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RESEARCH PAPER · Advanced Optical Materials · 2024

C6N7(NH2)3·H3PO4: Strong Second Harmonic Generation and Giant Birefringence Benefiting from Amino Substitution Strategy

Ruqing Wei, Hongbo Huang, Daqing Yang, Ying Wang, Bingbing Zhang

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C6N7(NH2)3·H3PO4: Strong Second Harmonic Generation and Giant Birefringence Benefiting from Amino Substitution StrategyOriginal“Three functions in one”: multifunctional rare-earth cyamelurates with magnetism, luminescence, and giant optical nonlinearity6Exploring ultra-high optical anisotropy in polyiodides7Hg 2 (HTe 2 O 5 )(PO 4 ): a novel phosphate crystal with enhanced birefringence enabled by the synergistic modification of multiple functional groups12Realizing large birefringence via S-substitution and anisotropic arrangement optimization4Zwitterionic Glycine-Based Antimony Fluorides with Exceptional Ultraviolet Nonlinear Optical Properties11SnHPO4: A Layered Tin(II) Phosphate with Enhanced Birefringence51Ultra‐High Optical Anisotropy with UV Transmission Achieved by Rational Arrangement of Extended π‐Conjugated Groups5Ultra‐High Optical Anisotropy with UV Transmission Achieved by Rational Arrangement of Extended π‐Conjugated Groups46(3‐C6H10N2)ZnX4 (X = Cl and Br): Two Excellent UV Nonlinear Optical Crystals Designed by Combination of π‐conjugated and [ZnX4]2− Tetrahedral Units26NH4PO3HCH3 and NH4PO3CH2NH3: Two Phosphate Derivatives with Deep-UV Cutoff Edges and Moderate Birefringence1(NH4)Na3Zn4(PO4)4:An open-framework zincophosphate exhibiting well-balanced optical and thermal performance1Giant Birefringence and Strong Third-Order Nonlinear Optical Response in a Hybrid Crystal Templated by a Push–Pull π-Conjugated System6La(SO3NH2)2NO3·H2O: synergistic anion engineering of the first rare-earth nitrate sulfamate defying transparency-birefringence-nonlinearity trade-offs in ultraviolet nonlinear optics8Five-Membered [C 5 O 5 ] 2 – Rings as Birefringence-Active Genes for Ultrabirefringent Crystals27[C(NH 2 ) 3 ] 2 PO 3 (OH): A Deep-Ultraviolet Birefringent Crystal Enabled by Synergy of π-Conjugated Cations and Heteroleptic Tetrahedra2From centrosymmetric (C 4 H 8 N 5 )(SbF 4 ) to polar (C 4 H 7 N 4 O)(SbF 4 ): a new UV nonlinear optical material achieved by functional group modulation8Synergistic dual-modification strategy of π-conjugated cations and tetrahedra: rational design of ultraviolet high-birefringence monofluorophosphates0The condensation of π-conjugated units: a new paradigm for designing high-performance optical crystals4Hydrogen‐Bond‐Modulated Alignment of Iminodiacetic Acid Cations for Achieving Ultraviolet Second Harmonic Generation6Strong Optical Nonlinearity in Polar Hypophosphites via Chiral Cation Assembly1Interlayer Electronic Decoupling Unlocks Giant Birefringence in π‐Conjugated Metal‐Organic Frameworks0Exceptional Solar‐Blind Birefringence Engineered by Complementary Hydrogen‐Bond Ordering of π‐Conjugated Units0Steric‐Guided Coordination Engineering Enables Significantly Optimized Optical Anisotropy via Sulfur‐Driven [C 5 H 5 NS] Birefringence‐Active Groups0Charge and structural flexibility of tartrate groups enable high-performance ultraviolet nonlinear optical crystals0

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24 direct citing papers saved.

  1. “Three functions in one”: multifunctional rare-earth cyamelurates with magnetism, luminescence, and giant optical nonlinearity

    Chemical Science · 2025-01-01

    Jing Zhang, Yuxiao Liu, Fangyan Wang, Pifu Gong, Zhaoyi Li, Xinyuan Zhang, Fei Liang, Shu Hai Guo, Zhanggui Hu, Yicheng Wu

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  2. Exploring ultra-high optical anisotropy in polyiodides

    Inorganic Chemistry Frontiers · 2025-01-01

    Mingye Han, Hongbo Huang, Siyu Li, Xiao Yan, Bingbing Zhang, Ying Wang

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  3. Hg 2 (HTe 2 O 5 )(PO 4 ): a novel phosphate crystal with enhanced birefringence enabled by the synergistic modification of multiple functional groups

    Inorganic Chemistry Frontiers · 2025-01-01

    Pengfei Li, Chun‐Li Hu, Bo Zhang, Jiang‐Gao Mao, Fang Kong

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  4. Realizing large birefringence via S-substitution and anisotropic arrangement optimization

    Inorganic Chemistry Frontiers · 2025-01-01

    Zhiwei Sun, Bingbing Wu, Zihao Yu, Qingran Ding, Yu‐Ling Wang, Ming Zhong, Sangen Zhao, Junhua Luo

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  5. Zwitterionic Glycine-Based Antimony Fluorides with Exceptional Ultraviolet Nonlinear Optical Properties

    Chemistry of Materials · 2025-01-20

    Yunseung Kuk, Zhiyong Bai, Yang Li, Kang Min Ok

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  6. SnHPO4: A Layered Tin(II) Phosphate with Enhanced Birefringence

    Inorganic Chemistry · 2025-01-23

    Xinyue Shi, Xueqing Liu, Chunxiao Nie, Yangkai Zhang, Degao Zhong, Bing Teng, Zhoubin Lin, Yisheng Huang, Shijia Sun

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  7. Ultra‐High Optical Anisotropy with UV Transmission Achieved by Rational Arrangement of Extended π‐Conjugated Groups

    Angewandte Chemie · 2025-03-25

    Danyang Dou, Chao Wei, Bingbing Zhang, Daqing Yang, Ying Wang

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  8. Ultra‐High Optical Anisotropy with UV Transmission Achieved by Rational Arrangement of Extended π‐Conjugated Groups

    Angewandte Chemie International Edition · 2025-03-25

    Danyang Dou, Chao Wei, Bingbing Zhang, Daqing Yang, Ying Wang

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  9. (3‐C6H10N2)ZnX4 (X = Cl and Br): Two Excellent UV Nonlinear Optical Crystals Designed by Combination of π‐conjugated and [ZnX4]2− Tetrahedral Units

    Small · 2025-03-27

    Chuanying Shen, Jie Liu, Defu Sun, Kang Yang, Bingbing Zhang, Kui Wu, Jiyang Wang, Duanliang Wang

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  10. NH4PO3HCH3 and NH4PO3CH2NH3: Two Phosphate Derivatives with Deep-UV Cutoff Edges and Moderate Birefringence

    Inorganic Chemistry · 2025-05-01

    Chenhui Hu, Jiale Qu, Jinghui Hu, Junjie Liu, Wenchao Hu, Xiangzhan Jiang

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  11. (NH4)Na3Zn4(PO4)4:An open-framework zincophosphate exhibiting well-balanced optical and thermal performance

    Journal of Molecular Structure · 2025-06-07

    Chen-Yuan Ma, Qiang Tu, Yu-Ming Pan, Pei De Han, Meihong Duan, Zhi Gang Fang

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  12. Giant Birefringence and Strong Third-Order Nonlinear Optical Response in a Hybrid Crystal Templated by a Push–Pull π-Conjugated System

    ACS Materials Letters · 2025-08-01

    V. Sivasubramani, Zilong Chen, Xu Die, Zhihua Yang, Luyong Zhang, Xueling Hou, Fangfang Zhang, Muthu Senthil Pandian, P. Ramasamy

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  13. La(SO3NH2)2NO3·H2O: synergistic anion engineering of the first rare-earth nitrate sulfamate defying transparency-birefringence-nonlinearity trade-offs in ultraviolet nonlinear optics

    Science China Chemistry · 2025-08-08

    Huan Zhou, Meng Cheng, Shilie Pan, Zhihua Yang

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  14. Five-Membered [C 5 O 5 ] 2 – Rings as Birefringence-Active Genes for Ultrabirefringent Crystals

    Journal of the American Chemical Society · 2025-09-16

    Jiachen Lu, Yang Li, Kang Min Ok

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  15. [C(NH 2 ) 3 ] 2 PO 3 (OH): A Deep-Ultraviolet Birefringent Crystal Enabled by Synergy of π-Conjugated Cations and Heteroleptic Tetrahedra

    ACS Applied Optical Materials · 2025-12-16

    Huan Zhou, Meng Cheng, Zhihua Yang, Shilie Pan

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  16. From centrosymmetric (C 4 H 8 N 5 )(SbF 4 ) to polar (C 4 H 7 N 4 O)(SbF 4 ): a new UV nonlinear optical material achieved by functional group modulation

    Chemical Science · 2026-01-01

    Zhixiang Wang, Chun-Li Hu, Chuan‐Fu Sun, Jiang‐Gao Mao, Fang Kong

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  17. Synergistic dual-modification strategy of π-conjugated cations and tetrahedra: rational design of ultraviolet high-birefringence monofluorophosphates

    Journal of Materials Chemistry C · 2026-01-01

    Huan Zhou, Meng Cheng, Yuqi Qin, Congwei Xie, Junjie Li, Xueling Hou, Zhihua Yang

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  18. The condensation of π-conjugated units: a new paradigm for designing high-performance optical crystals

    Chemical Society Reviews · 2026-01-01

    Hangwei Jia, Bailin Chen, Fangfang Zhang, Xueling Hou, Shilie Pan

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  19. Hydrogen‐Bond‐Modulated Alignment of Iminodiacetic Acid Cations for Achieving Ultraviolet Second Harmonic Generation

    Advanced Optical Materials · 2026-01-09

    Limin Duan, Xiaomin Zhang, Yan Chun Xiao, Daqing Yang, Y. Y. Wang, Bingbing Zhang

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  20. Strong Optical Nonlinearity in Polar Hypophosphites via Chiral Cation Assembly

    Chemistry of Materials · 2026-04-21

    Yiran Zhang, Qiao Xia, Xiaotian Zhang, Zhipeng Huang, Mark Graeme Humphrey, Liming Cheng, Kasper Moth‐Poulsen, C L Zhang, Chao Wu

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  21. Interlayer Electronic Decoupling Unlocks Giant Birefringence in π‐Conjugated Metal‐Organic Frameworks

    Advanced Materials · 2026-06-18

    Jia-Xiang Zhang, Xinyan Wu, Weishan Li, Haolin Zhong, Jinkun Guo, Qingsheng Zeng, Mao‐Yin Ran, Ze‐Fan Yao, Yu‐Qing Zheng, Qingqing Ji, Jin‐Hu Dou

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  22. Exceptional Solar‐Blind Birefringence Engineered by Complementary Hydrogen‐Bond Ordering of π‐Conjugated Units

    Small · 2026-08-05

    Qianxi Hu, Junwei Feng, Long Chen, Minqiang Gai

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  23. Steric‐Guided Coordination Engineering Enables Significantly Optimized Optical Anisotropy via Sulfur‐Driven [C 5 H 5 NS] Birefringence‐Active Groups

    Small · 2026-08-14

    Jiachen Lu, Chong‐An Chen, Wei Zeng, Kang Min Ok

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  24. Charge and structural flexibility of tartrate groups enable high-performance ultraviolet nonlinear optical crystals

    Chinese Journal of Structural Chemistry · 2026-09-01

    Hongbo Huang, Yinsong Zhao, Yining Wang, Jiaxing Wang, Hanyu Chen, Daqing Yang, Ying Wang, Bingbing Zhang

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