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RESEARCH PAPER · Coordination Chemistry Reviews · 2024

Evaluation and prospect of Mid-Infrared nonlinear optical materials in f0 rare earth (RE = Sc, Y, La) chalcogenides

Linfeng Dong, Shengzi Zhang, Pifu Gong, Lei Kang, Zheshuai Lin

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Evaluation and prospect of Mid-Infrared nonlinear optical materials in f0 rare earth (RE = Sc, Y, La) chalcogenidesOriginalChemical modulation of A I RE III C IV QVI4 family compounds for band gap and optical anisotropy enhancement16Computer-aided screening of bismuth molybdates nonlinear optical crystals γ -Bi 2 MoO 64Heteroanionic [VO x S 4− x ] groups: tetrahedral units with large birefringence for mid-infrared nonlinear optical crystals9Rare-earth chalcogenidotetrachloride clusters (RE3ECl4, RE = Dy, Gd, Y; E = S, Se, Te): syntheses and materials properties4Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units66Breaking Symmetry for SHG Response: Lanthanide Acetate Crystals via Water Molecule Regulation Strategy5LaAgSiS4: Increasing Optical Birefringence in Rare Earth Chalcogenide by Addition of Planar [AgS3] Groups5Prismatic crystal field stabilized divalent rare-earth chalcogenide REIIBII6CIII6QVI16 with bifunctionality30First-Principles High-Throughput Screening and Experimental Verification of III-VIB Transition Metal Chalcogenides Nonlinear Optical Crystals16Prediction and Evaluation of Li 2 ZnS 2 Crystals as Mid‐Infrared Nonlinear Optical Material with High Thermal Conductivity7Strong Second‐Harmonic Generation Responses in Salt‐Inclusion Oxychalcogenides Enabled by the Highly Distorted Polyhedra with Mixed‐Anions4Nonlinear Optical Effects Modulated by Distinctive Monovalent Cations with Lone Electron Pairs in AGaI 4 (A = Ga + , In + )4Chalcophosphates: A plentiful source of infrared nonlinear optical materials42Engineering an Excellent β ‐BaB 2 O 4 ‐Inspired UV Nonlinear Optical Material Through Secondary Building Unit Substitution21Engineering an Excellent β ‐BaB 2 O 4 ‐Inspired UV Nonlinear Optical Material Through Secondary Building Unit Substitution6A new selenide semiconductor NaMn3Ga3Se8 with strong second-harmonic generation and significant luminescence property5Cation Equivalent Multisubstitution Realizing Structure Transformation and Balanced Nonlinear Optical Performance of Quaternary Eu-Based Chalcogenides8La3Ga5HfO14: Rare-Earth Polyhedron Coupled with Structural Protected Octahedron for Designing Nonlinear Optical Material with Wide Bandgap and Well-Balanced Properties5KYSiSe 4 : A Rare-Earth Selenide Infrared Nonlinear Optical Crystal with Wide Infrared Transparency and Well-Balanced E g and SHG Response9Stabilization of the Polar 0D Cs4Nb2–xTaxS11 with Phase-Matched Second-Harmonic Generation and High Laser-Induced Damage Threshold4Intense red emission from highly elastic and thermally stable phosphate glass doped with Ce3+, Nd3+, and Ce3+/Nd3+ ions3Coordination-mediated interfacial enrichment for efficient extraction of ultra-dilute rare earth ions via high-density affinity sites electrode3Construction of chitosan/wurtzite multiple sites on mesoporous halloysite and selective removal of Al(III) from rare earth ions solution: Microcalorimetry investigation2A high-performance IR nonlinear optical material Sr 3 MnGe 2 S 8 achieved via partial cation substitution-induced structural transformation2Crystalline Order Yet Glass-Like Heat Transport Driven by Hidden Local Distortions as the Structural Origin of Ultralow Thermal Conductivity in AgErTe 23A Homoatomic Heteroleptic Coordination Strategy for Exceptional Infrared Linear and Nonlinear Optical Properties in ANb 2 PS 4 (S 2 ) 3 (A = K,Rb,Cs)3A series of langasite-type compounds: size effect regulation for cation occupation and enhanced SHG response1ABCQ4型硫属化物红外非线性光学材料的构效关系（特邀）0Polyhedral replacement-guided design of Ce3MnGaSe7 featuring strong second-harmonic genera-tion and high laser-induced damage threshold0Simultaneously switching both the magnetic behaviors and nonlinear optical processes in mononuclear DyIII complexes0Tailoring linear and nonlinear optical properties of 2D Sc 2 C MXenes via surface termination modulation0高性能硫属化物红外非线性光学材料构效关系（特邀）0Confinement-assembled ultraviolet nonlinear optical crystal from pyridine-expanded π-systems with exhibiting strong SHG and birefringence19Harnessing tetrahedral diversity: The path to superior diamond-like IR NLO crystals15Simultaneously switching both the magnetic behavior and nonlinear optical process in mononuclear DyIII complexes via the coordination role of enantiopure N3-pincers2K 3 YGe 3 O 9 : A Rare-Earth Germanate Nonlinear Optical Crystal with a Short Ultraviolet Cutoff Edge and Moderate Second-Harmonic Generation Response1Photo-induced tuning of nonlinear near-infrared optical characteristics in Ge5Se80In15 thin films0Rb 2 ZnGe 3 Se 8 : A Large-Birefringence Layered Chalcogenide Enabled by Anisotropic Electrons in Tetrahedral Units0Salt-Inclusion Rare-Earth Chalcogenides: Exploring Infrared Nonlinear Optical Crystals via a Guest-Framework Modulation Strategy0Mid‐ to Far‐Infrared Nonlinear Optical Crystals: Design Strategies, Structure–Property Relationships and Engineering Prospects0Research advances in rare-earth nonlinear optical crystalline materials in 20251Advances in metal selenite nonlinear optical materials: halogens directed structure modulation and property optimization0EuMn6Ga6S16: A Wide Bandgap Europium-Based Nonlinear Optical Sulfide0d-f synergistic effect contributing record-high second-harmonic generation response in phase-matchable Mn-based chalcogenides0Vacancy-Driven Tetrahedral Distortion in Defect Diamond-Like Selenides for Exceptional Second-Order Nonlinearity0

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  2. Computer-aided screening of bismuth molybdates nonlinear optical crystals γ -Bi 2 MoO 6

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  3. Heteroanionic [VO x S 4− x ] groups: tetrahedral units with large birefringence for mid-infrared nonlinear optical crystals

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    Shengzi Zhang, Linfeng Dong, Bohui Xu, Huige Chen, Hao Huo, Fei Liang, Rui Fen Wu, Pifu Gong, Zheshuai Lin

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  4. Rare-earth chalcogenidotetrachloride clusters (RE3ECl4, RE = Dy, Gd, Y; E = S, Se, Te): syntheses and materials properties

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    Lei Li, Tianjiao Xue, You‐Song Ding, Zhiping Zheng

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  5. Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units

    Coordination Chemistry Reviews · 2024-07-03

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  6. Breaking Symmetry for SHG Response: Lanthanide Acetate Crystals via Water Molecule Regulation Strategy

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    Yaolong Zhu, Yong Tao, Can Yang, Yuwei Kang, Xuefei Wang, Jie Gou, Yi Xiong, Qi Wu

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  7. LaAgSiS4: Increasing Optical Birefringence in Rare Earth Chalcogenide by Addition of Planar [AgS3] Groups

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  8. Prismatic crystal field stabilized divalent rare-earth chalcogenide REIIBII6CIII6QVI16 with bifunctionality

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  9. First-Principles High-Throughput Screening and Experimental Verification of III-VIB Transition Metal Chalcogenides Nonlinear Optical Crystals

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  10. Prediction and Evaluation of Li 2 ZnS 2 Crystals as Mid‐Infrared Nonlinear Optical Material with High Thermal Conductivity

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  11. Strong Second‐Harmonic Generation Responses in Salt‐Inclusion Oxychalcogenides Enabled by the Highly Distorted Polyhedra with Mixed‐Anions

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  13. Chalcophosphates: A plentiful source of infrared nonlinear optical materials

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  14. Engineering an Excellent β ‐BaB 2 O 4 ‐Inspired UV Nonlinear Optical Material Through Secondary Building Unit Substitution

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  16. A new selenide semiconductor NaMn3Ga3Se8 with strong second-harmonic generation and significant luminescence property

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  17. Cation Equivalent Multisubstitution Realizing Structure Transformation and Balanced Nonlinear Optical Performance of Quaternary Eu-Based Chalcogenides

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  18. La3Ga5HfO14: Rare-Earth Polyhedron Coupled with Structural Protected Octahedron for Designing Nonlinear Optical Material with Wide Bandgap and Well-Balanced Properties

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  21. Intense red emission from highly elastic and thermally stable phosphate glass doped with Ce3+, Nd3+, and Ce3+/Nd3+ ions

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