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(3‐C6H10N2)ZnX4 (X = Cl and Br): Two Excellent UV Nonlinear Optical Crystals Designed by Combination of π‐conjugated and [ZnX4]2− Tetrahedral Units

Chuanying Shen, Jie Liu, Defu Sun, Kang Yang, Bingbing Zhang, Kui Wu, Jiyang Wang, Duanliang Wang

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(3‐C6H10N2)ZnX4 (X = Cl and Br): Two Excellent UV Nonlinear Optical Crystals Designed by Combination of π‐conjugated and [ZnX4]2− Tetrahedral UnitsOriginalLigand substitution in organic–inorganic hybrid zinc iodides for second-harmonic generation7Strong second-harmonic generation response in an organic–inorganic hybrid antimony bromide1Multifunctional Cd‐based Hybrid with Large Birefringence Achieving Excellent Second Harmonic Generation and Reversible Temperature‐Activated Fluorescence for Anti‐counterfeiting16Halogen-Engineered Copper-Based Materials with Multicolor Emission for Dual-Functional Anticounterfeiting and LED Applications9Designing Hybrid Sb-Based Nonlinear Optical Crystals with Large Birefringence by Combining the Lone Pair and π-Conjugated Genes10Structural Evolution of Hybrid Bismuth-Based Halides toward Enhanced Second-Harmonic Generation Response and Birefringence through Multisite Chemical Substitution7Achieving Dual-Color Luminescence via Halogen Regulation in Copper-Based Halides for Anticounterfeiting3Investigation of the growth, linear optical, and nonlinear optical (NLO) characteristics of 1-methyl-2-[2-(3,4,5-Trimethoxy-phenyl)-vinyl]-pyridinium+anthraquinone-2-sulfonate−dihydrate (TMAS) organic single crystal3Organic Halogen Substitution-Driven Halogen Bonding Induces Polar 3D Supramolecular Framework and Second-Harmonic-Generation Response7Remarkable Disparity of Second Harmonic Generation Response in Two Inorganic–Organic Hybrid Metal Thiocyanates5Tunable dual-emission in a hybrid [Ph3PH]2[ZnI4] system: The role of {ZnI…HP} interactions and proton transfer in 3ILCT/3L(X + M)CT phosphorescence1Efficient Mn 2+ Red Emission in a Hybrid Halide Induced by Octahedral Distortion3A Cu + -doped zinc organic halide with temperature-dependent dual-color emission as a thermochromic molecular thermometer2Enhanced Photoluminescence in Hybrid Manganese Halides via Halogen Regulation for LED Applications10Na2(C6H4NO3)2·H2O: A promising ultraviolet nonlinear optical crystal with strong second-harmonic generation effect and large birefringence1Chiral-Unit-Driven Short-Wave Ultraviolet Nonlinear Optical Acetates with Balanced Overall Optical Properties3Strategically designed deep-ultraviolet optical crystals with balanced properties by small heteroatom substitution1Confinement-assembled ultraviolet nonlinear optical crystal from pyridine-expanded π-systems with exhibiting strong SHG and birefringence18The modulation of structural polarity facilitating the gradient enhancement of second harmonic generation effects in hybrid metal halides5Hybrid Cd 2+ -Based Halide Birefringent Crystals Achieving Tunable Dual-Color Emission for Multifunctional LED and Anticounterfeiting Applications2C 6 H 7 NCl·X (X = Cl, Br): Outstanding Multifunctional Nonlinear Optical and Birefringent Crystals Enabled by Incorporation of π‐Conjugated Moieties2A New Zn(II) Hybrid Crystal: Structural, Thermal, Non‐Linear Optical, Quantum Chemical Study and Antioxidant Investigations of 2‐Amino‐4‐methylpyridinium Tetrahalozincate(II)0D‐π‐A Type Pure Organic Small Molecular Nonlinear Optical Materials in Quantum Information Technology0Halogen-Driven Modulation of Structural Symmetry and Optical Properties in Hybrid Copper(I) Halides: Tunable Luminescence, Birefringence, and Composition-Dependent Second-Harmonic Generation0Assembly of dual π-conjugated units toward enhanced birefringence in a 2D organic sulfonate crystal0Short-UV Metal Halide Nitrates: Moderate SHG in K3Sb(NO3)3F3 and Enhanced Optical Anisotropy in K3Zn(NO3)X4 (X = Cl, Br)0

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  1. Ligand substitution in organic–inorganic hybrid zinc iodides for second-harmonic generation

    Dalton Transactions · 2025-01-01

    Juan Cheng, Gangji Yi, Ying Long, Qinglan Zhong, Guohong Zou, Lindong Luan, Zhien Lin

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  2. Strong second-harmonic generation response in an organic–inorganic hybrid antimony bromide

    Dalton Transactions · 2025-01-01

    Xuemei Wen, Gangji Yi, Qinglan Zhong, Caihong Guo, Hongmei Zeng, Guohong Zou, Zhien Lin

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  3. Multifunctional Cd‐based Hybrid with Large Birefringence Achieving Excellent Second Harmonic Generation and Reversible Temperature‐Activated Fluorescence for Anti‐counterfeiting

    Advanced Optical Materials · 2025-05-21

    Duanliang Wang, Qiwei Xing, Defu Sun, Chuanrui Zhu, Kui Wu, Bingbing Zhang, Guangxia Liu, Jiyang Wang, Chuanying Shen

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  4. Halogen-Engineered Copper-Based Materials with Multicolor Emission for Dual-Functional Anticounterfeiting and LED Applications

    ACS Applied Materials & Interfaces · 2025-07-22

    Chenyi Zhang, Duanliang Wang, Chuanrui Zhu, Xiao‐Wu Lei, Lingqiang Meng, Chuanying Shen

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  5. Designing Hybrid Sb-Based Nonlinear Optical Crystals with Large Birefringence by Combining the Lone Pair and π-Conjugated Genes

    Inorganic Chemistry · 2025-07-28

    Kang Yang, Duanliang Wang, Fangcong Liu, Chuanrui Zhu, Qiyao Wang, Kui Wu, Jiyang Wang, Chuanying Shen

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  6. Structural Evolution of Hybrid Bismuth-Based Halides toward Enhanced Second-Harmonic Generation Response and Birefringence through Multisite Chemical Substitution

    Inorganic Chemistry · 2025-07-28

    Yifan Fu, Wen‐Dong Yao, Qiao‐Feng Huang, Shufang Yan, Wenlong Liu, Jiajing Wu

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  7. Achieving Dual-Color Luminescence via Halogen Regulation in Copper-Based Halides for Anticounterfeiting

    Inorganic Chemistry · 2025-08-20

    Chenyi Zhang, Chuanrui Zhu, Baopeng Shan, Jiaxi Ding, Xiao‐Wu Lei, Longyun Xu, Chuanying Shen

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  8. Investigation of the growth, linear optical, and nonlinear optical (NLO) characteristics of 1-methyl-2-[2-(3,4,5-Trimethoxy-phenyl)-vinyl]-pyridinium+anthraquinone-2-sulfonate−dihydrate (TMAS) organic single crystal

    Journal of Molecular Structure · 2025-09-06

    Raji Vinayagamoorthy, Anand Sekar, L. Poornima, Ravi Shanker Babu, M. Usha Rani

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  9. Organic Halogen Substitution-Driven Halogen Bonding Induces Polar 3D Supramolecular Framework and Second-Harmonic-Generation Response

    Inorganic Chemistry · 2025-09-17

    Mingchang Wang, Jiajia Li, Yan Chen, Ke‐Zhao Du, Jin Chen

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  10. Remarkable Disparity of Second Harmonic Generation Response in Two Inorganic–Organic Hybrid Metal Thiocyanates

    Inorganic Chemistry · 2025-09-19

    Xuemei Wen, Yue Zhou, Qinglan Zhong, Jing Li, Guohong Zou, Zhien Lin

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  11. Tunable dual-emission in a hybrid [Ph3PH]2[ZnI4] system: The role of {ZnI…HP} interactions and proton transfer in 3ILCT/3L(X + M)CT phosphorescence

    Journal of Photochemistry and Photobiology A Chemistry · 2025-11-04

    Alexey S. Berezin

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  12. Efficient Mn 2+ Red Emission in a Hybrid Halide Induced by Octahedral Distortion

    Advanced Optical Materials · 2025-11-17

    Yibo Cui, Jiawei Lin, Kunjie Liu, Yuhe Shao, Lingyu Chi, Ruonan Yao, Haonan Wu, Zhongnan Guo, Jing Wei Zhao, Quanlin Liu

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  13. A Cu + -doped zinc organic halide with temperature-dependent dual-color emission as a thermochromic molecular thermometer

    Dalton Transactions · 2025-11-29

    Yu‐Fang Wu, Ya-Hui Li, Zhi-Meng Sui, Yu-Kun Wei, Ruihan Wei, Xi Chen, Xiao Yang, Zhiwei Chen, Zhihong Jing, Cheng‐Yang Yue

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  14. Enhanced Photoluminescence in Hybrid Manganese Halides via Halogen Regulation for LED Applications

    Inorganic Chemistry · 2025-12-09

    Chuanying Shen, Jie Liu, Zhengao Xie, Xun-Wang Yan, Chuanrui Zhu, Xiao‐Wu Lei, Duanliang Wang

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  15. Na2(C6H4NO3)2·H2O: A promising ultraviolet nonlinear optical crystal with strong second-harmonic generation effect and large birefringence

    Chinese Journal of Structural Chemistry · 2025-12-23

    Xuan Pang, Leyan Nian, Yongzhang Wang, Chunmei Huang

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  16. Chiral-Unit-Driven Short-Wave Ultraviolet Nonlinear Optical Acetates with Balanced Overall Optical Properties

    The Journal of Physical Chemistry Letters · 2025-12-26

    Zi-Xuan Zhao, Wei Chen, Hui‐Yan Zhao, Mengjiao Xu, Chao He, Qi Wei, Guo-Ming Wang

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  17. Strategically designed deep-ultraviolet optical crystals with balanced properties by small heteroatom substitution

    Inorganic Chemistry Frontiers · 2026-01-01

    Mei Hu, Zhencheng Wu, Xin Su, Hongheng Chen, Qun Jing, Zhaohui Chen, Ming‐Hsien Lee

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  18. Confinement-assembled ultraviolet nonlinear optical crystal from pyridine-expanded π-systems with exhibiting strong SHG and birefringence

    Science China Chemistry · 2026-01-04

    Chunmei Huang, Xuan Pang, Fuming M. Li, Shumei Cao, Shilie Pan, Miriding Mutailipu

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  19. The modulation of structural polarity facilitating the gradient enhancement of second harmonic generation effects in hybrid metal halides

    Science China Chemistry · 2026-01-04

    Ru‐Ling Tang, Die-Xue Yang, Jian-Dong Guo, C. Z. Chen, Wenlong Liu, Sheng‐Ping Guo

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  20. Hybrid Cd 2+ -Based Halide Birefringent Crystals Achieving Tunable Dual-Color Emission for Multifunctional LED and Anticounterfeiting Applications

    ACS Applied Materials & Interfaces · 2026-01-14

    Duanliang Wang, Qiwei Xing, Zhengao Xie, Xunwang Yan, Chuanrui Zhu, Bingbing Zhang, Xiao‐Wu Lei, Chuanying Shen

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  21. C 6 H 7 NCl·X (X = Cl, Br): Outstanding Multifunctional Nonlinear Optical and Birefringent Crystals Enabled by Incorporation of π‐Conjugated Moieties

    Advanced Optical Materials · 2026-02-28

    Chuanying Shen, Jiaxi Ding, Zhengao Xie, Kang Yang, Xunwang Yan, Bingbing Zhang, Kui Wu, Jiyang Wang, Duanliang Wang

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  22. A New Zn(II) Hybrid Crystal: Structural, Thermal, Non‐Linear Optical, Quantum Chemical Study and Antioxidant Investigations of 2‐Amino‐4‐methylpyridinium Tetrahalozincate(II)

    ChemistrySelect · 2026-05-28

    N. Archana, Mageswaran Vijayasri, Krishnaraj Dayanidhi, S. Parthiban, Karuppasamy Pichan

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  23. D‐π‐A Type Pure Organic Small Molecular Nonlinear Optical Materials in Quantum Information Technology

    Advanced Quantum Technologies · 2026-09-01

    Chuanxin Liao, Jialong Cui, D H Zhang, Qi Zhang, Xiaofu Zhang, Yunru Fan, 郭光灿, Qiang Zhou

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  24. Halogen-Driven Modulation of Structural Symmetry and Optical Properties in Hybrid Copper(I) Halides: Tunable Luminescence, Birefringence, and Composition-Dependent Second-Harmonic Generation

    Inorganic Chemistry · 2026-09-09

    Man Xu, Hai‐Ping Xu, Ji‐Fen Guo, Ming Liu, Ye-Hang Chen, Sheng‐Ping Guo

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  25. Assembly of dual π-conjugated units toward enhanced birefringence in a 2D organic sulfonate crystal

    Science China Chemistry · 2026-09-15

    Longyun Xu, Hanjing Huang, Conggang Li, Huijian Zhao, Conghe Liu, Kaidong Xu, Jina Wang, Ning Ye, Zhanggui Hu

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  26. Short-UV Metal Halide Nitrates: Moderate SHG in K3Sb(NO3)3F3 and Enhanced Optical Anisotropy in K3Zn(NO3)X4 (X = Cl, Br)

    Inorganic Chemistry · 2026-09-28

    Xiangtian Liu, Bingchen Xiao, Lei Hou, Wencong Li, Wenlong Zhao, Kaixin Yin, Haonan Pei, Xiaonan Li, Zhuangzhuang Dong, Lili Liu

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