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RESEARCH PAPER · Chemistry of Materials · 2022

Cs2Bi2OSi2O7: A Promising Bismuth Silicate Nonlinear Optical Crystal with Face-Sharing BiO5 Polyhedra Exhibiting Strengthened Second Harmonic Generation Response and Birefringence

Wenli Zhao, Conggang Li, Tao Han, Jinmiao Jiao, Yuheng She, Dianxing Ju, Fei Liang, Ning Ye, Zhanggui Hu, Yicheng Wu

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Cs2Bi2OSi2O7: A Promising Bismuth Silicate Nonlinear Optical Crystal with Face-Sharing BiO5 Polyhedra Exhibiting Strengthened Second Harmonic Generation Response and BirefringenceOriginalCsB 3 O 4 (OH) 2 : a new deep-ultraviolet birefringent crystal with [B 3 O 4 (OH) 2 ] anionic group8Shedding Light on the Structure and Characterization of K2ZnGe2O6: A Phase-Matchable Nonlinear Optical Crystal19Pb5(GeO4)(Ge2O7) and Pb3.32Ca1.68(GeO4)(Ge2O7): Two Nonlinear Optical Germanates Induced by Diverse PbOx Polyhedra17Synthesis, structure, characterization, and electronic structure calculation of a new molecule-inclusion strontium gallate Sr6(Ga12O24)·Bi2O32Achieving broadband ultraviolet to mid-infrared transparency in germanate-based nonlinear optical crystals Cs 3 REGe 3 O 9 (RE = Y, Gd)16Deep-ultraviolet nonlinear-optical crystal BaNa2[PO3(OH)]2 with large birefringence and strong second-harmonic-generation response8High stability and moderate second-order nonlinear optical properties of hybrid lead-free perovskite [(CH 3 ) 3 NCH 2 Cl]CdCl 3 bulk crystals12KNa 2 La 2 (BO 3 ) 3 : a shortite-type lanthanide borate exhibiting strong nonlinear optical activity induced by isolated [BO 3 ] triangles and distorted [LaO 9 ] polyhedra26LiVTeO 5 : a mid-infrared nonlinear optical vanadium tellurate crystal exhibiting enhanced second harmonic generation activities and notable birefringence21Small Changes, Big Impact: Tungsten Bronzes with Extremely Large Second Harmonic Generation Achieved by the Transition Metal Doping on the B‐Site26Polar Bismuth Selenite Iodate Oxide BiSeIO6 with Three Types of Lone Pair Cations in One Structure6A Polar Tetragonal Tungsten Bronze with Colossal Second‐Harmonic Generation18Ultraviolet Crystal with Strong Optical Nonlinearity by Creating Halogen-Centered Secondary Building Blocks15Rational Design of a Niobium Tellurite Crystal Nb2Te3O11 Exhibiting Good Overall Infrared NLO Performance by Structural Genetic Engineering17Tailored Synthesis of Two Metal Borates KSrM3B2O9 (M = Al and Ga) Exhibiting Wide Ultraviolet Transparency4K4ZnV5O15Cl: A Congruent‐Melting Mid‐Infrared Nonlinear Optical Crystal Combined with Strong Second‐Harmonic Generation and High Laser‐Induced Damage Threshold14A defect pyrochlore-like acentric cubic lead titanium-tellurate crystal exhibiting strong second harmonic generation activity and an extended transparent window4Ba 5 Y 12 Zn[O(SiO 4 )] 8 : a novel non-centrosymmetric silicate with a short ultraviolet cut-off edge featuring [ZnSi 4 O 16 ] and [SiO 4 ] units3Computer-aided screening of bismuth molybdates nonlinear optical crystals γ -Bi 2 MoO 63Li13YGe4O16: A Mid-infrared Rare-Earth Germanate Nonlinear Optical Crystal Featuring a Broad Transmission Range and an Enlarged Band Gap10Theoretical Investigation of Structural, Electronic and Optical Properties of Cs3MoO4(HCO3) with NLO Active Functional Units2Two Acentric Zn-Based l -Tartrates with Moderate Second Harmonic Generation Responses and Large Birefringence6A congruent-melting rubidium zinc vanadium oxychloride exhibiting strong mid-infrared second-harmonic generation and high laser-induced damage threshold6Theoretical insight on structure, electronic, and optical properties of two d 0–d 10 electron transition-metal oxyhalides SHG materials2Ba3Zn4Si4O15: A Novel Centrosymmetric Silicate with Isolated SiO4 and Si2O7 Units0Bi(SO4)F·H2O and Bi(SO4)(NO3)·3H2O: Chemical Substitution-Induced Birefringence Enhancement in Bismuth Sulfates6La3Ga5M0.5Sn0.5O14, (M = Ge, Si): Design and Synthesis of Two Langasite Nonlinear Optical Materials with Large Second Harmonic Generation and Birefringence Induced by Distorted (Sn/M)O6 Octahedra4K4Cd3Ge4O13: A Congruent-Melting Germanate Nonlinear Optical Crystal with a Moderate Second-Harmonic Generation Intensity and Broad Transparent Window2Lanthanide Contraction Eliminates Disorder while Holding Robust Second Harmonic Generation in a Series of Polyiodates13Cationic Coordination Modification Drives Birefringence and Nonlinear Effect Double Lifting in Sulfate4Two-Step Substitutions of Square Pyramidal VO5 with CdO4Br to Achieve Higher Laser-Induced Damage Threshold from Polar Oxybromides Rb4CdV5O15Br to Rb3CdV4O12Br10Vacancy-Enhanced Biotite Nanosheets for Optical Limiters6Exploration of bismuth-based nanomaterials: From fundamental concepts to innovative synthesis techniques and emerging applications18Ca 7 (TeO 3 ) 6 (MoO 4 ): A Promising Mid-Infrared Nonlinear Optical Crystal Activated via a Module-Oriented Dimensionality Reduction Strategy34Tailoring ordered structures with distorted [TeO 3 ] and aligned [ScO 6 ] motifs for balanced nonlinear optical properties in rare-earth tellurate crystals5LiBa 2 GaSi 2 O 8 : A Noncentrosymmetric Silicate Exhibiting Wide Transmission Range and Moderate Second Harmonic Generation Response2A promising mid-infrared nonlinear optical crystal with well-balanced properties0BaScSi2O6F: A barium-containing rare-earth metal silicate fluoride with a short cutoff edge0Strategic Integration Between Trigonal Architecture Construction and Molecular Polarization Enhancement for Record SHG Effect in Selenates4Strategic Integration Between Trigonal Architecture Construction and Molecular Polarization Enhancement for Record SHG Effect in Selenates0Rational design of a quasi-0D tungsten tellurite nonlinear optical crystal with exceptionally balanced properties1Breaking Inversion Symmetry via Vanadium Coordination Engineering in Bismuth Vanadium Selenites0Cation-regulated orientational coherence in one-dimensional antimony fluoride selenate chains modulates ultraviolet second-Harmonic generation0

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  1. CsB 3 O 4 (OH) 2 : a new deep-ultraviolet birefringent crystal with [B 3 O 4 (OH) 2 ] anionic group

    Dalton Transactions · 2022-01-01

    Xinyue Wang, Bingbing Zhang, Daqing Yang, Ying Wang

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  2. Shedding Light on the Structure and Characterization of K2ZnGe2O6: A Phase-Matchable Nonlinear Optical Crystal

    Inorganic Chemistry · 2022-07-13

    Jinmiao Jiao, Fei Liang, Conggang Li, Tao Han, Wenli Zhao, Yuheng She, Ning Ye, Zhanggui Hu, Yicheng Wu

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  3. Pb5(GeO4)(Ge2O7) and Pb3.32Ca1.68(GeO4)(Ge2O7): Two Nonlinear Optical Germanates Induced by Diverse PbOx Polyhedra

    Inorganic Chemistry · 2022-08-17

    Mei Yan, Ru‐Ling Tang, Gang-Xiang Liu, Lei Huai, Wenlong Liu, Sheng‐Ping Guo

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  4. Synthesis, structure, characterization, and electronic structure calculation of a new molecule-inclusion strontium gallate Sr6(Ga12O24)·Bi2O3

    Journal of Solid State Chemistry · 2022-10-06

    Lei Huai, Lunan Zhang, Beibei Zhang, Guangan Jia, Wen‐Dong Yao, Wenlong Liu, Ru‐Ling Tang

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  5. Achieving broadband ultraviolet to mid-infrared transparency in germanate-based nonlinear optical crystals Cs 3 REGe 3 O 9 (RE = Y, Gd)

    Inorganic Chemistry Frontiers · 2023-01-01

    Jinmiao Jiao, Conggang Li, Yuheng She, Ning Ye, Zhanggui Hu, Yicheng Wu

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  6. Deep-ultraviolet nonlinear-optical crystal BaNa2[PO3(OH)]2 with large birefringence and strong second-harmonic-generation response

    Chinese Journal of Structural Chemistry · 2023-01-01

    Yuanyu Yang, Yao Guo, Yi-Gang Chen, Chengbo Li, Xian‐Ming Zhang

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  7. High stability and moderate second-order nonlinear optical properties of hybrid lead-free perovskite [(CH 3 ) 3 NCH 2 Cl]CdCl 3 bulk crystals

    CrystEngComm · 2023-01-01

    Chuanying Shen, Jie Liu, Kui Wu, Longyun Xu, Defu Sun, Yangyang Dang, Jiyang Wang, Duanliang Wang

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  8. KNa 2 La 2 (BO 3 ) 3 : a shortite-type lanthanide borate exhibiting strong nonlinear optical activity induced by isolated [BO 3 ] triangles and distorted [LaO 9 ] polyhedra

    Inorganic Chemistry Frontiers · 2023-01-01

    Jie Song, Conggang Li, Jinmiao Jiao, Yuheng She, Wenli Zhao, Fei Liang, Ning Ye, Zhanggui Hu, Yicheng Wu

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  9. LiVTeO 5 : a mid-infrared nonlinear optical vanadium tellurate crystal exhibiting enhanced second harmonic generation activities and notable birefringence

    Inorganic Chemistry Frontiers · 2023-01-01

    Yuheng She, Jinmiao Jiao, Zheng Wang, Jing Chai, Song Jie, Ning Ye, Zhanggui Hu, Yicheng Wu, Conggang Li

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  10. Small Changes, Big Impact: Tungsten Bronzes with Extremely Large Second Harmonic Generation Achieved by the Transition Metal Doping on the B‐Site

    Advanced Functional Materials · 2023-01-26

    Yejin Pi, Yunseung Kuk, Kang Min Ok

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  11. Polar Bismuth Selenite Iodate Oxide BiSeIO6 with Three Types of Lone Pair Cations in One Structure

    Inorganic Chemistry · 2023-01-27

    Lei Geng, Wenfei Li, Baozhu Zhu, Shihua Ma, Baotong Liu, Kaiyue Jiang, Hong‐Yan Lu, Chang‐Yu Meng

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  12. A Polar Tetragonal Tungsten Bronze with Colossal Second‐Harmonic Generation

    Advanced Science · 2023-04-23

    Yunseung Kuk, Seong Bin Bae, Sang Mo Yang, Kang Min Ok

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  13. Ultraviolet Crystal with Strong Optical Nonlinearity by Creating Halogen-Centered Secondary Building Blocks

    Chemistry of Materials · 2023-07-06

    Xuping Shi, Abudukadi Tudi, Minqiang Gai, Zhihua Yang, Shujuan Han, Shilie Pan

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  14. Rational Design of a Niobium Tellurite Crystal Nb2Te3O11 Exhibiting Good Overall Infrared NLO Performance by Structural Genetic Engineering

    Inorganic Chemistry · 2023-10-12

    Tinghui Zhang, Jinmiao Jiao, Wenli Zhao, Fulei Wang, Fei Liang, Ning Ye, Zhanggui Hu, Yicheng Wu, Conggang Li

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  15. Tailored Synthesis of Two Metal Borates KSrM3B2O9 (M = Al and Ga) Exhibiting Wide Ultraviolet Transparency

    Inorganic Chemistry · 2023-10-23

    Shuaifeng Li, Jinmiao Jiao, Yuheng She, Ning Ye, Zhanggui Hu, Yicheng Wu, Conggang Li

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  16. K4ZnV5O15Cl: A Congruent‐Melting Mid‐Infrared Nonlinear Optical Crystal Combined with Strong Second‐Harmonic Generation and High Laser‐Induced Damage Threshold

    Advanced Optical Materials · 2023-12-12

    Wenfei Li, Lei Geng, Chang‐Yu Meng, Shihua Ma, Baozhu Zhu, You‐Zhao Lan, Qi Wu

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  17. A defect pyrochlore-like acentric cubic lead titanium-tellurate crystal exhibiting strong second harmonic generation activity and an extended transparent window

    Inorganic Chemistry Frontiers · 2024-01-01

    Tinghui Zhang, Lili Li, Jing Chai, Haitao Zhou, Ning Ye, Zhanggui Hu, Yicheng Wu, Conggang Li

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  18. Ba 5 Y 12 Zn[O(SiO 4 )] 8 : a novel non-centrosymmetric silicate with a short ultraviolet cut-off edge featuring [ZnSi 4 O 16 ] and [SiO 4 ] units

    New Journal of Chemistry · 2024-01-01

    Aihaimaitijiang Ababaikeri, Xueting Pan, Gulimeikereyi Tuniyazi, Xiangzhan Jiang, Yanhui Zhang, Dilnur Malik

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  19. Computer-aided screening of bismuth molybdates nonlinear optical crystals γ -Bi 2 MoO 6

    Inorganic Chemistry Frontiers · 2024-01-01

    Xuefan Wang, Yan Xiao, Wenjing Tan, Hongbo Huang, Daqing Yang, Ying Wang, Bingbing Zhang

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  20. Li13YGe4O16: A Mid-infrared Rare-Earth Germanate Nonlinear Optical Crystal Featuring a Broad Transmission Range and an Enlarged Band Gap

    Inorganic Chemistry · 2024-02-15

    Jinmiao Jiao, Conggang Li, Yuheng She, Haiyan Shi, Wenhao Di, Ning Ye, Zhanggui Hu, Yicheng Wu

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  21. Theoretical Investigation of Structural, Electronic and Optical Properties of Cs3MoO4(HCO3) with NLO Active Functional Units

    European Journal of Inorganic Chemistry · 2024-03-06

    Jinyu Hu, Yinsheng Huang, Hui Zhu, Huiyan Zhao, Chao He, Xihu Wang

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  22. Two Acentric Zn-Based l -Tartrates with Moderate Second Harmonic Generation Responses and Large Birefringence

    Inorganic Chemistry · 2024-03-14

    Ting Yu, Jiahao Wan, Jingye Yang, Xiaokang Luo, Man Xie, Lehui Liu, Hongming Liu

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  23. A congruent-melting rubidium zinc vanadium oxychloride exhibiting strong mid-infrared second-harmonic generation and high laser-induced damage threshold

    Journal of Alloys and Compounds · 2024-04-14

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  24. Theoretical insight on structure, electronic, and optical properties of two d 0–d 10 electron transition-metal oxyhalides SHG materials

    Journal of Physics D Applied Physics · 2024-06-12

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  25. Ba3Zn4Si4O15: A Novel Centrosymmetric Silicate with Isolated SiO4 and Si2O7 Units

    Zeitschrift für anorganische und allgemeine Chemie · 2024-06-19

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  26. Bi(SO4)F·H2O and Bi(SO4)(NO3)·3H2O: Chemical Substitution-Induced Birefringence Enhancement in Bismuth Sulfates

    Inorganic Chemistry · 2024-07-04

    Jiachen Lu, Yang Li, Yunseung Kuk, Seung-Hun Choi, Kyungmo Kim, Chanhee Ko, Zhiyong Bai, Kang Min Ok

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  27. La3Ga5M0.5Sn0.5O14, (M = Ge, Si): Design and Synthesis of Two Langasite Nonlinear Optical Materials with Large Second Harmonic Generation and Birefringence Induced by Distorted (Sn/M)O6 Octahedra

    Inorganic Chemistry · 2024-07-25

    Jingxuan Hou, Jiajia Wang, Fei Liang, Shihui Ma, Hongwei Yu, Hongping Wu, Ning Ye, Zhanggui Hu, Yicheng Wu

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  28. K4Cd3Ge4O13: A Congruent-Melting Germanate Nonlinear Optical Crystal with a Moderate Second-Harmonic Generation Intensity and Broad Transparent Window

    Inorganic Chemistry · 2024-09-30

    Yujun Wang, Jing Chai, Jinmiao Jiao, Xianghao Kong, Tinghui Zhang, Ning Ye, Zhanggui Hu, Yicheng Wu, Conggang Li

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  29. Lanthanide Contraction Eliminates Disorder while Holding Robust Second Harmonic Generation in a Series of Polyiodates

    Chemistry of Materials · 2024-10-04

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  30. Cationic Coordination Modification Drives Birefringence and Nonlinear Effect Double Lifting in Sulfate

    Inorganic Chemistry · 2024-12-18

    Jiahao Wan, Ping Wang, Zhenhua Li, Chunxiang Wu, Weining Zheng, Lehui Liu, Hongming Liu

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  31. Two-Step Substitutions of Square Pyramidal VO5 with CdO4Br to Achieve Higher Laser-Induced Damage Threshold from Polar Oxybromides Rb4CdV5O15Br to Rb3CdV4O12Br

    Inorganic Chemistry · 2025-03-24

    Baozhu Zhu, Lei Geng, Shoubao Zhang, Shuo Han, Chang‐Yu Meng, You‐Zhao Lan, Qi Wu

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  32. Vacancy-Enhanced Biotite Nanosheets for Optical Limiters

    ACS Applied Nano Materials · 2025-04-15

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  33. Exploration of bismuth-based nanomaterials: From fundamental concepts to innovative synthesis techniques and emerging applications

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  34. Ca 7 (TeO 3 ) 6 (MoO 4 ): A Promising Mid-Infrared Nonlinear Optical Crystal Activated via a Module-Oriented Dimensionality Reduction Strategy

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  35. Tailoring ordered structures with distorted [TeO 3 ] and aligned [ScO 6 ] motifs for balanced nonlinear optical properties in rare-earth tellurate crystals

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  36. LiBa 2 GaSi 2 O 8 : A Noncentrosymmetric Silicate Exhibiting Wide Transmission Range and Moderate Second Harmonic Generation Response

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  37. A promising mid-infrared nonlinear optical crystal with well-balanced properties

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  38. BaScSi2O6F: A barium-containing rare-earth metal silicate fluoride with a short cutoff edge

    Journal of Molecular Structure · 2026-01-15

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  39. Strategic Integration Between Trigonal Architecture Construction and Molecular Polarization Enhancement for Record SHG Effect in Selenates

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  40. Strategic Integration Between Trigonal Architecture Construction and Molecular Polarization Enhancement for Record SHG Effect in Selenates

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  41. Rational design of a quasi-0D tungsten tellurite nonlinear optical crystal with exceptionally balanced properties

    Science China Chemistry · 2026-03-19

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  42. Breaking Inversion Symmetry via Vanadium Coordination Engineering in Bismuth Vanadium Selenites

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  43. Cation-regulated orientational coherence in one-dimensional antimony fluoride selenate chains modulates ultraviolet second-Harmonic generation

    Chinese Chemical Letters · 2026-09-01

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