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RESEARCH PAPER · Coordination Chemistry Reviews · 2023

Comprehensive review on multiple mixed-anion ligands, physicochemical performances and application prospects in metal oxysulfides

Jing Xu, Kui Wu

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Comprehensive review on multiple mixed-anion ligands, physicochemical performances and application prospects in metal oxysulfidesOriginalAn overview of Mg-based IR nonlinear optical materials23Heteroanion-introduction-driven birefringence enhancement in oxychalcogenide Ba 3 M II Ge 3 O 2 S 8 (M II = Mn, Cd)19Recent advances in IR nonlinear optical chalcogenides with well-balanced comprehensive performance57Breaking Through the Trade‐Off Between Wide Band Gap and Large SHG Coefficient in Mercury‐Based Chalcogenides for IR Nonlinear Optical Application49Cation and anion co-partial substitution induced centrosymmetric to noncentrosymmetric structural transformation to construct nonlinear-optical rare-earth oxythiogermanates13Chemical perspectives on heteroanionic compounds: a potential playground for multiferroics7Heteroanionic [VO x S 4− x ] groups: tetrahedral units with large birefringence for mid-infrared nonlinear optical crystals9Partial substitution with a significant effect: coexistence of a wide band gap and large birefringence in the oxychalcogenide AEGe 2 O 4 Se (AE = Sr and Ba)17Pb 6 Ba 3 Si 2 S 8 I 10 : a new thiohalide with a quasi-two-dimensional structure and wide band gap2Rare-earth-based chalcogenides and their derivatives: an encouraging IR nonlinear optical material candidate70Ba10In2Mn11Si3O12S18: First Hexanary Oxychalcogenide Containing an Infrequent Three-Dimensional Noncentrosysmmetric Framework8The first Hg-based oxychalcogenide Sr2HgGe2OS6: Achieving balanced IR nonlinear optical properties through synergistic cation and anion substitution28Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units66Ag 2 GeS 3 : A Diamond‐Like Chalcogenide as an IR Nonlinear Optical Material with Outstanding Second‐Harmonic Generation Response28Rational design and dynamic reconstruction of phosphorus-doped amorphous high-entropy oxysulfide for efficient overall alkaline water splitting22Balanced IR Nonlinear Optical Performance Achieved by Cation–Anion Module Cosubstitution in V-Based Salt-Inclusion Oxychalcogenides22Facile one-step synthesis of Fe-doped Mo 3 (O,S) 4− x /La 4 Mo 2 O 11 nanocomposites for efficient photodegradation of dye pollutants2Layered Anion‐Mixed Oxycompounds: Synthesis, Properties, and Applications29Oxygen‐Substitution Induced High‐Performance Nonlinear Optical Properties: Witnessed by the First Quaternary Oxythiostannate12Phosphonocarboxylates in Mixed‐Ligated Approach with Diverse Structural Features (0D to 3D), and Studies of Non‐Covalent Interactions for Revealed Proton Conduction0Zero-Dimensional Oxyselenide Ba12[(Ga2OSe5)3(Si2O7)]: Enhanced Optical Anisotropy through Heteroanionic Engineering4Eu(II) 4 Eu(III) 2 Ge 3 S 11 O 2 : a Single‐Element Mixed‐Valence Engineering Breakthrough for Strongly Enhanced Nonlinearity and Anisotropy in Rare‐Earth Oxysulfides8Assembly of Highly Polarizable “Linkers” with Heteroleptic Groups for Inducing Large Optical Anisotropy in Ba2SnIIGe3O8S and Ba3SnIIGe3O2S82Ba 3 S[SnOS 3 ] and [Ba 2 Sn]S[Ge 2 O 7 ]: two antiperovskite oxychalcogenides with good IR nonlinear optical performances2Tracing nitridation reaction toward efficient production of oxynitride glasses as hosts for bright luminescence centers0A Homoatomic Heteroleptic Coordination Strategy for Exceptional Infrared Linear and Nonlinear Optical Properties in ANb 2 PS 4 (S 2 ) 3 (A = K,Rb,Cs)3Hydrophilic Ligand‐Assisted Synthesis of Water‐Dispersible Transition Metal Sulfide Nanoparticles1Achieving phase matching in infrared nonlinear optical crystal Cd3ZnSiS6 via isovalent substitution from Cd4SiS60High‐Performance Infrared Nonlinear Optical Crystals Discovery Guided by High‐Throughput Computation, Machine Learning, and Experimental Verification6High‐Performance Infrared Nonlinear Optical Crystals Discovery Guided by High‐Throughput Computation, Machine Learning, and Experimental Verification3Heterometallic Ge–O–Sn-Bridged Oxychalcogenides Sr3GeSnO4Q3 (Q = S, Se) with Wide Band Gaps and Moderate Infrared Nonlinear Optical Responses0Single and Binary Adsorption of Methyl Orange and Phosphate onto Magnesium Oxysulfite/Sulfate: Equilibrium, Kinetics, and Surface Interactions0

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  1. An overview of Mg-based IR nonlinear optical materials

    Inorganic Chemistry Frontiers · 2023-01-01

    Jiaxiang Zhang, Mao‐Yin Ran, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  2. Heteroanion-introduction-driven birefringence enhancement in oxychalcogenide Ba 3 M II Ge 3 O 2 S 8 (M II = Mn, Cd)

    Inorganic Chemistry Frontiers · 2023-01-01

    Shenghua Zhou, Mao‐Yin Ran, Wenbo Wei, A-Yang Wang, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  3. Recent advances in IR nonlinear optical chalcogenides with well-balanced comprehensive performance

    Materials Today Physics · 2023-05-26

    Hedi Yang, Mao‐Yin Ran, Wenbo Wei, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  4. Breaking Through the Trade‐Off Between Wide Band Gap and Large SHG Coefficient in Mercury‐Based Chalcogenides for IR Nonlinear Optical Application

    Small · 2023-10-02

    Mao‐Yin Ran, Shenghua Zhou, Wenbo Wei, Bingxuan Li, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  5. Cation and anion co-partial substitution induced centrosymmetric to noncentrosymmetric structural transformation to construct nonlinear-optical rare-earth oxythiogermanates

    Inorganic Chemistry Frontiers · 2024-01-01

    Nan Zhang, Mei Yang, Wen‐Dong Yao, Wei Xu, Wenfeng Zhou, Wenlong Liu, Sheng‐Ping Guo

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  6. Chemical perspectives on heteroanionic compounds: a potential playground for multiferroics

    Materials Chemistry Frontiers · 2024-01-01

    Karishma Prasad, Vivian Nguyen, Bingheng Ji, Jasmine Quah, Danielle Goodwin, Jian Wang

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  7. Heteroanionic [VO x S 4− x ] groups: tetrahedral units with large birefringence for mid-infrared nonlinear optical crystals

    Inorganic Chemistry Frontiers · 2024-01-01

    Shengzi Zhang, Linfeng Dong, Bohui Xu, Huige Chen, Hao Huo, Fei Liang, Rui Fen Wu, Pifu Gong, Zheshuai Lin

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  8. Partial substitution with a significant effect: coexistence of a wide band gap and large birefringence in the oxychalcogenide AEGe 2 O 4 Se (AE = Sr and Ba)

    Inorganic Chemistry Frontiers · 2024-01-01

    Mao‐Yin Ran, Shenghua Zhou, Wenbo Wei, A-Yang Wang, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  9. Pb 6 Ba 3 Si 2 S 8 I 10 : a new thiohalide with a quasi-two-dimensional structure and wide band gap

    Dalton Transactions · 2024-01-01

    Zhao Wang, Jiazheng Zhou, Linan Wang, Wenqi Jin, Yingying Kong, Yu Chu, Junjie Li

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  10. Rare-earth-based chalcogenides and their derivatives: an encouraging IR nonlinear optical material candidate

    Chemical Science · 2024-01-01

    Ping Feng, Jiaxiang Zhang, Mao‐Yin Ran, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  11. Ba10In2Mn11Si3O12S18: First Hexanary Oxychalcogenide Containing an Infrequent Three-Dimensional Noncentrosysmmetric Framework

    Inorganic Chemistry · 2024-02-23

    A-Yang Wang, Mao‐Yin Ran, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  12. The first Hg-based oxychalcogenide Sr2HgGe2OS6: Achieving balanced IR nonlinear optical properties through synergistic cation and anion substitution

    Materials Today Physics · 2024-04-17

    Mao‐Yin Ran, Shenghua Zhou, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  13. Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units

    Coordination Chemistry Reviews · 2024-07-03

    Bo Zhang, Mao‐Yin Ran, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  14. Ag 2 GeS 3 : A Diamond‐Like Chalcogenide as an IR Nonlinear Optical Material with Outstanding Second‐Harmonic Generation Response

    Advanced Optical Materials · 2024-07-04

    Hong Chen, Mao‐Yin Ran, Shenghua Zhou, Xin‐Tao Wu, Hua Lin

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  15. Rational design and dynamic reconstruction of phosphorus-doped amorphous high-entropy oxysulfide for efficient overall alkaline water splitting

    Chemical Engineering Journal · 2024-10-10

    Han-Ming Zhang, Jiakang Li, Chengcheng Dong, Caizhen Zhu, Jian Xu, Lihao Zuo, Jinfeng Sun

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  16. Balanced IR Nonlinear Optical Performance Achieved by Cation–Anion Module Cosubstitution in V-Based Salt-Inclusion Oxychalcogenides

    Chemistry of Materials · 2024-12-03

    Mao-Yin Ran, Sheng-Hua Zhou, Bingxuan Li, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  17. Facile one-step synthesis of Fe-doped Mo 3 (O,S) 4− x /La 4 Mo 2 O 11 nanocomposites for efficient photodegradation of dye pollutants

    New Journal of Chemistry · 2025-01-01

    Sleshi Fentie Tadesse, Worku Lakew Kebede, Dong–Hau Kuo

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  18. Layered Anion‐Mixed Oxycompounds: Synthesis, Properties, and Applications

    Advanced Science · 2025-02-07

    Yange Luan, Yumin Li, Zhong Li, Baoyue Zhang, Jian Zhen Ou

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  19. Oxygen‐Substitution Induced High‐Performance Nonlinear Optical Properties: Witnessed by the First Quaternary Oxythiostannate

    Small · 2025-03-27

    Rui Xiao, Wen‐Dong Yao, Wenhao Xing, Jian Tang, Wenwen Jiang, Nian‐Tzu Suen, Wenlong Yin, Sheng‐Ping Guo

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  20. Phosphonocarboxylates in Mixed‐Ligated Approach with Diverse Structural Features (0D to 3D), and Studies of Non‐Covalent Interactions for Revealed Proton Conduction

    Chemistry - An Asian Journal · 2025-04-07

    Syed Meheboob Elahi

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  21. Zero-Dimensional Oxyselenide Ba12[(Ga2OSe5)3(Si2O7)]: Enhanced Optical Anisotropy through Heteroanionic Engineering

    Inorganic Chemistry · 2025-04-11

    Yong‐Fang Shi, Shenghua Zhou, Bo Zhang, Xin-Tao Wu, Hua Lin, Qi‐Long Zhu

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  22. Eu(II) 4 Eu(III) 2 Ge 3 S 11 O 2 : a Single‐Element Mixed‐Valence Engineering Breakthrough for Strongly Enhanced Nonlinearity and Anisotropy in Rare‐Earth Oxysulfides

    Small · 2025-07-10

    Jingjing Xu, Yan Xiao, Dazhi Lu, Bingbing Zhang, Kui Wu, Haohai Yu, Huaijin Zhang

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  23. Assembly of Highly Polarizable “Linkers” with Heteroleptic Groups for Inducing Large Optical Anisotropy in Ba2SnIIGe3O8S and Ba3SnIIGe3O2S8

    Inorganic Chemistry · 2025-09-30

    Jiaxue Wang, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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  24. Ba 3 S[SnOS 3 ] and [Ba 2 Sn]S[Ge 2 O 7 ]: two antiperovskite oxychalcogenides with good IR nonlinear optical performances

    Inorganic Chemistry Frontiers · 2025-11-24

    Jiaxue Wang, Yixin Song, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  25. Tracing nitridation reaction toward efficient production of oxynitride glasses as hosts for bright luminescence centers

    Journal of the Ceramic Society of Japan · 2025-12-10

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  26. A Homoatomic Heteroleptic Coordination Strategy for Exceptional Infrared Linear and Nonlinear Optical Properties in ANb 2 PS 4 (S 2 ) 3 (A = K,Rb,Cs)

    Inorganic Chemistry · 2025-12-31

    Yumiao Niu, Yan Chun Xiao, Yidan Chen, Chu Chu, Daqing Yang, Ying Wang, Bingbing Zhang

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  27. Hydrophilic Ligand‐Assisted Synthesis of Water‐Dispersible Transition Metal Sulfide Nanoparticles

    Advanced Functional Materials · 2026-03-26

    Can Li, Fucheng Gao, Jia Meng, Lei Yu, Fenglong Wang, Y. Ruan, Yanyan Jiang

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  28. Achieving phase matching in infrared nonlinear optical crystal Cd3ZnSiS6 via isovalent substitution from Cd4SiS6

    Journal of Solid State Chemistry · 2026-04-02

    Ya Yang, Yan Xiao, Ying Zhang, Weiping Guo, Ziwei Li, Bingbing Zhang, Guoqiang Wang, Naifeng Zhuang, Zhong‐Zhen Luo, Zhigang Zou

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  29. High‐Performance Infrared Nonlinear Optical Crystals Discovery Guided by High‐Throughput Computation, Machine Learning, and Experimental Verification

    Angewandte Chemie International Edition · 2026-04-24

    Yan Xiao, Zhaoxi Yu, Yumiao Niu, Yidan Chen, Lin Shen, Daqing Yang, Ying Wang, Bingbing Zhang

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  30. High‐Performance Infrared Nonlinear Optical Crystals Discovery Guided by High‐Throughput Computation, Machine Learning, and Experimental Verification

    Angewandte Chemie · 2026-04-24

    Yan Xiao, Zhaoxi Yu, Yumiao Niu, Yidan Chen, Lin Shen, Daqing Yang, Ying Wang, Bingbing Zhang

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  31. Heterometallic Ge–O–Sn-Bridged Oxychalcogenides Sr3GeSnO4Q3 (Q = S, Se) with Wide Band Gaps and Moderate Infrared Nonlinear Optical Responses

    Inorganic Chemistry · 2026-07-25

    Cihai Hong, Aoge Yao, Chunlan Tang, Zhihui Zhang, Jian Tang, Lei Kang, Jing Zhao, Wenlong Yin, Bin Kang

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  32. Single and Binary Adsorption of Methyl Orange and Phosphate onto Magnesium Oxysulfite/Sulfate: Equilibrium, Kinetics, and Surface Interactions

    Water · 2026-10-08

    Duygu Keskin, Nilüfer Ülgüdür

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