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RESEARCH PAPER · Inorganic Chemistry · 2022

Noncentrosymmetric (C3H7N6)6(H2PO4)4(HPO4)·4H2O and Centrosymmetric (C3H7N6)2SO4·2H2O: Exploration of Acentric Structure by Combining Planar and Tetrahedral Motifs via Hydrogen Bonds

Shu‐Fang Li, Liang Hu, Yao Ma, Fei‐Fei Mao, Jie Zheng, Xiu‐Du Zhang, Dong Yan

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Noncentrosymmetric (C3H7N6)6(H2PO4)4(HPO4)·4H2O and Centrosymmetric (C3H7N6)2SO4·2H2O: Exploration of Acentric Structure by Combining Planar and Tetrahedral Motifs via Hydrogen BondsOriginalC(NH2)3Rb(I3O8)(IO3)(I2O6H2): An unprecedented organic–inorganic hybrid polyiodate with two different polyiodate groups13KC9H5O6(H2O): A Promising UV Nonlinear-Optical Material with Large Birefringence Based on a π-Conjugated (C9H5O6)−Group11Na 2 (C 4 O 4 )(H 3 BO 3 )(H 2 O) 4 ·H 3 BO 3 : the first borate-squarate with strong SHG response obtained by superior synergy11Unveiling the Superior Optical Properties of Novel Melamine‐Based Nonlinear Optical Material with Strong Second‐Harmonic Generation and Giant Optical Anisotropy74(C 2 H 10 N 2 )[Zn 2 (HPO 4 ) 2 Cl 2 ]: substitution-activated new short-wave ultraviolet phosphate with pivotal dual-property enhancement5(C 3 N 6 H 7 )BF 4 ·H 2 O and (C 3 N 6 H 7 )SO 3 CH 3 ·H 2 O with large birefringence induced by coplanar π-conjugated [C 3 N 6 H 7 ] + groups33Designing promising ultraviolet (UV) birefringent crystals with different hydrogen-bonded phosphate frameworks18Large optical anisotropy in noncentrosymmetric phosphate with pseudo 2D intercalated layer16Research progress in optical materials with cationic organic planar π-conjugated groups containing CN bonds34[C(NH2)3]6Mo7O24: A Guanidinium Molybdate as a UV Nonlinear Optical Crystal with Large Birefringence17First-principles screening of metal–organic frameworks for entangled photon pair generation5Rational Combination of π‐Conjugated and Non‐π‐Conjugated Groups Achieving Strong Nonlinear Optical Response, Large Optical Anisotropy, and UV Light‐Switchable Fluorescence65NiCo2O4 Electrocatalyst Doped with Phosphorus for Improved Oxygen Evolution Reaction16Intramolecular Hydrogen Bonds Enhance Structure Coplanarity, Resulting in Significant Birefringence in Bridged-Bipyridine Halides7[C(NH2)3]10(MoO3)10(PO4)2(HPO4)2·5H2O: Synergy effect of multiple functional units results in significant birefringence10Old tree blossoms anew: Research progress on the structures and optical properties of ultraviolet selenites56C6N7(NH2)3·H3PO4: Strong Second Harmonic Generation and Giant Birefringence Benefiting from Amino Substitution Strategy24(C10N2H10)(HI2O6)(HIO3)(IO3): A Birefringent Material Featuring Large π-Conjugated Organic Cation and Two Types of Iodate Anions2Stimulus-responsive multifunctions in a zinc( ii ) sulfate complex: photochromism, photoswitching nonlinear optical properties, amine detection and visual film application9Amino substitution strategy achieves significant blue shift while preserving high optical anisotropy: A2(H3C3N4S2)2•H2O (A =NH4, K, Rb, Cs)6[C3H7N6]3[B3O5(OH)2] and [C3H8N6]4[B12O19(OH)6]: Two Melamine Borates with Large Birefringence13Functional assembly and modification of nonlinear optical fundamental motifs in phosphates27Chiral-Unit-Oriented Design of Non-π-Conjugated Noncentrosymmetric Phosphates with Short Absorption Edges4(C6H10N2)ZnX4·H2O (X=Cl and Br): Excellent nonlinear optical properties and temperature induced photoluminescence for encryption23(3‐C6H10N2)ZnX4 (X = Cl and Br): Two Excellent UV Nonlinear Optical Crystals Designed by Combination of π‐conjugated and [ZnX4]2− Tetrahedral Units26Hydrogen‐Bonded Assembly of Functional Units for Constructing Linear and Nonlinear Optical Crystals10Multifunctional Cd‐based Hybrid with Large Birefringence Achieving Excellent Second Harmonic Generation and Reversible Temperature‐Activated Fluorescence for Anti‐counterfeiting16Decoupling the SHG‐Birefringence Trade‐off in UV NLO Materials via Triple‐Control Coordination Engineering: Achieving Synergistic Performance Optimization88Decoupling the SHG‐Birefringence Trade‐off in UV NLO Materials via Triple‐Control Coordination Engineering: Achieving Synergistic Performance Optimization13Hydrothermal Synthesis and Characterization of the Melamine‐Based Second‐Harmonic Generation Material HgCl2(C3N6H6)0Effect of Multiple Hydrogen Bonding on the π-Conjugated Groups and Optical Properties in Molecular Crystals5Integrating Fluorinated [BF 4 ] Anion With π‐Conjugated Six‐Membered Rings for Short‐Wavelength UV Frequency Conversion17Integrating Fluorinated [BF 4 ] Anion With π‐Conjugated Six‐Membered Rings for Short‐Wavelength UV Frequency Conversion2Halogenated Metal–Organic Frameworks for Entangled Photon Pair Generation0Chiral-Unit-Driven Short-Wave Ultraviolet Nonlinear Optical Acetates with Balanced Overall Optical Properties3Strategically designed deep-ultraviolet optical crystals with balanced properties by small heteroatom substitution1Two hydrated ionic cocrystals of phenylphosphonate exhibiting second-harmonic generation and proton conductivity0

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  1. C(NH2)3Rb(I3O8)(IO3)(I2O6H2): An unprecedented organic–inorganic hybrid polyiodate with two different polyiodate groups

    Journal of Solid State Chemistry · 2022-08-28

    Dong Yan, Yao Ma, Ru‐Ling Tang, Liang Hu, Fei‐Fei Mao, Jie Zheng, Xiu‐Du Zhang, Shu‐Fang Li

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  2. KC9H5O6(H2O): A Promising UV Nonlinear-Optical Material with Large Birefringence Based on a π-Conjugated (C9H5O6)−Group

    Inorganic Chemistry · 2022-09-02

    Shu‐Fang Li, Liang Hu, Ru‐Ling Tang, Yao Ma, Fei‐Fei Mao, Jie Zheng, Xiu‐Du Zhang, Dong Yan

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  3. Na 2 (C 4 O 4 )(H 3 BO 3 )(H 2 O) 4 ·H 3 BO 3 : the first borate-squarate with strong SHG response obtained by superior synergy

    Chemical Communications · 2022-12-01

    Dong Yan, Yao Ma, Hongbo Huang, Bingbing Zhang, Ru‐Ling Tang, Liang Hu, Fei‐Fei Mao, Jie Zheng, Xiu‐Du Zhang, Shu‐Fang Li

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  4. Unveiling the Superior Optical Properties of Novel Melamine‐Based Nonlinear Optical Material with Strong Second‐Harmonic Generation and Giant Optical Anisotropy

    Small · 2023-03-27

    Zhiyong Bai, Jihyun Lee, Heewon Kim, Chun‐Li Hu, Kang Min Ok

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  5. (C 2 H 10 N 2 )[Zn 2 (HPO 4 ) 2 Cl 2 ]: substitution-activated new short-wave ultraviolet phosphate with pivotal dual-property enhancement

    Journal of Materials Chemistry C · 2024-01-01

    Zhi Gang Fang, Yu-Ming Pan, Pei Han, Bing‐Ping Yang, Meihong Duan

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  6. (C 3 N 6 H 7 )BF 4 ·H 2 O and (C 3 N 6 H 7 )SO 3 CH 3 ·H 2 O with large birefringence induced by coplanar π-conjugated [C 3 N 6 H 7 ] + groups

    Inorganic Chemistry Frontiers · 2024-01-01

    Hangwei Jia, Die Xu, Zi‐Jian Li, Muhammad Sharjeel Arif, Yansheng Jiang, Xueling Hou

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  7. Designing promising ultraviolet (UV) birefringent crystals with different hydrogen-bonded phosphate frameworks

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  8. Large optical anisotropy in noncentrosymmetric phosphate with pseudo 2D intercalated layer

    Inorganic Chemistry Frontiers · 2024-01-01

    Qiao Xia, Xingxing Jiang, Qi Lu, Chao Wu, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Kazuyuki Tatsumi, Chi Zhang

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  9. Research progress in optical materials with cationic organic planar π-conjugated groups containing CN bonds

    Inorganic Chemistry Frontiers · 2024-01-01

    Hangwei Jia, Xueling Hou, Shilie Pan

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  10. [C(NH2)3]6Mo7O24: A Guanidinium Molybdate as a UV Nonlinear Optical Crystal with Large Birefringence

    Inorganic Chemistry · 2024-02-13

    Meng-Han Lv, Shu‐Fang Li, Meng-Meng Ren, Jiaxin Wang, Ru‐Ling Tang, Jin Chen, Hongbo Huang, Bingbing Zhang, Dong Yan

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  11. First-principles screening of metal–organic frameworks for entangled photon pair generation

    Materials for Quantum Technology · 2024-02-23

    S. Shanmuga Sundara Raj, Simón Paiva, Rubén A. Fritz, Felipe Herrera, Yamil J. Colón

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  12. Rational Combination of π‐Conjugated and Non‐π‐Conjugated Groups Achieving Strong Nonlinear Optical Response, Large Optical Anisotropy, and UV Light‐Switchable Fluorescence

    Advanced Science · 2024-03-13

    Danyang Dou, Qi Shi, Huimin Li, Bingbing Zhang, Daqing Yang, Ying Wang

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  13. NiCo2O4 Electrocatalyst Doped with Phosphorus for Improved Oxygen Evolution Reaction

    ACS Applied Nano Materials · 2024-05-29

    Shu‐Fang Li, Xin Li, Dong Yan

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  14. Intramolecular Hydrogen Bonds Enhance Structure Coplanarity, Resulting in Significant Birefringence in Bridged-Bipyridine Halides

    Crystal Growth & Design · 2024-05-30

    Wenjie He, Xin Liu, Ling Chen, Li‐Ming Wu

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  15. [C(NH2)3]10(MoO3)10(PO4)2(HPO4)2·5H2O: Synergy effect of multiple functional units results in significant birefringence

    Journal of Solid State Chemistry · 2024-06-12

    Yang Zhang, Yang Zhang, Meng-Han Lv, Shu‐Fang Li, Hongbo Huang, Bingbing Zhang, Dong Yan

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  16. Old tree blossoms anew: Research progress on the structures and optical properties of ultraviolet selenites

    Coordination Chemistry Reviews · 2024-06-15

    Pengfei Li, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

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  17. C6N7(NH2)3·H3PO4: Strong Second Harmonic Generation and Giant Birefringence Benefiting from Amino Substitution Strategy

    Advanced Optical Materials · 2024-08-22

    Ruqing Wei, Hongbo Huang, Daqing Yang, Ying Wang, Bingbing Zhang

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  18. (C10N2H10)(HI2O6)(HIO3)(IO3): A Birefringent Material Featuring Large π-Conjugated Organic Cation and Two Types of Iodate Anions

    Inorganic Chemistry · 2024-10-19

    Yuhang Wang, De-Xuan Jiang, De‐Xuan Liu, Fu-Ying Li, He Zhao, Jie Pan, Qi Wei, Li Wei, Guo‐Yu Yang

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  19. Stimulus-responsive multifunctions in a zinc( ii ) sulfate complex: photochromism, photoswitching nonlinear optical properties, amine detection and visual film application

    Journal of Materials Chemistry C · 2024-10-31

    Shuai Liang, Shi-Kun Yan, Yu-Xuan Wen, Yanrui Zhao, Jin Zhang, Ji‐Xiang Hu, Guo-Ming Wang

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  20. Amino substitution strategy achieves significant blue shift while preserving high optical anisotropy: A2(H3C3N4S2)2•H2O (A =NH4, K, Rb, Cs)

    Chinese Chemical Letters · 2024-11-10

    Shuang Zhao, Fei Jia, Kaibei Zhan, Rui‐Xi Wang, Pengfei Tan, Lin Shen, Li‐Ming Wu, Ling Chen

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  21. [C3H7N6]3[B3O5(OH)2] and [C3H8N6]4[B12O19(OH)6]: Two Melamine Borates with Large Birefringence

    Inorganic Chemistry · 2024-11-18

    Ya-Lan Deng, Chun‐Li Hu, Jiang‐Gao Mao

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  22. Functional assembly and modification of nonlinear optical fundamental motifs in phosphates

    Coordination Chemistry Reviews · 2024-11-27

    Fan Liu, Pifu Gong, Zheshuai Lin, Lei Kang

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  23. Chiral-Unit-Oriented Design of Non-π-Conjugated Noncentrosymmetric Phosphates with Short Absorption Edges

    The Journal of Physical Chemistry Letters · 2025-02-17

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  24. (C6H10N2)ZnX4·H2O (X=Cl and Br): Excellent nonlinear optical properties and temperature induced photoluminescence for encryption

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  25. (3‐C6H10N2)ZnX4 (X = Cl and Br): Two Excellent UV Nonlinear Optical Crystals Designed by Combination of π‐conjugated and [ZnX4]2− Tetrahedral Units

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  26. Hydrogen‐Bonded Assembly of Functional Units for Constructing Linear and Nonlinear Optical Crystals

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  27. Multifunctional Cd‐based Hybrid with Large Birefringence Achieving Excellent Second Harmonic Generation and Reversible Temperature‐Activated Fluorescence for Anti‐counterfeiting

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  28. Decoupling the SHG‐Birefringence Trade‐off in UV NLO Materials via Triple‐Control Coordination Engineering: Achieving Synergistic Performance Optimization

    Angewandte Chemie International Edition · 2025-05-22

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  29. Decoupling the SHG‐Birefringence Trade‐off in UV NLO Materials via Triple‐Control Coordination Engineering: Achieving Synergistic Performance Optimization

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  30. Hydrothermal Synthesis and Characterization of the Melamine‐Based Second‐Harmonic Generation Material HgCl2(C3N6H6)

    European Journal of Inorganic Chemistry · 2025-07-02

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  31. Effect of Multiple Hydrogen Bonding on the π-Conjugated Groups and Optical Properties in Molecular Crystals

    Inorganic Chemistry · 2025-11-03

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  32. Integrating Fluorinated [BF 4 ] Anion With π‐Conjugated Six‐Membered Rings for Short‐Wavelength UV Frequency Conversion

    Angewandte Chemie International Edition · 2025-11-26

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  33. Integrating Fluorinated [BF 4 ] Anion With π‐Conjugated Six‐Membered Rings for Short‐Wavelength UV Frequency Conversion

    Angewandte Chemie · 2025-11-26

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  34. Halogenated Metal–Organic Frameworks for Entangled Photon Pair Generation

    Chemistry of Materials · 2025-12-14

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  35. Chiral-Unit-Driven Short-Wave Ultraviolet Nonlinear Optical Acetates with Balanced Overall Optical Properties

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  36. Strategically designed deep-ultraviolet optical crystals with balanced properties by small heteroatom substitution

    Inorganic Chemistry Frontiers · 2026-01-01

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  37. Two hydrated ionic cocrystals of phenylphosphonate exhibiting second-harmonic generation and proton conductivity

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