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RESEARCH PAPER · Chemical Communications · 2022

Cd 2 (IO 3 )(PO 4 ) and Cd 1.62 Mg 0.38 (IO 3 )(PO 4 ): metal iodate-phosphates with large SHG responses and wide band gaps

Qianqian Chen, Chun‐Li Hu, Li-Jia Yao, Jin Chen, Ming‐Yang Cao, Bingxuan Li, Jiang‐Gao Mao

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Cd 2 (IO 3 )(PO 4 ) and Cd 1.62 Mg 0.38 (IO 3 )(PO 4 ): metal iodate-phosphates with large SHG responses and wide band gapsOriginalCaCe(IO 3 ) 3 (IO 3 F)F: a promising nonlinear optical material containing both IO 3 − and IO 3 F 2− anions22ZrF2(IO3)2 and RbGaF3(IO3): Two Promising Birefringent Crystals Featuring 1D Metal-Fluoride Cationic Chains and Wide Bandgaps22[M(OH) 2 ] 3 (IO 3 )(SeO 4 )·H 2 O (M = Ga and In): metal iodate–selenate nonlinear optical materials with a hexagonal tungsten oxide-type topology20Na 7 (SeO 4 ) 3 (IO 3 ) and K 2 (SeO 4 )[IO 2 (OH)]: two new iodate-selenates with short-wave UV cutoff edge and large birefringence8Structure and optical property evolution in PbM(PO 4 )X (M = Zn, Sn; X = halogen): SHG effect and birefringence21C(NH2)3(I3O8)(HI3O8)(H2I2O6)(HIO3)4·3H2O: An Unprecedented Asymmetric Guanidinium Polyiodate with a Strong Second-Harmonic-Generation Response and a Wide Band Gap16Recent advances of inorganic phosphates with UV/DUV cutoff edge and large second harmonic response7The First UV Nonlinear Optical Selenite Material: Fluorination Control in CaYF(SeO 3 ) 2 and Y 3 F(SeO 3 ) 485The First UV Nonlinear Optical Selenite Material: Fluorination Control in CaYF(SeO3)2 and Y3F(SeO3)47Comprehensive study on the hydrochar for adsorption of Cd(II): preparation, characterization, and mechanisms11Advances in aliovalent substitution strategy for the design and synthesis of nonlinear optical materials: d0 transition metal/gallium iodates and selenites70α- and β-(C4H5N2O)(IO3)·HIO3: Two SHG Materials Based on Organic–Inorganic Hybrid Iodates14A survey of stereoactive oxysalts for linear and nonlinear optical applications40Chemical Composition and Spectroscopic Characteristics of Alexandrite Effect Apatite from the Akzhailyau Mountains of Kazakhstan4Ba 4 B 14 O 25 : A Deep Ultraviolet Transparent Nonlinear Optical Crystal with Strong Second Harmonic Generation Response Achieved by a Boron‐Rich Closed‐Loop Strategy12Ba 2 Ga 2 F 6 (IO 3 )(PO 4 ): the first fluoride-containing iodate-phosphate with a 1D [Ga 2 F 6 (IO 3 )(PO 4 )] 4− helix chain2Centrosymmetric CaBaMF8 and Noncentrosymmetric Li2CaMF8 (M = Zr, Hf): Dimension Variation and Nonlinear Optical Activity Resulting from an Isovalent Cation Substitution-Oriented Design17Lanthanide Contraction Eliminates Disorder while Holding Robust Second Harmonic Generation in a Series of Polyiodates13MgPO2F3: An Ultraviolet Nonlinear Optical System with an Extremely Short Phase-Matching Wavelength Achieved by Introducing Dual-Type Fluorine via Structure Prediction1Achieving balanced UV SHG responses, optical band gaps and birefringence in rare earth compounds Ln(IO 3 )(SO 4 )·3H 2 O (Ln = Y, Gd, Er, Ho, Dy, Eu)4Cationic Modification in Hybrid Iodates: A Pathway to Superior Performance12From AgHgI(SO4) to AgHg3I3.2Cl1.8(SO4): Symmetry Breaking of the Belousovite‐Type Topology by Mixed Halides to Achieve Strong Nonlinear Optical Effect14Multifunctional Cd‐based Hybrid with Large Birefringence Achieving Excellent Second Harmonic Generation and Reversible Temperature‐Activated Fluorescence for Anti‐counterfeiting16A balance in SHG response, band gap and birefringence in a series of rare-earth sulfate-iodate6KCd(IO 3 ) 2 Cl: A New UV NLO Crystal with Balanced Optical Properties Engineering via Target‐Driven Multi‐Ion Substitution Strategy7Isovalent cation substitution strategy for enhancing nonlinear optical properties of iodate-selenate materials0Hydrogen-Bond-Directed Assembly of Polyanionic Cluster [Mo 2 O 5 (IO 3 ) 4 ] 2– for Nonlinear Optical Crystal Design0Non-π-conjugated tetrahedra-based optical crystals: The improvement of the linear and nonlinear optical properties by the combination of trigonal pyramidal [XO3] (X = I, Se, Te) units1

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  1. CaCe(IO 3 ) 3 (IO 3 F)F: a promising nonlinear optical material containing both IO 3 − and IO 3 F 2− anions

    Inorganic Chemistry Frontiers · 2022-01-01

    Nan Ma, Chun‐Li Hu, Jin Chen, Zhi Gang Fang, Yu Huang, Bingxuan Li, Jiang‐Gao Mao

    Read original paper ↗ ·

  2. ZrF2(IO3)2 and RbGaF3(IO3): Two Promising Birefringent Crystals Featuring 1D Metal-Fluoride Cationic Chains and Wide Bandgaps

    Inorganic Chemistry · 2022-10-26

    Jin Chen, Ke‐Zhao Du

    Read original paper ↗ ·

  3. [M(OH) 2 ] 3 (IO 3 )(SeO 4 )·H 2 O (M = Ga and In): metal iodate–selenate nonlinear optical materials with a hexagonal tungsten oxide-type topology

    Inorganic Chemistry Frontiers · 2023-01-01

    Qianqian Chen, Chun‐Li Hu, Bingxuan Li, Jiang‐Gao Mao

    Read original paper ↗ ·

  4. Na 7 (SeO 4 ) 3 (IO 3 ) and K 2 (SeO 4 )[IO 2 (OH)]: two new iodate-selenates with short-wave UV cutoff edge and large birefringence

    Journal of Materials Chemistry C · 2023-01-01

    Wen Dong Song, Jinxuan Ren, Jinwen Tan, Liling Cao, Xuehua Dong, Ling Huang, Daojiang Gao, Guohong Zou

    Read original paper ↗ ·

  5. Structure and optical property evolution in PbM(PO 4 )X (M = Zn, Sn; X = halogen): SHG effect and birefringence

    Inorganic Chemistry Frontiers · 2023-01-01

    Xiaobao Li, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao

    Read original paper ↗ ·

  6. C(NH2)3(I3O8)(HI3O8)(H2I2O6)(HIO3)4·3H2O: An Unprecedented Asymmetric Guanidinium Polyiodate with a Strong Second-Harmonic-Generation Response and a Wide Band Gap

    Inorganic Chemistry · 2023-01-19

    Dong Yan, Meng-Meng Ren, Fei‐Fei Mao, Yu Ma, Ru‐Ling Tang, Bingbing Zhang, Yao Ma, Xiu‐Du Zhang, Shu‐Fang Li

    Read original paper ↗ ·

  7. Recent advances of inorganic phosphates with UV/DUV cutoff edge and large second harmonic response

    Chinese Journal of Structural Chemistry · 2023-02-13

    Boxuan Zhang, Zhaohui Chen

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  8. The First UV Nonlinear Optical Selenite Material: Fluorination Control in CaYF(SeO 3 ) 2 and Y 3 F(SeO 3 ) 4

    Angewandte Chemie International Edition · 2023-02-27

    Pengfei Li, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao

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  9. The First UV Nonlinear Optical Selenite Material: Fluorination Control in CaYF(SeO3)2 and Y3F(SeO3)4

    Angewandte Chemie · 2023-02-27

    Pengfei Li, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao

    Read original paper ↗ ·

  10. Comprehensive study on the hydrochar for adsorption of Cd(II): preparation, characterization, and mechanisms

    Environmental Science and Pollution Research · 2023-04-15

    Han Xu, Zirui Wang, Nan Lü, Jiaqing Tang, Ping Lu, Ke Zhu, Jiunian Guan, Til Feike

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  11. Advances in aliovalent substitution strategy for the design and synthesis of nonlinear optical materials: d0 transition metal/gallium iodates and selenites

    Coordination Chemistry Reviews · 2023-05-22

    Zhiyong Bai, Kang Min Ok

    Read original paper ↗ ·

  12. α- and β-(C4H5N2O)(IO3)·HIO3: Two SHG Materials Based on Organic–Inorganic Hybrid Iodates

    Inorganic Chemistry · 2023-08-11

    Qianqian Chen, Chun‐Li Hu, Mingzhi Zhang, Bingxuan Li, Jiang‐Gao Mao

    Read original paper ↗ ·

  13. A survey of stereoactive oxysalts for linear and nonlinear optical applications

    Materials Today Physics · 2023-08-12

    Pengfei Li, Jiang‐Gao Mao, Fang Kong

    Read original paper ↗ ·

  14. Chemical Composition and Spectroscopic Characteristics of Alexandrite Effect Apatite from the Akzhailyau Mountains of Kazakhstan

    Minerals · 2023-08-28

    C. H. Zhang, Chaoyang Chen, Zhibin Li, Andy Hsi-Tien Shen

    Read original paper ↗ ·

  15. Ba 4 B 14 O 25 : A Deep Ultraviolet Transparent Nonlinear Optical Crystal with Strong Second Harmonic Generation Response Achieved by a Boron‐Rich Closed‐Loop Strategy

    Small · 2023-11-08

    Weijie Xie, Ru‐Ling Tang, Shengnan Yan, Nan Ma, Chun‐Li Hu, Jiang‐Gao Mao

    Read original paper ↗ ·

  16. Ba 2 Ga 2 F 6 (IO 3 )(PO 4 ): the first fluoride-containing iodate-phosphate with a 1D [Ga 2 F 6 (IO 3 )(PO 4 )] 4− helix chain

    Dalton Transactions · 2024-01-01

    Miao‐Bin Xu, Jiajia Li, Huai‐Yu Wu, Nan Ma, Ning Yu, Mo-Fan Zhuo, Jin Chen, Ke‐Zhao Du

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  17. Centrosymmetric CaBaMF8 and Noncentrosymmetric Li2CaMF8 (M = Zr, Hf): Dimension Variation and Nonlinear Optical Activity Resulting from an Isovalent Cation Substitution-Oriented Design

    Inorganic Chemistry · 2024-03-06

    Mei Yan, Ru‐Ling Tang, Wei Xu, Wenlong Liu, Sheng‐Ping Guo

    Read original paper ↗ ·

  18. Lanthanide Contraction Eliminates Disorder while Holding Robust Second Harmonic Generation in a Series of Polyiodates

    Chemistry of Materials · 2024-10-04

    Zhenhua Li, Yi Shui, Zhengli Liang, Lehui Liu, Jiahao Wan, Xingxing Jiang, Zheshuai Lin, Hongming Liu

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  19. MgPO2F3: An Ultraviolet Nonlinear Optical System with an Extremely Short Phase-Matching Wavelength Achieved by Introducing Dual-Type Fluorine via Structure Prediction

    The Journal of Physical Chemistry C · 2024-11-26

    Xue Bai, Xin Su, Wenqi Jin

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  20. Achieving balanced UV SHG responses, optical band gaps and birefringence in rare earth compounds Ln(IO 3 )(SO 4 )·3H 2 O (Ln = Y, Gd, Er, Ho, Dy, Eu)

    Dalton Transactions · 2025-01-01

    Shihua Ma, Lei Geng, Baozhu Zhu, Changyu Meng

    Read original paper ↗ ·

  21. Cationic Modification in Hybrid Iodates: A Pathway to Superior Performance

    Inorganic Chemistry · 2025-01-03

    Jingjing Zhao, Shu‐Fang Li, Meng-Han Lv, Jiaxin Wang, Ru‐Ling Tang, Hongbo Huang, Bingbing Zhang, Dong Yan

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  22. From AgHgI(SO4) to AgHg3I3.2Cl1.8(SO4): Symmetry Breaking of the Belousovite‐Type Topology by Mixed Halides to Achieve Strong Nonlinear Optical Effect

    Laser & Photonics Review · 2025-04-30

    Qian‐Qian Chen, Ming‐Zhi Zhang, Jin Chen, Bingxuan Li, Chun‐Li Hu, Jiang‐Gao Mao

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  23. Multifunctional Cd‐based Hybrid with Large Birefringence Achieving Excellent Second Harmonic Generation and Reversible Temperature‐Activated Fluorescence for Anti‐counterfeiting

    Advanced Optical Materials · 2025-05-21

    Duanliang Wang, Qiwei Xing, Defu Sun, Chuanrui Zhu, Kui Wu, Bingbing Zhang, Guangxia Liu, Jiyang Wang, Chuanying Shen

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  24. A balance in SHG response, band gap and birefringence in a series of rare-earth sulfate-iodate

    Journal of Molecular Structure · 2025-07-01

    Chunxiang Wu, Y. X. Li, Zhengli Liang, Xiao Mei Jiang, Xiao Jiang, Hui Fang, Lixiang Qin, Xingyuan Bai, Lehui Liu, Lehui Liu, Xingxing Jiang, Xingxing Jiang, Hongming Liu, Hongming Liu

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  25. KCd(IO 3 ) 2 Cl: A New UV NLO Crystal with Balanced Optical Properties Engineering via Target‐Driven Multi‐Ion Substitution Strategy

    Small · 2025-12-15

    Lei Hou, Siyu Li, Wencong Li, Bingchen Xiao, Yaoqing Chu, Bingbing Zhang, Ying Wang, Xinglong Chen, Lili Liu

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  26. Isovalent cation substitution strategy for enhancing nonlinear optical properties of iodate-selenate materials

    Journal of Alloys and Compounds · 2025-12-31

    Yinglei Han, Tongqing Sun, Hongde Liu, Dahuai Zheng, Shiguo Liu, Yongfa Kong, Jingjun Xu

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  27. Hydrogen-Bond-Directed Assembly of Polyanionic Cluster [Mo 2 O 5 (IO 3 ) 4 ] 2– for Nonlinear Optical Crystal Design

    Inorganic Chemistry · 2026-07-07

    Yi-Xiang Wang, Shu‐Fang Li, Xin-Ran Hao, Zhixiang Wang, Chu Chu, Bingbing Zhang, Dong Yan

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  28. Non-π-conjugated tetrahedra-based optical crystals: The improvement of the linear and nonlinear optical properties by the combination of trigonal pyramidal [XO3] (X = I, Se, Te) units

    Coordination Chemistry Reviews · 2026-08-12

    Meiqi Liu, Miao Zhang, Ziyang Wang, Shizheng Li, Yang Zhao, Jiahang Liu, Jianmin Gu, Weiwei Cao, Desong Wang, Tianhui Wu

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