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RESEARCH PAPER · Dalton Transactions · 2022

LiSrSbS 3 : parallel configurations of lone pair electrons inducing a large birefringence

Alimujiang Yalikun, Kewang Zhang, Jian Wei Han, Zhihua Yang

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LiSrSbS 3 : parallel configurations of lone pair electrons inducing a large birefringenceOriginalCs4Zn5P6S18I2: the Largest Birefringence in Chalcohalide Achieved by Highly Polarizable Nonlinear Optical Functional Motifs21Greatly enhanced optical anisotropy in thiophosphates inspired by rational coupling of tetrahedra and ethane-like [P 2 S 6 ] 4− groups7Simple aliovalent cation substitution to induce strong optical anisotropy enhancement in a rare thioantimonate( v ) family3Stereochemically Active Lone Pair Leads to Birefringence in the Vacancy Ordered Cs3Sb2Cl9 Perovskite Single Crystals13Hg4InS2Cl5: Achieving Giant Optical Anisotropy by Introducing Well‐Aligned Linear [Hg2S2] Units14NaCaGa 3 S 6 : a mixed alkali metal and alkaline earth metal sulfide with a distinctive [Ga 5 S 10 ] ∞ layered framework0Stereochemically active lone pair-induced large optical anisotropy in a novel infrared birefringent crystal Ba 2 La 2 Sb 4 S 10 (S 2 )5Recent progress in structural design strategies of high-birefringence optical crystals54Research progress and future prospect of chalcogenides with large optical anisotropy46Designing High-Performance Short-Wave UV Tellurium-Based Mixed Halides Birefringent Crystals via Halogen Substitution Engineering4Synergistic Enhancement of Band Gap and Optical Anisotropy via Functional-Site Cosubstitution in Antiperovskite-Type Chalcohalides [Ba2K][X][MS4] (M = Ge, Si; X = Cl, Br)2Optimal three-dimensional [Ag 4 P 2 S 6 ]-framework assembly directed by a threefold roto-inversion axis for enhanced birefringence0Anion-Centered Engineering for Simultaneously Enhancing Birefringence and Band Gap in Chalcogenides1Structural Anion Geometry-Regulated Molecular Alignment in [C 10 H 8 NO 2 ]-Based Crystals for Enhancing Ultraviolet Birefringence0Rb 2 ZnGe 3 Se 8 : A Large-Birefringence Layered Chalcogenide Enabled by Anisotropic Electrons in Tetrahedral Units0Domino‐Effect Amplification via Covalent‐Chain Engineering for Giant Birefringence in NaAsQ 2 (Q = S, Se) Crystals0

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  1. Cs4Zn5P6S18I2: the Largest Birefringence in Chalcohalide Achieved by Highly Polarizable Nonlinear Optical Functional Motifs

    Small · 2023-07-18

    Xian‐Dan Chai, Mingze Li, Shujuan Lin, Wen‐Fa Chen, Xiao‐Ming Jiang, Bin‐Wen Liu, Guo‐Cong Guo

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  2. Greatly enhanced optical anisotropy in thiophosphates inspired by rational coupling of tetrahedra and ethane-like [P 2 S 6 ] 4− groups

    Inorganic Chemistry Frontiers · 2024-01-01

    Ning Zhao, Dazhi Lu, Jingjing Xu, Kui Wu, Haohai Yu, Huaijin Zhang

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  3. Simple aliovalent cation substitution to induce strong optical anisotropy enhancement in a rare thioantimonate( v ) family

    Inorganic Chemistry Frontiers · 2024-01-01

    Qixian Ren, Wangfei Che, Mengmeng Chen, Cui Chen, Yabo Wu, Zhi Su

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  4. Stereochemically Active Lone Pair Leads to Birefringence in the Vacancy Ordered Cs3Sb2Cl9 Perovskite Single Crystals

    The Journal of Physical Chemistry Letters · 2024-03-11

    Shramana Guha, Amit Dalui, Piyush Kanti Sarkar, Sima Roy, Atanu Paul, Sujit Kamilya, Abhishake Mondal, Indra Dasgupta, D. D. Sarma, Somobrata Acharya

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  5. Hg4InS2Cl5: Achieving Giant Optical Anisotropy by Introducing Well‐Aligned Linear [Hg2S2] Units

    Advanced Optical Materials · 2024-12-13

    Qixian Ren, Yu Chu, Wenqi Jin, Mengmeng Chen, Cui Chen, Yabo Wu, Shilie Pan

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  6. NaCaGa 3 S 6 : a mixed alkali metal and alkaline earth metal sulfide with a distinctive [Ga 5 S 10 ] ∞ layered framework

    Dalton Transactions · 2025-01-01

    Jiale Chen, Haipeng Zhou, Huimin Sha, Jinfeng Liu, Xiu Zhu, Guisheng Xu, Jiankang Wang

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  7. Stereochemically active lone pair-induced large optical anisotropy in a novel infrared birefringent crystal Ba 2 La 2 Sb 4 S 10 (S 2 )

    Inorganic Chemistry Frontiers · 2025-01-01

    Jingdong Yan, Xiangran Kong, Shichao Cheng, Tao Liu, Hongwei Leng, Yunfei Shang, Zuotao Lei, Chunhui Yang

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  8. Recent progress in structural design strategies of high-birefringence optical crystals

    Coordination Chemistry Reviews · 2025-05-08

    A-Lan Xu, Mao‐Yin Ran, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  9. Research progress and future prospect of chalcogenides with large optical anisotropy

    Coordination Chemistry Reviews · 2025-06-20

    Zhen-Cheng Wu, Sheng‐Ping Guo

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  10. Designing High-Performance Short-Wave UV Tellurium-Based Mixed Halides Birefringent Crystals via Halogen Substitution Engineering

    Crystal Growth & Design · 2025-06-24

    Xiang Mao, Yu Yan, Yingzi Zhang, Xuehua Dong, Ling Huang, Liling Cao, Daojiang Gao, Guohong Zou

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  11. Synergistic Enhancement of Band Gap and Optical Anisotropy via Functional-Site Cosubstitution in Antiperovskite-Type Chalcohalides [Ba2K][X][MS4] (M = Ge, Si; X = Cl, Br)

    Inorganic Chemistry · 2025-08-26

    Yong‐Fang Shi, Shenghua Zhou, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  12. Optimal three-dimensional [Ag 4 P 2 S 6 ]-framework assembly directed by a threefold roto-inversion axis for enhanced birefringence

    Inorganic Chemistry Frontiers · 2026-01-01

    MF Zhang, C Hu, Jiang‐Gao Mao

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  13. Anion-Centered Engineering for Simultaneously Enhancing Birefringence and Band Gap in Chalcogenides

    Chemistry of Materials · 2026-01-19

    Chao-Hong Xie, Lu Liu, Xiao‐Ming Jiang, Bin-Wen Liu, Guo‐Cong Guo

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  14. Structural Anion Geometry-Regulated Molecular Alignment in [C 10 H 8 NO 2 ]-Based Crystals for Enhancing Ultraviolet Birefringence

    Crystal Growth & Design · 2026-04-07

    YaoGuo Shen, Yiman Yang, Jiajia Xiong, Xinyi Wang

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  15. Rb 2 ZnGe 3 Se 8 : A Large-Birefringence Layered Chalcogenide Enabled by Anisotropic Electrons in Tetrahedral Units

    Inorganic Chemistry · 2026-06-15

    Xinchen Chen, Yabo Wu, Wangfei Che, Shuyi Mi, Juanjuan Lu, Chen Cui

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  16. Domino‐Effect Amplification via Covalent‐Chain Engineering for Giant Birefringence in NaAsQ 2 (Q = S, Se) Crystals

    Laser & Photonics Review · 2026-09-24

    Bo Zhang, Weiqi Huang, Yang Chi, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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