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RESEARCH PAPER · Small · 2025

Oxygen‐Substitution Induced High‐Performance Nonlinear Optical Properties: Witnessed by the First Quaternary Oxythiostannate

Rui Xiao, Wen‐Dong Yao, Wenhao Xing, Jian Tang, Wenwen Jiang, Nian‐Tzu Suen, Wenlong Yin, Sheng‐Ping Guo

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Oxygen‐Substitution Induced High‐Performance Nonlinear Optical Properties: Witnessed by the First Quaternary OxythiostannateOriginalElectronic Profiles, Optical Absorption, and High Thermoelectric Performance of X Cu 3 GeSe 4 ( X = K, Rb, Cs): A Computational Approach7A Series of Pentanary Rare-Earth Oxysulfides Obtained by Heterovalent Cation and Anion Cosubstitution Exhibiting Nonlinear Optical Activity and Ultrawide Band Gaps1Doubling Polarizability Anisotropy of The Tetrahedral Motifs to Achieve Phase Matching for Melilite-Type Compound2Reactive flux assisted metal oxide–boron–sulfur routine for syntheses of CsRESiS 4 (RE = Sm, Gd–Ho): featuring nonlinear optical activity and wide band gaps5Ba 3 S[SnOS 3 ] and [Ba 2 Sn]S[Ge 2 O 7 ]: two antiperovskite oxychalcogenides with good IR nonlinear optical performances2Structural Symmetry and Mixed‐anion Engineering in Halopnictides for Extraordinary Second‐Harmonic Generation6Structural Symmetry and Mixed‐anion Engineering in Halopnictides for Extraordinary Second‐Harmonic Generation3A series of langasite-type compounds: size effect regulation for cation occupation and enhanced SHG response1Mg Substitution in BaGa 4 Se 7 : Synthesis, Structure, and Property Modulation2Synergistic Distortion Engineering: Activating Nonlinear Optical Response in Quaternary Chalcogenides via Lattice‐Induced [MnS 4 ] Asymmetry1Cd/V Ratio-Driven Centrosymmetric Transition of Crystal Structures in Cesium Cadmium Vanadate Oxychlorides Cs 3 CdV 4 O 12 Cl and CsCdV 2 O 6 Cl0Heterometallic Ge–O–Sn-Bridged Oxychalcogenides Sr3GeSnO4Q3 (Q = S, Se) with Wide Band Gaps and Moderate Infrared Nonlinear Optical Responses0

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  1. Electronic Profiles, Optical Absorption, and High Thermoelectric Performance of X Cu 3 GeSe 4 ( X = K, Rb, Cs): A Computational Approach

    International Journal of Energy Research · 2025-01-01

    Muhammad Saeed, Rajwali Khan, Khamael Mohammed Abualnaja, Atif Mossad Ali, Kiran Batool, Ghulam Murtaza

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  2. A Series of Pentanary Rare-Earth Oxysulfides Obtained by Heterovalent Cation and Anion Cosubstitution Exhibiting Nonlinear Optical Activity and Ultrawide Band Gaps

    Inorganic Chemistry · 2025-07-10

    Zhi Bing Deng, Qiu-Yang Du, Fang-Xu Tian, Zong-Ze Li, Mingyang Li, Mao‐Yin Ran, Wenlong Liu, Sheng‐Ping Guo

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  3. Doubling Polarizability Anisotropy of The Tetrahedral Motifs to Achieve Phase Matching for Melilite-Type Compound

    Inorganic Chemistry · 2025-08-18

    Zhi Bing Deng, Rui Xiao, Mao‐Yin Ran, Ao Guo, Xiang Chen, Wenlong Liu, Sheng‐Ping Guo

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  4. Reactive flux assisted metal oxide–boron–sulfur routine for syntheses of CsRESiS 4 (RE = Sm, Gd–Ho): featuring nonlinear optical activity and wide band gaps

    Inorganic Chemistry Frontiers · 2025-11-05

    Zhen-Cheng Wu, Fang-Xu Tian, Rui Xiao, Mao-Yin Ran, Wenlong Liu, Wen-Tong Chen, Sheng-Ping Guo

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  5. Ba 3 S[SnOS 3 ] and [Ba 2 Sn]S[Ge 2 O 7 ]: two antiperovskite oxychalcogenides with good IR nonlinear optical performances

    Inorganic Chemistry Frontiers · 2025-11-24

    Jiaxue Wang, Yixin Song, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  6. Structural Symmetry and Mixed‐anion Engineering in Halopnictides for Extraordinary Second‐Harmonic Generation

    Angewandte Chemie International Edition · 2025-12-18

    Yi‐Bing Huang, Bin‐Wen Liu, Wei Wu, Xiao‐Ming Jiang, Xiyue Cheng, Guo‐Qiang Wang, Guo‐Cong Guo

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  7. Structural Symmetry and Mixed‐anion Engineering in Halopnictides for Extraordinary Second‐Harmonic Generation

    Angewandte Chemie · 2025-12-18

    Yi‐Bing Huang, Bin‐Wen Liu, Wei Wu, Xiao‐Ming Jiang, Xiyue Cheng, Guo‐Qiang Wang, Guo‐Cong Guo

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  8. A series of langasite-type compounds: size effect regulation for cation occupation and enhanced SHG response

    Inorganic Chemistry Frontiers · 2026-01-01

    Zhi Deng, Nian‐Tzu Suen, Zhen‐Cheng Wu, Huizhi Gao, Sheng‐Ping Guo

    Read original paper ↗ ·

  9. Mg Substitution in BaGa 4 Se 7 : Synthesis, Structure, and Property Modulation

    Chemistry of Materials · 2026-03-24

    Chi Wang, Guohong Tang, Kexin Huang, Yuhang Du, Jinsong Wei, Baojun Chen, Zhiyu He, Wei Huang

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  10. Synergistic Distortion Engineering: Activating Nonlinear Optical Response in Quaternary Chalcogenides via Lattice‐Induced [MnS 4 ] Asymmetry

    Advanced Optical Materials · 2026-04-21

    Guili Wang, Siyang Luo, Ming‐Hsien Lee, Jiyong Yao

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  11. Cd/V Ratio-Driven Centrosymmetric Transition of Crystal Structures in Cesium Cadmium Vanadate Oxychlorides Cs 3 CdV 4 O 12 Cl and CsCdV 2 O 6 Cl

    Inorganic Chemistry · 2026-05-14

    Xindan Xu, Lei Geng, Baozhu Zhu, Shoubao Zhang, Yuqi Song, Changyu Meng

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  12. Heterometallic Ge–O–Sn-Bridged Oxychalcogenides Sr3GeSnO4Q3 (Q = S, Se) with Wide Band Gaps and Moderate Infrared Nonlinear Optical Responses

    Inorganic Chemistry · 2026-07-25

    Cihai Hong, Aoge Yao, Chunlan Tang, Zhihui Zhang, Jian Tang, Lei Kang, Jing Ling Zhao, Wenlong Yin, Bin Kang

    Read original paper ↗ ·
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