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RESEARCH PAPER · Inorganic Chemistry Frontiers · 2025

Isovalent cation substitution drives structural transformation and infrared nonlinear optical activity in Eu-based chalcogenides

Ping Feng, Shenghua Zhou, Mao‐Yin Ran, Bingxuan Li, Xin-Tao Wu, Hua Lin, Qi‐Long Zhu

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Isovalent cation substitution drives structural transformation and infrared nonlinear optical activity in Eu-based chalcogenidesOriginalTernary Antimony Selenide Semiconductors: Synthesis, Crystal Structure, Electronic Structure, and Optical Properties5From Centrosymmetric Eu 2 Ga 2 S 5 to Noncentrosymmetric EuMg 6 Ga 6 S 16 via Introduction of Distorted MgS 6 Octahedron: Featuring Wide Bandgap and Nonlinear Optical Activity3Structure-property relationships in IR nonlinear optical chalcogenides with stereochemically active lone pairs29A high-performance IR nonlinear optical material Sr 3 MnGe 2 S 8 achieved via partial cation substitution-induced structural transformation2ABCQ4型硫属化物红外非线性光学材料的构效关系（特邀）0SrMnGeS 4 : A Two-Dimensional Layered Chalcogenide with Magnetic Triangular Lattice0Discovery of Noncentrosymmetric Sr 3 As 2 S 7 and Sr 3 As 2 Se 2.5 S 4.5 Featuring As 3+ /As 5+ Coordination and Their Strong Nonlinear Optical Response2Synergistic Distortion Engineering: Activating Nonlinear Optical Response in Quaternary Chalcogenides via Lattice‐Induced [MnS 4 ] Asymmetry1Circumventing the Eg–SHG trade-off in selenides: Salt-inclusion [X4Br2][MGa4Se10] with concurrent large band gap and strong nonlinear optical response1Structural origins of the thermal properties of Ba2BiInSe50d-f synergistic effect contributing record-high second-harmonic generation response in phase-matchable Mn-based chalcogenides0

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  1. Ternary Antimony Selenide Semiconductors: Synthesis, Crystal Structure, Electronic Structure, and Optical Properties

    Inorganic Chemistry · 2025-06-18

    James Pirez, Subhendu Jana, Eric A. Gabilondo, Scott McGuigan, P. Shiv Halasyamani, Paul A. Maggard

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  2. From Centrosymmetric Eu 2 Ga 2 S 5 to Noncentrosymmetric EuMg 6 Ga 6 S 16 via Introduction of Distorted MgS 6 Octahedron: Featuring Wide Bandgap and Nonlinear Optical Activity

    Inorganic Chemistry · 2025-08-21

    Qiu-Yang Du, Wen‐Dong Yao, Xu-Bin Ni, Wenfeng Zhou, Wenlong Liu, Sheng‐Ping Guo

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  3. Structure-property relationships in IR nonlinear optical chalcogenides with stereochemically active lone pairs

    Coordination Chemistry Reviews · 2025-09-03

    Hong Chen, Xin‐Tao Wu, Hua Lin

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  4. A high-performance IR nonlinear optical material Sr 3 MnGe 2 S 8 achieved via partial cation substitution-induced structural transformation

    Inorganic Chemistry Frontiers · 2025-11-14

    A-Lan Xu, Mao‐Yin Ran, Zuju Ma, Xin-Tao Wu, Hua Lin, Qi‐Long Zhu

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  5. ABCQ4型硫属化物红外非线性光学材料的构效关系（特邀）

    Chinese Journal of Lasers · 2026-01-01

    王硕 Wang Shuo, 张成龙 Zhang Chenglong, 黄君本 Huang Junben, Ailijiang Abudurusuli, 吐沙姑·阿不都吾甫 Abudouwufu Tushagu

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  6. SrMnGeS 4 : A Two-Dimensional Layered Chalcogenide with Magnetic Triangular Lattice

    Inorganic Chemistry · 2026-01-21

    Chenyao Zhao, Yanhong Wang, Yun Lv, SeungGyum Jung, Hyun‐Joo Koo, Myung‐Hwan Whangbo, Hongcheng Lu

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  7. Discovery of Noncentrosymmetric Sr 3 As 2 S 7 and Sr 3 As 2 Se 2.5 S 4.5 Featuring As 3+ /As 5+ Coordination and Their Strong Nonlinear Optical Response

    Chemistry of Materials · 2026-01-27

    Vidyanshu Mishra, Jinseong Kim, Joshua Lim, Manya Rishi, Joon Ik Jang, Abishek K. Iyer

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  8. Synergistic Distortion Engineering: Activating Nonlinear Optical Response in Quaternary Chalcogenides via Lattice‐Induced [MnS 4 ] Asymmetry

    Advanced Optical Materials · 2026-04-21

    Guili Wang, Siyang Luo, Ming‐Hsien Lee, Jiyong Yao

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  9. Circumventing the Eg–SHG trade-off in selenides: Salt-inclusion [X4Br2][MGa4Se10] with concurrent large band gap and strong nonlinear optical response

    Chinese Chemical Letters · 2026-05-01

    A-Lan Xu, Sheng-Hua Zhou, Bing-Xuan Li, Bo Zhang, Xin-Tao Wu, Hua Lin, Qi‐Long Zhu

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  10. Structural origins of the thermal properties of Ba2BiInSe5

    Materials Chemistry and Physics · 2026-05-25

    Wilarachchige D. C. B. Gunatilleke, George S. Nolas

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  11. d-f synergistic effect contributing record-high second-harmonic generation response in phase-matchable Mn-based chalcogenides

    Chinese Chemical Letters · 2026-09-01

    Yu‐Xuan Zhang, Sheng-Xian Xiao, Zhen-Cheng Wu, Mao‐Yin Ran, Sheng‐Ping Guo

    Read original paper ↗ ·
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