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RESEARCH PAPER · ACS Applied Materials & Interfaces · 2020

Zn3B7O13Cl: A New Deep-Ultraviolet Transparency Nonlinear Optical Crystal with Boracite Structure

Zheyao Xiong, Jiangang He, Bing Hu, Pai Shan, Zujian Wang, Rongbing Su, Chao He, Xiaoming Yang, Xifa Long

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Zn3B7O13Cl: A New Deep-Ultraviolet Transparency Nonlinear Optical Crystal with Boracite StructureOriginalZn(NH 3 )CO 3 : a “three-in-one” UV nonlinear optical crystal built by a polar molecule bonding strategy18Second-order nonlinear optical property of the ultraviolet transparent alkali metal-rare earth metal carbonate Na3Y(CO3)3.3H2O5Polar polymorphism: β-Ca2[B5O8(OH)]2[B(OH)3]·H2O—synthesis, structure and nonlinear optical property11Sr2Pb(BeB5O10)(BO3): An Excellent Ultraviolet Nonlinear-Optical Beryllium Borate by the Pb-Modified Construction of a Conjugated System and Lone-Pair Effect14An excellent lead oxyiodide with a strong second-harmonic generation response and a large birefringence induced by the oriented arrangement of highly distorted [PbO 4 I 2 ] polyhedra13Crystal growth and functional properties of rare mineral Mn3B7O13Cl2Experimental and first-principles studies on photoluminescence of Ce3+-doped calcium chloroborate Ca2BO3Cl5Balance of Deep-Ultraviolet Transparency and Large Second Harmonic Generation Response in a Silicate Crystal9Alkali metal sulfate: A new non-π-conjugated deep-ultraviolet quasi-phase matching crystal27An Optimized KBe2BO3F2‐Like Structure: The Unity of Deep‐Ultraviolet Transparency, Nonlinear Optical Property, and Ferroelectricity22From Phosphate Fluoride to Fluorophosphate: Design of Novel Ultraviolet/Deep-Ultraviolet Nonlinear Optical Materials for BePO3F with Optical Property Enhancement34Finding a Deep‐UV Borate BaZnB4O8 with Edge‐sharing [BO4] Tetrahedra and Strong Optical Anisotropy20The origin of pyroelectricity in boracite at varying temperatures0Efficient blue-luminescence in boracite Zn3B7O13Cl and its further enhancement via anion substitution and post-annealing treatment0Crystal growth and spontaneous polarization mechanism of polar metal borate halides: Mn 3 B 7 O 13 Cl2Breaking Boundaries: Giant Ultraviolet Birefringence in Dimension‐Reduced Zn‐Based Crystals66Breaking Boundaries: Giant Ultraviolet Birefringence in Dimension‐Reduced Zn‐Based Crystals8A3Sc(SO4)3 (A = K, Rb, Cs): Three Deep‐Ultraviolet Transparent Alkali‐Scandium Sulfates with Strong Second‐Harmonic Generation Response and High Thermal Stability14Na2MP3O9 (M = K, Rb): Two Potential Zero-Order Waveplate Materials with DUV Cutoff Edges2Promising UV/DUV nonlinear optical materials with X-membered (X = multiples of 6) rings in anhydrous inorganic borates20A Cobalt Borate Built by {B 12 } and {Co 3 } Clusters for Photothermal Conversion1The Enhancement of Phase‐Matching Capability by Recombining π‐Conjugated Group in Nonlinear Optical Sulfates1Emergent Deep‐Ultraviolet Ferroelectrics: Structure and Polarization Mechanism0Two transition metal borates built from unprecedented {B11} clusters with nonlinear optical properties0

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  1. Zn(NH 3 )CO 3 : a “three-in-one” UV nonlinear optical crystal built by a polar molecule bonding strategy

    Journal of Materials Chemistry C · 2021-01-01

    Hong‐Xin Tang, Qirui Shui, Ruibiao Fu, Ziqi Zhou, Wen-Xiu Bao, Zuju Ma, Xin‐Tao Wu

    Read original paper ↗ ·

  2. Second-order nonlinear optical property of the ultraviolet transparent alkali metal-rare earth metal carbonate Na3Y(CO3)3.3H2O

    Journal of Solid State Chemistry · 2021-02-28

    Chao Wu, Lin Lin, Tianhui Wu, Zhipeng Huang, Chi Zhang

    Read original paper ↗ ·

  3. Polar polymorphism: β-Ca2[B5O8(OH)]2[B(OH)3]·H2O—synthesis, structure and nonlinear optical property

    Journal of Solid State Chemistry · 2021-04-19

    Qi–Ming Qiu, Xuyan Li, Chong‐An Chen, Kening Sun, Guo‐Yu Yang

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  4. Sr2Pb(BeB5O10)(BO3): An Excellent Ultraviolet Nonlinear-Optical Beryllium Borate by the Pb-Modified Construction of a Conjugated System and Lone-Pair Effect

    Inorganic Chemistry · 2021-06-18

    Zhe Dai, Yi-Gang Chen, Yao Guo, Fang Wang, Yuanyu Yang, Xian‐Ming Zhang

    Read original paper ↗ ·

  5. An excellent lead oxyiodide with a strong second-harmonic generation response and a large birefringence induced by the oriented arrangement of highly distorted [PbO 4 I 2 ] polyhedra

    Inorganic Chemistry Frontiers · 2022-01-01

    Ziqi Zhou, Ruibiao Fu, Hong‐Xin Tang, Zuju Ma, Xin‐Tao Wu

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  6. Crystal growth and functional properties of rare mineral Mn3B7O13Cl

    Journal of Crystal Growth · 2022-01-04

    Jiesen Guo, Ruijin Sun, Fei Chen, Munan Hao, Yuxin Ma, Qiangqiang Wang, Yuetong Wu, Dongxu Hou, Zeyu Zhang, Tianming Liu, Zhibin Li, Dezhong Meng, Changchun Zhao

    Read original paper ↗ ·

  7. Experimental and first-principles studies on photoluminescence of Ce3+-doped calcium chloroborate Ca2BO3Cl

    Journal of Luminescence · 2022-01-06

    Irina V. Berezovskaya, Shihang Zhou, Bibo Lou, Min Yu Yin, Chong‐Geng Ma, Anatolii S. Voloshinovskii, Vladimir P. Dotsenko

    Read original paper ↗ ·

  8. Balance of Deep-Ultraviolet Transparency and Large Second Harmonic Generation Response in a Silicate Crystal

    Crystal Growth & Design · 2022-04-04

    Zheyao Xiong, Jing Xu, Haotian Tian, Hongyuan Sha, Zujian Wang, Rongbing Su, Chao He, Xiaoming Yang, Xifa Long

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  9. Alkali metal sulfate: A new non-π-conjugated deep-ultraviolet quasi-phase matching crystal

    Scripta Materialia · 2022-04-28

    Hongyuan Sha, Junxin Xu, Lingxiong Huang, Zheyao Xiong, Zujian Wang, Rongbing Su, Chao He, Xiaoming Yang, Xifa Long

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  10. An Optimized KBe2BO3F2‐Like Structure: The Unity of Deep‐Ultraviolet Transparency, Nonlinear Optical Property, and Ferroelectricity

    Advanced Optical Materials · 2022-05-02

    Hongyuan Sha, Junxin Xu, Zheyao Xiong, Zujian Wang, Rongbing Su, Chao He, Xiaoming Yang, Xifa Long, Ying Liu

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  11. From Phosphate Fluoride to Fluorophosphate: Design of Novel Ultraviolet/Deep-Ultraviolet Nonlinear Optical Materials for BePO3F with Optical Property Enhancement

    ACS Applied Materials & Interfaces · 2022-08-18

    Mengfan Wu, Junwei Feng, Congwei Xie, Abudukadi Tudi, Dongdong Chu, Juanjuan Lu, Shilie Pan, Zhihua Yang

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  12. Finding a Deep‐UV Borate BaZnB4O8 with Edge‐sharing [BO4] Tetrahedra and Strong Optical Anisotropy

    Chemistry - A European Journal · 2022-10-25

    Jian Wei Han, Kaitong Liu, Long Chen, Fuming Li, Zhihua Yang, Fangfang Zhang, Shilie Pan, Miriding Mutailipu

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  13. The origin of pyroelectricity in boracite at varying temperatures

    Research Square · 2023-01-05

    Qiang-qiang wang, Ruijin Sun, Jiesen Guo, Yuetong Wu, Yuxin Ma, Fei Chen, Tianming Liu, Haodong Li, Fanshu Meng, Dezhong Meng, Changchun Zhao

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  14. Efficient blue-luminescence in boracite Zn3B7O13Cl and its further enhancement via anion substitution and post-annealing treatment

    Journal of Luminescence · 2023-06-10

    Suyin Zhang, Qinhua Wei, Hang Yin, Gao Tang, Zhenhua Chen, Xiaoli Xu, Laishun Qin

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  15. Crystal growth and spontaneous polarization mechanism of polar metal borate halides: Mn 3 B 7 O 13 Cl

    CrystEngComm · 2024-01-01

    Haodong Li, Duo Zhang, Jiesen Guo, Qiangqiang Wang, Yuxin Ma, Munan Hao, Yuetong Wu, Fanshu Meng, Tianming Liu, Yibo Xu, Chen Xu, Changchun Zhao, Dezhong Meng, Zhiyuan Zheng, Ruijin Sun

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  16. Breaking Boundaries: Giant Ultraviolet Birefringence in Dimension‐Reduced Zn‐Based Crystals

    Angewandte Chemie International Edition · 2024-06-26

    Yang Li, Kang Min Ok

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  17. Breaking Boundaries: Giant Ultraviolet Birefringence in Dimension‐Reduced Zn‐Based Crystals

    Angewandte Chemie · 2024-06-26

    Yang Li, Kang Min Ok

    Read original paper ↗ ·

  18. A3Sc(SO4)3 (A = K, Rb, Cs): Three Deep‐Ultraviolet Transparent Alkali‐Scandium Sulfates with Strong Second‐Harmonic Generation Response and High Thermal Stability

    Advanced Optical Materials · 2024-07-16

    Zilong Geng, Ruibiao Fu, Zuju Ma, Xintao Wu

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  19. Na2MP3O9 (M = K, Rb): Two Potential Zero-Order Waveplate Materials with DUV Cutoff Edges

    Inorganic Chemistry · 2025-03-04

    Huanhuan Zhao, Chenxu Li, Yi Huang, Qun Jing, Xuebin Yu, Zhaohui Chen

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  20. Promising UV/DUV nonlinear optical materials with X-membered (X = multiples of 6) rings in anhydrous inorganic borates

    Coordination Chemistry Reviews · 2025-08-26

    Bailin Chen, Shuai An, Xueling Hou, Shilie Pan

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  21. A Cobalt Borate Built by {B 12 } and {Co 3 } Clusters for Photothermal Conversion

    Inorganic Chemistry · 2025-11-21

    Chong‐An Chen, Zhenwen Wang, Guo‐Yu Yang

    Read original paper ↗ ·

  22. The Enhancement of Phase‐Matching Capability by Recombining π‐Conjugated Group in Nonlinear Optical Sulfates

    Advanced Optical Materials · 2026-04-25

    Lilin Yang, Qinghe Li, Dongling Yang, Hongyuan Sha, Zujian Wang, Xiaoming Yang, Rongbing Su, Bin Su, Chao He, Xifa Long

    Read original paper ↗ ·

  23. Emergent Deep‐Ultraviolet Ferroelectrics: Structure and Polarization Mechanism

    Advanced Functional Materials · 2026-08-31

    Zujian Wang, Hongyuan Sha, Xiaoming Yang, Chao He, Fangfang Zhang, Xifa Long, Shilie Pan

    Read original paper ↗ ·

  24. Two transition metal borates built from unprecedented {B11} clusters with nonlinear optical properties

    Science China Chemistry · 2026-09-22

    Juan Chen, Guo-Yu Yang

    Read original paper ↗ ·
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