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RESEARCH PAPER · Inorganic Chemistry · 2025

Two-Step Substitutions of Square Pyramidal VO5 with CdO4Br to Achieve Higher Laser-Induced Damage Threshold from Polar Oxybromides Rb4CdV5O15Br to Rb3CdV4O12Br

Baozhu Zhu, Lei Geng, Shoubao Zhang, Shuo Han, Chang‐Yu Meng, You‐Zhao Lan, Qi Wu

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Two-Step Substitutions of Square Pyramidal VO5 with CdO4Br to Achieve Higher Laser-Induced Damage Threshold from Polar Oxybromides Rb4CdV5O15Br to Rb3CdV4O12BrOriginalCd 5 Te 4 O 12 X 2 (X = Cl, Br, I): a new oxyhalide family with [CdO 4 X] mixed anionic units and adjustable optical properties4Cs2CdV2O6Br2: A Mid-Infrared Nonlinear Optical Vanadate Containing Both d0/d10 Transition Metal Cations and Bromine Anions5KF·[SO 2 (NH 2 ) 2 ]: the First Deep‐Ultraviolet Transparent Sulfonamide Fluoride Nonlinear Optical Crystal with Novel Cairo Pentagonal Structure13KF·[SO 2 (NH 2 ) 2 ]: the First Deep‐Ultraviolet Transparent Sulfonamide Fluoride Nonlinear Optical Crystal with Novel Cairo Pentagonal Structure5A Band‐Orientation Co‐Anchoring Strategy for the Design of a High‐Performance Mid‐Infrared Nonlinear Optical Crystal3A Band‐Orientation Co‐Anchoring Strategy for the Design of a High‐Performance Mid‐Infrared Nonlinear Optical Crystal12Mid Infrared Nonlinear Optical Series A 4 MV 5 O 15 X (A = K, Rb; M = Zn, Cd; X = Cl, Br) with Strong Second Harmonic Generation Responses3Te–Se replacement induced structural transition and enhanced band gaps in Cd 5 Se 4 O 12 Cl 2 and Cd 5 Se 4 O 12 Br 21InO6X (X = Cl, Br): distinct functional motif family for nonlinear optical materials5Cd/V Ratio-Driven Centrosymmetric Transition of Crystal Structures in Cesium Cadmium Vanadate Oxychlorides Cs 3 CdV 4 O 12 Cl and CsCdV 2 O 6 Cl0

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  1. Cd 5 Te 4 O 12 X 2 (X = Cl, Br, I): a new oxyhalide family with [CdO 4 X] mixed anionic units and adjustable optical properties

    Dalton Transactions · 2025-01-01

    Maqsood Iqbal, Jiazheng Zhou, Hongshan Wang, Juanjuan Lu, Shilie Pan, Junjie Li

    Read original paper ↗ ·

  2. Cs2CdV2O6Br2: A Mid-Infrared Nonlinear Optical Vanadate Containing Both d0/d10 Transition Metal Cations and Bromine Anions

    Inorganic Chemistry · 2025-06-30

    Lei Geng, Baozhu Zhu, You‐Zhao Lan, Chang‐Yu Meng, Qi Wu

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  3. KF·[SO 2 (NH 2 ) 2 ]: the First Deep‐Ultraviolet Transparent Sulfonamide Fluoride Nonlinear Optical Crystal with Novel Cairo Pentagonal Structure

    Angewandte Chemie International Edition · 2025-09-14

    Yuchen Yan, Xin Wen, Piao Tang, Jingyao Lu, Jindong Chen, Jiyang Wang, Zhanggui Hu, Ning Ye, Guang Peng

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  4. KF·[SO 2 (NH 2 ) 2 ]: the First Deep‐Ultraviolet Transparent Sulfonamide Fluoride Nonlinear Optical Crystal with Novel Cairo Pentagonal Structure

    Angewandte Chemie · 2025-09-14

    Yuchen Yan, Xin Wen, Piao Tang, Jingyao Lu, Jindong Chen, Jiyang Wang, Zhanggui Hu, Ning Ye, Guang Peng

    Read original paper ↗ ·

  5. A Band‐Orientation Co‐Anchoring Strategy for the Design of a High‐Performance Mid‐Infrared Nonlinear Optical Crystal

    Angewandte Chemie · 2025-10-17

    Haochen Li, Haotian Tian, Pifu Gong, Tianyu Wang, Hongyu Liu, Bing Li, Qian Wu, Mingjun Xia

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  6. A Band‐Orientation Co‐Anchoring Strategy for the Design of a High‐Performance Mid‐Infrared Nonlinear Optical Crystal

    Angewandte Chemie International Edition · 2025-10-17

    Haochen Li, Haotian Tian, Pifu Gong, Tianyu Wang, Hongyu Liu, Bing Li, Qian Wu, Mingjun Xia

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  7. Mid Infrared Nonlinear Optical Series A 4 MV 5 O 15 X (A = K, Rb; M = Zn, Cd; X = Cl, Br) with Strong Second Harmonic Generation Responses

    Inorganic Chemistry · 2025-12-23

    Haochen Li, Jinhua Wang, Haotian Tian, Xiaodong Zhang, T. Wang, Hongrui Liu, Bing Li, Pengyun Chen, Pifu Gong, Qian Wu, Shu Hai Guo, Mingjun Xia

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  8. Te–Se replacement induced structural transition and enhanced band gaps in Cd 5 Se 4 O 12 Cl 2 and Cd 5 Se 4 O 12 Br 2

    Dalton Transactions · 2026-01-01

    Maqsood Iqbal, Jiazheng Zhou, Aqsa Munawar, Juanjuan Lu, Junjie Li

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  9. InO6X (X = Cl, Br): distinct functional motif family for nonlinear optical materials

    Science China Materials · 2026-01-04

    Dan-Dan Zhou, Chunli Hu, Bingxuan Li, Jianggao Mao, Fang Kong

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  10. Cd/V Ratio-Driven Centrosymmetric Transition of Crystal Structures in Cesium Cadmium Vanadate Oxychlorides Cs 3 CdV 4 O 12 Cl and CsCdV 2 O 6 Cl

    Inorganic Chemistry · 2026-05-14

    Xindan Xu, Lei Geng, Baozhu Zhu, Shoubao Zhang, Yuqi Song, Changyu Meng

    Read original paper ↗ ·
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