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RESEARCH PAPER · Inorganic Chemistry Frontiers · 2024

Heteroanionic [VO x S 4− x ] groups: tetrahedral units with large birefringence for mid-infrared nonlinear optical crystals

Shengzi Zhang, Linfeng Dong, Bohui Xu, Huige Chen, Hao Huo, Fei Liang, Rui Fen Wu, Pifu Gong, Zheshuai Lin

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Heteroanionic [VO x S 4− x ] groups: tetrahedral units with large birefringence for mid-infrared nonlinear optical crystalsOriginalBalanced IR Nonlinear Optical Performance Achieved by Cation–Anion Module Cosubstitution in V-Based Salt-Inclusion Oxychalcogenides22First-principles study of mechanism of high birefringence in alkali metal vanadates AV3O8 (A = Li, Na, K, Rb)0Synthesis and Characterization of (H7C5N2)6(V10O28)·2H2O with Edge-Sharing VO6 Octahedra Exhibiting Large Birefringence2Rational Design of a Deep-Ultraviolet Nonlinear Optical Crystal25Ba 3 S[SnOS 3 ] and [Ba 2 Sn]S[Ge 2 O 7 ]: two antiperovskite oxychalcogenides with good IR nonlinear optical performances2A Homoatomic Heteroleptic Coordination Strategy for Exceptional Infrared Linear and Nonlinear Optical Properties in ANb 2 PS 4 (S 2 ) 3 (A = K,Rb,Cs)3Structure‐Property‐Application Correlations of Early Transition Metal Chalcogenides: A Dichalcogenide‐Centered Perspective5Rb 2 ZnGe 3 Se 8 : A Large-Birefringence Layered Chalcogenide Enabled by Anisotropic Electrons in Tetrahedral Units0Domino‐Effect Amplification via Covalent‐Chain Engineering for Giant Birefringence in NaAsQ 2 (Q = S, Se) Crystals0

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  1. Balanced IR Nonlinear Optical Performance Achieved by Cation–Anion Module Cosubstitution in V-Based Salt-Inclusion Oxychalcogenides

    Chemistry of Materials · 2024-12-03

    Mao-Yin Ran, Sheng-Hua Zhou, Bingxuan Li, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  2. First-principles study of mechanism of high birefringence in alkali metal vanadates AV3O8 (A = Li, Na, K, Rb)

    Acta Physica Sinica · 2025-01-01

    WAN Fuhong, DING Jiafu, Zhihao He, WANG Yunjie, Jian CUI, LI Jia-jun, Xin SU, Yineng HUANG

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  3. Synthesis and Characterization of (H7C5N2)6(V10O28)·2H2O with Edge-Sharing VO6 Octahedra Exhibiting Large Birefringence

    Inorganic Chemistry · 2025-07-07

    Deshuai Xiao, Xinyuan Zhang, Pifu Gong, Zheshuai Lin, Zhanggui Hu, Ning Ye

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  4. Rational Design of a Deep-Ultraviolet Nonlinear Optical Crystal

    Journal of the American Chemical Society · 2025-08-26

    Haonan Liu, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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  5. Ba 3 S[SnOS 3 ] and [Ba 2 Sn]S[Ge 2 O 7 ]: two antiperovskite oxychalcogenides with good IR nonlinear optical performances

    Inorganic Chemistry Frontiers · 2025-11-24

    Jiaxue Wang, Yixin Song, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  6. A Homoatomic Heteroleptic Coordination Strategy for Exceptional Infrared Linear and Nonlinear Optical Properties in ANb 2 PS 4 (S 2 ) 3 (A = K,Rb,Cs)

    Inorganic Chemistry · 2025-12-31

    Yumiao Niu, Yan Chun Xiao, Yidan Chen, Chu Chu, Daqing Yang, Ying Wang, Bingbing Zhang

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  7. Structure‐Property‐Application Correlations of Early Transition Metal Chalcogenides: A Dichalcogenide‐Centered Perspective

    Small · 2026-02-09

    Sachin Jaidka, Aayush Gupta, Daksh Shelly, Yashpreet Kaur, Anushka Garg, Seul‐Yi Lee, Soo‐Jin Park

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  8. Rb 2 ZnGe 3 Se 8 : A Large-Birefringence Layered Chalcogenide Enabled by Anisotropic Electrons in Tetrahedral Units

    Inorganic Chemistry · 2026-06-15

    Xinchen Chen, Yabo Wu, Wangfei Che, Shuyi Mi, Juanjuan Lu, Chen Cui

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  9. Domino‐Effect Amplification via Covalent‐Chain Engineering for Giant Birefringence in NaAsQ 2 (Q = S, Se) Crystals

    Laser & Photonics Review · 2026-09-24

    Bo Zhang, Weiqi Huang, Yang Chi, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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