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RESEARCH PAPER · Inorganic Chemistry Frontiers · 2024

Designing promising ultraviolet (UV) birefringent crystals with different hydrogen-bonded phosphate frameworks

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Designing promising ultraviolet (UV) birefringent crystals with different hydrogen-bonded phosphate frameworksOriginalExploring short-wavelength birefringent crystals via triggering cooperative arrangement between different π-conjugated groups8Halogen Bond Unlocks Ultra‐High Birefringence73Halogen Bond Unlocks Ultra‐High Birefringence14Strategically designed anisotropic organic–inorganic metal halides (OIMHs) with superior balance between bandgap and birefringence12Hg[CS(NH 2 ) 2 ] 4 (SiF 6 ): a fluorosilicate crystal with large birefringence achieved via multi-functional group modification6Hydrogen bonding regulation-oriented design of pyridine sulfonate as a promising UV birefringent crystal characterized by enhanced structural anisotropy11Optimizing optical anisotropy in low-dimensional structures via intralayer hydrogen bonding modulation and anionic substitution17Chiral-Unit-Oriented Design of Non-π-Conjugated Noncentrosymmetric Phosphates with Short Absorption Edges4Metal Cation Engineered UV Birefringent Crystals in π‐Conjugated Sulfonates with Record‐High Optical Anisotropy17Hydrogen‐Bonded Assembly of Functional Units for Constructing Linear and Nonlinear Optical Crystals10(NH4)Na3Zn4(PO4)4:An open-framework zincophosphate exhibiting well-balanced optical and thermal performance1Breaking the Birefringence Barrier in B–O Crystals via B–C π-scaffolding36A novel metal-free crystal demonstrating superior birefringence attributed to the synergistic interaction of dual π-conjugated units8Organic Halogen Substitution-Driven Halogen Bonding Induces Polar 3D Supramolecular Framework and Second-Harmonic-Generation Response7Achieving Ultra‐High Optical Anisotropy via Structural Regulation and Coplanar Engineering of Extended π‐Conjugated [H 2–x C 3 N 3 S 3 ] (x = 1, 2) Groups3Hydrogen‐Bond‐Modulated Alignment of Iminodiacetic Acid Cations for Achieving Ultraviolet Second Harmonic Generation6Strong Optical Nonlinearity in Polar Hypophosphites via Chiral Cation Assembly1Crystal growth, structural characterization and optoelectronic properties of 2-aminobenzylaminium picrate organic single crystal0

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  1. Exploring short-wavelength birefringent crystals via triggering cooperative arrangement between different π-conjugated groups

    Chemical Communications · 2024-01-01

    Xiao Wang, Tingwen Han, Kenneth Reinhard Poeppelmeier, Xueling Hou, Shilie Pan, Fangfang Zhang

    Read original paper ↗ ·
  2. Halogen Bond Unlocks Ultra‐High Birefringence

    Angewandte Chemie International Edition · 2024-07-10

    Jin Chen, Mingsheng Xu, Huai‐Yu Wu, Jun‐Yan Wu, Ke‐Zhao Du

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  3. Halogen Bond Unlocks Ultra‐High Birefringence

    Angewandte Chemie · 2024-07-10

    Jin Chen, Miao‐Bin Xu, Huai‐Yu Wu, Jun‐Yan Wu, Ke‐Zhao Du

    Read original paper ↗ ·
  4. Strategically designed anisotropic organic–inorganic metal halides (OIMHs) with superior balance between bandgap and birefringence

    Inorganic Chemistry Frontiers · 2024-12-16

    Mingchang Wang, Huaiyu Wu, Miao‐Bin Xu, Jiajia Li, Ke‐Zhao Du, Jin Chen

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  5. Hg[CS(NH 2 ) 2 ] 4 (SiF 6 ): a fluorosilicate crystal with large birefringence achieved via multi-functional group modification

    Dalton Transactions · 2025-01-01

    Pengfei Li, Xinlei Liu, Si-Qi Zhou, Mingchang Wang, Jingjing Wu, Yu‐Wu Zhong, Jiannian Yao

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  6. Hydrogen bonding regulation-oriented design of pyridine sulfonate as a promising UV birefringent crystal characterized by enhanced structural anisotropy

    Chemical Science · 2025-01-01

    Longyun Xu, Conggang Li, Shuaifeng Li, Huijian Zhao, Xianghao Kong, Zaixin Qu, Wen-Jie Feng, Ke Xu, Ning Ye, Zhanggui Hu

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  7. Optimizing optical anisotropy in low-dimensional structures via intralayer hydrogen bonding modulation and anionic substitution

    Materials Horizons · 2025-01-01

    Muhammad Sharjeel Arif, Xu Liu, Hangwei Jia, Zhihua Yang, Xueling Hou, Shilie Pan

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  8. Chiral-Unit-Oriented Design of Non-π-Conjugated Noncentrosymmetric Phosphates with Short Absorption Edges

    The Journal of Physical Chemistry Letters · 2025-02-17

    Kai Huang, Xi-Ming Dong, Chao He, Zi-Xuan Zhao, Wei Chen, Hui‐Yan Zhao, Ji‐Xiang Hu, Qi Wei, Guo‐Ming Wang

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  9. Metal Cation Engineered UV Birefringent Crystals in π‐Conjugated Sulfonates with Record‐High Optical Anisotropy

    Small · 2025-04-07

    Zichang Wang, Qing‐Yu Liu, Zhihua Yang, Xueling Hou, Minqiang Gai

    Read original paper ↗ ·
  10. Hydrogen‐Bonded Assembly of Functional Units for Constructing Linear and Nonlinear Optical Crystals

    Advanced Optical Materials · 2025-04-29

    Ziqi Chen, Changyou Liu, Chenxu Li, Juanjuan Lu, Zhihua Yang, Shilie Pan, Miriding Mutailipu

    Read original paper ↗ ·
  11. (NH4)Na3Zn4(PO4)4:An open-framework zincophosphate exhibiting well-balanced optical and thermal performance

    Journal of Molecular Structure · 2025-06-07

    Chen-Yuan Ma, Qiang Tu, Yu-Ming Pan, Pei De Han, Meihong Duan, Zhi Gang Fang

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  12. Breaking the Birefringence Barrier in B–O Crystals via B–C π-scaffolding

    Journal of the American Chemical Society · 2025-07-04

    Jiajia Li, Miao‐Bin Xu, Mingchang Wang, Zhi Wei Lin, Yuan Hua Lin, Yun-Xia Hu, Jia-Min Lian, Jin Chen, Ke‐Zhao Du

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  13. A novel metal-free crystal demonstrating superior birefringence attributed to the synergistic interaction of dual π-conjugated units

    Science China Materials · 2025-07-07

    Die-Xue Yang, Ru‐Ling Tang, Yi‐Lei Lv, Bing-Wei Miao, Wenlong Liu, Sheng‐Ping Guo

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  14. Organic Halogen Substitution-Driven Halogen Bonding Induces Polar 3D Supramolecular Framework and Second-Harmonic-Generation Response

    Inorganic Chemistry · 2025-09-17

    Mingchang Wang, Jiajia Li, Yan Chen, Ke‐Zhao Du, Jin Chen

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  15. Achieving Ultra‐High Optical Anisotropy via Structural Regulation and Coplanar Engineering of Extended π‐Conjugated [H 2–x C 3 N 3 S 3 ] (x = 1, 2) Groups

    Advanced Functional Materials · 2025-12-12

    Muhammad Arif, Xu Liu, Hangwei Jia, Zhihua Yang, Xueling Hou, Shilie Pan

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  16. Hydrogen‐Bond‐Modulated Alignment of Iminodiacetic Acid Cations for Achieving Ultraviolet Second Harmonic Generation

    Advanced Optical Materials · 2026-01-09

    Limin Duan, Xiaomin Zhang, Yan Chun Xiao, Daqing Yang, Y. Y. Wang, Bingbing Zhang

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  17. Strong Optical Nonlinearity in Polar Hypophosphites via Chiral Cation Assembly

    Chemistry of Materials · 2026-04-21

    Yiran Zhang, Qiao Xia, Xiaotian Zhang, Zhipeng Huang, Mark Graeme Humphrey, Liming Cheng, Kasper Moth‐Poulsen, C L Zhang, Chao Wu

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  18. Crystal growth, structural characterization and optoelectronic properties of 2-aminobenzylaminium picrate organic single crystal

    Journal of Materials Science Materials in Electronics · 2026-05-01

    A. Aditya Prasad, K.Koteswara Rao, R. Rajesh, C. Balakrishnan, Swathi Ganti, SP. Meenakshisundaram

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