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RESEARCH PAPER · Inorganic Chemistry · 2020

A(H3C3N3O3)(NO3) (A = K, Rb): Alkali-Metal Nitrate Isocyanurates with Strong Optical Anisotropy

Xia Hao, Min Luo, Chensheng Lin, Guang Peng, Tao Yan, Donghong Lin, Liling Cao, Xifa Long, Guangsai Yang, Ning Ye

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A(H3C3N3O3)(NO3) (A = K, Rb): Alkali-Metal Nitrate Isocyanurates with Strong Optical AnisotropyOriginal2(C 3 H 7 N 6 ) + ·2Cl − ·H 2 O: an ultraviolet nonlinear optical crystal with large birefrigence and strong second-harmonic generation78Mechanochemical Synthesis of an Ionic Cocrystal with Large Birefringence Resulting from Neutral Planar π-Conjugated Groups26Co-crystal AX·(H 3 C 3 N 3 O 3 ) (A = Na, Rb, Cs; X = Br, I): a series of strongly anisotropic alkali halide cyanurates with a planar structural motif and large birefringence13K 2 Pb(H 2 C 3 N 3 O 3 ) 4 (H 2 O) 4 : a potential UV nonlinear optical material with large birefringence50Two bismuth iodate sulfates with enhanced optical anisotropy17Two metal-free cyanurate crystals with a large optical birefringence resulting from the combination of π-conjugated units17Zn(H 2 C 3 N 3 O 3 ) 2 ·3H 2 O: the first single- d 10 transition metal based ultraviolet hydroisocyanurate crystal with large birefringence18Cyanurates consisting of intrinsic planar π-conjugated 6-membered rings: An emerging source of optical functional materials111Stepwise Li Substitution Induced Structure Evolution and Improved Nonlinear Optical Performance for Diamond-like Sulfides28Synthesis and Characterization of New-Type Ionic Cocrystals with Cyanuric Acid and Alkali Halides: AX·(H3C3N3O3)2 (A = Rb, Cs; X = Cl, Br)6(C 3 N 6 H 7 ) 2 SiF 6 ·H 2 O: an ultraviolet birefringent crystal exceeding the intrinsic energy gap of an organic reagent38[C(NH 2 ) 3 ] 2 S 2 O 8 : combining delocalized and localized π-conjugate units to achieve strong optical anisotropy21Potential optical functional crystals with large birefringence: Recent advances and future prospects322Cd4InO(BO3)3: A New Nonlinear Optical Crystal Exhibiting Strong Second Harmonic Generation Effect and Moderate Birefringence2Directional Construction of New Nonlinear Optical Bifunctional Units through Molecular Engineering Design Inspired by the B 3 O 7 -Typed Configuration23(C3N6H7)2SbF5·H2O Exhibiting Strong Optical Anisotropy from the Optimal Arrangement of π-Conjugated (C3N6H7)+ Groups31Li0.5Na0.5AlB2O4F2: Fluoroaluminoborate with Aligned 1∞[BO2] Chain Induced by Unprecedented [AlO3F3]6− Species Features Enhanced Birefringence30A 0.5 H 2 C 6 N 7 O 3 ·4H 2 O (A = Ca 2+ , Sr 2+ ) iso-cyamelurates with ultra-large π-conjugated group and excellent nonlinear optical properties10C 10 H 10 ClNO 3 : exploration of birefringent crystals in an isoquinoline system20C 10 H 6 NO 2 Cd(NO 3 )·2H 2 O: a birefringent crystal with an enlarged band-gap derived from covalent edge-sharing connection4Dramatically improved optical anisotropy by realizing stereochemically active lone pairs in a sulfate system, K 2 SO 4 ·HIO 323Ultrastable 3D cage-like metal–organic frameworks constructed using polydentate cyanurate ligands and their gas adsorption properties6Two Carboxylate-Cyanurates with Strong Optical Anisotropy and Large Band Gaps6Recent Development of Sn II , Sb III ‐based Birefringent Material: Crystal Chemistry and Investigation of Birefringence130Recent Development of SnII, SbIII‐based Birefringent Material: Crystal Chemistry and Investigation of Birefringence6Cs 2 Mg(H 2 C 3 N 3 S 3 ) 4 ·8H 2 O: An Excellent Birefringent Material with Giant Optical Anisotropy in π-Conjugated Trithiocyanurate19Naphthalene-Like Unit That Induces Strong Optical Anisotropy in C10H8NO2Br and C10H8NO2Br·H2O12C14H10BrNO2: A Birefringent Crystal with an Expanded π-Conjugated Group13Sr(NH2SO3)(NO3)·H2O: An Ultraviolet Nonlinear Optical Material Exhibiting Strong Second-Harmonic Generation Response and Sufficient Birefringence10Alkali-metal isocyanurate Cs 3 (H 2 C 3 N 3 O 3 ) 3 (H 3 C 3 N 3 O 3 )·3H 2 O: synthesis and characterization0C 8 H 6 IN 3 O 4 : a birefringent crystal induced by uniformly aligned hybrid groups10Crystal clear: unveiling giant birefringence in organic–inorganic cocrystals33AYSO4F2 (A = K, Rb): [YO4F4] Polyhedra Enhancement of Birefringence in Non-π-Conjugated Sulfate Systems9C9H7NBrX (X = Cl, Br, NO3): Three Excellent Birefringent Crystals with Distinct Optical Anisotropy Regulated by Anions34[C8H6BrN2O]Cl and [C8H6IN2O]Cl: Two birefringent crystals with π-conjugated quinazoline groups2Chiral-driven formation of hybrid cyanurates with large birefringence2Theoretical Insights into the Efficient Reduction of Nitrate to Ammonia on Crystalline Carbon Nitride3Deep-ultraviolet sulfamate halides with halogen-centered secondary building units for enhanced optical anisotropy4Recent progress in structural design strategies of high-birefringence optical crystals54Assisting the Effective Design of an SBBO-Like Vanadium-Iodate Crystal with Mixed Metal Cations2Four Benzoguanamine-Based Birefringent Crystals with Excellent Optical Anisotropy5A one-pot method in water to synthesize a new cyanurate K(H 2 C 3 N 3 O 3 )·H 2 O with large birefringence2KTeOPO 4 and NH 4 SnClSO 4 : two new KTiOPO 4 derivatives as birefringent crystals featuring enhanced optical anisotropy0(C 6 H 7 N 2 O)NO 3 : π-Conjugation-Driven Synergistic Enhancement of Second-Harmonic Generation and Birefringence0Structural Anion Geometry-Regulated Molecular Alignment in [C 10 H 8 NO 2 ]-Based Crystals for Enhancing Ultraviolet Birefringence0Decoupling Contributions of Distinct Strategies for Enhancing Polarizability Anisotropy in Crystals Containing π-Conjugated Groups0

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  1. 2(C 3 H 7 N 6 ) + ·2Cl − ·H 2 O: an ultraviolet nonlinear optical crystal with large birefrigence and strong second-harmonic generation

    Chemical Communications · 2020-01-01

    Lehui Liu, Chun‐Li Hu, Zhiyong Bai, Feifei Yuan, Yisheng Huang, Lizhen Zhang, Zhoubin Lin

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  2. Mechanochemical Synthesis of an Ionic Cocrystal with Large Birefringence Resulting from Neutral Planar π-Conjugated Groups

    Crystal Growth & Design · 2020-11-10

    Xianghe Meng, Kaijin Kang, Youquan Liu, Jian Tang, Xingxing Jiang, Wenlong Yin, Zheshuai Lin, Mingjun Xia

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  3. Co-crystal AX·(H 3 C 3 N 3 O 3 ) (A = Na, Rb, Cs; X = Br, I): a series of strongly anisotropic alkali halide cyanurates with a planar structural motif and large birefringence

    Dalton Transactions · 2021-01-01

    Jinhui Wang, Xinyuan Zhang, Fei Liang, Zhanggui Hu, Yicheng Wu

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  4. K 2 Pb(H 2 C 3 N 3 O 3 ) 4 (H 2 O) 4 : a potential UV nonlinear optical material with large birefringence

    Inorganic Chemistry Frontiers · 2021-01-01

    Yan Chen, Chun‐Li Hu, Zhi Gang Fang, Jiang‐Gao Mao

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  5. Two bismuth iodate sulfates with enhanced optical anisotropy

    Dalton Transactions · 2021-01-01

    Yilin Li, Chun‐Li Hu, Jin Chen, Jiang‐Gao Mao

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  6. Two metal-free cyanurate crystals with a large optical birefringence resulting from the combination of π-conjugated units

    Dalton Transactions · 2021-01-01

    Xiaomeng Liu, Lei Kang, Ruixin Guo, Zheshuai Lin

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  7. Zn(H 2 C 3 N 3 O 3 ) 2 ·3H 2 O: the first single- d 10 transition metal based ultraviolet hydroisocyanurate crystal with large birefringence

    Dalton Transactions · 2021-01-01

    Dandan Wang, Xinyuan Zhang, Fei Liang, Zhanggui Hu, Yicheng Wu

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  8. Cyanurates consisting of intrinsic planar π-conjugated 6-membered rings: An emerging source of optical functional materials

    Coordination Chemistry Reviews · 2021-04-14

    Xianghe Meng, Wenlong Yin, Mingjun Xia

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  9. Stepwise Li Substitution Induced Structure Evolution and Improved Nonlinear Optical Performance for Diamond-like Sulfides

    Inorganic Chemistry · 2021-07-27

    Wenfeng Zhou, Qingming Zhang, Wen‐Dong Yao, Huaiguo Xue, Sheng‐Ping Guo

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  10. Synthesis and Characterization of New-Type Ionic Cocrystals with Cyanuric Acid and Alkali Halides: AX·(H3C3N3O3)2 (A = Rb, Cs; X = Cl, Br)

    Crystal Growth & Design · 2021-11-19

    Jinhui Wang, Xinyuan Zhang, Fei Liang, Zhanggui Hu, Yicheng Wu

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  11. (C 3 N 6 H 7 ) 2 SiF 6 ·H 2 O: an ultraviolet birefringent crystal exceeding the intrinsic energy gap of an organic reagent

    Inorganic Chemistry Frontiers · 2022-01-01

    Yaoguo Shen, Yingwu Zhou, Xiaoling Xue, Hualiang Yu, Sangen Zhao, Junhua Luo

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  12. [C(NH 2 ) 3 ] 2 S 2 O 8 : combining delocalized and localized π-conjugate units to achieve strong optical anisotropy

    Inorganic Chemistry Frontiers · 2022-01-01

    Man Zhang, Bingbing Zhang, Daqing Yang, Ying Wang

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  13. Potential optical functional crystals with large birefringence: Recent advances and future prospects

    Coordination Chemistry Reviews · 2022-02-08

    Abudukadi Tudi, Shujuan Han, Zhihua Yang, Shilie Pan

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  14. Cd4InO(BO3)3: A New Nonlinear Optical Crystal Exhibiting Strong Second Harmonic Generation Effect and Moderate Birefringence

    Crystals · 2022-02-15

    Runqing Liu, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  15. Directional Construction of New Nonlinear Optical Bifunctional Units through Molecular Engineering Design Inspired by the B 3 O 7 -Typed Configuration

    ACS Applied Materials & Interfaces · 2022-07-07

    Huixin Fan, Chensheng Lin, Fei Liang, Haotian Tian, Shijun Huang, Yuqiao Zhou, Shixian Ke, Bingxuan Li, Ning Ye, Min Luo

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  16. (C3N6H7)2SbF5·H2O Exhibiting Strong Optical Anisotropy from the Optimal Arrangement of π-Conjugated (C3N6H7)+ Groups

    Inorganic Chemistry · 2022-08-31

    Yaoguo Shen, Bo Wen Chen, Hao Chen, Junhua Luo

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  17. Li0.5Na0.5AlB2O4F2: Fluoroaluminoborate with Aligned 1∞[BO2] Chain Induced by Unprecedented [AlO3F3]6− Species Features Enhanced Birefringence

    Advanced Optical Materials · 2022-11-17

    Ziting Yan, Dongdong Chu, Min Zhang, Zhihua Yang, Shilie Pan

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  18. A 0.5 H 2 C 6 N 7 O 3 ·4H 2 O (A = Ca 2+ , Sr 2+ ) iso-cyamelurates with ultra-large π-conjugated group and excellent nonlinear optical properties

    Inorganic Chemistry Frontiers · 2023-01-01

    Xiaoguang Du, Fangyan Wang, Fei Liang, Zhanggui Hu, Yicheng Wu, Xinyuan Zhang

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  19. C 10 H 10 ClNO 3 : exploration of birefringent crystals in an isoquinoline system

    Inorganic Chemistry Frontiers · 2023-01-01

    Hao Chen, Shaobin Zhang, Bo Wen Chen, Yaoguo Shen, Junhua Luo

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  20. C 10 H 6 NO 2 Cd(NO 3 )·2H 2 O: a birefringent crystal with an enlarged band-gap derived from covalent edge-sharing connection

    Dalton Transactions · 2023-01-01

    Yu Wang, Yaoguo Shen, Weiqi Huang, Sangen Zhao

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  21. Dramatically improved optical anisotropy by realizing stereochemically active lone pairs in a sulfate system, K 2 SO 4 ·HIO 3

    Inorganic Chemistry Frontiers · 2023-01-01

    Zhiyong Bai, Kang Min Ok

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  22. Ultrastable 3D cage-like metal–organic frameworks constructed using polydentate cyanurate ligands and their gas adsorption properties

    Dalton Transactions · 2023-01-01

    Wenhao Xing, Kaijin Kang, Jian Tang, Chunlan Tang, Wenlong Yin, Bin Kang, Jianguo Deng

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  23. Two Carboxylate-Cyanurates with Strong Optical Anisotropy and Large Band Gaps

    Inorganic Chemistry · 2023-01-23

    Yan Chen, Chun‐Li Hu, Zhi Gang Fang, Jiang‐Gao Mao

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  24. Recent Development of Sn II , Sb III ‐based Birefringent Material: Crystal Chemistry and Investigation of Birefringence

    Angewandte Chemie International Edition · 2023-03-13

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  25. Recent Development of SnII, SbIII‐based Birefringent Material: Crystal Chemistry and Investigation of Birefringence

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  26. Cs 2 Mg(H 2 C 3 N 3 S 3 ) 4 ·8H 2 O: An Excellent Birefringent Material with Giant Optical Anisotropy in π-Conjugated Trithiocyanurate

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    Xia Hao, Chensheng Lin, Min Luo, Yuqiao Zhou, Ning Ye, Enbo Shangguan

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  27. Naphthalene-Like Unit That Induces Strong Optical Anisotropy in C10H8NO2Br and C10H8NO2Br·H2O

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  28. C14H10BrNO2: A Birefringent Crystal with an Expanded π-Conjugated Group

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  29. Sr(NH2SO3)(NO3)·H2O: An Ultraviolet Nonlinear Optical Material Exhibiting Strong Second-Harmonic Generation Response and Sufficient Birefringence

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  30. Alkali-metal isocyanurate Cs 3 (H 2 C 3 N 3 O 3 ) 3 (H 3 C 3 N 3 O 3 )·3H 2 O: synthesis and characterization

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  31. C 8 H 6 IN 3 O 4 : a birefringent crystal induced by uniformly aligned hybrid groups

    Journal of Materials Chemistry C · 2024-01-01

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  32. Crystal clear: unveiling giant birefringence in organic–inorganic cocrystals

    Chemical Science · 2024-01-01

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  33. AYSO4F2 (A = K, Rb): [YO4F4] Polyhedra Enhancement of Birefringence in Non-π-Conjugated Sulfate Systems

    Inorganic Chemistry · 2024-02-27

    Zhencheng Wu, Huimin Li, Xueling Hou, Zhihua Yang, Hongsheng Shi

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  34. C9H7NBrX (X = Cl, Br, NO3): Three Excellent Birefringent Crystals with Distinct Optical Anisotropy Regulated by Anions

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    Yaoguo Shen, Mingliang Ding, Gang Chen, Yingjie Luo, Sangen Zhao, Junhua Luo

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  35. [C8H6BrN2O]Cl and [C8H6IN2O]Cl: Two birefringent crystals with π-conjugated quinazoline groups

    Inorganic Chemistry Communications · 2024-09-16

    Zhifeng Tang, Hai‐Lan Huang, Yuxin Zhou, Yu Wang, Yaoguo Shen, Renwen Yan, Lin Wu

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  36. Chiral-driven formation of hybrid cyanurates with large birefringence

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  37. Theoretical Insights into the Efficient Reduction of Nitrate to Ammonia on Crystalline Carbon Nitride

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  38. Deep-ultraviolet sulfamate halides with halogen-centered secondary building units for enhanced optical anisotropy

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  39. Recent progress in structural design strategies of high-birefringence optical crystals

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  41. Four Benzoguanamine-Based Birefringent Crystals with Excellent Optical Anisotropy

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  42. A one-pot method in water to synthesize a new cyanurate K(H 2 C 3 N 3 O 3 )·H 2 O with large birefringence

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  43. KTeOPO 4 and NH 4 SnClSO 4 : two new KTiOPO 4 derivatives as birefringent crystals featuring enhanced optical anisotropy

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  44. (C 6 H 7 N 2 O)NO 3 : π-Conjugation-Driven Synergistic Enhancement of Second-Harmonic Generation and Birefringence

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  45. Structural Anion Geometry-Regulated Molecular Alignment in [C 10 H 8 NO 2 ]-Based Crystals for Enhancing Ultraviolet Birefringence

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  46. Decoupling Contributions of Distinct Strategies for Enhancing Polarizability Anisotropy in Crystals Containing π-Conjugated Groups

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