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RESEARCH PAPER · Chemistry - A European Journal · 2022

Oxychalcogenides: A Promising Class of Materials for Nonlinear Optical Crystals with Mixed‐Anion Groups

Yu-Jie Zhang, Hongping Wu, Zhanggui Hu, Hongwei Yu

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Oxychalcogenides: A Promising Class of Materials for Nonlinear Optical Crystals with Mixed‐Anion GroupsOriginalAn overview of Mg-based IR nonlinear optical materials22Sr6Ge3OSe11: A Rationally Designed Noncentrosymmetric Oxyselenide with Polar [GeOSe3] Building Blocks16Recent progress of newly developed functional building units and corresponding nonlinear optical materials14La4Ga2S8O3: A Rare-Earth Gallium Oxysulfide with Disulfide Ions5Eu 2 MGe 2 OS 6 (M = Mn, Fe, Co): Three Melilite-Type Rare-Earth Oxythiogermanates Exhibiting Balanced Nonlinear-Optical Behaviors21Ga-based IR nonlinear optical materials: Synthesis, structures, and properties65Chemical perspectives on heteroanionic compounds: a potential playground for multiferroics7Laser power and high-temperature dependent Raman studies of layered bismuth and copper-based oxytellurides for optoelectronic applications15Partial substitution with a significant effect: coexistence of a wide band gap and large birefringence in the oxychalcogenide AEGe 2 O 4 Se (AE = Sr and Ba)17A comprehensive review on synthesis, properties, and applications of quaternary transition metal oxychalcogenides19Ba10In2Mn11Si3O12S18: First Hexanary Oxychalcogenide Containing an Infrequent Three-Dimensional Noncentrosysmmetric Framework8Anhydrous Aluminum Iodate: Strong Second Harmonic Generation Effect Contributed by Unbonded and Antibonding Orbitals3Wide-Gap p-Type Layered Oxychalcogenides AE2CuInO3Ch (AE: Alkaline Earth; Ch: Chalcogen): Unusually Low Residual Carrier Concentration and Green-to-Red Emission7La2O2MQ2 phases: Stability and synthetic challenges0Ultrathin two-dimensional titanium oxysulfide for enhanced sensitivity and stability of room temperature NO2 sensing30Balanced IR Nonlinear Optical Performance Achieved by Cation–Anion Module Cosubstitution in V-Based Salt-Inclusion Oxychalcogenides22Enhanced two-photon absorption in hydrothermally synthesized La 2 O 6 Te nanorods for visible light photodetection18La 3 (Ga 3 S 3 O 3 )(Si 2 O 7 ): An Oxychalcogenide Demonstrating Ultrawide Optical Bandgap and Favorable Birefringence Propelled by Divergent Anionic Groups6Emergent Mid‐Infrared Nonlinear Optical Candidates With Targeted Balance Performances17La 2 ZnGa 2 S 6 O: a melilite-type transition metal oxysulfide achieving a well-balanced nonlinear optical behavior5Mixed-anion chalcogenide-halide semiconductors A 2 BaTaS 4 Cl (A = K, Rb, Cs) and K 2 BaNbS 4 Cl1Structural diversity and photocurrent responses of multi-component chalcogenidometalates8Unveiling Na 2 Fe 2 S 2 O oxychalcogenide: a high-performance thermoelectric and optoelectronic material for sustainable energy conversion02D Chiral Ag(I) Complexes with A-π–A- and D-π–A-Type Dicarboxylic Acid Ligands: Presenting Significant Differences in Nonlinear Optical Responses5Layered Anion‐Mixed Oxycompounds: Synthesis, Properties, and Applications29Strong Second‐Harmonic Generation Responses in Salt‐Inclusion Oxychalcogenides Enabled by the Highly Distorted Polyhedra with Mixed‐Anions4Rate-Dependent Mechanoluminescence in SrZn2S2O:Mn2+ for Time-Characterized Optoelectronic Devices8Tunable Synthesis of 2D Bismuth Oxyhydroxide and Oxysulfide from Solid–Liquid Interfacial Reaction for High Performance Optoelectronic Gas Sensing8Zero-Dimensional Oxyselenide Ba12[(Ga2OSe5)3(Si2O7)]: Enhanced Optical Anisotropy through Heteroanionic Engineering4A Computational Analysis of ZrSe2O6 and HfSe2O6 Oxychalcogenides: Wide-Bandgap Semiconductors with Strain-Tunable Properties0V2O9Te2 Nanorods for Broadband Visible Light Photoresponse and NLO Applications: An Experimental and Computational Approach11Eu(II) 4 Eu(III) 2 Ge 3 S 11 O 2 : a Single‐Element Mixed‐Valence Engineering Breakthrough for Strongly Enhanced Nonlinearity and Anisotropy in Rare‐Earth Oxysulfides8ABCQ4型硫属化物红外非线性光学材料的构效关系（特邀）0Growth of large crystals of Janus phase RhSeCl using self-selecting vapour growth1Cu-Based La and Ce Oxytelluride Nanomaterials for Broadband Visible Light Photoresponse and Nonlinear Optical Applications7

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  1. An overview of Mg-based IR nonlinear optical materials

    Inorganic Chemistry Frontiers · 2023-01-01

    Jiaxiang Zhang, Mao‐Yin Ran, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  2. Sr6Ge3OSe11: A Rationally Designed Noncentrosymmetric Oxyselenide with Polar [GeOSe3] Building Blocks

    Chemistry of Materials · 2023-03-27

    Luke T. Menezes, Eliana Gage, Abdeljalil Assoud, Mingli Liang, P. Shiv Halasyamani, Holger Kleinke

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  3. Recent progress of newly developed functional building units and corresponding nonlinear optical materials

    Chinese Journal of Structural Chemistry · 2023-05-11

    Wenjing Tan, Chenyang Zhang, Chenyang Zhang, Tingting Huang, Bingbing Zhang

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  4. La4Ga2S8O3: A Rare-Earth Gallium Oxysulfide with Disulfide Ions

    Inorganic Chemistry · 2023-06-22

    Hong Juan Yan, Kotaro Fujii, Houria Kabbour, Akira Chikamatsu, Yu Meng, Yoshitaka Matsushita, Masatomo Yashima, Kazunari Yamaura, Yoshihiro Tsujimoto

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  5. Eu 2 MGe 2 OS 6 (M = Mn, Fe, Co): Three Melilite-Type Rare-Earth Oxythiogermanates Exhibiting Balanced Nonlinear-Optical Behaviors

    Inorganic Chemistry · 2023-09-28

    Nan Zhang, Xiao Fen Huang, Wen‐Dong Yao, Yao Chen, Zheng-Rui Pan, Bingxuan Li, Wenlong Liu, Sheng‐Ping Guo

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  6. Ga-based IR nonlinear optical materials: Synthesis, structures, and properties

    Coordination Chemistry Reviews · 2023-12-21

    Jiaxiang Zhang, Ping Feng, Mao‐Yin Ran, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  7. Chemical perspectives on heteroanionic compounds: a potential playground for multiferroics

    Materials Chemistry Frontiers · 2024-01-01

    Karishma Prasad, Vivian Nguyen, Bingheng Ji, Jasmine Quah, Danielle Goodwin, Jian Wang

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  8. Laser power and high-temperature dependent Raman studies of layered bismuth and copper-based oxytellurides for optoelectronic applications

    Physical Chemistry Chemical Physics · 2024-01-01

    Prabhukrupa Chinmay Kumar, Subrata Senapati, Monalisa Pradhan, Gopal Krushna Pradhan, Ramakanta Naik

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  9. Partial substitution with a significant effect: coexistence of a wide band gap and large birefringence in the oxychalcogenide AEGe 2 O 4 Se (AE = Sr and Ba)

    Inorganic Chemistry Frontiers · 2024-01-01

    Mao‐Yin Ran, Shenghua Zhou, Wenbo Wei, A-Yang Wang, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  10. A comprehensive review on synthesis, properties, and applications of quaternary transition metal oxychalcogenides

    FlatChem · 2024-01-24

    Prabhukrupa Chinmay Kumar, Subrata Senapati, Ramakanta Naik

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  11. Ba10In2Mn11Si3O12S18: First Hexanary Oxychalcogenide Containing an Infrequent Three-Dimensional Noncentrosysmmetric Framework

    Inorganic Chemistry · 2024-02-23

    A-Yang Wang, Mao‐Yin Ran, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  12. Anhydrous Aluminum Iodate: Strong Second Harmonic Generation Effect Contributed by Unbonded and Antibonding Orbitals

    Inorganic Chemistry · 2024-03-20

    Yang Chi, Mei-Ling Xin

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  13. Wide-Gap p-Type Layered Oxychalcogenides AE2CuInO3Ch (AE: Alkaline Earth; Ch: Chalcogen): Unusually Low Residual Carrier Concentration and Green-to-Red Emission

    Chemistry of Materials · 2024-06-04

    Xinyi He, Tatsuya Cho, Takayoshi Katase, Kota Hanzawa, Suguru Kitani, Hidenori Hiramatsu, Hideo Hosono, Toshio Kamiya

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  14. La2O2MQ2 phases: Stability and synthetic challenges

    Solid State Sciences · 2024-10-09

    Glen R. Hebberd, Budhika G. Mendis, Leon Bowen, Stewart J. Clark, Emma E. McCabe

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  15. Ultrathin two-dimensional titanium oxysulfide for enhanced sensitivity and stability of room temperature NO2 sensing

    Ceramics International · 2024-11-20

    Tao Tang, Zhong Li, Yao Yang Liu, Yongli Chen, Yin Fen Cheng, Yi Fei Liang, Jing Hao Zhuang, Xin Hu, Azmira Jannat, Rui Ou, Kai‐Da Xu, Jian Zhen Ou, Jian Zhen Ou

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  16. Balanced IR Nonlinear Optical Performance Achieved by Cation–Anion Module Cosubstitution in V-Based Salt-Inclusion Oxychalcogenides

    Chemistry of Materials · 2024-12-03

    Mao-Yin Ran, Sheng-Hua Zhou, Bingxuan Li, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  17. Enhanced two-photon absorption in hydrothermally synthesized La 2 O 6 Te nanorods for visible light photodetection

    Nanoscale · 2024-12-09

    Prabhukrupa Chinmay Kumar, Swikruti Supriya, Ashutosh Mohapatra, Chinnaiyah Sripan, Ramakanta Naik

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  18. La 3 (Ga 3 S 3 O 3 )(Si 2 O 7 ): An Oxychalcogenide Demonstrating Ultrawide Optical Bandgap and Favorable Birefringence Propelled by Divergent Anionic Groups

    ACS Materials Letters · 2024-12-19

    Ming‐Shu Zhang, Shao‐Min Pei, Xiao‐Ming Jiang, Bin‐Wen Liu, Guo‐Cong Guo

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  19. Emergent Mid‐Infrared Nonlinear Optical Candidates With Targeted Balance Performances

    Small · 2024-12-23

    Junben Huang, Ailijiang Abudurusuli, Zhihua Yang, Shilie Pan

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  20. La 2 ZnGa 2 S 6 O: a melilite-type transition metal oxysulfide achieving a well-balanced nonlinear optical behavior

    Dalton Transactions · 2025-01-01

    Jingjing Xu, Yan Xiao, Xiaowen Wu, Bingbing Zhang, Kui Wu

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  21. Mixed-anion chalcogenide-halide semiconductors A 2 BaTaS 4 Cl (A = K, Rb, Cs) and K 2 BaNbS 4 Cl

    Dalton Transactions · 2025-01-01

    Thomas S. Ie, Siddhartha S. Nathan, James M. Rondinelli, Mercouri G. Kanatzidis

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  22. Structural diversity and photocurrent responses of multi-component chalcogenidometalates

    Inorganic Chemistry Frontiers · 2025-01-01

    Chang Liu, Wen-Jing Tian, Mao‐Yin Ran, Pan Gao, Panpan Jing, Yi Liu, Hua Lin

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  23. Unveiling Na 2 Fe 2 S 2 O oxychalcogenide: a high-performance thermoelectric and optoelectronic material for sustainable energy conversion

    Sustainable Energy & Fuels · 2025-01-01

    Muhammad Haseeb, Muhammad Bashir, Athar Javed, Asma Munir, Muhammad Rafiq, Altaf Hussain

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  24. 2D Chiral Ag(I) Complexes with A-π–A- and D-π–A-Type Dicarboxylic Acid Ligands: Presenting Significant Differences in Nonlinear Optical Responses

    Inorganic Chemistry · 2025-01-10

    Congli Gao, Xiaoyu Cai, Jinying Huang, Qianrong Li, Huajie Kong, Jimei Yao, Yang Wang, Xi-Li Li

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  25. Layered Anion‐Mixed Oxycompounds: Synthesis, Properties, and Applications

    Advanced Science · 2025-02-07

    Yange Luan, Yumin Li, Zhong Li, Baoyue Zhang, Jian Zhen Ou

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  26. Strong Second‐Harmonic Generation Responses in Salt‐Inclusion Oxychalcogenides Enabled by the Highly Distorted Polyhedra with Mixed‐Anions

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  27. Rate-Dependent Mechanoluminescence in SrZn2S2O:Mn2+ for Time-Characterized Optoelectronic Devices

    The Journal of Physical Chemistry C · 2025-02-26

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  28. Tunable Synthesis of 2D Bismuth Oxyhydroxide and Oxysulfide from Solid–Liquid Interfacial Reaction for High Performance Optoelectronic Gas Sensing

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  29. Zero-Dimensional Oxyselenide Ba12[(Ga2OSe5)3(Si2O7)]: Enhanced Optical Anisotropy through Heteroanionic Engineering

    Inorganic Chemistry · 2025-04-11

    Yong‐Fang Shi, Shenghua Zhou, Bo Zhang, Xin-Tao Wu, Hua Lin, Qi‐Long Zhu

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  30. A Computational Analysis of ZrSe2O6 and HfSe2O6 Oxychalcogenides: Wide-Bandgap Semiconductors with Strain-Tunable Properties

    The Journal of Physical Chemistry C · 2025-05-26

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  31. V2O9Te2 Nanorods for Broadband Visible Light Photoresponse and NLO Applications: An Experimental and Computational Approach

    ACS Applied Electronic Materials · 2025-06-23

    Prabhukrupa Chinmay Kumar, Jagadish Kumar, Chinnaiyah Sripan, Ramakanta Naik

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  32. Eu(II) 4 Eu(III) 2 Ge 3 S 11 O 2 : a Single‐Element Mixed‐Valence Engineering Breakthrough for Strongly Enhanced Nonlinearity and Anisotropy in Rare‐Earth Oxysulfides

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    Jingjing Xu, Yan Xiao, Dazhi Lu, Bingbing Zhang, Kui Wu, Haohai Yu, Huaijin Zhang

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  33. ABCQ4型硫属化物红外非线性光学材料的构效关系（特邀）

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  34. Growth of large crystals of Janus phase RhSeCl using self-selecting vapour growth

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    Anastasiia Lukovkina, Maria A. Herz, X. N. Lin, Volodymyr Multian, Alberto F. Morpurgo, E. Giannini, Fabian O. von Rohr

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  35. Cu-Based La and Ce Oxytelluride Nanomaterials for Broadband Visible Light Photoresponse and Nonlinear Optical Applications

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