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RESEARCH PAPER · Inorganic Chemistry · 2023

Optimal Design of Mid-Infrared Nonlinear-Optical Crystals: From SrZnSnSe 4 to SrZnSiSe 4

Mengjie Ma, Junhui Dang, Yuandong Wu, Xiao‐Ming Jiang, Dajiang Mei

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Optimal Design of Mid-Infrared Nonlinear-Optical Crystals: From SrZnSnSe 4 to SrZnSiSe 4OriginalA 0.5 H 2 C 6 N 7 O 3 ·4H 2 O (A = Ca 2+ , Sr 2+ ) iso-cyamelurates with ultra-large π-conjugated group and excellent nonlinear optical properties10Rational Design of Noncentrosymmetric Organic–Inorganic Hybrids with a π-Conjugated Pyridium-Type Cation for High Nonlinear-Optical Performance19A ll HgM IV S 4 (A ll = Sr, Ba, M IV = Si, Ge): A Series of Materials with Large Second Harmonic Generation Response and Wide Band Gaps27Double alkaline earth metals sulfide SrMgGeS4 with high laser-induced damage threshold and strong second-harmonic generation29Regulating the key performance parameters for Hg-based IR NLO chalcogenides via bandgap engineering strategy26Structural strategy for advancing nonlinear optical effects in 1D-[MX 2 ] ∞ chains: internal distortion and atomic types2Temperature Dependence of the Second Harmonic Generation Efficiency in Sn2P2(S1-xSex)6Powders2Cs 3 In(In 4 Se 7 )(P 2 Se 6 ): A Multi‐Chromophore Chalcogenide with Excellent Nonlinear Optical Property Designed by Group Grafting55Cs3In(In4Se7)(P2Se6): A Multi‐Chromophore Chalcogenide with Excellent Nonlinear Optical Property Designed by Group Grafting2A Rare Earth Chalcogenide Nonlinear Optical Crystal KLaGeS4: Achieving Good Balance among Band Gap, Second Harmonic Generation Effect, and Birefringence12Effects of different groups on phase-matching and SHG in “3+4” Pn materials0K2HgGe3Se8: A Quaternary Hg-Based Selenide with Nonlinear Optical Properties6From HgGa2(SeO3)4 to Hg2Ga(SeO3)2F: The first HgI-based selenite birefringent crystal triggered by linear groups and fluoride ions29Isovalent cation substitution drives structural transformation and infrared nonlinear optical activity in Eu-based chalcogenides11Nonlinear Optical Effects Modulated by Distinctive Monovalent Cations with Lone Electron Pairs in AGaI 4 (A = Ga + , In + )4Research progress and future prospect of chalcogenides with large optical anisotropy46SrZnSiS4: Shattering the 4.0 eV Threshold toward Dual-Optimized Bandgap and Second-Harmonic Generation5ABCQ4型硫属化物红外非线性光学材料的构效关系（特邀）0SrMnGeS 4 : A Two-Dimensional Layered Chalcogenide with Magnetic Triangular Lattice0CdY 2 Si 2 S 8 : A Wide Bandgap IR NLO Material with d 10 Metal-Induced Structure Transformation from CS to NCS1Synergistic Distortion Engineering: Activating Nonlinear Optical Response in Quaternary Chalcogenides via Lattice‐Induced [MnS 4 ] Asymmetry1Cation-substitution-driven electronic, nonlinear optical, elastic, and thermal transport properties of layered AeHgGeSe4 (Ae = Ba, Sr): A first-principles study0

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  1. A 0.5 H 2 C 6 N 7 O 3 ·4H 2 O (A = Ca 2+ , Sr 2+ ) iso-cyamelurates with ultra-large π-conjugated group and excellent nonlinear optical properties

    Inorganic Chemistry Frontiers · 2023-01-01

    Xiaoguang Du, Fangyan Wang, Fei Liang, Zhanggui Hu, Yicheng Wu, Xinyuan Zhang

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  2. Rational Design of Noncentrosymmetric Organic–Inorganic Hybrids with a π-Conjugated Pyridium-Type Cation for High Nonlinear-Optical Performance

    Inorganic Chemistry · 2023-08-25

    Limei Zhang, Xinyuan Zhang, Fei Liang, Zhanggui Hu, Yicheng Wu

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  3. A ll HgM IV S 4 (A ll = Sr, Ba, M IV = Si, Ge): A Series of Materials with Large Second Harmonic Generation Response and Wide Band Gaps

    Advanced Optical Materials · 2023-09-28

    Xingyu Zhang, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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  4. Double alkaline earth metals sulfide SrMgGeS4 with high laser-induced damage threshold and strong second-harmonic generation

    Materials Today Physics · 2023-09-29

    Hongshan Wang, Yu Chu, Xueting Pan, Zhihua Yang, Shilie Pan, Junjie Li

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  5. Regulating the key performance parameters for Hg-based IR NLO chalcogenides via bandgap engineering strategy

    Chinese Chemical Letters · 2023-12-12

    A-Yang Wang, Shenghua Zhou, Mao‐Yin Ran, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  6. Structural strategy for advancing nonlinear optical effects in 1D-[MX 2 ] ∞ chains: internal distortion and atomic types

    RSC Advances · 2024-01-01

    Chaoyi Zhu

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  7. Temperature Dependence of the Second Harmonic Generation Efficiency in Sn2P2(S1-xSex)6Powders

    Unknown journal · 2024-01-01

    Gary A. Sevison, P. Shiv Halasyamani, Jonathan E. Slagle, Mariacristina Rumi

    Read original paper ↗ ·

  8. Cs 3 In(In 4 Se 7 )(P 2 Se 6 ): A Multi‐Chromophore Chalcogenide with Excellent Nonlinear Optical Property Designed by Group Grafting

    Angewandte Chemie International Edition · 2024-02-01

    Zhen Qian, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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  9. Cs3In(In4Se7)(P2Se6): A Multi‐Chromophore Chalcogenide with Excellent Nonlinear Optical Property Designed by Group Grafting

    Angewandte Chemie · 2024-02-02

    Zhen Qian, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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  10. A Rare Earth Chalcogenide Nonlinear Optical Crystal KLaGeS4: Achieving Good Balance among Band Gap, Second Harmonic Generation Effect, and Birefringence

    Inorganic Chemistry · 2024-06-03

    Yang Liu, Xiangming Li, Shuchang Wu, Mengjie Ma, Xiao‐Ming Jiang, Yuandong Wu, Dajiang Mei

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  11. Effects of different groups on phase-matching and SHG in “3+4” Pn materials

    Physica B Condensed Matter · 2024-07-15

    Chaoyi Zhu, Guojie Jin

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  12. K2HgGe3Se8: A Quaternary Hg-Based Selenide with Nonlinear Optical Properties

    Inorganic Chemistry · 2024-08-26

    Guili Wang, Pifu Gong, Jiyong Yao

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  13. From HgGa2(SeO3)4 to Hg2Ga(SeO3)2F: The first HgI-based selenite birefringent crystal triggered by linear groups and fluoride ions

    Chinese Chemical Letters · 2024-11-03

    Pengfei Li, Chun‐Li Hu, Bo Zhang, Jiang‐Gao Mao, Fang Kong

    Read original paper ↗ ·

  14. Isovalent cation substitution drives structural transformation and infrared nonlinear optical activity in Eu-based chalcogenides

    Inorganic Chemistry Frontiers · 2025-01-01

    Ping Feng, Shenghua Zhou, Mao‐Yin Ran, Bingxuan Li, Xin-Tao Wu, Hua Lin, Qi‐Long Zhu

    Read original paper ↗ ·

  15. Nonlinear Optical Effects Modulated by Distinctive Monovalent Cations with Lone Electron Pairs in AGaI 4 (A = Ga + , In + )

    Small · 2025-02-24

    Hao Huo, Aoge Yao, Zheshuai Lin, Lei Kang

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  16. Research progress and future prospect of chalcogenides with large optical anisotropy

    Coordination Chemistry Reviews · 2025-06-20

    Zhen-Cheng Wu, Sheng‐Ping Guo

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  17. SrZnSiS4: Shattering the 4.0 eV Threshold toward Dual-Optimized Bandgap and Second-Harmonic Generation

    Inorganic Chemistry · 2025-09-04

    Huilin Yin, Xia Wu, Shuchang Wu, Changsheng Sun, Chengxiao Wang, Jiaman Sun, Yang Liu, Xiao‐Ming Jiang, Ximeng Lv, Dajiang Mei

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  18. ABCQ4型硫属化物红外非线性光学材料的构效关系（特邀）

    Chinese Journal of Lasers · 2026-01-01

    王硕 Wang Shuo, 张成龙 Zhang Chenglong, 黄君本 Huang Junben, Ailijiang Abudurusuli, 吐沙姑·阿不都吾甫 Abudouwufu Tushagu

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  19. SrMnGeS 4 : A Two-Dimensional Layered Chalcogenide with Magnetic Triangular Lattice

    Inorganic Chemistry · 2026-01-21

    Chenyao Zhao, Yanhong Wang, Yun Lv, SeungGyum Jung, Hyun‐Joo Koo, Myung‐Hwan Whangbo, Hongcheng Lu

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  20. CdY 2 Si 2 S 8 : A Wide Bandgap IR NLO Material with d 10 Metal-Induced Structure Transformation from CS to NCS

    Inorganic Chemistry · 2026-03-26

    Hongbo Zhang, Haixia Wang, Aoya He, Jiaze Sun, Jindou Hu, G. L. Li

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  21. Synergistic Distortion Engineering: Activating Nonlinear Optical Response in Quaternary Chalcogenides via Lattice‐Induced [MnS 4 ] Asymmetry

    Advanced Optical Materials · 2026-04-21

    Guili Wang, Siyang Luo, Ming‐Hsien Lee, Jiyong Yao

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  22. Cation-substitution-driven electronic, nonlinear optical, elastic, and thermal transport properties of layered AeHgGeSe4 (Ae = Ba, Sr): A first-principles study

    Computational Condensed Matter · 2026-08-12

    Saravana Karthikeyan SKS, Shaik Gouse Peera, Chang Yi Kong

    Read original paper ↗ ·
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