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RESEARCH PAPER · Advanced Optical Materials · 2024

A3Sc(SO4)3 (A = K, Rb, Cs): Three Deep‐Ultraviolet Transparent Alkali‐Scandium Sulfates with Strong Second‐Harmonic Generation Response and High Thermal Stability

Zilong Geng, Ruibiao Fu, Zuju Ma, Xintao Wu

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A3Sc(SO4)3 (A = K, Rb, Cs): Three Deep‐Ultraviolet Transparent Alkali‐Scandium Sulfates with Strong Second‐Harmonic Generation Response and High Thermal StabilityOriginalA 3 Sc(PO 4 ) 2 (A = Li, Na): rare earth cations effectively regulate phosphate structures for enhanced birefringence4A remarkable solar-blind ultraviolet nonlinear optical crystal with comprehensive performance and enhanced thermal stability4A strongly birefringent sulfate crystal with a wide second-harmonic generation phase-matching range4K 2 SO 4 (NH 3 SO 3 ) 2 and Cs 2 SO 4 (NH 3 SO 3 ) 3 : two deep-UV transparent sulfamate-sulfates with moderate birefringence2Na6(SO4)2SiF6: A Stable Sulfate Fluosilicate with Wide Deep-Ultraviolet Transparency Window and Strong Second-Harmonic Generation Response4Dual-anion synergy drives remarkable birefringence in sulfate–nitrate crystals1Breaking the SHG-stability trade-off in UV nonlinear optical materials by polar-layer-dense-locking4Tailoring linear and nonlinear optical properties of 2D Sc 2 C MXenes via surface termination modulation0RbLa(SO 4 ) 2 : A KBBF-like Deep-UV Transparent Rare Earth Sulfate with Strong SHG Response and High Thermal Stability Enabled by Multicomponent Structural Design2Confinement π‐Conjugated Moiety Tailoring to Achieve Record Deep‐UV Nonlinearity in Sulfates0Magnesium Methylphosphonate Ultraviolet Nonlinear Optical Crystal With Ultrawide Bandgap and Strong Second‐Harmonic Generation Response0Cation-sulfur-driven dimensional reduction engineering for tailoring sulfonate birefringent crystals with enhanced anisotropy2Experimental investigation on the recovery of scandium from a laterite nickel ore hydrometallurgical process via selective precipitation0Rational Design of a Strong Nonlinear Optical Crystal With Ultrawide Bandgap via Fine‐Tuning of Channel Structures0

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  1. A 3 Sc(PO 4 ) 2 (A = Li, Na): rare earth cations effectively regulate phosphate structures for enhanced birefringence

    Dalton Transactions · 2025-01-01

    Hongheng Chen, Xudong Leng, Mei Hu, Yibo Han, Haiming Duan, Qun Jing, Zhaohui Chen, Ming‐Hsien Lee

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  2. A remarkable solar-blind ultraviolet nonlinear optical crystal with comprehensive performance and enhanced thermal stability

    Materials Chemistry Frontiers · 2025-01-01

    Jialin Zeng, Shuangcheng Li, Ruibiao Fu, Zilong Geng, Yiting Luo, Senfu Lei, Zuju Ma

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  3. A strongly birefringent sulfate crystal with a wide second-harmonic generation phase-matching range

    Journal of Materials Chemistry C · 2025-01-01

    Zhiyong Bai, Shanshan Chen, Xu Chen, Yong Wang, Xinwei Zhou, Yipeng Song, Yanqiang Li, Sangen Zhao, Junhua Luo

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  4. K 2 SO 4 (NH 3 SO 3 ) 2 and Cs 2 SO 4 (NH 3 SO 3 ) 3 : two deep-UV transparent sulfamate-sulfates with moderate birefringence

    Dalton Transactions · 2025-01-01

    Yun Ji, Huili Zhang, Xin Wen, Jindong Chen, Guangsai Yang, Yuchen Yan, Guang Peng, Ning Ye

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  5. Na6(SO4)2SiF6: A Stable Sulfate Fluosilicate with Wide Deep-Ultraviolet Transparency Window and Strong Second-Harmonic Generation Response

    Chemistry of Materials · 2025-10-02

    Zilong Geng, Zuju Ma, Ruibiao Fu, Xintao Wu

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  6. Dual-anion synergy drives remarkable birefringence in sulfate–nitrate crystals

    Inorganic Chemistry Frontiers · 2025-11-24

    LeHui Liu, FeiFei Yuan, YiSheng Huang, LiZhen Zhang, ZhouBin Lin

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  7. Breaking the SHG-stability trade-off in UV nonlinear optical materials by polar-layer-dense-locking

    Chemical Science · 2026-01-01

    Jiaqi QIAN, Yunjie Wang, Jiafu Ding, Xin Su, Qi Wu

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  8. Tailoring linear and nonlinear optical properties of 2D Sc 2 C MXenes via surface termination modulation

    Dalton Transactions · 2026-01-01

    Zehui Fang, Yantong Lu, Ling Ren, Hua Lin, Rongjian Sa, Zuju Ma

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  9. RbLa(SO 4 ) 2 : A KBBF-like Deep-UV Transparent Rare Earth Sulfate with Strong SHG Response and High Thermal Stability Enabled by Multicomponent Structural Design

    Inorganic Chemistry · 2026-02-02

    Ye Tao, Xiaohui Zhang, Chenglong Xu, Qianshuang Lu, J. N. Tan, Yingjie Li, Junzi Li, Jianke Pan, Feng Su, Tingchao He, Haifeng Dong, Heng Wang, Zhi Chen, Chengmin Ji, Xiujun Yu, Xiaopeng Li

    Read original paper ↗ ·

  10. Confinement π‐Conjugated Moiety Tailoring to Achieve Record Deep‐UV Nonlinearity in Sulfates

    Angewandte Chemie · 2026-03-05

    Yujie Fan, Cheng Hu, Li Wu, Chensheng Lin, Chao Wang, Huixin Fan, Tao Yan, Min Luo

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  11. Magnesium Methylphosphonate Ultraviolet Nonlinear Optical Crystal With Ultrawide Bandgap and Strong Second‐Harmonic Generation Response

    Advanced Optical Materials · 2026-03-24

    Senfu Lei, Zuju Ma, Zilong Geng, Wenjing Yang, Yulu Wu, Xiaofan Tong, Shuangcheng Li, Ruibiao Fu, Yiting Luo

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  12. Cation-sulfur-driven dimensional reduction engineering for tailoring sulfonate birefringent crystals with enhanced anisotropy

    Chinese Journal of Structural Chemistry · 2026-05-02

    Hanjing Huang, Longyun Xu, Wenli Zhao, Huijian Zhao, Xianghao Kong, Ning Ye, Zhanggui Hu, Conggang Li

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  13. Experimental investigation on the recovery of scandium from a laterite nickel ore hydrometallurgical process via selective precipitation

    Hydrometallurgy · 2026-06-08

    Mengqi Wang, Jianhua Tian, Yanhua Luan, Zexuan Su, Lifang Zhang, Yiming Fan, Wenjiao Yuan

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  14. Rational Design of a Strong Nonlinear Optical Crystal With Ultrawide Bandgap via Fine‐Tuning of Channel Structures

    Laser & Photonics Review · 2026-08-15

    Zilong Geng, Zuju Ma, Ruibiao Fu, Xin-Tao Wu

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