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RESEARCH PAPER · Inorganic Chemistry · 2022

Ag 4 B 7 O 12 X (X = Cl, Br, I) Heptaborate Family: Comprehensive Crystal Chemistry, Thermal Stability Trends, Topology, and Vibrational Anharmonicity

Sergey N. Volkov, Dmitri O. Charkin, Vera A. Firsova, Lev S. Manelis, A. M. Banaru, Alexey V. Povolotskiy, Valentina A. Yukhno, M. Yu. Arsent’ev, Yevgeny E. Savchenko, В. Л. Уголков, Maria Georgievna Krzhizhanovskaya, Р. С. Бубнова, Sergey M. Aksenov

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Ag 4 B 7 O 12 X (X = Cl, Br, I) Heptaborate Family: Comprehensive Crystal Chemistry, Thermal Stability Trends, Topology, and Vibrational AnharmonicityOriginalThe study of mineral behavior at low and high temperatures and their properties using a combination of different methods has not become routine yet1Gram–Charlier approach for anharmonic atomic displacements in inorganic solids: A review16A novel contribution to the M3B6O10X hexaborate family: The new silver compound Ag3B6O10Br and thermal behavior of Ag3B6O10(NO3) and Na3B6O10I9Exploration of silver borates with diverse low-dimensional anion frameworks by introducing monovalent heteroanions6Synthesis, Characterization and Optical Properties of Two Novel Metal Borates1The further development of the borate nitrate family: Synthesis and characterization of Ag12(B9O18)(NO3)3 with unique isolated B9O18 clusters, 9B:6Δ3□:3(<2Δ□>–)<3□>6Synthesis and Crystal Structure of the First Aqueous Silver Borate Nitrate Ag3B4O6(OH)2(NO3)4Expanding silver fluorooxoborate crystal chemistry: Ag 2 B 5 O 8 F with 3D double interpenetrating frameworks and Ag 3 B 5 O 8 F 2 with 2D layers5Investigation of the Size Control of Copper Ferrite Nanoparticles on their Electrical Properties in a Ferrofluid System using Oleic Acid Surfactant as an Energy Harvester0Crystal Chemistry of Silver Borates with Salt Inclusion Structure2Unraveling low thermal expansion of CrBO3 via atomic scale analysis: Flexible CrO6 octahedron vs rigid BO3 triangle group2Topological diversity of layered pentaborates: Synthesis, characterization, thermal behavior and optical properties of Ag2[B5O8(OH)] with a new type structure1On the border between layered and framework motifs: Ag2[B8O12(OH)2], a novel silver borate with corrugated open-framework layers and unusual hydrogen bonding0

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  1. The study of mineral behavior at low and high temperatures and their properties using a combination of different methods has not become routine yet

    Acta Crystallographica Section B Structural Science Crystal Engineering and Materials · 2023-04-12

    Sergey M. Aksenov

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  2. Gram–Charlier approach for anharmonic atomic displacements in inorganic solids: A review

    Crystallography Reviews · 2023-07-03

    Sergey N. Volkov, Dmitri O. Charkin, Vera A. Firsova, Sergey M. Aksenov, Р. С. Бубнова

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  3. A novel contribution to the M3B6O10X hexaborate family: The new silver compound Ag3B6O10Br and thermal behavior of Ag3B6O10(NO3) and Na3B6O10I

    Solid State Sciences · 2023-10-04

    Sergey N. Volkov, Dmitri O. Charkin, Vadim E. Kireev, В. Л. Уголков, Maria Georgievna Krzhizhanovskaya, Nikita Sergeyevich Tsvetov, Yulia A. Vaitieva, Sergey M. Aksenov, Р. С. Бубнова

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  4. Exploration of silver borates with diverse low-dimensional anion frameworks by introducing monovalent heteroanions

    New Journal of Chemistry · 2024-01-01

    Lei Huai, Wenlong Liu, Beibei Zhang, Ru‐Ling Tang, Yi‐Lei Lv, Yue‐Qi Wei, Sheng‐Ping Guo

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  5. Synthesis, Characterization and Optical Properties of Two Novel Metal Borates

    ChemistrySelect · 2024-04-11

    Menghan Zhou, Hui Yang, Zhifen Guo, Cuixia Xu, Xiaomin Gu, Yuan Hua Lin

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  6. The further development of the borate nitrate family: Synthesis and characterization of Ag12(B9O18)(NO3)3 with unique isolated B9O18 clusters, 9B:6Δ3□:3(<2Δ□>–)<3□>

    Journal of Crystal Growth · 2024-07-31

    Sergey N. Volkov, Dmitri O. Charkin, Ivan A. Marsiy, Daria A. Banaru, Alexey V. Povolotskiy, Alevtina N. Gosteva, M. Yu. Arsent’ev, Maria Georgievna Krzhizhanovskaya, В. Л. Уголков, Yevgeny E. Savchenko, Vadim E. Kireev, Sergey M. Aksenov, Р. С. Бубнова

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  7. Synthesis and Crystal Structure of the First Aqueous Silver Borate Nitrate Ag3B4O6(OH)2(NO3)

    Journal of Structural Chemistry · 2024-10-01

    Yuliua O. Kopylova, Sergey N. Volkov, Sergey M. Aksenov, Р. С. Бубнова

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  8. Expanding silver fluorooxoborate crystal chemistry: Ag 2 B 5 O 8 F with 3D double interpenetrating frameworks and Ag 3 B 5 O 8 F 2 with 2D layers

    Dalton Transactions · 2025-01-01

    Sergey N. Volkov, Xia Yang, Vadim E. Kireev, A. M. Banaru, Shujuan Han, Alevtina N. Gosteva, M. Yu. Arsent’ev, Dmitri O. Charkin, Alexey V. Povolotskiy, Yevgeny E. Savchenko, Maria Georgievna Krzhizhanovskaya, Stepan A. Vorobiev, Yulia A. Vaitieva, Sergey M. Aksenov, Fangfang Zhang

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  9. Investigation of the Size Control of Copper Ferrite Nanoparticles on their Electrical Properties in a Ferrofluid System using Oleic Acid Surfactant as an Energy Harvester

    E3S Web of Conferences · 2025-01-01

    Ardan Rezon Prasetio, Kimi Alexander Lie, Samuel Jason Liwanto Lie, Rosy Eko Saputro, Willyanto Anggono

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  10. Crystal Chemistry of Silver Borates with Salt Inclusion Structure

    Crystallography Reports · 2025-04-01

    S. N. Volkov, Dmitri O. Charkin, Sergey M. Aksenov, A. M. Banaru, Yu.O. Kopylova, Р. С. Бубнова

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  11. Unraveling low thermal expansion of CrBO3 via atomic scale analysis: Flexible CrO6 octahedron vs rigid BO3 triangle group

    Journal of Applied Physics · 2025-09-03

    Dingfeng Yang, Yuanyuan Li

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  12. Topological diversity of layered pentaborates: Synthesis, characterization, thermal behavior and optical properties of Ag2[B5O8(OH)] with a new type structure

    Journal of Solid State Chemistry · 2026-04-02

    Yu.A. Vaitieva, A. M. Banaru, A.N. Gosteva, M. Yu. Arsent’ev, M.G. Krzhizhanovskaya, S. K. Volkov, Sergey M. Aksenov

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  13. On the border between layered and framework motifs: Ag2[B8O12(OH)2], a novel silver borate with corrugated open-framework layers and unusual hydrogen bonding

    Journal of Solid State Chemistry · 2026-08-05

    A. M. Banaru, Yu.A. Vaitieva, A. N. Gosteva, M. Yu. Arsent’ev, A. A. Kompanchenko, Y. E. Savchenko, Maria Georgievna Krzhizhanovskaya, S. N. Volkov, Sergey M. Aksenov

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