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RESEARCH PAPER · Coordination Chemistry Reviews · 2024

Functional assembly and modification of nonlinear optical fundamental motifs in phosphates

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Functional assembly and modification of nonlinear optical fundamental motifs in phosphatesOriginal1D Bi ribbon/[PO 4 ] synergy-driven bismuth phosphates for ultraviolet nonlinear optical crystals with large SHG and birefringence0Coordinated assembly of alkali and alkaline earth metals with the perfluorinated [AlF 6 ] group to design deep-ultraviolet zero-order waveplate materials2Two mixed P–O anionic phosphates with a distinctive structural transformation and deep ultraviolet cutoff edge0层状结构深紫外非线性光学晶体研究进展(特邀)2Sb2(TeO4)(SO4): An Anhydrous Tellurite Sulfate with Large Birefringence and Enhanced Thermal Stability8[C( NH2 )3] 2SiF6 : Design of Deep Ultraviolet Crystals with Large Birefringence Based on a Fluorination‐Oriented Strategy13Pioneering sulfophosphite crystals: Co-assembly of phosphite and sulfate units in novel inorganic architectures0Tuning the Anionic Configuration in ASc2(P2O7)2 (A = Ba, Pb) through A-Site Cationic Coordination Engineering0Reactive flux assisted metal oxide–boron–sulfur routine for syntheses of CsRESiS 4 (RE = Sm, Gd–Ho): featuring nonlinear optical activity and wide band gaps5Stepwise Substitution Strategy for Beryllium-Based Selenites with Enhanced SHG Response, Moderate Birefringence, and Short UV Cutoff Edges6REXCO3 (RE = La, Ce, Y; X = OH, F) with circular alignment of anionic motifs induced extraordinary nonlinear optical effects0[C(NH 2 ) 3 ] 2 PO 3 (OH): A Deep-Ultraviolet Birefringent Crystal Enabled by Synergy of π-Conjugated Cations and Heteroleptic Tetrahedra2(C 4 H 8 N 5 )(PhPHO 2 )·H 2 O: a polar ionic cocrystal with strong second-harmonic generation and high birefringence0Synergistic dual-modification strategy of π-conjugated cations and tetrahedra: rational design of ultraviolet high-birefringence monofluorophosphates0Truss bridge-like anhydrous stacking in hybrid crystals triggers ultra-high stability and robust birefringence0Two hydrated ionic cocrystals of phenylphosphonate exhibiting second-harmonic generation and proton conductivity0Sn 4+ /Sn 2+ Aliovalent Substitution: A Strategy for Local Structure Engineering to Enhance Birefringence and Trigger Structural Symmetry Transition0Enhanced tripling-performance in [C(NH2)3]4P2O7·H2O as UV nonlinear optical material due to π-conjugated cation and hydrogen bonding intervention1NH 4 B 3 PO 6 (OH) 3 : A Hydroxyborophosphate with Short DUV Cutoff Edge and Large Birefringence2Accelerated Discovery of Fluorophosphates as Deep‐Ultraviolet Nonlinear Optical Materials in the Y–P–O–F System: Unveiling New Composition‐Structure‐Property Rules1Peroxide‐Assisted Solvate Engineering Enables Record‐High Birefringence in a Solar‐Blind Transparent Crystal0Peroxide‐Assisted Solvate Engineering Enables Record‐High Birefringence in a Solar‐Blind Transparent Crystal0A Strategy for Enhancing the Optical Anisotropy of Phosphates via Tetrahedral Unit Modification0Design of deep-ultraviolet nonlinear optical BePNO2 guided by non-π-conjugated NLO-active unit0Research advances in rare-earth nonlinear optical crystalline materials in 20250Potential Deep Ultraviolet Phosphate With Y‐Based: 1 [(PO 3 ) 4 ] ∞ Chains AYP 4 O 12 (A = K, NH 4 ) and the First [P 3 O 10 ] Anionic Framework KLiYP 3 O 100Three Rare‐Earth Metal Borates Synthesized via a Cation Substitution Strategy as Potential Zero‐Order Waveplate Materials0

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  1. 1D Bi ribbon/[PO 4 ] synergy-driven bismuth phosphates for ultraviolet nonlinear optical crystals with large SHG and birefringence

    Inorganic Chemistry Frontiers · 2025-01-01

    Lei Wu, Xudong Leng, Bao Jiang, Xueyin Fu, Yi Huang, Xue Yu, Qun Jing, Zhaohui Chen

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  2. Coordinated assembly of alkali and alkaline earth metals with the perfluorinated [AlF 6 ] group to design deep-ultraviolet zero-order waveplate materials

    Dalton Transactions · 2025-01-01

    Shaohua Liu, Lili Zhang, Ke Li, Xiaotian Ma, Xifa Long, Yun Mo Yang

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  3. Two mixed P–O anionic phosphates with a distinctive structural transformation and deep ultraviolet cutoff edge

    Dalton Transactions · 2025-01-01

    Lei Wu, Hongyu Huang, Jialong Wang, Qun Jing, Yi Huang, Xuebin Yu, Zhaohui Chen

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  4. 层状结构深紫外非线性光学晶体研究进展(特邀)

    Chinese Journal of Lasers · 2025-01-01

    彭广 Peng Guang, 韩言鸣 Han Yanming, 叶宁 Ye Ning

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  5. Sb2(TeO4)(SO4): An Anhydrous Tellurite Sulfate with Large Birefringence and Enhanced Thermal Stability

    Inorganic Chemistry · 2025-04-08

    Xi-Ming Dong, Kai Huang, Hui‐Yan Zhao, Chao He, Xing‐Tao An, Qi Wei, Guo‐Yu Yang

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  6. [C( NH2 )3] 2SiF6 : Design of Deep Ultraviolet Crystals with Large Birefringence Based on a Fluorination‐Oriented Strategy

    Chinese Journal of Chemistry · 2025-06-24

    Shaohua Liu, Xiaoqin Ma, Xifa Long, Yun Mo Yang

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  7. Pioneering sulfophosphite crystals: Co-assembly of phosphite and sulfate units in novel inorganic architectures

    Journal of Solid State Chemistry · 2025-08-29

    Zong-Jie Zhao, Fuxing Lin, Kun Hu, Cheng He, Shufeng Yan, Wangchuan Xiao, Jian‐Han Zhang

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  8. Tuning the Anionic Configuration in ASc2(P2O7)2 (A = Ba, Pb) through A-Site Cationic Coordination Engineering

    Inorganic Chemistry · 2025-09-05

    Bao Jiang, Hongheng Chen, Xianmeng He, Lei Wu, Xueyin Fu, Yi Huang, Qun Jing, Zhaohui Chen

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  9. Reactive flux assisted metal oxide–boron–sulfur routine for syntheses of CsRESiS 4 (RE = Sm, Gd–Ho): featuring nonlinear optical activity and wide band gaps

    Inorganic Chemistry Frontiers · 2025-11-05

    Zhen-Cheng Wu, Fang-Xu Tian, Rui Xiao, Mao-Yin Ran, Wenlong Liu, Wen-Tong Chen, Sheng-Ping Guo

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  10. Stepwise Substitution Strategy for Beryllium-Based Selenites with Enhanced SHG Response, Moderate Birefringence, and Short UV Cutoff Edges

    Chemistry of Materials · 2025-11-17

    Yurui Wang, Xuehua Dong, Wei Zeng, Ling Huang, Zhien Lin, Hongmei Zeng, Guohong Zou

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  11. REXCO3 (RE = La, Ce, Y; X = OH, F) with circular alignment of anionic motifs induced extraordinary nonlinear optical effects

    Chinese Journal of Structural Chemistry · 2025-12-10

    Fan Liu, Pifu Gong, Zheshuai Lin, Lei Kang

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  12. [C(NH 2 ) 3 ] 2 PO 3 (OH): A Deep-Ultraviolet Birefringent Crystal Enabled by Synergy of π-Conjugated Cations and Heteroleptic Tetrahedra

    ACS Applied Optical Materials · 2025-12-16

    Huan Zhou, Meng Cheng, Zhihua Yang, Shilie Pan

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  13. (C 4 H 8 N 5 )(PhPHO 2 )·H 2 O: a polar ionic cocrystal with strong second-harmonic generation and high birefringence

    Journal of Materials Chemistry C · 2026-01-01

    Peng Zhuang, Bing‐Ping Yang, Jiang‐Gao Mao

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  14. Synergistic dual-modification strategy of π-conjugated cations and tetrahedra: rational design of ultraviolet high-birefringence monofluorophosphates

    Journal of Materials Chemistry C · 2026-01-01

    Huan Zhou, Meng Cheng, Yuqi Qin, Congwei Xie, Junjie Li, Xueling Hou, Zhihua Yang

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  15. Truss bridge-like anhydrous stacking in hybrid crystals triggers ultra-high stability and robust birefringence

    Inorganic Chemistry Frontiers · 2026-01-01

    Ping Wang, Qiya Huang, Xiaoli Meng, Lehui Liu, Qi Wu, Hongming Liu

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  16. Two hydrated ionic cocrystals of phenylphosphonate exhibiting second-harmonic generation and proton conductivity

    Materials Chemistry Frontiers · 2026-01-01

    Peng Zhuang, Chun‐Li Hu, Bing‐Ping Yang, Jiang‐Gao Mao

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  17. Sn 4+ /Sn 2+ Aliovalent Substitution: A Strategy for Local Structure Engineering to Enhance Birefringence and Trigger Structural Symmetry Transition

    Inorganic Chemistry · 2026-01-29

    Bao Jiang, Hongheng Chen, Lei Wu, Xueyin Fu, Maierhaba Abudoureheman, Qun Jing, Yu-hong Su, Zhaohui Chen

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  18. Enhanced tripling-performance in [C(NH2)3]4P2O7·H2O as UV nonlinear optical material due to π-conjugated cation and hydrogen bonding intervention

    Chinese Journal of Structural Chemistry · 2026-03-07

    Lei Wu, Enshen Wang, Bao Jiang, Xueyin Fu, Kechen Sun, Maierhaba Abudoureheman, Zhaohui Chen, Qun Jing, Yuhong Su

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  19. NH 4 B 3 PO 6 (OH) 3 : A Hydroxyborophosphate with Short DUV Cutoff Edge and Large Birefringence

    Inorganic Chemistry · 2026-03-27

    Bailin Chen, Yansheng Jiang, Hangwei Jia, Shuai An, Xueling Hou, Shilie Pan

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  20. Accelerated Discovery of Fluorophosphates as Deep‐Ultraviolet Nonlinear Optical Materials in the Y–P–O–F System: Unveiling New Composition‐Structure‐Property Rules

    Laser & Photonics Review · 2026-05-19

    Wenqi Jin, Congwei Xie, Ran An, Shilie Pan, Zhihua Yang

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  21. Peroxide‐Assisted Solvate Engineering Enables Record‐High Birefringence in a Solar‐Blind Transparent Crystal

    Angewandte Chemie International Edition · 2026-06-22

    Yang Li, Congcong Jin, Kang Min Ok

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  22. Peroxide‐Assisted Solvate Engineering Enables Record‐High Birefringence in a Solar‐Blind Transparent Crystal

    Angewandte Chemie · 2026-06-22

    Yang Li, Congcong Jin, Kang Min Ok

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  23. A Strategy for Enhancing the Optical Anisotropy of Phosphates via Tetrahedral Unit Modification

    Crystal Growth & Design · 2026-06-26

    Bao Jiang, Hongheng Chen, Lei Wu, Xueyin Fu, Maierhaba Abudoureheman, Yi Huang, Ailijiang Abudurusuli, Qun Jing, Xue Yu, Zhaohui Chen

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  24. Design of deep-ultraviolet nonlinear optical BePNO2 guided by non-π-conjugated NLO-active unit

    Computational Materials Today · 2026-07-08

    Jiaxiang Li, Junwei Feng, Wenqi Jin, Qi Song, Congwei Xie, Yu Xie

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  25. Research advances in rare-earth nonlinear optical crystalline materials in 2025

    Journal of Rare Earths · 2026-07-21

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  26. Potential Deep Ultraviolet Phosphate With Y‐Based: 1 [(PO 3 ) 4 ] ∞ Chains AYP 4 O 12 (A = K, NH 4 ) and the First [P 3 O 10 ] Anionic Framework KLiYP 3 O 10

    European Journal of Inorganic Chemistry · 2026-09-15

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  27. Three Rare‐Earth Metal Borates Synthesized via a Cation Substitution Strategy as Potential Zero‐Order Waveplate Materials

    Advanced Optical Materials · 2026-09-30

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