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RESEARCH PAPER · ACS Applied Materials & Interfaces · 2022

From Phosphate Fluoride to Fluorophosphate: Design of Novel Ultraviolet/Deep-Ultraviolet Nonlinear Optical Materials for BePO3F with Optical Property Enhancement

Mengfan Wu, Junwei Feng, Congwei Xie, Abudukadi Tudi, Dongdong Chu, Juanjuan Lu, Shilie Pan, Zhihua Yang

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42 direct citing works

From Phosphate Fluoride to Fluorophosphate: Design of Novel Ultraviolet/Deep-Ultraviolet Nonlinear Optical Materials for BePO3F with Optical Property EnhancementOriginalM(NH2SO3)2·xH2O (M = Ca, Pb, x = 0, 1, 4): Effect of Hydrogen Bonding on Structural Transformations and Second Harmonic Generation of Metal Sulfamates26C 3 N 6 H 7 SO 3 NH 2 : non-π-conjugated tetrahedra decoupling π-conjugated groups achieving large optical anisotropy and wide band gap29Synthesis and characterization of a new isoxazolone-based nonlinear optical crystal: MPMOI7Rational Design of the First Ammonium Magnesium Borate with Deep-Ultraviolet Cutoff Edge and Moderate Birefringence and Further Investigation into the Nature of Ammonium in the Borate System15Fluorooxoborates: A precious treasure of deep-ultraviolet nonlinear optical materials24Target‐Driven Design of Deep‐UV Nonlinear Optical Materials via Interpretable Machine Learning125Na4[B6O9 (OH)3](H2O) Cl: A Deep-Ultraviolet Transparent Nonlinear Optical Borate Chloride with {[B6O9 (OH)3]3–}∞ Chains5A prediction-driven database to enable rapid discovery of nonlinear optical materials46Achieving great optical anisotropy with the well-directed alignment of π-conjugated groups due to hydrogen bonds9Nonlinear Optical Phosphide CuInSi2P4: The Inaugural Member of Diamond-Like Family I–III–IV2–V4 Inspired by ZnGeP216(C 2 H 10 N 2 )[Zn 2 (HPO 4 ) 2 Cl 2 ]: substitution-activated new short-wave ultraviolet phosphate with pivotal dual-property enhancement5KBa 3 M 2 F 14 Cl (M = Zr, Hf): novel short-wavelength mixed metal halides with the largest second-harmonic generation responses contributed by mixed functional moieties37Novel antimony phosphates with enlarged birefringence induced by lone pair cations4From ZnF2 to ZnF2(H2O)4: Partial Substitution Achieves Structural Transformation and Nonlinear Optical Activity while Keeping Short Ultraviolet Cutoff Edge19Rational Combination of π‐Conjugated and Non‐π‐Conjugated Groups Achieving Strong Nonlinear Optical Response, Large Optical Anisotropy, and UV Light‐Switchable Fluorescence65A perspective on deep-ultraviolet nonlinear optical materials13Effect of synthesis conditions on the thermoluminescence of Li9Mg3[PO4]4F3 fluorophosphate6[Rb3BaCl][In8Se14]: Compressed chalcopyrite-type selenide achieved by polycationic substitution strategy toward excellent nonlinear optical property18Nonlinear optical properties of La3+-Doped tellurite-zinc glasses: Impact of chemical bonding and physical properties via Raman and XPS38From Ba2Bi2Zn(PO4)4 to Ba2Bi2Cu(PO4)4: Rational design of an ultraviolet phosphate with enhanced birefringence2MgPO2F3: An Ultraviolet Nonlinear Optical System with an Extremely Short Phase-Matching Wavelength Achieved by Introducing Dual-Type Fluorine via Structure Prediction1Functional assembly and modification of nonlinear optical fundamental motifs in phosphates27Computer‐Aided Development of New Nonlinear Optical Materials38Computer‐Aided Development of New Nonlinear Optical Materials14Emergent Mid‐Infrared Nonlinear Optical Candidates With Targeted Balance Performances17Optimizing optical anisotropy in low-dimensional structures via intralayer hydrogen bonding modulation and anionic substitution17新型非线性光学晶体和双折射晶体的研究进展（特邀）4Synthesis and spectroscopic analysis of Ba3Ca2(PO4)3F: Eu3+/Tb3+ fluorapatite structured phosphor for optical applications18Two-dimensional graphene-like BeO sheet: a promising deep-ultraviolet nonlinear optical material with strong and highly tunable second harmonic generation5Tuning structural symmetry to enhance the linear and nonlinear optical response of NaM(PO3)3 (M= Ba, Cd, Ca) metaphosphates for next-generation deep-UV photonics1Toward the vacuum-ultraviolet frontier in nonlinear optical frequency conversion: phase-matching mechanisms across dimensions and architectures2Recent Progress in Lanthanide-Activated Halo-Phosphors for White Light-Emitting Diodes and Photovoltaic Efficiency Enhancement: A Comprehensive Review0Potential Deep Ultraviolet Phosphate With Y‐Based: 1 [(PO 3 ) 4 ] ∞ Chains AYP 4 O 12 (A = K, NH 4 ) and the First [P 3 O 10 ] Anionic Framework KLiYP 3 O 100Hydrothermal growth, structural and optical properties of large-sized Cs2SiF6 single crystals as promising DUV optical window materials0

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  1. M(NH2SO3)2·xH2O (M = Ca, Pb, x = 0, 1, 4): Effect of Hydrogen Bonding on Structural Transformations and Second Harmonic Generation of Metal Sulfamates

    Inorganic Chemistry · 2022-12-12

    Danyang Dou, Bingjie Cai, Bingbing Zhang, Ying Wang

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  2. C 3 N 6 H 7 SO 3 NH 2 : non-π-conjugated tetrahedra decoupling π-conjugated groups achieving large optical anisotropy and wide band gap

    Materials Chemistry Frontiers · 2023-01-01

    Danyang Dou, Qi Shi, Yunjie Bai, Cheng Chen, Bingbing Zhang, Ying Wang

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  3. Synthesis and characterization of a new isoxazolone-based nonlinear optical crystal: MPMOI

    CrystEngComm · 2023-01-01

    Ying Yang, Jianjuan Zhao, Xinyuan Zhang, Zhanggui Hu, Yicheng Wu

    Read original paper ↗ ·

  4. Rational Design of the First Ammonium Magnesium Borate with Deep-Ultraviolet Cutoff Edge and Moderate Birefringence and Further Investigation into the Nature of Ammonium in the Borate System

    Inorganic Chemistry · 2023-01-18

    Feixiang Wang, Mengfan Wu, Zhihua Yang, Xifa Long, Yun Mo Yang, Shilie Pan

    Read original paper ↗ ·

  5. Fluorooxoborates: A precious treasure of deep-ultraviolet nonlinear optical materials

    Chinese Journal of Structural Chemistry · 2023-02-03

    Hongkang Su, Ziting Yan, Xueling Hou, Min Zhang

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  6. Target‐Driven Design of Deep‐UV Nonlinear Optical Materials via Interpretable Machine Learning

    Advanced Materials · 2023-03-16

    Mengfan Wu, Evgenii Tikhonov, Abudukadi Tudi, Ivan A. Kruglov, Xueling Hou, Congwei Xie, Shilie Pan, Zhihua Yang

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  7. Na4[B6O9 (OH)3](H2O) Cl: A Deep-Ultraviolet Transparent Nonlinear Optical Borate Chloride with {[B6O9 (OH)3]3–}∞ Chains

    Inorganic Chemistry · 2023-06-12

    Ru‐Ling Tang, Lei Huai, Wenlong Liu

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  8. A prediction-driven database to enable rapid discovery of nonlinear optical materials

    Science China Materials · 2023-10-16

    Congwei Xie, Evgenii Tikhonov, Dongdong Chu, Mengfan Wu, Ivan A. Kruglov, Shilie Pan, Zhihua Yang

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  9. Achieving great optical anisotropy with the well-directed alignment of π-conjugated groups due to hydrogen bonds

    Journal of Saudi Chemical Society · 2023-12-16

    Chenhui Hu, Junjie Liu, Jiale Qu, Jinghui Hu, Xiangzhan Jiang

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  10. Nonlinear Optical Phosphide CuInSi2P4: The Inaugural Member of Diamond-Like Family I–III–IV2–V4 Inspired by ZnGeP2

    ACS Applied Materials & Interfaces · 2023-12-27

    Ming‐Shu Zhang, Bin‐Wen Liu, Xiao‐Ming Jiang, Guo‐Cong Guo

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  11. (C 2 H 10 N 2 )[Zn 2 (HPO 4 ) 2 Cl 2 ]: substitution-activated new short-wave ultraviolet phosphate with pivotal dual-property enhancement

    Journal of Materials Chemistry C · 2024-01-01

    Zhi Gang Fang, Yu-Ming Pan, Pei Han, Bing‐Ping Yang, Meihong Duan

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  12. KBa 3 M 2 F 14 Cl (M = Zr, Hf): novel short-wavelength mixed metal halides with the largest second-harmonic generation responses contributed by mixed functional moieties

    Chemical Science · 2024-01-01

    Mei Yan, Chun‐Li Hu, Ru‐Ling Tang, Wen‐Dong Yao, Wenlong Liu, Sheng‐Ping Guo

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  13. Novel antimony phosphates with enlarged birefringence induced by lone pair cations

    Dalton Transactions · 2024-01-01

    Mei Hu, Jialong Wang, Nuerbiye Tuerhong, Zhiyuan Zhang, Qun Jing, Zhaohui Chen, Yonglei Yang, Ming‐Hsien Lee

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  14. From ZnF2 to ZnF2(H2O)4: Partial Substitution Achieves Structural Transformation and Nonlinear Optical Activity while Keeping Short Ultraviolet Cutoff Edge

    Inorganic Chemistry · 2024-01-17

    Yue‐Qi Wei, Wei Xu, Lei Huai, Yi‐Lei Lv, Wenlong Liu, Sheng‐Ping Guo, Ru‐Ling Tang

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  15. Rational Combination of π‐Conjugated and Non‐π‐Conjugated Groups Achieving Strong Nonlinear Optical Response, Large Optical Anisotropy, and UV Light‐Switchable Fluorescence

    Advanced Science · 2024-03-13

    Danyang Dou, Qi Shi, Huimin Li, Bingbing Zhang, Daqing Yang, Ying Wang

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  16. A perspective on deep-ultraviolet nonlinear optical materials

    Journal of Applied Physics · 2024-03-28

    Xu Liu, Zhihua Yang, Shilie Pan

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  17. Effect of synthesis conditions on the thermoluminescence of Li9Mg3[PO4]4F3 fluorophosphate

    Ceramics International · 2024-05-14

    D.A. Akulov, Michael O. Kalinkin, R. M. Αbashev, Α. I. Surdo, Olga Grigorievna Reznitskikh, Д. Г. Келлерман

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  18. [Rb3BaCl][In8Se14]: Compressed chalcopyrite-type selenide achieved by polycationic substitution strategy toward excellent nonlinear optical property

    Science China Materials · 2024-05-16

    Fan Wu, Wen‐Fa Chen, Zixuan Wu, Xiao‐Ming Jiang, Bin‐Wen Liu, Guo‐Cong Guo

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  19. Nonlinear optical properties of La3+-Doped tellurite-zinc glasses: Impact of chemical bonding and physical properties via Raman and XPS

    Ceramics International · 2024-11-09

    J.L. Clabel H., João V. P. Valverde, G. Lozano C., Euclydes Marega Jr., Valmor Roberto Mastelaro, Cléber Renato Mendonça

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  20. From Ba2Bi2Zn(PO4)4 to Ba2Bi2Cu(PO4)4: Rational design of an ultraviolet phosphate with enhanced birefringence

    Journal of Alloys and Compounds · 2024-11-26

    Yin-Jie Peng, Yanbo Li, Jun Li, Chao-Qian Li, Baichuan Wang, Zhi Gang Fang, Meihong Duan

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  21. MgPO2F3: An Ultraviolet Nonlinear Optical System with an Extremely Short Phase-Matching Wavelength Achieved by Introducing Dual-Type Fluorine via Structure Prediction

    The Journal of Physical Chemistry C · 2024-11-26

    Xue Bai, Xin Su, Wenqi Jin

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  22. Functional assembly and modification of nonlinear optical fundamental motifs in phosphates

    Coordination Chemistry Reviews · 2024-11-27

    Fan Liu, Pifu Gong, Zheshuai Lin, Lei Kang

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  23. Computer‐Aided Development of New Nonlinear Optical Materials

    Angewandte Chemie International Edition · 2024-12-05

    Hongshan Wang, Miriding Mutailipu, Zhihua Yang, Shilie Pan, Junjie Li

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  24. Computer‐Aided Development of New Nonlinear Optical Materials

    Angewandte Chemie · 2024-12-05

    Hongshan Wang, Miriding Mutailipu, Zhihua Yang, Shilie Pan, Junjie Li

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  25. Emergent Mid‐Infrared Nonlinear Optical Candidates With Targeted Balance Performances

    Small · 2024-12-23

    Junben Huang, Ailijiang Abudurusuli, Zhihua Yang, Shilie Pan

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  26. Optimizing optical anisotropy in low-dimensional structures via intralayer hydrogen bonding modulation and anionic substitution

    Materials Horizons · 2025-01-01

    Muhammad Sharjeel Arif, Xu Liu, Hangwei Jia, Zhihua Yang, Xueling Hou, Shilie Pan

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  27. 新型非线性光学晶体和双折射晶体的研究进展（特邀）

    Chinese Journal of Lasers · 2025-01-01

    韩树娟 Han Shujuan, 杨志华 Yang Zhihua, 张方方 Zhang Fangfang, 李广卯 Li Guangmao, 李俊杰 Li Junjie, 吴雅博 Wu Yabo, 储冬冬 Chu Dongdong, 程孟 Cheng Meng, 张文彬 Zhang Wenbin, 丁文 Ding Wen, 潘世烈 Pan Shilie

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  28. Synthesis and spectroscopic analysis of Ba3Ca2(PO4)3F: Eu3+/Tb3+ fluorapatite structured phosphor for optical applications

    Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy · 2025-03-22

    Shruti Prabhakar Dhale, Amol Nande, Nilesh Sureshrao Ugemuge, Vartika S. Singh, Sanjiv V. Moharil

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  29. Two-dimensional graphene-like BeO sheet: a promising deep-ultraviolet nonlinear optical material with strong and highly tunable second harmonic generation

    Science China Materials · 2025-11-06

    Linlin Liu, Congwei Xie, Abudukadi Tudi, Keith T. Butler, Zhihua Yang

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  30. Tuning structural symmetry to enhance the linear and nonlinear optical response of NaM(PO3)3 (M= Ba, Cd, Ca) metaphosphates for next-generation deep-UV photonics

    Ceramics International · 2026-04-07

    Mayssa Karray, Iheb Garoui, Ahlem Guesmi, Naoufel Ben Hamadi, Houcine Naı̈li, Abderrazek Oueslati

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  31. Toward the vacuum-ultraviolet frontier in nonlinear optical frequency conversion: phase-matching mechanisms across dimensions and architectures

    Progress in Materials Science · 2026-07-09

    Zhihua Yang, Shilie Pan

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  32. Recent Progress in Lanthanide-Activated Halo-Phosphors for White Light-Emitting Diodes and Photovoltaic Efficiency Enhancement: A Comprehensive Review

    Journal of Fluorescence · 2026-07-13

    Rahul V. Tikale, Swati Bishnoi, S.J. Dhoble

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  33. Potential Deep Ultraviolet Phosphate With Y‐Based: 1 [(PO 3 ) 4 ] ∞ Chains AYP 4 O 12 (A = K, NH 4 ) and the First [P 3 O 10 ] Anionic Framework KLiYP 3 O 10

    European Journal of Inorganic Chemistry · 2026-09-15

    Jingru Xu, Jiawei Zhao, Paipai Zhang, Juhui Cui, Hong Lei Du, Minqiang Gai

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  34. Hydrothermal growth, structural and optical properties of large-sized Cs2SiF6 single crystals as promising DUV optical window materials

    Optical Materials · 2026-09-29

    Changcheng Tang, Lin Han, Ye Lei, 周安秀, Ximei Ye, Yongming Huang, Chao Yang, Dakun Zhou, Xingxing Jiang, Zheshuai Lin

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