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RESEARCH PAPER · Angewandte Chemie · 2018

Learning from a Mineral Structure toward an Ultra‐Narrow‐Band Blue‐Emitting Silicate Phosphor RbNa3(Li3SiO4)4:Eu2+

Hongxu Liao, Ming Zhao, Мaxim S. Моlokeev, Quanlin Liu, Zhiguo Xia

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Learning from a Mineral Structure toward an Ultra‐Narrow‐Band Blue‐Emitting Silicate Phosphor RbNa3(Li3SiO4)4:Eu2+OriginalControl of Narrow-Band Emission in Phosphor Materials for Application in Light-Emitting Diodes160Emerging substance class with narrow-band blue/green-emitting rare earth phosphors for backlight display application31Moisture‐Resistant Mn4+‐Doped Core–Shell‐Structured Fluoride Red Phosphor Exhibiting High Luminous Efficacy for Warm White Light‐Emitting Diodes176Moisture‐Resistant Mn4+‐Doped Core–Shell‐Structured Fluoride Red Phosphor Exhibiting High Luminous Efficacy for Warm White Light‐Emitting Diodes35One‐Step Loading on Natural Mineral Halloysite Nanotube: An Effective Way to Enhance the Stability of Perovskite CsPbX3 (X = Cl, Br, I) Quantum Dots46Design of a novel scandium silicate based blue-emitting phosphor with high efficiency and robust thermal stability for warm WLEDs and field emission displays36Functional layered materials with heavy metal lone pair cations, Pb 2+ , Bi 3+ , and Te 4+90Discovery of New Narrow‐Band Phosphors with the UCr 4 C 4 ‐Related Type Structure by Alkali Cation Effect137Layered Bismuth Oxyfluoride Nitrates Revealing Large Second-Harmonic Generation and Photocatalytic Properties37The exploration of structure evolution and photoluminescence property in Ca9Al1-Y (PO4)7:Eu2+ solid solution phosphors via the construction of bi-directional relationships30Realizing Visible Light Excitation of Tb3+ via Highly Efficient Energy Transfer from Ce3+ for LED‐Based Applications63Green and red emitting YBO3:Ln3+ (Ln=Eu, Tb) phosphors for detection of latent fingerprint56Ca 2 Na 2 La 6 (SiO 4 ) 4 (PO 4 ) 2 O: Eu 2+ /Eu 3+ : A visual dual‐emitting fluorescent ratiometric temperature sensor30Structural Evolution and Effect of the Neighboring Cation on the Photoluminescence of Sr(LiAl 3 ) 1− x (SiMg 3 ) x N 4 :Eu 2+ Phosphors70Structural Evolution and Effect of the Neighboring Cation on the Photoluminescence of Sr(LiAl3)1−x(SiMg3)xN4:Eu2+ Phosphors11Emerging ultra-narrow-band cyan-emitting phosphor for white LEDs with enhanced color rendition515Cation Substitution Induced Adjustment on Lattice Structure and Photoluminescence Properties of Mg14Ge5O24:Mn4+: Optimized Emission for w‐LED and Thermometry Applications99The structure and photoluminescence properties of a novel orange emission phosphor Ba3Sc1.9Al0.1B4O12: Eu2+ excited by NUV light10Application of thermally coupled energy levels in Er3+ doped CdMoO4 phosphors: Enhanced solid-state lighting and non-contact thermometry48High thermal stable blue-emitting alkali silicate phosphor, Eu2+-activated Na2Mg2Si6O151Site‐Selective Occupancy of Eu 2+ Toward Blue‐Light‐Excited Red Emission in a Rb 3 YSi 2 O 7 :Eu Phosphor221Site‐Selective Occupancy of Eu2+Toward Blue‐Light‐Excited Red Emission in a Rb3YSi2O7:Eu Phosphor102Eu3+-Activated NaGdF4 Nanorods for Near-Ultraviolet Light-Triggered Indoor Illumination89Full visible spectra emission introduced by crystal-site engineering in β-Ca3(PO4)2-type solid solution phosphors for high quality white light emitting diodes application63Novel cyan‐emitting KBaScSi 2 O 7 :Eu 2+ phosphors with ultrahigh quantum efficiency and excellent thermal stability for WLEDs57Ultra-narrow band blue-emitting Ba5SiO4Cl6: Eu2+ phosphors with excellent thermal stability18Data-Driven Discovery of Full-Visible-Spectrum Phosphor133Trap distribution and photo‐stimulated luminescence in LaSrAl 3 O 7 :Eu 2+ long‐lasting phosphors for optical data storage43Zero‐Thermal Quenching of Mn2+ Red Luminescence via Efficient Energy Transfer from Eu2+ in BaMgP2O7113UV or blue light excited red persistent perovskite phosphor with millisecond lifetime for use in AC‐LEDs12A Double‐Band Emitter with Ultranarrow‐Band Blue and Narrow‐Band Green Luminescence15Design, synthesis, crystal structure and luminescent properties of a new tantalum-phosphate K 3 BiTaP 3 O 13 with negligible concentration quenching and good thermostability22Closing the Cyan Gap Toward Full-Spectrum LED Lighting with NaMgBO3:Ce3+170A K 3 ScSi 2 O 7 :Eu 2+ based phosphor with broad-band NIR emission and robust thermal stability for NIR pc-LEDs109A useful valence-alterable optical probe for the prediction of material characteristics based on theoretical calculations5Full-visible-spectrum lighting realized by a novel Eu 2+ -doped cyan-emitting borosilicate phosphor25Phase stabilization of red-emitting olivine-type NaMgPO 4 :Eu 2+ phosphors via molten-phase quenching29Cuboid-Size-Controlled Color-Tunable Eu-Doped Alkali–Lithosilicate Phosphors85Recent progress on discovery of novel phosphors for solid state lighting88Eu2+-doped ultra-broadband VIS-NIR emitting phosphor126Design rule for the emission linewidth of Eu 2+ -activated phosphors14Dual‐Shelled RbLi(Li 3 SiO 4 ) 2 :Eu 2+ @Al 2 O 3 @ODTMS Phosphor as a Stable Green Emitter for High‐Power LED Backlights90Dual‐Shelled RbLi(Li3SiO4)2:Eu2+@Al2O3@ODTMS Phosphor as a Stable Green Emitter for High‐Power LED Backlights8Violet-light-excitable super-narrow band green emitting phosphor for high-quality white LEDs9Thermally Stable Phosphor KBa2(PO3)5:Eu2+ with Broad-Band Cyan Emission Caused by Multisite Occupancy of Eu2+57A novel narrow-band blue-emitting phosphor of Bi3+-activated Sr3Lu2Ge3O12 based on a highly symmetrical crystal structure used for WLEDs and FEDs183Illuminating Nitridoberylloaluminates: The Highly Efficient Red-Emitting Phosphor Sr2[BeAl3N5]:Eu2+39Narrow-band emitters in LED backlights for liquid-crystal displays217Broadband NaK2Li[Li3SiO4]4:Ce Alkali Lithosilicate Blue Phosphors19A high efficient and anti-thermal dual-emission blue-green phosphors for warm white LEDs3Zero-thermal-quenching and improved chemical stability of a UCr4C4-type phosphor via crystal site engineering42A novel broad-band cyan light-emitting oxynitride based phosphor used for realizing the full-visible-spectrum lighting of WLEDs21A data-driven approach to predicting band gap, excitation, and emission energies for Eu 2+ -activated phosphors28A novel red-emitting phosphor Mg 2 Y 2 Al 2 Si 2 O 12 :Ce 3+ /Mn 2+ for blue chip-based white LEDs8Full spectrum light-emitting diodes based on a new efficient zirconium silicate green phosphor for healthy lighting29Highly efficient blue-emitting phosphor of Sr[B 8 O 11 (OH) 4 ]:Eu 2+ prepared by a self-reduction method19Luminescence property improvement and controllable color regulation of a novel Bi 3+ doped Ca 2 Ta 2 O 7 green phosphor through charge compensation engineering and energy transfer19Improving the thermal stability and luminescent efficiency of (Ba,Sr)3SiO5:Eu2+ phosphors by structure, bandgap engineering and soft chemistry synthesis method98Vacancies Substitution Tuning Photoluminescence and Distortion Triggered Eu Migration in NASICON-Type Phosphors11Superior thermally-stable narrow-band green emitter from Mn2+-doped zero thermal expansion (ZTE) material78Creating a Green-Emitting Phosphor through Selective Rare-Earth Site Preference in NaBaB 9 O 15 :Eu 2+68The angular overlap model of ligand field theory for f elements: An intuitive approach building bridges between theory and experiment39Rb[Li5Si2O7] – A Latecomer in the Family of Alkali Lithosilicates Hiding a Green‐Emitting Lithosilicate2Designing a Thermally Robust Green-Emitting Phosphor Rb2HfSi2O7: Eu2+ by an Atomic Chain Vibration Model and Its White Light-Emitting Diode Application16Ba 2+ -driven site-selective substitution of Mn 2+ ions and persistent luminescence of Sr 1-x Ba x Ga 2 Si 2 O 8 :Mn 2+ phosphors3Design of a broadband cyan-emitting phosphor with robust thermal stability for high-power WLED application52Importance of Long‐Range Channel Sr Displacements for the Narrow Emission in Sr[Li2Al2O2N2]:Eu2+ Phosphor20Ca[B 8 O 11 (OH) 4 ] : Eu 2+ – A Highly Efficient Deep Blue‐Emitting Phosphor Prepared by Low‐Temperature Self‐reduction12Novel Narrow Band Cyan‐Green Phosphor LiK 7 [Li 3 SiO 4 ] 8 :Eu 2+ with Enhanced Suppression of Second Broad Band Emission17Linking Macro- and Micro-structural Analysis with Luminescence Control in Oxynitride Phosphors for Light-Emitting Diodes13Eu3Be22N16O: A Highly Condensed Oxonitridoberyllate1Chasing Down the Eu2+ Ions: The Delicate Structure−Property Relationships in the Ultra‐Narrow Band Phosphor K1.6Na2.1Li0.3[Li3SiO4]4:Eu2+35Machine learning identification of experimental conditions for the synthesis of single-phase white phosphors19Structure tailoring and defect engineering of LED phosphors with enhanced thermal stability and superior quantum efficiency44Development of narrow band emitting phosphors for backlighting displays and solid state lighting using a clean and green energy technology22Designing a novel Eu 2+ -doped hafnium-silicate phosphor for an energy-down-shift layer of CsPbI 3 solar cells9Sc dopant induced tailoring of persistent luminescence in Na 3 YSi 3 O 9 :Eu 2+ for information recording8The crystal structure and luminescence properties of the first lithium oxonitridolithosilicate Li 3 SiNO 2 :Eu 2+8Microscopic Mechanism of the Heat‐Induced Blueshift in Phosphors and a Logarithmic Energy Dependence on the Nearest Dopant–Vacancy Distance24Microscopic Mechanism of the Heat‐Induced Blueshift in Phosphors and a Logarithmic Energy Dependence on the Nearest Dopant–Vacancy Distance1Preparation of M2B5O9Cl:Eu2+ (M=Sr, Ca) blue phosphors by a facile low-temperature self-reduction method and their enhanced luminescent properties25Role of the Rigid Host Structure in Narrow-Band Green Emission of Eu2+ in Rb2Na2(Li3SiO4)4: Insights into Electron–Phonon Coupling15Evolutionary Generation of Phosphor Materials and Their Progress in Future Applications for Light-Emitting Diodes563Blue light‐excitable Eu‐doped yellow emitting borate KSr 4 B 3 O 9 phosphor for white light‐emitting diodes14Design of a europium‐activated lithium‐silicate cyan phosphor via cation substitution3Ultrastable Photoluminescence Enabled by 1D Rare-Earth Metal–Organic Frameworks Based on Double Thiacalix[4]arene-Capped Nodes19Seeking new, ultra-narrow-band blue emitting phosphors with high color purity for wide color gamut displays24Novel near-ultraviolet-excited and thermally-stable blue-emitting phosphor for healthy WLED lighting30Highly efficient and thermally stable MnII-based phosphor-in-glass towards warm WLED4Recent progress in Ce 3+ /Eu 2+ -activated LEDs and persistent phosphors: focusing on the local structure and the electronic structure137Ba 4 Al 7 Li 28.08 O 26.92 N 1.08 , the Barium Oxonitridolithoaluminate with a Highly Condensed LiO 4 Tetrahedra Framework3An Efficient Narrow-band Blue-emitting Phosphor Ba3Y2B6O15:Bi3+ and Its Application7Bright white electroluminescence from polycrystalline dysprosium-doped yttrium gallium garnet nanofilms fabricated by atomic layer deposition on silicon3Eu 2+ luminescence in CaYGaO 4 olivine: a new efficient red phosphor for warm illumination47Oxygen-vacancy rich in melilite to modulate the persistent luminescence for multi-functional applications17Broadband orange-emitting Sr 3Si 8O 4N 10:Eu 2+ phosphor discovered by a modified single-particle-diagnosis approach18Mixed Microscopic Eu 2+ Occupancies in the Next‐Generation Red LED Phosphor Sr[Li 2 Al 2 O 2 N 2 ]:Eu 2+ (SALON:Eu 2+ )37Ultra-small Stokes shift induced thermal robust efficient blue-emitting alkaline phosphate phosphors for LWUV WLEDs20Defect engineering towards anti-temperature quenching luminescence for application in light emitting diodes14A First-Principles Explanation of the Luminescent Line Shape of SrLiAl 3 N 4 :Eu 2+ Phosphor for Light-Emitting Diode Applications22Scalable Synthesis of Lead‐Free Tetramethylammonium Manganese Halides for Highly Efficient Backlight Displays42High-Quantum-Efficiency Blue Phosphors with Superior Thermal Stability Derived from Eu3+-Doped Faujasite Y Zeolite11Unusual red luminescence and super thermal stability of a new narrow-band emission phosphor for backlight display application21Narrow-band green phosphor RbK 2 Na(Li 3 SiO 4 ) 4 :Eu 2+ with excellent thermal stability and high efficiency for wide color gamut displays8Eu3+ hypersensitive transition modulation: A novel red garnet phosphors with high color purity and excellent thermal stability23Advanced Effect of the Substitution of Zn2+ on the Solid‐State Synthesis of Red Phosphor, High Temperature Phase NaMgPO4:Eu2+20Polyhedron Distortion and Site-Specific Rigidity in Garnet-Type Compounds7A Strategy for the Synthesis of Oxonitridosilicate Phosphors from Anionic Condensation8Reduction mechanism and energy transfer between Eu 3+ and Eu 2+ in Eu-doped materials synthesized in air atmosphere23Elucidation of trap energies of Gamma-irradiated BaMgAl10O17: Ce3+ phosphors for dosimetry applications1Isomorphism of Sr[Li3AlO4] and Sr[Li3GaO4] – Syntheses, Crystal Structure, and Europium(II) Luminescence8Optimization of blue-cyan emitting Bi3+-doped phosphors for NUV-driven WLEDs19Highly Efficient and Stable Narrow Band Green Emitting Phosphor of Sb 3+ /Ce 3+ Sensitized Cs 2 NaTbCl 6 for WLED36Achieving Eu 2+ Luminescence at Trivalent Lattice Site in Rb 3 Y(PO 4 ) 2 :Eu toward Multicolor Emissions by Carbon and Hydrogen Coreduction23Efficient narrow-band green phosphors for mini-LED displays using dual strategies of high concentration quenching and energy transfer13First-principles study of the electronic structure and optical properties of Eu2+ and Mn2+-doped NaLi3SiO4 phosphor2Prediction and explanation of the self-reduction of Eu3+ → Eu2+ and Mn4+ → Mn2+ using Site Occupancy Theory (SOT)6A narrow band blue phosphor NaBa 4 Al 2 B 8 O 18 Cl 3 :Eu 2+ for white light emitting diodes5A thermally stable Ce3+ activated green phosphor for illuminating and temperature sensing application10Structure regulation induced novel narrow-band blue light-emitting Eu2+-Activated nitroaluminosilicate phosphor for WLEDs and FEDs applications1Development of Eu 2+ ‐Doped UCr 4 C 4 ‐Type Phosphors Toward Advanced Display Applications22Chemical Pressure‐Induced FWHM Narrowing in Narrowband Green Phosphors for Laser Displays with Ultra‐High Saturation Thresholds9Activator – host structure relations of applied optical materials: a review7Narrow‐Band Green Phosphors for Advanced Display Technologies: Material Design, Performance Optimization, and Future Prospects6Ba2Y[BO3][Si2O6]:Ce3+ phosphor with high-efficiency blue emission and excellent quantum yield enabled by mixed-dimensional anionic framework engineering7In Situ Tandem Synthesis of Charged Boron‐Oxo Clusters into Highly Ordered Architectures0Chromium-activated phosphors: from theory to applications23Composites based on Eu2+-activated LiSr₄(BO₃)₃ as broadband red components for LEDs1A Non‐Stoichiometric Thioaluminate Phosphor with Severe Stacking Faults, Na 0.9 AlS 2 :Eu 2+1

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  1. Control of Narrow-Band Emission in Phosphor Materials for Application in Light-Emitting Diodes

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  2. Emerging substance class with narrow-band blue/green-emitting rare earth phosphors for backlight display application

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  3. Moisture‐Resistant Mn4+‐Doped Core–Shell‐Structured Fluoride Red Phosphor Exhibiting High Luminous Efficacy for Warm White Light‐Emitting Diodes

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  5. One‐Step Loading on Natural Mineral Halloysite Nanotube: An Effective Way to Enhance the Stability of Perovskite CsPbX3 (X = Cl, Br, I) Quantum Dots

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  6. Design of a novel scandium silicate based blue-emitting phosphor with high efficiency and robust thermal stability for warm WLEDs and field emission displays

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  7. Functional layered materials with heavy metal lone pair cations, Pb 2+ , Bi 3+ , and Te 4+

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  8. Discovery of New Narrow‐Band Phosphors with the UCr 4 C 4 ‐Related Type Structure by Alkali Cation Effect

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  9. Layered Bismuth Oxyfluoride Nitrates Revealing Large Second-Harmonic Generation and Photocatalytic Properties

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  10. The exploration of structure evolution and photoluminescence property in Ca9Al1-Y (PO4)7:Eu2+ solid solution phosphors via the construction of bi-directional relationships

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  11. Realizing Visible Light Excitation of Tb3+ via Highly Efficient Energy Transfer from Ce3+ for LED‐Based Applications

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  12. Green and red emitting YBO3:Ln3+ (Ln=Eu, Tb) phosphors for detection of latent fingerprint

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  13. Ca 2 Na 2 La 6 (SiO 4 ) 4 (PO 4 ) 2 O: Eu 2+ /Eu 3+ : A visual dual‐emitting fluorescent ratiometric temperature sensor

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  14. Structural Evolution and Effect of the Neighboring Cation on the Photoluminescence of Sr(LiAl 3 ) 1− x (SiMg 3 ) x N 4 :Eu 2+ Phosphors

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  15. Structural Evolution and Effect of the Neighboring Cation on the Photoluminescence of Sr(LiAl3)1−x(SiMg3)xN4:Eu2+ Phosphors

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  16. Emerging ultra-narrow-band cyan-emitting phosphor for white LEDs with enhanced color rendition

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  17. Cation Substitution Induced Adjustment on Lattice Structure and Photoluminescence Properties of Mg14Ge5O24:Mn4+: Optimized Emission for w‐LED and Thermometry Applications

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  18. The structure and photoluminescence properties of a novel orange emission phosphor Ba3Sc1.9Al0.1B4O12: Eu2+ excited by NUV light

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  19. Application of thermally coupled energy levels in Er3+ doped CdMoO4 phosphors: Enhanced solid-state lighting and non-contact thermometry

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  20. High thermal stable blue-emitting alkali silicate phosphor, Eu2+-activated Na2Mg2Si6O15

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  21. Site‐Selective Occupancy of Eu 2+ Toward Blue‐Light‐Excited Red Emission in a Rb 3 YSi 2 O 7 :Eu Phosphor

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  22. Site‐Selective Occupancy of Eu2+Toward Blue‐Light‐Excited Red Emission in a Rb3YSi2O7:Eu Phosphor

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  23. Eu3+-Activated NaGdF4 Nanorods for Near-Ultraviolet Light-Triggered Indoor Illumination

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  24. Full visible spectra emission introduced by crystal-site engineering in β-Ca3(PO4)2-type solid solution phosphors for high quality white light emitting diodes application

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  25. Novel cyan‐emitting KBaScSi 2 O 7 :Eu 2+ phosphors with ultrahigh quantum efficiency and excellent thermal stability for WLEDs

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  26. Ultra-narrow band blue-emitting Ba5SiO4Cl6: Eu2+ phosphors with excellent thermal stability

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  27. Data-Driven Discovery of Full-Visible-Spectrum Phosphor

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  28. Trap distribution and photo‐stimulated luminescence in LaSrAl 3 O 7 :Eu 2+ long‐lasting phosphors for optical data storage

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  29. Zero‐Thermal Quenching of Mn2+ Red Luminescence via Efficient Energy Transfer from Eu2+ in BaMgP2O7

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  30. UV or blue light excited red persistent perovskite phosphor with millisecond lifetime for use in AC‐LEDs

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  31. A Double‐Band Emitter with Ultranarrow‐Band Blue and Narrow‐Band Green Luminescence

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  32. Design, synthesis, crystal structure and luminescent properties of a new tantalum-phosphate K 3 BiTaP 3 O 13 with negligible concentration quenching and good thermostability

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  33. Closing the Cyan Gap Toward Full-Spectrum LED Lighting with NaMgBO3:Ce3+

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  34. A K 3 ScSi 2 O 7 :Eu 2+ based phosphor with broad-band NIR emission and robust thermal stability for NIR pc-LEDs

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  35. A useful valence-alterable optical probe for the prediction of material characteristics based on theoretical calculations

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  36. Full-visible-spectrum lighting realized by a novel Eu 2+ -doped cyan-emitting borosilicate phosphor

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  37. Phase stabilization of red-emitting olivine-type NaMgPO 4 :Eu 2+ phosphors via molten-phase quenching

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  38. Cuboid-Size-Controlled Color-Tunable Eu-Doped Alkali–Lithosilicate Phosphors

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  39. Recent progress on discovery of novel phosphors for solid state lighting

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  40. Eu2+-doped ultra-broadband VIS-NIR emitting phosphor

    Chemical Engineering Journal · 2020-01-27

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  41. Design rule for the emission linewidth of Eu 2+ -activated phosphors

    Journal of Luminescence · 2020-04-03

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  42. Dual‐Shelled RbLi(Li 3 SiO 4 ) 2 :Eu 2+ @Al 2 O 3 @ODTMS Phosphor as a Stable Green Emitter for High‐Power LED Backlights

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  43. Dual‐Shelled RbLi(Li3SiO4)2:Eu2+@Al2O3@ODTMS Phosphor as a Stable Green Emitter for High‐Power LED Backlights

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    Ming Zhao, Kun Cao, Mengjia Liu, Jing Zhang, Rong Chen, Qinyuan Zhang, Zhiguo Xia

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  44. Violet-light-excitable super-narrow band green emitting phosphor for high-quality white LEDs

    Journal of Luminescence · 2020-04-29

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  45. Thermally Stable Phosphor KBa2(PO3)5:Eu2+ with Broad-Band Cyan Emission Caused by Multisite Occupancy of Eu2+

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  46. A novel narrow-band blue-emitting phosphor of Bi3+-activated Sr3Lu2Ge3O12 based on a highly symmetrical crystal structure used for WLEDs and FEDs

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  47. Illuminating Nitridoberylloaluminates: The Highly Efficient Red-Emitting Phosphor Sr2[BeAl3N5]:Eu2+

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  48. Narrow-band emitters in LED backlights for liquid-crystal displays

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  49. Broadband NaK2Li[Li3SiO4]4:Ce Alkali Lithosilicate Blue Phosphors

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  50. A high efficient and anti-thermal dual-emission blue-green phosphors for warm white LEDs

    Applied Physics A · 2020-08-18

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