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RESEARCH PAPER · Advanced Optical Materials · 2023

A ll HgM IV S 4 (A ll = Sr, Ba, M IV = Si, Ge): A Series of Materials with Large Second Harmonic Generation Response and Wide Band Gaps

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A ll HgM IV S 4 (A ll = Sr, Ba, M IV = Si, Ge): A Series of Materials with Large Second Harmonic Generation Response and Wide Band GapsOriginalBa4Cd2Ge2Te9: A promising infrared functional crystal with large birefringent and photoluminescence properties2Chemical modulation of A I RE III C IV QVI4 family compounds for band gap and optical anisotropy enhancement16Effectively designing infrared nonlinear optical materials with magnetism, MMn 6 Ga 6 S 16 (M = Ca, Sr, Ba, and Pb), aided by stable open frameworks13Pb 6 Ba 3 Si 2 S 8 I 10 : a new thiohalide with a quasi-two-dimensional structure and wide band gap2β -CsHg 2 I 5 , a compound with rare [Hg 2 I 5 ] dimers and large optical anisotropy2[Na2PbI][Ga7S12]: Combining Diamond-Like Anionic Framework with Polycationic Chain toward Achieving Remarkable Nonlinear Optical Response21La3Ga5M0.5Sn0.5O14, (M = Ge, Si): Design and Synthesis of Two Langasite Nonlinear Optical Materials with Large Second Harmonic Generation and Birefringence Induced by Distorted (Sn/M)O6 Octahedra4K2HgGe3Se8: A Quaternary Hg-Based Selenide with Nonlinear Optical Properties6Realizing Excellent Infrared Nonlinear Optical Performance in Eu-Based Chalcogenides via Rational Cross Substitution Strategy26ACuGa 6 S 10 (A = Rb, Cs): Design and Synthesis of Two New Cavity‐Chalcopyrite Chalcogenides Based on “Iterative Substitution” Strategy4Emergent Mid‐Infrared Nonlinear Optical Candidates With Targeted Balance Performances18Designing infrared nonlinear optical crystals, Sr 2 MgSn 2 OS 6 and Sr 2 SnGa 2 OS 6 , with hybrid anionic frameworks via a double substitution strategy4Isovalent cation substitution drives structural transformation and infrared nonlinear optical activity in Eu-based chalcogenides11AgGaS2 and Derivatives: Design, Synthesis, and Optical Properties10Synergically Assembling Advantageous Groups toward High‐Performance Infrared Nonlinear Optical Materials A II CdSiSe 4 (A II = Sr, Ba)41SrZnGeSe 4 : a promising infrared nonlinear optical material with strong second harmonic generation and high laser-induced damage threshold4Gradient boosting-assisted polarization-independent SPR biosensor for multiplexed diagnostics and behavioural prediction22Diamond-Like HgIn2Q4 (Q = Se, Te) Synthesized by Flux-Assisted Boron-Chalcogen Method Exhibit Noteworthy Nonlinear Optical Properties Contributed by Three Types of Tetrahedral Motifs9SrZnSiS4: Shattering the 4.0 eV Threshold toward Dual-Optimized Bandgap and Second-Harmonic Generation7Ba-based IR nonlinear optical materials: synthesis, growth, structures, and properties6ABCQ4型硫属化物红外非线性光学材料的构效关系(特邀)0Effect of the cation-to-silicon ratio on structural transformation and optical performance in [NaSr 3 Cl 3 ][SiS 4 ] and [NaSr 4 SCl][Si 3 S 9 ]0高性能硫属化物红外非线性光学材料构效关系(特邀)0SrMnGeS 4 : A Two-Dimensional Layered Chalcogenide with Magnetic Triangular Lattice0Synergistic Distortion Engineering: Activating Nonlinear Optical Response in Quaternary Chalcogenides via Lattice‐Induced [MnS 4 ] Asymmetry2Cation-substitution-driven electronic, nonlinear optical, elastic, and thermal transport properties of layered AeHgGeSe4 (Ae = Ba, Sr): A first-principles study0Laporte Selection Rule Induced the Suppression of d ‐ d Transitions and Vacancies Enhanced the Second Harmonic Generation in I 4¯‐MnGa 2 S 40Vacancy-Driven Tetrahedral Distortion in Defect Diamond-Like Selenides for Exceptional Second-Order Nonlinearity0

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  1. Ba4Cd2Ge2Te9: A promising infrared functional crystal with large birefringent and photoluminescence properties

    Journal of Alloys and Compounds · 2023-12-29

    Mengran Sun, Haojian Su, Wenhao Liu, Jiyong Yao

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  2. Chemical modulation of A I RE III C IV QVI4 family compounds for band gap and optical anisotropy enhancement

    Inorganic Chemistry Frontiers · 2024-01-01

    Hongshan Wang, Xueting Pan, Shilie Pan, Junjie Li

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  3. Effectively designing infrared nonlinear optical materials with magnetism, MMn 6 Ga 6 S 16 (M = Ca, Sr, Ba, and Pb), aided by stable open frameworks

    Inorganic Chemistry Frontiers · 2024-01-01

    Kaixuan Li, Yujie Zhang, Xianchao Zhu, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  4. Pb 6 Ba 3 Si 2 S 8 I 10 : a new thiohalide with a quasi-two-dimensional structure and wide band gap

    Dalton Transactions · 2024-01-01

    Zhao Wang, Jiazheng Zhou, Linan Wang, Wenqi Jin, Yingying Kong, Yu Chu, Junjie Li

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  5. β -CsHg 2 I 5 , a compound with rare [Hg 2 I 5 ] dimers and large optical anisotropy

    Dalton Transactions · 2024-01-01

    Yingying Kong, Hongshan Wang, Wang Zhao, Qi Sun, Junjie Li, Shilie Pan

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  6. [Na2PbI][Ga7S12]: Combining Diamond-Like Anionic Framework with Polycationic Chain toward Achieving Remarkable Nonlinear Optical Response

    Chemistry of Materials · 2024-03-27

    Zixuan Wu, Wen‐Fa Chen, Xiao‐Ming Jiang, Bin‐Wen Liu, Guo‐Cong Guo

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  7. La3Ga5M0.5Sn0.5O14, (M = Ge, Si): Design and Synthesis of Two Langasite Nonlinear Optical Materials with Large Second Harmonic Generation and Birefringence Induced by Distorted (Sn/M)O6 Octahedra

    Inorganic Chemistry · 2024-07-25

    Jingxuan Hou, Jiajia Wang, Fei Liang, Shihui Ma, Hongwei Yu, Hongping Wu, Ning Ye, Zhanggui Hu, Yicheng Wu

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  8. K2HgGe3Se8: A Quaternary Hg-Based Selenide with Nonlinear Optical Properties

    Inorganic Chemistry · 2024-08-26

    Guili Wang, Pifu Gong, Jiyong Yao

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  9. Realizing Excellent Infrared Nonlinear Optical Performance in Eu-Based Chalcogenides via Rational Cross Substitution Strategy

    ACS Applied Materials & Interfaces · 2024-09-23

    Ping Feng, Sheng-Hua Zhou, Bingxuan Li, Jia-Xiang Zhang, Mao‐Yin Ran, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  10. ACuGa 6 S 10 (A = Rb, Cs): Design and Synthesis of Two New Cavity‐Chalcopyrite Chalcogenides Based on “Iterative Substitution” Strategy

    Chemistry - A European Journal · 2024-10-17

    Kaixuan Li, Xingyu Zhang, Binqiang Chai, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongping Wu

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  11. Emergent Mid‐Infrared Nonlinear Optical Candidates With Targeted Balance Performances

    Small · 2024-12-23

    Junben Huang, Ailijiang Abudurusuli, Zhihua Yang, Shilie Pan

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  12. Designing infrared nonlinear optical crystals, Sr 2 MgSn 2 OS 6 and Sr 2 SnGa 2 OS 6 , with hybrid anionic frameworks via a double substitution strategy

    Materials Chemistry Frontiers · 2025-01-01

    Zhen Qian, Deman Kong, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  13. Isovalent cation substitution drives structural transformation and infrared nonlinear optical activity in Eu-based chalcogenides

    Inorganic Chemistry Frontiers · 2025-01-01

    Ping Feng, Shenghua Zhou, Mao‐Yin Ran, Bingxuan Li, Xin-Tao Wu, Hua Lin, Qi‐Long Zhu

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  14. AgGaS2 and Derivatives: Design, Synthesis, and Optical Properties

    Nanomaterials · 2025-01-20

    Guansheng Xing, Bing Chen

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  15. Synergically Assembling Advantageous Groups toward High‐Performance Infrared Nonlinear Optical Materials A II CdSiSe 4 (A II = Sr, Ba)

    Advanced Functional Materials · 2025-03-24

    Hongshan Wang, Ran An, Zhihua Yang, Shilie Pan, Junjie Li

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  16. SrZnGeSe 4 : a promising infrared nonlinear optical material with strong second harmonic generation and high laser-induced damage threshold

    Optics Express · 2025-03-27

    Hongshan Wang, Ran An, Yi Du, Shilie Pan, Junjie Li

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  17. Gradient boosting-assisted polarization-independent SPR biosensor for multiplexed diagnostics and behavioural prediction

    Diamond and Related Materials · 2025-06-10

    Jacob Wekalao, Ashour M. Ahmed, Hussein A. Elsayed, Mohamed A. A. Abdelkawy, Amuthakkannan Rajakannu, Ahmed Mehaney, Stefano Bellucci

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  18. Diamond-Like HgIn2Q4 (Q = Se, Te) Synthesized by Flux-Assisted Boron-Chalcogen Method Exhibit Noteworthy Nonlinear Optical Properties Contributed by Three Types of Tetrahedral Motifs

    Inorganic Chemistry · 2025-06-24

    Jian Ping Cheng, Wen‐Dong Yao, Wenlong Liu, Sheng‐Ping Guo

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  19. SrZnSiS4: Shattering the 4.0 eV Threshold toward Dual-Optimized Bandgap and Second-Harmonic Generation

    Inorganic Chemistry · 2025-09-04

    Huilin Yin, Xia Wu, Shuchang Wu, Changsheng Sun, Chengxiao Wang, Jiaman Sun, Yang Liu, Xiao‐Ming Jiang, Ximeng Lv, Dajiang Mei

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  20. Ba-based IR nonlinear optical materials: synthesis, growth, structures, and properties

    Coordination Chemistry Reviews · 2025-11-19

    Wei Huang, Chi Wang, Guohong Tang, Kexin Huang, Baojun Chen, Z. Y. He, Z. Y. He

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  21. ABCQ4型硫属化物红外非线性光学材料的构效关系(特邀)

    Chinese Journal of Lasers · 2026-01-01

    王硕 Wang Shuo, 张成龙 Zhang Chenglong, 黄君本 Huang Junben, Ailijiang Abudurusuli, 吐沙姑·阿不都吾甫 Abudouwufu Tushagu

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  22. Effect of the cation-to-silicon ratio on structural transformation and optical performance in [NaSr 3 Cl 3 ][SiS 4 ] and [NaSr 4 SCl][Si 3 S 9 ]

    Chemical Communications · 2026-01-01

    Puxuan Wang, Youbin Wang, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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  23. 高性能硫属化物红外非线性光学材料构效关系(特邀)

    Chinese Journal of Lasers · 2026-01-01

    张成龙 Zhang Chenglong, 王硕 Wang Shuo, Ailijiang Abudurusuli, 黄君本 Huang Junben

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  24. SrMnGeS 4 : A Two-Dimensional Layered Chalcogenide with Magnetic Triangular Lattice

    Inorganic Chemistry · 2026-01-21

    Chenyao Zhao, Yanhong Wang, Yun Lv, SeungGyum Jung, Hyun‐Joo Koo, Myung‐Hwan Whangbo, Hongcheng Lu

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  25. Synergistic Distortion Engineering: Activating Nonlinear Optical Response in Quaternary Chalcogenides via Lattice‐Induced [MnS 4 ] Asymmetry

    Advanced Optical Materials · 2026-04-21

    Guili Wang, Siyang Luo, Ming‐Hsien Lee, Jiyong Yao

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  26. Cation-substitution-driven electronic, nonlinear optical, elastic, and thermal transport properties of layered AeHgGeSe4 (Ae = Ba, Sr): A first-principles study

    Computational Condensed Matter · 2026-08-12

    Saravana Karthikeyan SKS, Shaik Gouse Peera, Chang Yi Kong

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  27. Laporte Selection Rule Induced the Suppression of d ‐ d Transitions and Vacancies Enhanced the Second Harmonic Generation in I 4¯‐MnGa 2 S 4

    Small · 2026-08-23

    Weiping Guo, Ya Yang, Yi Fang, Hong‐Hua Cui, Lingyun Li, Yan Yu, Zhong‐Zhen Luo, Zhigang Zou

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  28. Vacancy-Driven Tetrahedral Distortion in Defect Diamond-Like Selenides for Exceptional Second-Order Nonlinearity

    Crystal Growth & Design · 2026-10-12

    Shuo Wang, Xu Liu, Chenglong Zhang, Ailijiang Abudurusuli, Ming‐Hsien Lee, Junben Huang

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