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RESEARCH ARTICLE · Angewandte Chemie · 2023

Intense d‐p Hybridization in Nb3O15 Tripolymer Induced the Largest Second Harmonic Generation Response and Birefringence in Germanates

Kaichuang Chen, Chensheng Lin, Jindong Chen, Guangsai Yang, Haotian Tian, Min Luo, Tao Yan, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Ning Ye, Guang Peng

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Intense d‐p Hybridization in Nb3O15 Tripolymer Induced the Largest Second Harmonic Generation Response and Birefringence in GermanatesOriginalAchieving broadband ultraviolet to mid-infrared transparency in germanate-based nonlinear optical crystals Cs 3 REGe 3 O 9 (RE = Y, Gd)16Optimized arrangement of non-π-conjugated PO 3 NH 3 units leads to enhanced ultraviolet optical nonlinearity in NaPO 3 NH 328Rb 8 Nb 10 Ge 6 O 41 : a new niobium-germanate crystal featuring unique one-dimensional [Nb 7 O 30 ] ∞ chains and wide mid-IR transparency2A Band‐Orientation Co‐Anchoring Strategy for the Design of a High‐Performance Mid‐Infrared Nonlinear Optical Crystal2Realizing Phase‐Matching of Nonlinear Optical [ABa 3 Br 2 ][Ga 5 Se 10 ] (A = Cs, Rb, K, Na) Through Large Anisotropic Lattice Distortion6Positional Isomerism Controls Polarity and Nonlinear Optical Properties in One‐Dimensional Hybrid Germanium Halides0Hierarchical Ordering Decouples the SHG–Birefringence–LIDT Trade‐Off in a Single‐Phase Mid‐Infrared Nonlinear Optical Crystal0

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  1. Achieving broadband ultraviolet to mid-infrared transparency in germanate-based nonlinear optical crystals Cs 3 REGe 3 O 9 (RE = Y, Gd)

    Inorganic Chemistry Frontiers · 2023

    Jinmiao Jiao, Conggang Li, Yuheng She, Ning Ye, Zhanggui Hu, Yicheng Wu

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  2. Optimized arrangement of non-π-conjugated PO 3 NH 3 units leads to enhanced ultraviolet optical nonlinearity in NaPO 3 NH 3

    Inorganic Chemistry Frontiers · 2024

    Lingli Wu, Haotian Tian, Chensheng Lin, Xin Yi Zhao, Huixin Fan, Pengxiang Dong, Shunda Yang, Ning Ye, Min Luo

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  3. Rb 8 Nb 10 Ge 6 O 41 : a new niobium-germanate crystal featuring unique one-dimensional [Nb 7 O 30 ] ∞ chains and wide mid-IR transparency

    Dalton Transactions · 2024

    Jing Chai, Yuheng She, Jinmiao Jiao, Lili Li, Ning Ye, Zhanggui Hu, Yicheng Wu, Conggang Li

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  4. A Band‐Orientation Co‐Anchoring Strategy for the Design of a High‐Performance Mid‐Infrared Nonlinear Optical Crystal

    Angewandte Chemie · 2025

    Haochen Li, Haotian Tian, Pifu Gong, Tianyu Wang, Hongyu Liu, Bing Li, Qian Wu, Mingjun Xia

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  5. Realizing Phase‐Matching of Nonlinear Optical [ABa 3 Br 2 ][Ga 5 Se 10 ] (A = Cs, Rb, K, Na) Through Large Anisotropic Lattice Distortion

    Angewandte Chemie · 2026

    Meng‐Na Jing, Si‐Fan Lu, Xiao‐Ming Jiang, Bin‐Wen Liu, Guo‐Cong Guo

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  6. Positional Isomerism Controls Polarity and Nonlinear Optical Properties in One‐Dimensional Hybrid Germanium Halides

    Angewandte Chemie · 2026

    Shaohua Xiao, Xingxing Jiang, Kaining Duanmu, Chao Wu, Zheshuai Lin, Zhipeng Huang, Jinhu Yang, Mark Graeme Humphrey, C L Zhang

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  7. Hierarchical Ordering Decouples the SHG–Birefringence–LIDT Trade‐Off in a Single‐Phase Mid‐Infrared Nonlinear Optical Crystal

    Angewandte Chemie · 2026

    Yan Guo, Ming‐Xin Li, Yi Guo, Bin‐Wen Liu, Xiao‐Ming Jiang, Guo‐Cong Guo

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