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RESEARCH PAPER · Chemical Communications · 2022

(N 2 H 6 )[HPO 3 F] 2 : maximizing the optical anisotropy of deep-ultraviolet fluorophosphates

Haotian Qiu, Fuming Li, Congcong Jin, Juanjuan Lu, Zhihua Yang, Shilie Pan, Miriding Mutailipu

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(N 2 H 6 )[HPO 3 F] 2 : maximizing the optical anisotropy of deep-ultraviolet fluorophosphatesOriginalBa 2 Zn 2 B 6 O 13 : coplanar [B 2 O 5 ] in unnoted U-shaped [B 6 O 13 ] groups achieving large birefringence6Bridging oxygen atoms in trigonal prism units driven strong second-harmonic-generation efficiency in Sr 3 Ge 2 O 4 Te 318Large optical anisotropy differentiation induced by the anion-directed regulation of structures29The Pnictogen Bond, Together with Other Non-Covalent Interactions, in the Rational Design of One-, Two- and Three-Dimensional Organic-Inorganic Hybrid Metal Halide Perovskite Semiconducting Materials, and Beyond38BaSb(H2PO2)3Cl2: An excellent UV nonlinear optical hypophosphite exhibiting strong second-harmonic generation response32NaK5Zn2(B5O10)2 and β-K3ZnB5O10: Two Zincoborates with Deep-UV Cutoff Edge9SbHPO3F: 2D van der Waals Layered Phosphite Exhibiting Large Birefringence32The transformation of a zero-dimensional cluster into a one-dimensional chain structure achieving a dramatically enhanced birefringence in tin( ii )-based oxalates33BaB2P2O8F2: A Fluoroborophosphate with [B2P2O8F2]∞ Layers and Deep-Ultraviolet Cutoff Edge4Synthesis, structural and electrical properties of two congruent isotypic diphosphates: Li2Na2P2O7 and Li3NaP2O73Stereochemically Active Tin(II)‐Induced Enhancement of Birefringence in SnIISnIV(PO4)2 and SrSn(PO4)PO2(OH)23Structure and electrical properties of AM(PO3)4: A = Li, Na and M = Ce and Pr1“Cation Activation”: An Effective Strategy for the Enhancement of Birefringence36ASb(SO4)2 (A = Rb, Cs): Two short-wave UV antimony sulfates exhibiting large birefringence43Mixed Alkali Metal and Alkaline Earth Metal Scandium Borate Birefringence Material with Layered Structure and Short Ultraviolet Cutoff Edge17Chemical Composition and Spectroscopic Characteristics of Alexandrite Effect Apatite from the Akzhailyau Mountains of Kazakhstan4Optically Anisotropic Mixed-Metal Fluoroiodate Ba2[GaF5(IO3F)] with a Wide Optical Transparent Window and a Moderate Birefringence6(C 2 H 10 N 2 )[Zn 2 (HPO 4 ) 2 Cl 2 ]: substitution-activated new short-wave ultraviolet phosphate with pivotal dual-property enhancement5Designing promising ultraviolet (UV) birefringent crystals with different hydrogen-bonded phosphate frameworks18Novel antimony phosphates with enlarged birefringence induced by lone pair cations4Old tree blossoms anew: Research progress on the structures and optical properties of ultraviolet selenites56Tetrahedra Modification of Phosphates for Optical Anisotropy Enhancement13A new ultraviolet-transparent molybdate featuring a layered structure and moderate birefringence0Optimizing optical anisotropy in low-dimensional structures via intralayer hydrogen bonding modulation and anionic substitution17Chiral-Unit-Oriented Design of Non-π-Conjugated Noncentrosymmetric Phosphates with Short Absorption Edges4Sb2(TeO4)(SO4): An Anhydrous Tellurite Sulfate with Large Birefringence and Enhanced Thermal Stability8[CON3H6BF4]: An Efficient Metal‐Free Borate with Optimized Birefringence Achieved by Structural Design Strategy15(NH4)Na3Zn4(PO4)4:An open-framework zincophosphate exhibiting well-balanced optical and thermal performance1Divalent Methylhydrazinium─An Ultrasmall Organic Cation for Construction of Hybrid Perovskites4[C(NH2)3]Pb(C2O4)Cl·H2O: A halogen- and lone-pair-tuned UV crystal with large birefringence originated from cooperative π-conjugation6Ba 3 (MoO 2 F 3 )PO 4 F 2 : Rational Design and Synthesis of an Alkaline-Earth Phosphate Fluoride as a Birefringent Crystal1A multi-scale birefringence modulation strategy in DUV/UV crystals induced by organic cations1Halogen-Substitution-Modulated Lone-Pair Orientation in Sb(H 2 PO 2 ) 2 X (X = Cl, F) for Enhanced UV Birefringence1

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  1. Ba 2 Zn 2 B 6 O 13 : coplanar [B 2 O 5 ] in unnoted U-shaped [B 6 O 13 ] groups achieving large birefringence

    Chemical Communications · 2022-01-01

    Rui Zhang, Xin Su, Jie Zhang, Dulin Wen, Yineng Huang

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  2. Bridging oxygen atoms in trigonal prism units driven strong second-harmonic-generation efficiency in Sr 3 Ge 2 O 4 Te 3

    Chemical Communications · 2022-01-01

    Mengran Sun, Wenhao Xing, Ming‐Hsien Lee, Jiyong Yao

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  3. Large optical anisotropy differentiation induced by the anion-directed regulation of structures

    Inorganic Chemistry Frontiers · 2022-01-01

    Xuehua Dong, Ying Long, Ling Huang, Liling Cao, Daojiang Gao, Jian Bi, Guohong Zou

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  4. The Pnictogen Bond, Together with Other Non-Covalent Interactions, in the Rational Design of One-, Two- and Three-Dimensional Organic-Inorganic Hybrid Metal Halide Perovskite Semiconducting Materials, and Beyond

    International Journal of Molecular Sciences · 2022-08-08

    Arpita Varadwaj, Pradeep R. Varadwaj, Helder M. Marques, Koichi Yamashita

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  5. BaSb(H2PO2)3Cl2: An excellent UV nonlinear optical hypophosphite exhibiting strong second-harmonic generation response

    Materials Today Physics · 2022-10-05

    Y. Long, X. Dong, Lilian Huang, Hongmei Zeng, Zhien Lin, Liujiang Zhou, Guangtian Zou

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  6. NaK5Zn2(B5O10)2 and β-K3ZnB5O10: Two Zincoborates with Deep-UV Cutoff Edge

    Inorganic Chemistry · 2022-10-10

    Wenjuan Ma, Jie Zhang, Feng Yu, Bin Dai

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  7. SbHPO3F: 2D van der Waals Layered Phosphite Exhibiting Large Birefringence

    Inorganic Chemistry · 2022-10-20

    Ying Long, Xuehua Dong, Ling Huang, Hongmei Zeng, Zhien Lin, Guohong Zou

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  8. The transformation of a zero-dimensional cluster into a one-dimensional chain structure achieving a dramatically enhanced birefringence in tin( ii )-based oxalates

    Inorganic Chemistry Frontiers · 2023-01-01

    Liying Ren, Linhong Cheng, Xiaoyan Zhou, Jinxuan Ren, Liling Cao, Ling Huang, Xuehua Dong, Yuqiao Zhou, Daojiang Gao, Guohong Zou

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  9. BaB2P2O8F2: A Fluoroborophosphate with [B2P2O8F2]∞ Layers and Deep-Ultraviolet Cutoff Edge

    Inorganic Chemistry · 2023-01-04

    Jinbin Fan, Mengfan Wu, Bingliang Cheng, Jian Wei Han

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  10. Synthesis, structural and electrical properties of two congruent isotypic diphosphates: Li2Na2P2O7 and Li3NaP2O7

    Applied Physics A · 2023-01-13

    R. Jemaï, K. Khirouni, M. Gargouri

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  11. Stereochemically Active Tin(II)‐Induced Enhancement of Birefringence in SnIISnIV(PO4)2 and SrSn(PO4)PO2(OH)2

    Chemistry - A European Journal · 2023-05-03

    Lihan Deng, Ruonan Zhang, Jie Zhang, Wenlong Xie, Chunyan Bai, Zhihua Yang, Xueling Hou, Shujuan Han, Shilie Pan

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  12. Structure and electrical properties of AM(PO3)4: A = Li, Na and M = Ce and Pr

    Materials Chemistry and Physics · 2023-05-06

    Pallabi Saha, K. Sandeep Rao, Sudhanshu K. Deshpande, Srungarpu Nagabhusan Achary, A.K. Tyagi

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  13. “Cation Activation”: An Effective Strategy for the Enhancement of Birefringence

    Advanced Optical Materials · 2023-05-12

    Chenhui Hu, Mengfan Wu, Miao Zhang, Jian Wei Han, Xueling Hou, Feng Zhang, Zhihua Yang, Shilie Pan

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  14. ASb(SO4)2 (A = Rb, Cs): Two short-wave UV antimony sulfates exhibiting large birefringence

    Chinese Chemical Letters · 2023-06-07

    Yang Lan, Jinxuan Ren, Pu Zhang, Xuehua Dong, Ling Huang, Liling Cao, Daojiang Gao, Guohong Zou

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  15. Mixed Alkali Metal and Alkaline Earth Metal Scandium Borate Birefringence Material with Layered Structure and Short Ultraviolet Cutoff Edge

    Inorganic Chemistry · 2023-06-15

    Wenhao Liu, Pifu Gong, Weiqi Huang, Mengran Sun, Sangen Zhao, Zheshuai Lin, Jiyong Yao

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  16. Chemical Composition and Spectroscopic Characteristics of Alexandrite Effect Apatite from the Akzhailyau Mountains of Kazakhstan

    Minerals · 2023-08-28

    C. H. Zhang, Chaoyang Chen, Zhibin Li, Andy Hsi-Tien Shen

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  17. Optically Anisotropic Mixed-Metal Fluoroiodate Ba2[GaF5(IO3F)] with a Wide Optical Transparent Window and a Moderate Birefringence

    Inorganic Chemistry · 2023-10-17

    Yuhang Wang, Fu-Ying Li, Dong‐Xue Jiao, Qi Wei, Li Wei, Guo‐Yu Yang

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  18. (C 2 H 10 N 2 )[Zn 2 (HPO 4 ) 2 Cl 2 ]: substitution-activated new short-wave ultraviolet phosphate with pivotal dual-property enhancement

    Journal of Materials Chemistry C · 2024-01-01

    Zhi Gang Fang, Yu-Ming Pan, Pei Han, Bing‐Ping Yang, Meihong Duan

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  19. Designing promising ultraviolet (UV) birefringent crystals with different hydrogen-bonded phosphate frameworks

    Inorganic Chemistry Frontiers · 2024-01-01

    Miao‐Bin Xu, Jin Chen, Huai‐Yu Wu, Jiajia Li, Ning Yu, Mo-Fan Zhuo, Fei‐Fei Mao, Ke‐Zhao Du

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  20. Novel antimony phosphates with enlarged birefringence induced by lone pair cations

    Dalton Transactions · 2024-01-01

    Mei Hu, Jialong Wang, Nuerbiye Tuerhong, Zhiyuan Zhang, Qun Jing, Zhaohui Chen, Yonglei Yang, Ming‐Hsien Lee

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  21. Old tree blossoms anew: Research progress on the structures and optical properties of ultraviolet selenites

    Coordination Chemistry Reviews · 2024-06-15

    Pengfei Li, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

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  22. Tetrahedra Modification of Phosphates for Optical Anisotropy Enhancement

    Advanced Optical Materials · 2024-08-29

    Haotian Qiu, Ran An, Junjie Li, Zhihua Yang, Shilie Pan, Miriding Mutailipu

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  23. A new ultraviolet-transparent molybdate featuring a layered structure and moderate birefringence

    New Journal of Chemistry · 2025-01-01

    Shiyu Du, Paipai Zhang, Haozhen Liu, Donghai An, Yanna Chen

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  24. Optimizing optical anisotropy in low-dimensional structures via intralayer hydrogen bonding modulation and anionic substitution

    Materials Horizons · 2025-01-01

    Muhammad Sharjeel Arif, Xu Liu, Hangwei Jia, Zhihua Yang, Xueling Hou, Shilie Pan

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  25. Chiral-Unit-Oriented Design of Non-π-Conjugated Noncentrosymmetric Phosphates with Short Absorption Edges

    The Journal of Physical Chemistry Letters · 2025-02-17

    Kai Huang, Xi-Ming Dong, Chao He, Zi-Xuan Zhao, Wei Chen, Hui‐Yan Zhao, Ji‐Xiang Hu, Qi Wei, Guo‐Ming Wang

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  26. Sb2(TeO4)(SO4): An Anhydrous Tellurite Sulfate with Large Birefringence and Enhanced Thermal Stability

    Inorganic Chemistry · 2025-04-08

    Xi-Ming Dong, Kai Huang, Hui‐Yan Zhao, Chao He, Xing‐Tao An, Qi Wei, Guo‐Yu Yang

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  27. [CON3H6BF4]: An Efficient Metal‐Free Borate with Optimized Birefringence Achieved by Structural Design Strategy

    Small · 2025-05-23

    Muhammad Arif, Xu Liu, Hangwei Jia, Zhihua Yang, Xueling Hou, Shilie Pan

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  28. (NH4)Na3Zn4(PO4)4:An open-framework zincophosphate exhibiting well-balanced optical and thermal performance

    Journal of Molecular Structure · 2025-06-07

    Chen-Yuan Ma, Qiang Tu, Yu-Ming Pan, Pei De Han, Meihong Duan, Zhi Gang Fang

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  29. Divalent Methylhydrazinium─An Ultrasmall Organic Cation for Construction of Hybrid Perovskites

    Chemistry of Materials · 2025-07-11

    Mirosław Mączka, Anna Gągor, Dagmara Stefańska, J. Hanuza, E. Kucharska, Jan K. Zaręba

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  30. [C(NH2)3]Pb(C2O4)Cl·H2O: A halogen- and lone-pair-tuned UV crystal with large birefringence originated from cooperative π-conjugation

    Journal of Molecular Structure · 2025-09-08

    Chao Ma, Yu-Ming Pan, Pei Feng Han, Meihong Duan

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  31. Ba 3 (MoO 2 F 3 )PO 4 F 2 : Rational Design and Synthesis of an Alkaline-Earth Phosphate Fluoride as a Birefringent Crystal

    Crystal Growth & Design · 2025-11-26

    Feng Xu, Mengya Qin, Bin Su, Chao He, Shaohua Yu, Yu Li, Rong Guo, Chan Zheng

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  32. A multi-scale birefringence modulation strategy in DUV/UV crystals induced by organic cations

    Materials Chemistry Frontiers · 2026-01-01

    Zhi Fang, G Xu, Wenhu Wang, Huanhuan Wang, Jian Wei Han

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  33. Halogen-Substitution-Modulated Lone-Pair Orientation in Sb(H 2 PO 2 ) 2 X (X = Cl, F) for Enhanced UV Birefringence

    Crystal Growth & Design · 2026-06-29

    Ying Long, Xuehua Dong, Lin Qi, Lindong Luan, Zichen Ren, Zhien Lin, Guohong Zou

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