwei Xie, Guangmao Li, Shilie Pan

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  10. Structure‐Prediction‐Oriented Synthesis of Thiophosphates as Promising Infrared Nonlinear Optical Materials

    Angewandte Chemie · 2024-06-03

    Yi Bo Huang, Dongdong Chu, Yong an Zhang, Congwei Xie, Guangmao Li, Shilie Pan

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  11. Na 2 B 12 Si 6 Se 18 : a novel B 12 -cluster-containing quaternary selenoborate framework material

    Dalton Transactions · 2024-12-09

    Gopabandhu Panigrahi, Hunter B. Tisdale, Gregory W. Morrison, Hans‐Conrad zur Loye

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  12. Hg4InS2Cl5: Achieving Giant Optical Anisotropy by Introducing Well‐Aligned Linear [Hg2S2] Units

    Advanced Optical Materials · 2024-12-13

    Qixian Ren, Yu Chu, Wenqi Jin, Mengmeng Chen, Cui Chen, Yabo Wu, Shilie Pan

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  13. (C 6 H 5 N 2 )HgCl 3 : Discovery of a Polar Hg‐Based Hybrid Halide as Preeminent Nonlinear Optical and Birefringent Material Activated by π‐Conjugated Organic Cation Substitution

    Advanced Optical Materials · 2024-12-30

    Ru‐Ling Tang, Die‐Xue Yang, Liang Ma, Yi‐Lei Lv, Wenlong Liu, Sheng‐Ping Guo

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  14. A π-conjugated organic molecule-modified strategy to achieve high-performance metal nitrate birefringent crystals

    Inorganic Chemistry Frontiers · 2025-01-01

    Yi‐Lei Lv, Liang Ma, Guo-Ren Zhu, Bing-Wei Miao, Wenlong Liu, Sheng‐Ping Guo, Ru‐Ling Tang

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  15. Selenoborates: a latent structure resource for infrared functional crystal materials

    Inorganic Chemistry Frontiers · 2025-01-01

    Yihan Yun, Abudukadi Tudi, Zhihua Yang, Guangmao Li, Shilie Pan

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  16. Stereochemically active lone pair-induced large optical anisotropy in a novel infrared birefringent crystal Ba 2 La 2 Sb 4 S 10 (S 2 )

    Inorganic Chemistry Frontiers · 2025-01-01

    Jingdong Yan, Xiangran Kong, Shichao Cheng, Tao Liu, Hongwei Leng, Yunfei Shang, Zuotao Lei, Chunhui Yang

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  17. Double Sb‐N Coordination Enables Record‐High Birefringence in UV‐Transparent Crystals

    Angewandte Chemie International Edition · 2025-03-11

    Pu Zhang, Xuehua Dong, Ling Huang, Zhien Lin, Yuqiao Zhou, Guohong Zou

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  18. Double Sb‐N Coordination Enables Record‐High Birefringence in UV‐Transparent Crystals

    Angewandte Chemie · 2025-03-11

    Pu Zhang, Xuehua Dong, Ling Huang, Zhien Lin, Yuqiao Zhou, Guohong Zou

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  19. Two-Step Substitutions of Square Pyramidal VO5 with CdO4Br to Achieve Higher Laser-Induced Damage Threshold from Polar Oxybromides Rb4CdV5O15Br to Rb3CdV4O12Br

    Inorganic Chemistry · 2025-03-24

    Baozhu Zhu, Lei Geng, Shoubao Zhang, Shuo Han, Chang‐Yu Meng, You‐Zhao Lan, Qi Wu

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  20. Designed Metal‐Free Quasi‐1D Crystals with Giant Birefringence

    Chemistry - A European Journal · 2025-04-07

    Yang Li, Jihyun Lee, Kang Min Ok

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  21. Synergistic Machine Learning Guided Discovery of ABa 3 (BSe 3 ) 2 X (A = Rb, Cs; X = Cl, Br, I): A Promising Family as Property‐Balanced IR Functional Materials

    Advanced Science · 2025-04-26

    Yihan Yun, Mengfan Wu, Zhihua Yang, Guangmao Li, Shilie Pan

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  22. Recent progress in structural design strategies of high-birefringence optical crystals

    Coordination Chemistry Reviews · 2025-05-08

    A-Lan Xu, Mao‐Yin Ran, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  23. KYSiSe 4 : A Rare-Earth Selenide Infrared Nonlinear Optical Crystal with Wide Infrared Transparency and Well-Balanced E g and SHG Response

    Inorganic Chemistry · 2025-06-16

    Haixia Wang, Wangfei Che, Hongbo Zhang, Xinfeng Guo, Limei Xiao, Yakun Tang, Guangmao Li

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  24. Cd 7 I 12 Q·As 4 Q n (Q = S, Se; n = 3, 4): In Situ Alteration of Functional Molecules in Polar Metal Inorganic Framework Tailoring High‐Performance Infrared Nonlinear Optical Crystals

    Laser & Photonics Review · 2025-06-20

    Huikang Jiang, Xuemei Shi, Lihua Gao, Guangsai Yang, Guang Peng, Ning Ye, Jindong Chen

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  25. Research progress and future prospect of chalcogenides with large optical anisotropy

    Coordination Chemistry Reviews · 2025-06-20

    Zhen-Cheng Wu, Sheng‐Ping Guo

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  26. Controlling d10 Metal in Phenylthiourea‐Based Hybrid Metal Halides to Actualize Dimensional Transformation and Significantly Improve the Birefringence

    Advanced Optical Materials · 2025-07-20

    Yi‐Lei Lv, Ru‐Ling Tang, Liang Ma, Cheng Chen, Wenlong Liu, Sheng‐Ping Guo

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  27. CsICl 2 : A Record-Birefringent Inorganic Crystal with Ultrawide Infrared Transparency Enabled by Linear Interhalogen ICl 2 – Units

    Journal of the American Chemical Society · 2025-07-21

    Chong‐An Chen, Yang Li, Congcong Jin, Kang Min Ok

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  28. CaYIIIS 4 (III = Ga, In): Two Olivine-Type Compounds Exhibiting Exceptional Birefringence Properties

    Inorganic Chemistry · 2025-08-21

    Chengbo Li, Haipeng Zhou, Y. Q. Chen, Jinfeng Liu, Xiu Zhu, Guisheng Xu, Jiankang Wang

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  29. Achieving giant optical anisotropy in the mid-far infrared region via ideal alignment of dual functional motifs

    Inorganic Chemistry Frontiers · 2026-01-01

    Yi-Wen Shan, Ming‐Zhi Zhang, C Hu, Jiang‐Gao Mao

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  30. Optical anisotropy in Mo–Te–O frameworks constructed from distorted MoO 6 and TeO 3 units

    Dalton Transactions · 2026-01-01

    Cheng He, Kun Hu, Jing-Yang Zhou, Long Wu, Jian‐Han Zhang

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  31. Anion-Centered Engineering for Simultaneously Enhancing Birefringence and Band Gap in Chalcogenides

    Chemistry of Materials · 2026-01-19

    Chao-Hong Xie, Lu Liu, Xiao‐Ming Jiang, Bin-Wen Liu, Guo‐Cong Guo

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