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RESEARCH PAPER · Inorganic Chemistry Frontiers · 2023

KNa 2 La 2 (BO 3 ) 3 : a shortite-type lanthanide borate exhibiting strong nonlinear optical activity induced by isolated [BO 3 ] triangles and distorted [LaO 9 ] polyhedra

Jie Song, Conggang Li, Jinmiao Jiao, Yuheng She, Wenli Zhao, Fei Liang, Ning Ye, Zhanggui Hu, Yicheng Wu

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KNa 2 La 2 (BO 3 ) 3 : a shortite-type lanthanide borate exhibiting strong nonlinear optical activity induced by isolated [BO 3 ] triangles and distorted [LaO 9 ] polyhedraOriginalTailored Synthesis of Two Metal Borates KSrM3B2O9 (M = Al and Ga) Exhibiting Wide Ultraviolet Transparency4A bifunctional primitive strategy induces enhancements of large second harmonic generation and wide UV transmittance in rare-earth borates containing [B 5 O 10 ] groups22A-site cation manipulation of exemplary second harmonic generation response and optical anisotropy in rare-earth borates18Discovery of a new bimetallic borate with strong optical anisotropy activated by π-conjugated [B 2 O 5 ] units3KNa 2 Lu(BO 3 ) 2 : A Rare-Earth Borate Crystal Characterized by an Enhanced Birefringence and Wide Ultraviolet Transparency Range19Synthesis, crystal structure and luminescent properties of a quinary borate-phosphate compound CsNa2Dy2(BO3)(PO4)21Li13YGe4O16: A Mid-infrared Rare-Earth Germanate Nonlinear Optical Crystal Featuring a Broad Transmission Range and an Enlarged Band Gap10Na3K6(CO3)3(NO3)2X·6H2O (X = NO3, Cl, Br): Exploring High-Performance UV Birefringent Crystals Induced by Coplanar π-Conjugated CO3 and NO3 Groups15Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units66A Rare-Earth-Based Borate Optical Crystal with Enlarged Dihedral Angles of Distinct [BO3] Groups Exhibiting a Wide UV Transparent Range8Ba2ScBSi2O9: A Mixed-Coordination Borosilicate with a Low B/Si Ratio Exhibiting Enhanced Second Harmonic Generation Response7Breaking Symmetry for SHG Response: Lanthanide Acetate Crystals via Water Molecule Regulation Strategy5Amino substitution strategy achieves significant blue shift while preserving high optical anisotropy: A2(H3C3N4S2)2•H2O (A =NH4, K, Rb, Cs)6Unveiling Noncentrosymmetric Pyridine Carboxylates from Centrosymmetric Templates through Motif Configuration Modulation in Zero-Dimensional System7Novel antimony-based mixed halides exhibiting an excellent SHG response and a broad transmission range20A potential UV nonlinear-optical crystal with a strong second-harmonic response: RbNa 2 Eu 2 (BO 3 ) 35Achieving balanced UV SHG responses, optical band gaps and birefringence in rare earth compounds Ln(IO 3 )(SO 4 )·3H 2 O (Ln = Y, Gd, Er, Ho, Dy, Eu)4Two alkali metal borates built by {Li@B 14 } and {B 15 } cluster units1Design of rare earth borate short-wave UV nonlinear optical crystals with strengthened second harmonic generation activities via cationic modification strategy11A Promising Short-Wave UV NLO Crystal with an Optimized KBBF-like Structure and Well-Balanced Properties Achieved via a Chemical Substitution Strategy6Syntheses, structural characterization, and nonlinear optical properties of mixed alkaline/alkaline earth metal borophosphates1Design and Synthesis of a Rare Earth Borate Ultraviolet Nonlinear Optical Crystal K 3 Lu 2 (BO 3 ) 38REV 3 (BO 3 ) 4 (RE = La–Nd): a series of rare earth vanadoborates exhibit large birefringence induced by distorted V III O 6 groups2Two scandium borate UV NLO crystals designed through chemical element substitution1Li 6 Lu(BO 3 ) 3 : A Rare-Earth Borate Crystal Exhibiting Large Birefringence and Broad UV Transparency1Cation-driven symmetry breaking in rare-earth borates toward ultraviolet nonlinear optical materials1

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  1. Tailored Synthesis of Two Metal Borates KSrM3B2O9 (M = Al and Ga) Exhibiting Wide Ultraviolet Transparency

    Inorganic Chemistry · 2023-10-23

    Shuaifeng Li, Jinmiao Jiao, Yuheng She, Ning Ye, Zhanggui Hu, Yicheng Wu, Conggang Li

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  2. A bifunctional primitive strategy induces enhancements of large second harmonic generation and wide UV transmittance in rare-earth borates containing [B 5 O 10 ] groups

    Chemical Science · 2024-01-01

    Shuaifeng Li, Weiming Li, Xiang Li, Guangsai Yang, Ning Ye, Zhanggui Hu, Yicheng Wu, Conggang Li

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  3. A-site cation manipulation of exemplary second harmonic generation response and optical anisotropy in rare-earth borates

    Chemical Science · 2024-01-01

    Jie Song, Huijian Zhao, Conggang Li, Ning Ye, Zhanggui Hu, Yicheng Wu

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  4. Discovery of a new bimetallic borate with strong optical anisotropy activated by π-conjugated [B 2 O 5 ] units

    Dalton Transactions · 2024-01-01

    Meihui Chen, Wei Wei, Jiawei Zhao, Donghai An, Yanna Chen

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  5. KNa 2 Lu(BO 3 ) 2 : A Rare-Earth Borate Crystal Characterized by an Enhanced Birefringence and Wide Ultraviolet Transparency Range

    Inorganic Chemistry · 2024-01-23

    Xianghao Kong, Jinmiao Jiao, Yuheng She, Ning Ye, Zhanggui Hu, Yicheng Wu, Conggang Li

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  6. Synthesis, crystal structure and luminescent properties of a quinary borate-phosphate compound CsNa2Dy2(BO3)(PO4)2

    Zeitschrift für Kristallographie - Crystalline Materials · 2024-01-23

    Kai Liu, Shipeng Yang, Junfeng Tian, Peixin Zhang, Xiaohan Hei, Zhongfeng Jiang

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  7. Li13YGe4O16: A Mid-infrared Rare-Earth Germanate Nonlinear Optical Crystal Featuring a Broad Transmission Range and an Enlarged Band Gap

    Inorganic Chemistry · 2024-02-15

    Jinmiao Jiao, Conggang Li, Yuheng She, Haiyan Shi, Wenhao Di, Ning Ye, Zhanggui Hu, Yicheng Wu

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  8. Na3K6(CO3)3(NO3)2X·6H2O (X = NO3, Cl, Br): Exploring High-Performance UV Birefringent Crystals Induced by Coplanar π-Conjugated CO3 and NO3 Groups

    Inorganic Chemistry · 2024-04-23

    Wencong Li, Junbo Wang, Lili Liu, Chunmei Huang, Yanyan Ding, Mengmeng Zhu, Jindan Tian, Hai-Xin Qi, Yaoqing Chu, Jiayue Xu

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  9. Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units

    Coordination Chemistry Reviews · 2024-07-03

    Bo Zhang, Mao‐Yin Ran, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  10. A Rare-Earth-Based Borate Optical Crystal with Enlarged Dihedral Angles of Distinct [BO3] Groups Exhibiting a Wide UV Transparent Range

    Inorganic Chemistry · 2024-07-26

    Jie Song, Xianghao Kong, Conggang Li, Jinmiao Jiao, Yuheng She, Ning Ye, Zhanggui Hu, Yicheng Wu

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  11. Ba2ScBSi2O9: A Mixed-Coordination Borosilicate with a Low B/Si Ratio Exhibiting Enhanced Second Harmonic Generation Response

    Inorganic Chemistry · 2024-08-21

    Ming Yang, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongping Wu

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  12. Breaking Symmetry for SHG Response: Lanthanide Acetate Crystals via Water Molecule Regulation Strategy

    Inorganic Chemistry · 2024-10-24

    Yaolong Zhu, Yong Tao, Can Yang, Yuwei Kang, Xuefei Wang, Jie Gou, Yi Xiong, Qi Wu

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  13. Amino substitution strategy achieves significant blue shift while preserving high optical anisotropy: A2(H3C3N4S2)2•H2O (A =NH4, K, Rb, Cs)

    Chinese Chemical Letters · 2024-11-10

    Shuang Zhao, Fei Jia, Kaibei Zhan, Rui‐Xi Wang, Pengfei Tan, Lin Shen, Li‐Ming Wu, Ling Chen

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  14. Unveiling Noncentrosymmetric Pyridine Carboxylates from Centrosymmetric Templates through Motif Configuration Modulation in Zero-Dimensional System

    Inorganic Chemistry · 2024-11-12

    Qingwen Zhu, Yong Tao, Can Yang, Jie Gou, Yaolong Zhu, Xuefei Wang, Qi Wu

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  15. Novel antimony-based mixed halides exhibiting an excellent SHG response and a broad transmission range

    Inorganic Chemistry Frontiers · 2024-12-05

    Luli Wang, Han Luo, Siyu Chen, Ling Huang, Liling Cao, Xuehua Dong, Guohong Zou

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  16. A potential UV nonlinear-optical crystal with a strong second-harmonic response: RbNa 2 Eu 2 (BO 3 ) 3

    Inorganic Chemistry Frontiers · 2025-01-01

    Dan Li, Jingyu Shang, Ming Gao, Jiangtao Fan, Zhangui Hu, Ping Peng, Yicheng Wu

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  17. Achieving balanced UV SHG responses, optical band gaps and birefringence in rare earth compounds Ln(IO 3 )(SO 4 )·3H 2 O (Ln = Y, Gd, Er, Ho, Dy, Eu)

    Dalton Transactions · 2025-01-01

    Shihua Ma, Lei Geng, Baozhu Zhu, Changyu Meng

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  18. Two alkali metal borates built by {Li@B 14 } and {B 15 } cluster units

    Dalton Transactions · 2025-01-01

    Mian Li, Dan Qin, Juan Chen, Qi Wei, Guo‐Yu Yang

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  19. Design of rare earth borate short-wave UV nonlinear optical crystals with strengthened second harmonic generation activities via cationic modification strategy

    Chinese Chemical Letters · 2025-02-27

    Huijian Zhao, Jie Song, Shuaifeng Li, Shuaifeng Li, Xianghao Kong, Conggang Li, Ning Ye, Zhanggui Hu

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  20. A Promising Short-Wave UV NLO Crystal with an Optimized KBBF-like Structure and Well-Balanced Properties Achieved via a Chemical Substitution Strategy

    Inorganic Chemistry · 2025-07-02

    Shuaifeng Li, Mengru Liu, Peng Zhao, Huijian Zhao, Ning Ye, Zhanggui Hu, Conggang Li

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  21. Syntheses, structural characterization, and nonlinear optical properties of mixed alkaline/alkaline earth metal borophosphates

    Journal of Solid State Chemistry · 2025-08-19

    Yang Pan, Jian Qiu Deng, Yucheng Hao, Xi Zhao, Yuanyuan Bao, Zixuan Fang, Chonghai Deng, Kunhong Hu, Wei Cheng, Yuan Hua Lin

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  22. Design and Synthesis of a Rare Earth Borate Ultraviolet Nonlinear Optical Crystal K 3 Lu 2 (BO 3 ) 3

    Inorganic Chemistry · 2025-10-20

    Mingyue Gu, Xianchao Zhu, Zhanggui Hu, Yicheng Wu

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  23. REV 3 (BO 3 ) 4 (RE = La–Nd): a series of rare earth vanadoborates exhibit large birefringence induced by distorted V III O 6 groups

    Chemical Communications · 2026-01-01

    Yu-Long Wei, Wen-Dong Yao, Yi‐Lei Lv, Liang Ma, Ru‐Ling Tang

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  24. Two scandium borate UV NLO crystals designed through chemical element substitution

    Chemical Communications · 2026-01-01

    Zelong Liu, Huijian Zhao, Longyun Xu, Ning Jia, Ning Ye, Zhanggui Hu, Conggang Li

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  25. Li 6 Lu(BO 3 ) 3 : A Rare-Earth Borate Crystal Exhibiting Large Birefringence and Broad UV Transparency

    Inorganic Chemistry · 2026-02-05

    Mingyue Gu, Xianchao Zhu, Zhanggui Hu, Yicheng Wu, Yongmin Guo

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  26. Cation-driven symmetry breaking in rare-earth borates toward ultraviolet nonlinear optical materials

    Materials Today Physics · 2026-07-04

    D K Li, Yujie Zhang, H Liu, Hongping Wu, Zhanggui Hu, Hongwei Yu

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